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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Exact Tuning of High-Q Optical Microresonators by Use of UV

In one of several alternative approaches to the design and fabrication of a "whispering-gallery" optical microresonator of high resonance quality (high Q), the index of refraction of the resonator material and, hence, the resonance frequencies. In this approach, a microresonator structure is prepared by forming it from an ultraviolet-sensitive material. Then the structure is subjected to controlled exposure to UV light while its resonance frequencies are monitored.

Savchankov, Anaotliy↗
NASA NTRS1992

Study of weld offset in longitudinally welded SSME HPFTP inlet

Welded joints are an essential part of rocket engine structures such as the Space Shuttle Main Engine (SSME) turbopumps. Defects produced in the welding process can be detrimental to weld performance. Recently, review of the SSME high pressure fuel turbopump (HPFTP) titanium inlet X-rays revealed several weld discrepancies such as penetrameter density issues, film processing discrepancies, weld width discrepancies, porosity, lack of fusion, and weld offsets. Currently, the sensitivity of welded structures to defects is of concern. From a fatigue standpoint, weld offset may have a serious effect since local yielding, in general, aggravates cyclic stress effects. Therefore, the weld offset issue is considered in this report. Using the FEM and beamlike plate approximations, parametric studies were conducted to determine the influence of weld offsets and a variation of weld widths in longitudinally welded cylindrical structures with equal wall thicknesses on both sides of the joint. Following the study, some conclusions are derived for the weld offsets.

Min, J. B.↗
NASA NTRS1984

Thematic Mapper simulator research for forest resource mapping in the Clearwater National Forest, Idaho

Per-pixel maximum likelihood digital classification and photo interpretation of Thematic Mapper Simulator (TMS) composited images for a managed conifer forest were used to evaluate both land cover and forest structure characteristics. TMS channels 4, 7, 5 and 3, which were found to be optimal for forest vegetation analysis, used the full range of the Thematic Mapper's spectral capability. Photo interpretation results indicate that a false color composite from TMS channels 4, 7, and 2 provided the highest accuracies; the combination of improved spatial, spectral and radiometric resolution of the Thematic Mapper yielded greater sensitivity to forest structural characteristics.

Brass, J. A.↗
DOE OSTI2025

Bridging reaction theory and nuclear structure in $π^±-$ 48 Ca scattering

Here, we extend the pion-nucleus multiple-scattering framework to include detailed second-order rescattering dynamics for nuclei with nonzero isospin. To account for intermediate charge-exchange and nucleon spin-flip effects, we develop a scattering potential that depends on the one- and two-body densities of the target nucleus. We compute one-body densities from coupled-cluster theory and two-body densities within the Hartree-Fock approximation. To estimate theoretical uncertainties, we employ modern nuclear Hamiltonians derived from chiral effective field theory. While the sensitivity to nuclear structure details is mild, second-order corrections are found to be sizable and essential for accurately reproducing differential cross sections measured in 𝜋 ± − 48 Ca elastic scattering within the Δ⁡(1232)-resonance region.

