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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Opportunities and challenges in cathode development for non-lithium-ion batteries

Lithium (Li)-ion batteries have stimulated the societal transformation to clean energy systems. This carry-on electricity is revolutionizing how society communicates, functions, and evolves efficiently by enabling mobile electronics, zero-emission electric vehicles, and stationary energy storage. In preparation for the sustainable energy future, however, there are growing concerns about depleting critical elements used in the Li technology (e.g., lithium, cobalt, and nickel), especially for large-scale applications that will accelerate the rate of elemental consumption. Various non-Li-based rechargeable batteries composed of earth-abundant elements, such as sodium, potassium, magnesium, and calcium, have been proposed and explored as alternative systems to promote sustainable development of energy storage. In this perspective, we discuss challenges in Li-ion batteries in the sustainability aspect and provide our opinions on the potential applications of non-Li-based batteries. We also highlight the current status, important progress, and remaining challenges of the Li-alternative technologies.

25 ENERGY STORAGE↗

Workshop Report On Sustainable Urban Development

The key workshop goal was to explore and document how NASA technologies, such as remote sensing, climate modeling, and high-end computing and visualization along with NASA assets such as Earth Observing Satellites (EOS) and Unmanned Aerial Vehicles (UAVs) can contribute to creating and managing a sustainable urban environment. The focus was on the greater Bay Area, but many aspects of the workshop were applicable to urban management at the local, regional and global scales. A secondary goal was to help NASA better understand the problems facing urban managers and to make city leaders in the Bay Area more aware of NASA's capabilities. By bringing members of these two groups together we hope to see the beginnings of new collaborations between NASA and those faced with instituting sustainable urban management in Bay Area cities.

Langhoff, Stephanie↗

The Lunar Lab Initiative

Analogous to terrestrial Antarctic basecamps at our south pole, space exploration outposts will be a combination of habitation and science-focused assets. The Artemis Exploration Roadmap endeavors to establish a sustained human presence on the lunar south pole starting in 2028. Within the planned Artemis Base Camp, most efforts to date have focused on the habitation assets or a mixture of science and habitation assets . With the recent advent of commercial lunar landing capabilities, the trade space can be further expanded to include dedicated science focused assets that ensure adequate science capability. To that end, the Forge, an innovation team initiative created at the Johnson Space Center (JSC), explored alternative ways to increase the science capabilities within the basecamp. The Forge uses structured brainstorming and facilitation to increase innovation within the assigned team, while executing its process in a rapid turnaround fashion for ideation and design study. As a pilot study for the Forge, a multi-disciplinary team investigated a lunar lab module to augment the lunar surface plans for Artemis. This formulation study evaluated the scientific and operational considerations for this dedicated crew space that would increase the capabilities of lunar surface science operations. The trade space evaluated single lunar lander delivery versus multiple lunar lander delivery for module assembly, alternative structural designs, the science instrument outfitting with mapping to scientific goals to maximize lunar science objectives, and how the lab would be operated. The lab operations options explored a stand-alone facility, as well as a facility integrated into a larger lunar surface complex, while evaluating crew usage and habitability considerations. The resulting alternatives were evaluated by the Forge team with a set of metrics to determine their originality, feasibility, and science performance, and thereby provide a recommendation to the lunar architecture planning team. Lessons learned from the lunar lab study were compiled to improve the process and tools for future Forge studies. Forward work, open issues, and challenges to further refine the design of the various science-focused asset options were also documented. By providing a robust science capability at humanity’s furthest outpost, we can plan for a sustained human lunar presence once the initial lunar surface access capability is well established.

