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At least 397 records · Page 22

Peeling-ballooning modes in spherical tokamaks: Multi-branch instabilities and effects beyond ideal MHD

A number of important physics effects on the stability of relatively high-n (n is the toroidal mode number) peeling-ballooning modes (PBMs) are investigated based on an equilibrium reconstructed from a NSTX discharge, utilizing extended magnetohydrodynamic (MHD) eigenvalue solvers. For a given toroidal mode number n, multiple branches of instabilities are computed, with the total number of unstable branches roughly linearly scaling with n. Most of the unstable branches are located in the plasma core region, but edge-localized branches, i.e., PBMs, are also identified at higher n-numbers. For the single-fluid-wise most unstable PBM with n = 19⁠, stabilizing/destabilizing effects due to various physics beyond ideal MHD are systematically investigated. Plasma toroidal flow is found to be weakly stabilizing. Local flow shear is generally stabilizing as well, with the degree of stabilization depending on the initial growth rate (without flow shear) of the mode. The plasma resistivity can strongly destabilize the PBM within the single-fluid framework. Anisotropic thermal transport, strong parallel sound wave damping, as well as two-fluid effects are all stabilizing to the mode. In particular, diamagnetic stabilization (within the two-fluid model) is found to be very strong for this mode.

Linear stability analysis↗

Fundamental Processes of Atomization in Fluid-Fluid Flows

This report outlines the major results of the grant "Fundamental Processes of Atomization in Fluid-Fluid Flows." These include: 1) the demonstration that atomization in liquid/liquid shear flow is driven by a viscous shear instability that triggers the formation of a long thin sheet; 2) discovery of a new mode of interfacial instability for oscillatory two-layer systems whereby a mode that originates within the less viscous liquid phase causes interfacial deformation as the oscillation proceeds; 3) the demonstration that rivulet formation from gravity front occurs because the local front shape specified by gravity and surface tension changes from a nose to a wedge geometry, thus triggering a large increase in viscous resistance; and 4) extension of the studies on nonlinear wave evolution on falling films and in stratified flow, particularly the evolution towards large-amplitude solitary waves that tend to generate drops.

McCready, M. J.↗

Oxidation of vehicle components by photoproduced holes.

The oxidation by ZnO holes of vehicle components in thermal control coatings has been examined to develop experimental methods to study such reactions and to identify what components to avoid because of their instability when in the presence of u.v.-produced holes. Two methods were used that show consistent results. An electrochemical technique with a single crystal ZnO anode was used for quantitative comparisons, and electron spin resonance was used to study more practical powder/vehicle systems. Alcohols and dioxane were shown to be readily oxidized by ZnO holes, whereas acetonitrile, neopentane, and ethyl acetate were oxidation resistant. Some resistance to the photooxidation was provided by recombination centers.

Sancier, K. M.↗

Current-driven plasma instabilities at high latitudes

Earlier Ogo 5 discussions of high-latitude magnetospheric wave-particle interaction phenomena associated with field aligned current systems are extended by considering some September 7, 1968, out-bound measurements and corresponding March 11, 1969, observations, when the spacecraft was traversing auroral L shells in midafternoon. It is shown that during moderate magnetospheric disturbances the most intense waves and currents were detected near sharp boundaries in the density of polar cleft electrons, and it is possible that local wave-particle interactions produced anomalous resistivity. Some observed changes in the electron distribution functions might be explained in terms of local acceleration, but significant causal questions about the dynamics remain open if one can use only local data from a single spacecraft in this region.

Scarf, F. L.↗

Engine Hydraulic Stability

An analytical injector model was developed specifically to analyze combustion instability coupling between the injector hydraulics and the combustion process. This digital computer dynamic injector model will, for any imposed chamber of inlet pressure profile with a frequency ranging from 100 to 3000 Hz (minimum) accurately predict/calculate the instantaneous injector flowrates. The injector system is described in terms of which flow segments enter and leave each pressure node. For each flow segment, a resistance, line lengths, and areas are required as inputs (the line lengths and areas are used in determining inertance). For each pressure node, volume and acoustic velocity are required as inputs (volume and acoustic velocity determine capacitance). The geometric criteria for determining inertances of flow segments and capacitance of pressure nodes was set. Also, a technique was developed for analytically determining time averaged steady-state pressure drops and flowrates for every flow segment in an injector when such data is not known. These pressure drops and flowrates are then used in determining the linearized flow resistance for each line segment of flow.