cluster models↗
NASA NTRS2011

Space Weathering Impact on Solar System Surfaces and Planetary Mission Science

We often look "through a glass, darkly" at solar system bodies with tenuous atmospheres and direct surface exposure to the local space environment. Space weathering exposure acts via universal space-surface interaction processes to produce a thin patina of outer material covering, potentially obscuring endogenic surface materials of greatest interest for understanding origins and interior evolution. Examples of obscuring exogenic layers are radiation crusts on cometary nuclei and iogenic components of sulfate hydrate deposits on the trailing hemisphere of Europa. Weathering processes include plasma ion implantation into surfaces, sputtering by charged particles and solar ultraviolet photons, photolytic chemistry driven by UV irradiation, and radiolytic chemistry evolving from products of charged particle irradiation. Regolith structure from impacts, and underlying deeper structures from internal evolution, affects efficacy of certain surface interactions, e.g. sputtering as affected by porosity and surface irradiation dosage as partly attenuated by local topographic shielding. These processes should be regarded for mission science planning as potentially enabling, e.g. since direct surface sputtering, and resultant surface-bound exospheres, can provide in-situ samples of surface composition to ion and neutral mass spectrometers on orbital spacecraft. Sample return for highest sensitivity compOSitional and structural analyses at Earth will usually be precluded by limited range of surface sampling, long times for return, and high cost. Targeted advancements in instrument technology would be more cost efficient for local remote and in-situ sample analysis. More realistic laboratory simulations, e.g. for bulk samples, are needed to interpret mission science observations of weathered surfaces. Space environment effects on mission spacecraft and science operations must also be specified and mitigated from the hourly to monthly changes in space weather and from longer term (e.g., solar cycle) evolution of space climate. Capable instrumentation on planetary missions can and should be planned to contribute to knowledge of interplanetary space environments. Evolving data system technologies such as virtual observatories should be explored for more interdisciplinary application to the science of planetary surface, atmospheric, magnetospheric, and interplanetary interactions.

Cooper, John F.↗
DOE OSTI2021

A strategy to identify materials exhibiting a large nonlinear phononics response: tuning the ultrafast structural response of LaAlO 3 with pressure

We use theory and first-principles calculations to investigate how structural changes induced by ultrafast optical excitation of infrared-active phonons change with hydrostatic pressure in LaAlO 3 . Our calculations show that the observed structural changes are sensitive to pressure, with the largest changes occurring at pressures near the boundary between the cubic perovskite and rhombohedral phases. We rationalize our findings by defining a figure of merit that depends only on intrinsic materials quantities, and show that the peak response near the phase boundary is dictated by different microscopic materials properties depending on the particular phonon mode being excited. Our work demonstrates how it is possible to systematically identify materials that may exhibit particularly large changes in structure and properties due to optical excitation of infrared-active phonons.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Simulation-guided analysis of resonant soft X-ray scattering for determining the microstructure of triblock copolymers

Resonant soft X-ray scattering (RSoXS) probes structure with chemical sensitivity that is useful for determining the morphology of multiblock copolymers. However, the hyperspectral scattering data produced by this technique can be challenging to interpret. Here, in this study, we use computational scattering simulations to extract the microstructure of a model triblock copolymer from the energy-dependent scattering from RSoXS. An ABC triblock terpolymer formed from poly(4-methylcaprolactone) (P4MCL), poly(2,2,2-trifluoroethylacrylate) (PTFEA), and poly (dodecylacrylate) (PDDA), P4MCL-block-PTFEA-block-PDDA, was synthesized as the model triblock system. Through quantitative evaluation of simulated scattering data from a physics-informed set of candidate structure models against experimental RSoXS data, we find the best agreement with hexagonally packed core–shell cylinders. This result is also consistent with electron-density reconstruction from hard X-ray scattering data evaluated against electron-density maps generated with the same model set. These results demonstrate the utility of simulation-guided scattering analysis to study complex microstructures that are challenging to image by microscopy.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Data-driven enhancement of coherent structure-based models for predicting instantaneous wall turbulence

Predictions of the spatial representation of instantaneous wall-bounded flows, via coherent structure-based models, are highly sensitive to the geometry of the representative structures employed by them. In this study, we propose a methodology to extract the three-dimensional (3-D) geometry of the statistically significant eddies from multi-point wall-turbulence datasets, for direct implementation into these models to improve their predictions. The methodology is employed here for reconstructing a 3-D statistical picture of the inertial wall coherent turbulence for all canonical wall-bounded flows, across a decade of friction Reynolds number (Re T ). These structures are responsible for the Re T -dependence of the skin-friction drag and also facilitate the inner-outer interactions, making them key targets of structure-based models. The empirical analysis brings out the geometric self-similarity of the large-scale wall-coherent motions and also suggests the hairpin packet as the representative flow structure for all wall-bounded flows, thereby aligning with the framework on which the attached eddy model (AEM) is based. The same framework is extended here to also model the very-large-scaled motions, with a consideration of their differences in internal versus external flows. Implementation of the empirically-obtained geometric scalings for these large structures into the AEM is shown to enhance the instantaneous flow predictions for all three velocity components. Finally, an active flow control system driven by the same geometric scalings is conceptualized, towards favourably altering the influence of the wall coherent motions on the skin-friction drag.