Lunar outpost↗

NASA Mars 2020 Landed Mission Development

In January of 2014, NASA received fifty-eight proposals from U.S. and international teams for science and exploration technology investigations, for consideration for inclusion as part of NASA's next mobile landed mission to Mars. The results of the competitive procurement were released in late July of 2014: Seven payloads were selected for the investigations that would contribute to meeting the overall objectives of the mission. The extraordinary scientific and technology development interest in the Mars 2020 mission is a direct result of NASA's sustained and coordinated plan for the exploration of Mars, and ultimately, its search for life elsewhere in the universe. The Mars 2020 Mission will preserve the heritage and directly build upon NASA's Mars Science Laboratory Mission and Curiosity Rover to implement its mission. In this paper, early development history leading to its development announcement, as well as key development status and design features for its implementation, is summarized.

MSR↗

NASA Mars 2020 landed mission development

In January of 2014, NASA received fifty-eight proposals from U.S. and international teams for science and exploration technology investigations, for consideration for inclusion as part of NASA’s next mobile landed mission to Mars. The results of the competitive procurement were released in late July of 2014: Seven payloads were selected for the investigations that would contribute to meeting the overall objectives of the mission. The extraordinary scientific and technology development interest in the Mars 2020 mission is a direct result of NASA’s sustained and coordinated plan for the exploration of Mars, and ultimately, its search for life elsewhere in the universe. The Mars 2020 Mission will preserve the heritage and directly build upon NASA’s Mars Science Laboratory Mission and Curiosity Rover to implement its mission. In this paper, early development history leading to its development announcement, as well as key development status and design features for its implementation, is summarized.

Abilleira, Fernando↗

To Mars by the Way of the Moon

The Vision for Space Exploration defines a new U.S. space exploration policy. In support of this policy, through a renewed spirit of discovery, NASA will: a) Implement a sustained and affordable human and robotic program to explore the Solar System and beyond; b) Extend human presence across the Solar System, staring with a human return to the moon by the year 2020, in preparation for human exploration of Mars and other destinations; c) Develop the innovative technologies, knowledge, and infrastructures both to explore and to support decisions about destination for future human exploration; and d) Promote international and commercial participation in exploration to further U.S. scientific, security, and economic interests.

Carpenter, Joyce↗

NASA's Space Launch System: Momentum Builds Toward First Launch

NASA's Space Launch System (SLS) is gaining momentum toward the first launch of a new exploration-class heavy lift launch vehicle for international exploration and science initiatives. The SLS comprises an architecture that begins with a vehicle capable of launching 70 metric tons (t) into low Earth orbit. It will launch the Orion Multi-Purpose Crew Vehicle (MPCV) on its first autonomous flight beyond the Moon and back in December 2017. Its first crewed flight follows in 2021. SLS can evolve to a130-t lift capability and serve as a baseline for numerous robotic and human missions ranging from a Mars sample return to delivering the first astronauts to explore another planet. The SLS Program formally transitioned from the formulation phase to implementation with the successful completion of the rigorous Key Decision Point C review in 2014. As a result, the Agency authorized the Program to move forward to Critical Design Review, scheduled for 2015. In the NASA project life cycle process, SLS has completed 50 percent of its major milestones toward first flight. Every SLS element manufactured development hardware for testing over the past year. Accomplishments during 2013/2014 included manufacture of core stage test articles, preparations for qualification testing the solid rocket boosters and the RS-25 main engines, and shipment of the first flight hardware in preparation for the Exploration Flight Test-1 (EFT-1) in 2014. SLS was conceived with the goals of safety, affordability, and sustainability, while also providing unprecedented capability for human exploration and scientific discovery beyond Earth orbit. In an environment of economic challenges, the SLS team continues to meet ambitious budget and schedule targets through the studied use of hardware, infrastructure, and workforce investments the United States made in the last half century, while selectively using new technologies for design, manufacturing, and testing, as well as streamlined management approaches that have increased decision velocity and reduced associated costs. This paper will summarize recent SLS Program accomplishments, as well as the challenges and opportunities ahead for the most powerful and capable launch vehicle in history.