Kesselring, R. C.↗

Local Distortions and Metal–Semiconductor–Metal Transition in Quasi-One-Dimensional Nanowire Compounds AV 3 Q 3 O δ (A = K, Rb, Cs and Q = Se, Te)

Metal cluster compounds have garnered renewed interest in the search for novel superconductors and topological semimetals owing to structural instabilities of metal-cluster geometries and broken symmetries. Here we synthesized needle-like crystals of the V-cluster-based quasi-one-dimensional (Q1D) materials AV 3 Q 3 O δ (A = K, Rb, Cs, Q= Se, Te) which can also be viewed as being composed of parallel nanowires. We examine how changes in their average and local structure control their electronic properties. All compounds crystallize in the TIFe 3 Te 3 -type structure (P6 3 /m space group) with infinite (V 3 )Q 3 ) - double-walled columnar chains separated by A + cations. Our single-crystal and synchrotron powder diffraction studies indicate oxygen atoms partially occupy the center site of the V 6 octahedral metal cluster cages in KV 3 Te 3 O 0.33 , RbV 3 Te 3 O 0.32 , and CsV 3 Te 3 O 0.35 , whereas KV 3 Se 3 is structurally oxygen-free. Our synchrotron X-ray pair distribution function (PDF) analyses indicate that the oxygen-free V 6 cluster octahedra in KV 3 Se 3 are highly distorted perpendicular to the chain direction even at room temperature, reducing the symmetry of the average structure from hexagonal P6 3 /m to monoclinic P2 1 /m. Our theoretical calculation supports this P2 1 /m distortion and suggests the structure further distorts to P2 1 or P2 1 /c at lower temperatures. In contrast, the oxygen-centered V-cluster in KV 3 Te 3 O 0.33 exhibits a V-3-triangle-trimerization along the chain direction. This feature is discernible from the local PDF and is consistent with lattice dynamical calculations based on density functional theory. Resistivity measurements indicate that KV 3 Se 3 exhibits metallic behavior, whereas a dramatic metal-semiconductor-metal transition emerges in KV 3 Te 3 O 6.33 , RbV 3 Te 3 O 0.32 , and CsV 3 Te 3 O 0.35 because of oxygen disorder and changes in local structure captured from our electronic structure analyses of the Fermi surface. Our investigation of the AV 3 Q 3 O 6 family demonstrates the importance of understanding local changes in structure driven by electronic instabilities, which can guide the search for new quantum materials in other low-dimensional cluster-compound materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Isoelectronic perturbations to f - d -electron hybridization and the enhancement of hidden order in URu 2 Si 2

Significance Phase transitions often manifest themselves in characteristic signatures in the electrical resistivity. Here, we track the temperature increase of the resistive signature of the hidden-order (HO) phase transition in URu 2 Si 2 , a mysterious phase with unknown order parameter. The application of pressure and the isoelectronic substitutions of Fe and Os ions for Ru are the only known perturbations to favor the HO phase. These perturbations are likely to cause increases in f - d -electron hybridization that lead to degeneracy and instabilities in the electronic band structure. The degeneracy is lifted by partial gapping of electronic states over the Fermi surface during the transition to HO. This and related investigations point to the importance of isoelectronic perturbations in generating emergent electronic phases.