42 ENGINEERING↗
NASA NTRS2018

Mangrove Canopy Height Globally Related to Precipitation, Temperature and Cyclone Frequency

Mangrove wetlands are among the most productive and carbon-dense ecosystems in the world. Their structural attributesvary considerably across spatial scales, yielding large uncertainties in regional and global estimates of carbon stocks. Here, wepresent a global analysis of mangrove canopy height gradients and aboveground carbon stocks based on remotely sensed measurementsand field data. Our study highlights that precipitation, temperature and cyclone frequency explain 74% of the globaltrends in maximum canopy height, with other geophysical factors influencing the observed variability at local and regionalscales. We find the tallest mangrove forests in Gabon, equatorial Africa, where stands attain 62.8 m. The total global mangrovecarbon stock (above- and belowground biomass, and soil) is estimated at 5.03 Pg, with a quarter of this value stored inIndonesia. Our analysis implies sensitivity of mangrove structure to climate change, and offers a baseline to monitor nationaland regional trends in mangrove carbon stocks.

Simard, Marc↗
NASA NTRS2022

Buckling Test and Analysis of the 8-Foot-Diameter Sandwich Composite Cylinder Test Article CTA8.2 as Part of the Shell Buckling Knockdown Factor Project: Test Dates 5-7 December 2017

It is well known that the buckling response of thin shell structures can be sensitive to small imperfections in the geometry and loading. The NASA Engineering and Safety Center (NESC) Shell Buckling Knockdown Factor Project (SBKF) has the goal of developing buckling design recommendations for select classes of metallic and composite shells. Part of completed SBKF work is described in this report. In particular, the test and analysis results from the second SBKF composite test article, CTA8.2, are described. This test was the second in a series of tests on sandwich composite cylinders that can be used to experimentally validate analysis methods, which in turn can be used to develop analysis-based shell buckling design guidelines for sandwich composite launch-vehicle cylindrical structures. CTA8.2 was an 8-foot diameter honeycomb-core sandwich cylinder that was fabricated and tested at the Marshall Space Flight Center (MSFC). The primary objectives of this test were to interrogate the structural capability of the composite test article, and to verify the test-article design and analysis approach for cylinders subjected to axial compression loads. This report contains the descriptions of the test-article design, fabrication, and test. The pre-test modeling and analysis methods, and corresponding results used in support of the test-article design and test planning, are also described. Additional post-test modeling and analysis efforts and results follow. Selected test results are compared to pre-test predictions and post-test analyses.

Adam Przekop↗
NASA NTRS2018

Mangrove Canopy Height Globally Related to Precipitation and Cyclone Frequency

Mangrove wetlands are among the most productive and carbon-dense ecosystems in the world. Their structural attributes vary considerably across spatial scales, yielding large uncertainties in regional and global estimates of carbon stocks. Here, we present a global analysis of mangrove canopy height gradients and aboveground carbon stocks based on remotely sensed measurements and field data. Our study highlights that precipitation, temperature and cyclone frequency explain 74% of the global trends in maximum canopy height, with other geophysical factors influencing the observed variability at local and regional scales. We find the tallest mangrove forests in Gabon, equatorial Africa, where stands attain 62.8 m. The total global mangrove carbon stock (above- and belowground biomass, and soil) is estimated at 5.03 Pg, with a quarter of this value stored in Indonesia. Our analysis implies sensitivity of mangrove structure to climate change, and offers a baseline to monitor national and regional trends in mangrove carbon stocks.