May, Todd A.↗

Overview of NASA’s Break the Ice Lunar Challenge Phase 1

As NASA works to extend human exploration of the solar system, a sustained presence on the Moon will be critical for developing and testing the technologies and systems needed for future missions to Mars and beyond. In situ resource utilization (ISRU)—the use of lunar materials for life support, fuel, energy, manufacturing, and construction—is necessary to limit the delivery of supplies from Earth. One of the most important of these resources is water. Water supports all life on Earth and will be critical to supporting human exploration beyond Earth. On the Moon, water is trapped in icy regolith at the lunar poles, including inside permanently dark and cold craters. Novel approaches are needed to excavate the icy regolith and transport it for processing in support of permanent human missions on the Moon. To accelerate the development of such approaches and to seek diverse ideas, NASA’s Centennial Challenges launched the Break the Ice Lunar Challenge in November 2020. Phase 1 of the challenge was focused on stimulating innovative approaches for excavating icy regolith and delivering water in extreme lunar environmental conditions. The challenge sought to incentivize solutions for maximizing water delivery while minimizing energy use and the mass of equipment required to be transported to the lunar surface. Submissions for phase 1 of the challenge were due in June 2021 and winners were announced in August 2021. This paper provides details about the execution of the challenge, solutions received, criteria used to select winning solutions, and status of the phase 2 of the challenge.

Naveen Vetcha↗

Cost Breakeven Analysis of Lunar In-Situ Propellant Production for Human Missions to the Moon and Mars

NASA is preparing to return humans to the lunar surface as a first step to a human exploration campaign of Mars. Both a sustained lunar campaign and a campaign of missions to Mars will require tens to hundreds of tonnes of propellant. Although this propellant could be delivered from Earth, an alternative approach is to use the potentially vast quantities of lunar ice to enable in-situ propellant production on the lunar surface. This study evaluates the cost breakeven for using lunar-derived propellants, as opposed to those delivered from Earth, in support of an extended human exploration campaign with both a multi-year presence on the Moon as well as multiple crewed missions to Mars. In so doing, the value of lunar propellant production is considered in the context of future exploration priorities, addressing the question: over what range of human missions to the lunar surface and Mars does in-situ propellant production trade favorably with propellant delivery from Earth on the basis of cost? The results of this analysis show that the magnitude and duration of the lunar campaign, more so than the Mars campaign, drive the breakeven and that without long lifetime ISRU systems, with greater than 5 years of autonomous operation before replacement, the demand in cis-lunar space for a Mars campaign favors propellant delivery from Earth.

Christopher A Jones↗

Cost Breakeven Analysis of Lunar In-Situ Propellant Production for Human Missions to the Moon and Mars

NASA is preparing to return humans to the lunar surface as a first step to a human exploration campaign of Mars. Both a sustained lunar campaign and a campaign of missions to Mars will require tens to hundreds of tonnes of propellant. Although this propellant could be delivered from Earth, an alternative approach is to use the potentially vast quantities of lunar ice to enable in-situ propellant production on the lunar surface. This study evaluates the cost breakeven for using lunar-derived propellants, as opposed to those delivered from Earth, in support of an extended human exploration campaign with both a multi-year presence on the Moon as well as multiple crewed missions to Mars. In so doing, the value of lunar propellant production is considered in the context of future exploration priorities, addressing the question: over what range of human missions to the lunar surface and Mars does in-situ propellant production trade favorably with propellant delivery from Earth on the basis of cost? The results of this analysis show that the magnitude and duration of the lunar campaign, more so than the Mars campaign, drive the breakeven and that without long lifetime ISRU systems, with greater than 5 years of autonomous operation before replacement, the demand in cis-lunar space for a Mars campaign favors propellant delivery from Earth.