Wolowiec, Christian T.↗

Deep Koopman Neural Network for Analyzing High-Energy-Density Simulations of Electrical Wire Explosions

Megaampere-scale electrical wire experiments (EWEs) provide a platform for studying magnetohydrodynamic (MHD) instability growth in magneto-inertial fusion (MIF) devices. Even when nonlinear simulations of these experiments can digitally reproduce much of the experimentally observed instability growth, interpreting the results and understanding mode growth and evolution can be non-trivial. As a first step toward providing better interpretation of these simulation features, this work investigates the use of a deep neural network that uses Koopman operator theory to analyze the dynamics of pulsed-power-driven explosions of EWEs. This deep neural network is trained on 1-D resistive MHD simulations of EWEs. This neural network learns to transform the nonlinear data into a lower-dimensional representation where the time dynamics are linear. Layers of this neural network are shown to learn features of the simulations, including the locations of shock waves and different physical regimes of the simulation. Using the learned features, the network can compress a time state of the simulation consisting of 5120 data point into a 36-parameter lower-dimensional latent space embedding. Furthermore, these embeddings are shown to be clustered in the latent space by initial radius and time state.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Nonlinear energy flow in a beam-plasma system

The three-dimensional character of the beam-plasma instability is investigated. The true beam-electron distribution function is resolved with a novel directional energy analyzer. The electron plasma waves are observed to develop a large spread in perpendicular wave numbers and damp in a relatively short distance producing an energetic electron tail on the background distribution. The damping is believed to be due to strong ion fluctuations which produce an anomalous resistivity.

Whelan, D. A.↗

The generation of rapid solar flare hard X-ray and microwave fluctuations in current sheets

The generation of rapid fluctuations, or spikes, in hard X-ray and microwave bursts via the disruption of electron heating and acceleration in current sheets is studied. It is found that 20 msec hard X-ray fluctuations can be thermally generated in a current sheet if the resistivity in the sheet is highly anomalous, the plasma density in the emitting region is relatively high, and the volume of the emitting region is greater than that of the current sheet. A specific mechanism for producing the fluctuations, involving heating in the presence of ion acoustic turbulence and a constant driving electric field, and interruption of the heating by a strong two-stream instability, is discussed. Variations upon this mechanism are also discussed. This mechanism also modulates electron acceleration, as required for the microwave spike emission. If the hard X-ray emission at energies less than approx. 1000 keV is nonthermal bremsstrahlung, the coherent modulation of electron acceleration in a large number of current sheets is required.

Holman, Gordon D.↗

Structural transition and possible pressure-induced superconductivity in a suboxide La 5 Pb 3 O

Here, in this study, we report a structural phase transition and its interplay with superconductivity in the suboxide La 5⁢ Pb 3 ⁢O. Upon cooling through 𝑇 𝑡 = 225K, La 5⁢ Pb 3⁢ O transforms from a high-temperature 𝐼⁢4/mcm to a low-temperature 𝑃⁢4/ncc structure in which La-Pb dimerization along the 𝑐 axis occurs. This transition is accompanied by anomalies in the temperature dependence of electrical resistivity and specific heat. High-pressure electrical transport measurements reveal that hydrostatic pressure suppresses the structural transition and possibly induces superconductivity with a maximum superconducting temperature of 10 K. Density functional theory calculations show minimal changes in the electronic density of states and no gap opening at 𝐸 𝐹 across 𝑇 𝑡 , suggesting that the transition is driven by bonding effects rather than Fermi surface instability. These findings establish La 5⁢ Pb 3 ⁢O as a promising platform for exploring the interplay between weak structural transitions and superconductivity.

Yan, Jiaqiang [Oak Ridge National Laboratory (ORNL↗

Characteristics of a Boat Type Seaplane During Take-off

This report, on the planing and get-away characteristics of the F-5-L, gives the results of the second of a series of take-off tests on three different seaplanes conducted by the National Advisory Committee for Aeronautics at the suggestion of the Bureau of Aeronautics, Navy Department. The single-float seaplane was the first tested and the twin-float seaplane is to be the third. The characteristics of the boat type were found to be similar to the single float, the main difference being the increased sluggishness and relatively larger planing resistance of the larger seaplane. At a water speed of 15 miles per hour the seaplane trims aft to about 12 degrees and remains in this angular position while plowing. At 2.25 miles per hour the planing stage is started and the planing angle is immediately lowered to about 10 degrees. As the velocity increases the longitudinal control becomes more effective but over control will produce instability. At the get-away the range of angle of attack is 19 degrees to 11 degrees with velocities from the stalling speed through about 25 per cent of the speed range.