Carbon cycle↗
NASA NTRS2003

Structural Fluctuations and Thermophysical Properties of Molten II-VI Compounds

The objectives of the project are to conduct ground-based experimental and theoretical research on the structural fluctuations and thermophysical properties of molten II-VI compounds to enhance the basic understanding of the existing flight experiments in microgravity materials science programs as well as to study the fundamental heterophase fluctuation phenomena in these melts by: 1) conducting neutron scattering analysis and measuring quantitatively the relevant thermophysical properties of the II-VI melts (such as viscosity, electrical conductivity, thermal diffusivity and density) as well as the relaxation characteristics of these properties to advance the understanding of the structural properties and the relaxation phenomena in these melts and 2) performing theoretical analyses on the melt systems to interpret the experimental results. All the facilities required for the experimental measurements have been procured, installed and tested. It has long been recognized that liquid Te presents a unique case having properties between those of metals and semiconductors. The electrical conductivity for Te melt increases rapidly at melting point, indicating a semiconductor-metal transition. Te melts comprise two features, which are usually considered to be incompatible with each other: covalently bound atoms and metallic-like behavior. Why do Te liquids show metallic behavior? is one of the long-standing issues in liquid metal physics. Since thermophysical properties are very sensitive to the structural variations of a melt, we have conducted extensive thermophysical measurements on Te melt.

Su, Ching-Hua↗
DOE OSTI2021

Role of a 3D Structure in Energy Transfer in Mixed-Ligand Metal–Organic Frameworks

We present a detailed investigation of the photophysical properties of mixed-ligand pyrene- and porphyrin-based metal–organic frameworks (MOFs) as a function of their 3D structure. Solvothermal reactions between metal salts (InCl 3 , Zr(acac) 4 , and ZrCl 4 ) and suitable ratios of 1,3,6,8-tetrakis(p-benzoic acid)pyrene (TBAPy) and meso-tetrakis- (4-carboxyphenyl)porphyrin (TCPP) were performed to prepare a series of mixed-ligand ROD-7, NU-901, and NU-1000 MOFs. Time-resolved and steady-state fluorescence measurements were conducted on the mixed-ligand MOFs to study their photophysics. Based on the results, we concluded that upon excitation of TBAPy linkers in the MOFs, singlet excitation energy migrates across TBAPy linkers until it finds a TCPP unit. TCPP acts as an energy trap and quenches the excitation. The efficiency of TBAPy-to-TBAPy energy transfer was found to be sensitive to the structural parameters of MOFs. Analysis of steady-state and time-resolved fluorescence data revealed that excitation energy transfer (EET) is most efficient in ROD-7, followed by NU-901 and NU-1000. We propose that topology that invokes the shorter interchromophoric distances between TBAPy linkers in ROD-7 is responsible for its higher EET efficiency. The distance dependence of the EET rate constant (kEET) was investigated to gain insight into the mechanistic aspects of energy transfer in MOFs. This study revealed that (a) energy transfer in MOFs deviates from the classical Förster model and (b) the geometrical arrangement of linkers influences the mechanism of EET in MOFs. A theoretical investigation was also performed to determine energy-transfer rate constants along different directions and assess the directionality of energy transfer in these MOFs. The magnitude of rate constants indicated that energy transfer in ROD-7 should be highly anisotropic along the stacking direction. Furthermore, these findings suggest that ROD-7 is a promising candidate to play the role of the light-harvesting and energy-transfer component in solar energy conversion devices, where directional energy transfer is required.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

DFT Plus DMFT Study of Spin-Charge-Lattice Coupling in Covalnt LaCoO{siub 3}.