Christopher A. Jones↗

Space-Based Solar Power: An Enabler for Expanded Lunar Surface Exploration and Mobility Operations

The achievement of industrial and scientific goals set by the National Aeronautics and Space Administration (NASA) Artemis missions within the Moon to Mars (M2M) architecture greatly relies on the breadth and efficacy of lunar surface exploration. The lunar surface environment presents various challenges and complexities to sustainable mission operations and activities. Power generation and distribution capabilities are vital for exploration on the lunar surface, which can enable activities such as subsurface sample collection, permanently shadowed region (PSR) prospecting, and lunar terrain mapping. Innovative power technologies that demonstrate flexibility, reliability, and high capacity are desirable to achieve sustainable operations and infrastructure on the lunar surface. Studies have proposed solar-powered spacecraft in cislunar orbit capable of beaming power to lunar surface assets as a solution to this problem. This study analyzes the benefit that space-based solar power (SBSP) assets could deliver to the M2M architecture by measuring its potential to augment lunar surface exploration opportunity. Qualitative measures of SBSP’s potential impact will include, but not be limited to, power available across surface elements, surface mobility range, and delivered landed mass. These measures are assessed for a notional surface architecture measured against its baseline configuration (no external power augmentation). Additionally, this presentation will provide an overview of the SBSP system design configuration trade space, subsystem parameter trade space, and results from preliminary spacecraft concept of operations (ConOps) and sizing.

Space-based solar power↗

Adsorption of Water on JSC-1A Lunar Simulant Samples

Remote sensing probes sent to the moon in the 1990s indicated that water may exist in areas such as the bottoms of deep, permanently shadowed craters at the lunar poles, buried under regolith. Water is of paramount importance for any lunar exploration and colonization project which would require self-sustainable systems. Therefore, investigating the interaction of water with lunar regolith is pertinent to future exploration. The lunar environment can be approximated in ultra-high vacuum systems such as those used in thermal desorption spectroscopy (TDS). Questions about water dissociation, surface wetting, degree of crystallization, details of water-ice transitions, and cluster formation kinetics can be addressed by TDS. Lunar regolith specimens collected during the Apollo missions are still available though precious, so testing with simulant is required before applying to use lunar regolith samples. Hence, we used for these studies JSC-1a, mostly an aluminosilicate glass and basaltic material containing substantial amounts of plagioclase, some olivine and traces of other minerals. Objectives of this project include: 1) Manufacturing samples using as little raw material as possible, allowing the use of surface chemistry and kinetics tools to determine the feasibility of parallel studies on regolith, and 2) Characterizing the adsorption kinetics of water on the regolith simulant. This has implications for the probability of finding water on the moon and, if present, for recovery techniques. For condensed water films, complex TDS data were obtained containing multiple features, which are related to subtle rearrangements of the water adlayer. Results from JSC-1a TDS studies indicate: 1) Water dissociation on JSC-1a at low exposures, with features detected at temperatures as high as 450 K and 2) The formation of 3D water clusters and a rather porous condensed water film. It appears plausible that the sub- m sized particles act as nucleation centers.

Goering, John↗

Biomanufacturing and Scale-Up: Pathways to Biochemicals, Biofuels, and Biomaterials

Advancing the bioeconomy requires the development of large-scale microbial bioprocesses capable of converting waste carbon streams into biofuels, biochemicals, and biomaterials at industrially relevant scales. While biomanufacturing has been successfully demonstrated at the laboratory scale for a wide range of chemicals, only a few have reached industrial-scale production. This is partly due to the inherent complexity of microbial systems, which rely on living cells with intricate metabolic pathways that are highly sensitive to environmental changes, making large-scale production difficult to optimize and predict. As a result, scaling-up bioprocesses remains a high-stakes challenge that requires deeper exploration. This involves integrating feedstock and microbial selection, upstream and downstream processes, and computational modelling, among other research efforts. Bulk and specialty chemicals derived from biological processes also face competition from fossil-based production routes, which have been refined through decades of technological advancements. While biologically derived molecules may offer more environmentally friendly production pathways than traditional chemical manufacturing, their widespread adoption depends on achieving cost parity-or superiority-relative to fossil-based methods. This emphasizes the importance of holistic research, including techno-economic analyses and life cycle assessments, to ensure both economic viability and environmental sustainability. This editorial and special issue explores state-of-the-art strategies for converting waste carbon sources into valuable products. It discusses how enzymes, single microbes (e.g., extremophiles), and microbiomes (e.g., through division of labor) can be integrated with upstream and downstream process innovations-such as consolidated bioprocessing and in situ product recovery-to improve the efficiency and scalability of biomanufacturing. The editorial further highlights the role of computational modelling in understanding, predicting, and controlling bioprocess performance across scales, and concludes by emphasizing the importance of techno-economic modelling to identify technologies that can move to market.