Crowley, J W↗

Structural Instability in Electrically Stressed, Oxygen Deficient BaTiO 3 Nanocrystals

The dynamics of oxygen vacancies under external stimuli dominates the performance of many solid-state devices, including capacitors, oxide memristors, anionic conductors, etc. By means of in-situ Transmission Electron Microscopy, we found in BaTiO 3 perovskite nanocrystals that formation of oxygen vacancies due to electrical stressing renders the oxide amorphizable under electron beam illumination, suggesting the presence of a threshold concentration of oxygen vacancy affecting the structural stability of BaTiO 3 crystals upon high energy radiation. In contrast to the structural change, the resistivity of the nanocrystal seems not liable to the amorphization prior to dielectric breakdown at higher voltage bias. Here, we propose that an increase in oxygen vacancy content promotes oxygen mobility in the perovskite structure allowing electron beam induced electric field to modify the local structural and composition. Our in-situ observations reveal the central role of oxygen vacancies in the structural stability of perovskites which is of paramount importance to their applications in extreme environments and suggest a potential new route to micro-processing perovskite oxides using the electron beam via oxygen vacancy management without severely compromising the electric property.

36 MATERIALS SCIENCE↗

Buckling and Damage Resistance of Transversely-Loaded Composite Shells

Experimental and numerical work was conducted to better understand composite shell response to transverse loadings which simulate damage-causing impact events. The quasi-static, centered, transverse loading response of laminated graphite/epoxy shells in a [+/-45(sub n)/O(sub n)](sub s) layup having geometric characteristics of a commercial fuselage are studied. The singly-curved composite shell structures are hinged along the straight circumferential edges and are either free or simply supported along the curved axial edges. Key components of the shell response are response instabilities due to limit-point and/or bifurcation buckling. Experimentally, deflection-controlled shell response is characterized via load-deflection data, deformation-shape evolutions, and the resulting damage state. Finite element models are used to study the kinematically nonlinear shell response, including bifurcation, limit-points, and postbuckling. A novel technique is developed for evaluating bifurcation from nonlinear prebuckling states utilizing asymmetric spatial discretization to introduce numerical perturbations. Advantages of the asymmetric meshing technique (AMT) over traditional techniques include efficiency, robustness, ease of application, and solution of the actual (not modified) problems. The AMT is validated by comparison to traditional numerical analysis of a benchmark problem and verified by comparison to experimental data. Applying the technique, bifurcation in a benchmark shell-buckling problem is correctly identified. Excellent agreement between the numerical and experimental results are obtained for a number of composite shells although predictive capability decreases for stiffer (thicker) specimens which is attributed to compliance of the test fixture. Restraining the axial edge (simple support) has the effect of creating a more complex response which involves unstable bifurcation, limit-point buckling, and dynamic collapse. Such shells were noted to bifurcate into asymmetric deformation modes but were undamaged during testing. Shells in this study which were damaged were not observed to bifurcate. Thus, a direct link between bifurcation and atypical damage could not be established although the mechanism (bifurcation) was identified. Recommendations for further work in these related areas are provided and include extensions of the AMT to other shell geometries and structural problems.

Wardle, Brian L.↗

Multiscale Characterization of Electrode-Induced Degradation in Perovskite Solar Cells

The stability of metal-halide-perovskite (MHP) solar cells must be understood and improved for the commercial viability of MHP technologies. Here, we apply multiscale characterization methods to study degradation modes, specifically electrode corrosion, for p-i-n MHP partial device stacks and full devices that are stored in the dark under an inert atmosphere. Our multiscale characterization approaches include full-device electro-optical performance using current-voltage (JV) curves and spatial imaging with electroluminescence (EL) and photoluminescence (PL). We further correlate interface properties using cross-sectional Kelvin probe force microscopy, which maps the nanoscale electric field properties, and electron microscopy, which demonstrates structural and chemical features. Devices stored as a full device stack degrade primarily by metal (Ag) electrode diffusion into the absorber, with formation of AgI byproducts and Ag accumulation near the indium tin oxide (ITO) contact. This causes decomposition of the perovskite absorber domains, loss of the potential drop at the electron transport layer (ETL)/perovskite interface near the metal contact, and increased equivalent resistance at the perovskite/hole transport layer (HTL) interface near the ITO contact. The devices stored without metal show a different degradation pathway dominated by corrosion of the ITO, creating voids at the ITO electrode surface with diffusion of In and Sn into the absorber. We conclude that metal electrode-induced degradation is the most severe degradation pathway under dark storage, but that ITO corrosion and absorber instability must also be mitigated. We further demonstrate mitigation of these degradation pathways by changes to the device stack, including a SnO x blocking layer at the ETL side and replacing ITO with FTO at the HTL side. These results provide a useful demonstration of specific dark degradation pathways at each electrode interface, as well as a unique multiscale example that links degradation of chemical, structural, and electrical interface properties to the full-device electro-optical characteristics.