We study energetics and the nature of both homogeneous and mixed spin (MS) states in LaCoO3 incorporating structural changes of the crystal volume expansion and the Co-O bond disproportionation (BD) during the spin-state transition using the density functional theory plus dynamical mean field theory (DFT + DMFT) method. DFT + DMFT predicts that energetics of both excited spin states are almost the same while DFT + U calculations of the same structures energetically favor the MS states and produce various metastable solutions whose energetics depend sensitively on final spin states. Within DFT + DMFT, the homogeneous spin state in the expanded crystal volume shows the multiconfigurational nature with non-negligible occupancy probabilities of both high spin (HS) and low spin (LS) states along with d(6) and d(7) charge configurations indicating the dynamically fluctuating nature of spin and charge states due to the Co-O covalency. The nature of the MS state under the BD structure reveals that Co sites with the long Co-O bonds develop a Mott insulating state and favor HS with a d(6) configuration, while more covalent Co sites with the short Co-O bonds occupy more LS states with a d(7) configuration and behave as a band insulator, as a result, charge ordering is induced in the BD structure from the spin-state ordering. We also find that both energetics and electronic structure sensitively depend on the Co-O covalency effect, which can be tuned by changing the double counting potential and the resulting d occupancy (N-d), and N-d close to 6.7 is consistent with the nature of the spin-state transition. Our results show that structural changes during the spin-state transition can play an important role in understanding energetics and electronic structure of LaCoO3.

Park, Hyowon↗
NASA NTRS2019

TPSAS-NF1676L-34013-DND

Currently, many experiments pursuing comprehensive characterization of the atmosphere include coordinated observations by both lidar and polarimeters in order to obtain important complimentary information about aerosol properties. The most advanced passive observations by space-based multi-angle polarimeters are sensitive to the properties of aerosol in total atmospheric column, but have very limited sensitivity to vertical structure of the atmosphere. Polarimeter observations can be used not only for retrieval of aerosol optical thickness, but also for deriving microphysical information about aerosol particle shape, size distribution, complex refractive index, and the properties of underlying surface (Dubovik et al., 2019). In a contrast, the lidar observations of atmospheric responses from different altitudes to laser pulses are designed to provide vertical profiles of atmospheric characteristics. Here we present the recent advancement in GRASP algorithm (Generalized Aerosol Retrieval of Atmospheric and Surface Properties) (Dubovik et al., 2011, 2014) that allows simultaneous inversion of co-incident lidar and polarimeter spaceborne observations and derives a united set of vertically resolved aerosol and surface parameters. Such synergetic retrieval is an extension to satellite data of the approach for synergetic processing of active and passive measurements developed earlier by (Lopatin et al., 2013) for ground-based observations. Another addition to these developments is the inclusion of Raman-shifted and volume depolarization backscattering observations that improve sensitivity to the vertical properties of aerosol, while polarimetric observations provide sufficient constraints on aerosol type and loading that generally are missing in lidar signals. The potential and limitations of such synergetic processing is illustrated by application to co-incident PARASOL and CALIPSO data.

Anton Lopatin↗
DOE OSTI2025

Experimental scheme for polarizing boron nuclei

Unraveling the internal structure of hadrons and nuclei in terms of the quarks and gluons of quantum chromodynamics is a central focus of current nuclear physics research. Directly observing gluonic states in the nucleus would be groundbreaking and is an objective of the future Electron-Ion Collider (EIC). Over 30 years ago, Jaffe and Manohar [R. L. Jaffe and A. Manohar, Phys. Lett. B 223 , 218 (1989)] identified a new double-helicity flip structure function, directly sensitive to exotic gluons. They pointed out that this could be measured in inclusive high-energy electron scattering from a transversely polarized nuclear target with spin 𝐼 ≥ 1. Here, in this work, we identify the spin-3 nucleus boron-10 as a particularly interesting system to search for exotic gluons. Leveraging technical advances in atomic physics over the past decade, we outline an experimental scheme to directly optically pump a beam of stable boron atoms to polarize the nuclear spin. Technical challenges to realize a spin-polarized beam of boron-10 in the EIC are discussed. The proposed scheme will also polarize the 11 B nucleus, which could significantly enhance the proton-boron fusion cross section.

atomic spectra↗
DOE OSTI2025

Constraining primordial non-Gaussianity from the large scale structure two-point and three-point correlation functions

Surveys of cosmological large-scale structure (LSS) are sensitive to the presence of local primordial non-Gaussianity (PNG), and may be used to constrain models of inflation. Local PNG, characterized by f NL ⁠, the amplitude of the quadratic correction to the potential of a Gaussian random field, is traditionally measured from LSS two-point and three-point clustering via the power spectrum and bi-spectrum. We propose a framework to measure f NL using the configuration space two-point correlation function (2pcf) monopole and three-point correlation function (3pcf) monopole of survey tracers. Our model estimates the effect of the scale-dependent bias induced by the presence of PNG on the 2pcf and 3pcf from the clustering of simulated dark matter haloes. We describe how this effect may be scaled to an arbitrary tracer of the cosmological matter density. The 2pcf and 3pcf of this tracer are measured to constrain the value of f NL ⁠. In LSS surveys, the effect of imaging systematics on two-point statistics is often degenerate with the PNG signal. Our proposed model employs three-point statistics primarily to break this degeneracy. Using simulations of luminous red galaxies observed by the Dark Energy Spectroscopic Instrument (DESI), we demonstrate the accuracy and constraining power of our method. Our forecast indicates the ability to constrain f NL to a precision of σf NL ≈ 22 with one year of DESI survey data, as well as the ability to constrain the imaging systematic weights in situ.

early Universe↗
NASA NTRS2001

The Impact on Simulated Storm Structure and Intensity of Variations in the Lifted Condensation Level and the Level of Free Convection

The sensitivities of convective storm structure and intensity to changes in the altitudes of the prestorm environmental lifted condensation level and level of free convection axe studied using a full-physics three-dimensional cloud model. Matrices of simulations are conducted for a range of LCL=LFC altitudes, using a single moderately-sheared curved hodograph trace in conjunction with 1 convective available potential energy values of either 800 or 2000 J/kg, with the matrices consisting of all four combinations of two distinct choices of buoyancy and shear profile shape. For each value of CAPE, the LCL=LFC altitudes are also allowed to vary in a series of simulations based on the most highly compressed buoyancy and shear profiles for that CAPE, with the environmental buoyancy profile shape, subcloud equivalent potential temperature, subcloud lapse rates of temperature and moisture, and wind profile held fixed. For each CAPE, one final simulation is conducted using a near optimal LFC, but a lowered LCL, with a neutrally buoyant environmental thermal profile specified in between. Results show that, for the buoyancy-starved small-CAPE environments, the simulated storms are supercells and are generally largest and most intense when LCL=LFC altitudes lie in the approximate range 1.5-2.5 km above the surface. The simulations show similar trends for the shear-starved large-CAPE environments, except that conversion from supercell to multicell morphology frequently occurs when the LCL is high. For choices of LCL=LFC height within the optimal 1.5-2.5 km range, peak storm updraft overturning efficiency may approaches unity relative to parcel theory, while for lower LCL=LFC heights, overturning efficiency is reduced significantly. The enhancements of overturning efficiency and updraft diameter with increasing LFC height are shown to be the result of systematic increases in the mean equivalent potential temperature of the updraft at cloud base. For the shear-starved environments, the tendency for outflow dominance is eliminated, but a large overturning efficiency maintained, when a low LCL is used in conjunction with a high LFC. The result regarding outflow dominance at high LCL is consistent with expectations, but the beneficial effect of a high LFC on convective overturning efficiency has not previously been widely recognized. The simulation findings here also appear to be consistent with statistics from previous severe storm environment climatologies, but provide a new framework for interpreting those statistics.

McCaul, Eugene W., Jr.↗