14 SOLAR ENERGY↗

MCZ: Striations in CZ silicon crystals grown under various axial magnetic field strengths

Suppression of fluid flow instabilities in the melt by the axial magnetic field in Czochralski silicon crystal growth (AMCZ) is investigated precisely by a high-sensitivity striation etching in conjunction with temperature measurements. The magnetic strength (B) was varied up to 4.0 kG, incremented in 0.5 kG/5 cm crystal length. The convection flow was substantially suppressed at B 1.0 kG. A low oxygen level of 2-3 ppma and a high resistivity of 400 ohm-cm is achieved in the AMCZ silicon crystals at B 1.0 kG. Details of the striation formation as a function of B are presented. Computer simulation of the magnetohydrodynamics of the AMCZ silicon crystal growth are discussed briefly with regard to the solute, especially oxygen segregation at B=0, 1.0, and 2.0 kG. Earlier studies in the inverted Bridgman growth of InSb and Ge, which have established the cause and effect relationship between the convection in the melt and the striation formation as well as the suppression of the convections in the melt by transverse magnetic field are reviewed.

Kim, G. K. M.↗

Evolution of solid electrolyte interphase and active material in the silicon wafer model system

Alloying anode materials for lithium-ion batteries, such as silicon (Si), are an important focus of materials research due to the demand for increased energy density for electric vehicles and stationary grid storage. However, progress towards next generation anode materials has been hindered by poor capacity retention due to the instability of the Si active material and the solid electrolyte interphase (SEI). Herein, the evolution of the active Si material and the SEI are simultaneously investigated from the perspective of chemical, structural, morphological, and electronic evolution in the Si wafer model system through its cycling life, using time-of-flight secondary ion mass spectrometry (TOF-SIMS), scanning transmission electron microscopy (STEM), atomic force microscopy (AFM), and scanning spreading resistance microscopy (SSRM). The results illustrate a dynamic evolution of the SEI and active Si material through cycling. Through an improved understanding of evolution of SEI and Si active material within the Si wafer model system, mitigation strategies may be designed to extend the lifetime of Si anodes.

25 ENERGY STORAGE↗

Understanding the negative triangularity ELM trigger and ELM free state on DIII-D with ECE-imaging

Here, the Electron Cyclotron Emission Imaging (ECEI) diagnostic was used to observe a finite-n interchange mode structure in the edge of negative triangularity shaped plasmas on DIII-D. At a small negative triangularity (δ u = -0.2), the plasma is in the H-mode with ELMs that are triggered by a low-n interchange mode. At a larger negative triangularity (δ u = -0.4) and low NBI power (2 MW), a dithering oscillation is observed that is triggered by a low-n interchange mode, whereas at higher NBI power (>2 MW), the edge reverts to L-mode and the low-n interchange mode is present continuously. In all cases, the edge pressure gradient is clamped when the interchange mode is present. It is concluded that the low-n interchange mode prevents the plasma from transitioning to H-mode at a large negative triangularity. This agrees with linear BOUT++ simulations which suggest that the interchange-type MHD can be a resistive ballooning mode whereby resistivity can significantly increase the finite-n ballooning mode growth rate. The absence of H-mode at large negative triangularity can, thus, be explained by the excitation of low-n pressure driven resistive ballooning modes in the plasma edge.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