09 BIOMASS FUELS↗

Drought-Tolerant Succulent Plants as an Alternative Crop Under Future Global Warming Scenarios in Sub-Saharan Africa

Globally, we are facing an emerging climate crisis, with impacts to be notably felt in semiarid regions across the world. Cultivation of drought-adapted succulent plants has been suggested as a nature-based solution that could: (i) reduce land degradation, (ii) increase agricultural diversification and provide both economic and environmentally sustainable income through derived bioproducts and bioenergy, (iii) help mitigate atmospheric CO 2 emissions and (iv) increase soil sequestration of CO 2 . Identifying where succulents can grow and thrive is an important prerequisite for the advent of a sustainable alternative ‘bioeconomy’. Here, we first explore the viability of succulent cultivation in Africa under future climate projections to 2100 using species distribution modelling to identify climatic parameters of greatest importance and regions of environmental suitability. Minimum temperatures and temperature variability are shown to be key controls in defining the theoretical distribution of three succulent species explored, and under both current and future SSP5 8.5 projections, the conditions required for the growth of at least one of the species are met in most parts of sub-Saharan Africa. These results are supplemented with an analysis of potentially available land for alternative succulent crop cultivation. In total, up to 1.5 billion ha could be considered ecophysiologically suitable and available for succulent cultivation due to projected declines in rangeland biomass and yields of traditional crops. These findings may serve to highlight new opportunities for farmers, governments and key stakeholders in the agriculture and energy sectors to invest in sustainable bioeconomic alternatives that deliver on environmental, social and economic goals.

agriculture↗

The Concept and Analytical Investigation of CO2 and Steam Co-Electrolysis for Resource Utilization in Space Exploration

CO2 acquisition and utilization technologies will have a vital role in designing sustainable and affordable life support and in situ fuel production architectures for human and robotic exploration of Moon and Mars. For long-term human exploration to be practical, reliable technologies have to be implemented to capture the metabolic CO2 from the cabin air and chemically reduce it to recover oxygen. Technologies that enable the in situ capture and conversion of atmospheric CO2 to fuel are essential for a viable human mission to Mars. This paper describes the concept and mathematical analysis of a closed-loop life support system based on combined electrolysis of CO2 and steam (co-electrolysis). Products of the coelectrolysis process include oxygen and syngas (CO and H2) that are suitable for life support and synthetic fuel production, respectively. The model was developed based on the performance of a co-electrolysis system developed at Idaho National Laboratory (INL). Individual and combined process models of the co-electrolysis and Sabatier, Bosch, Boudouard, and hydrogenation reactions are discussed and their performance analyses in terms of oxygen production and CO2 utilization are presented.

McKellar, Michael G.↗

Chemical looping conversion of CH4/CO2 to syngas on 5wt.%Ni@Ce0.6Zr0.4O2 catalyst: Impact of dynamic accumulation of surface carbon and oxygen vacancies

Syngas, a combination of carbon monoxide (CO) and hydrogen (H2), is a precursor to many chemicals and fuels, contributing to the billion-dollar global hydrocarbon industry. Chemical looping reforming (CLR) of the greenhouse gases methane (CH4) and carbon dioxide (CO2) allows for energy-efficient production of syngas. 5wt.% nickel (Ni) on ceria-zirconia (5wt%Ni@Ce0.6Zr0.4O2) mixed metal oxide catalyst was investigated here to explore pathways for enhanced syngas production on sustainable earth-abundant transition metal supported catalysts. The role of reduction-oxidation (redox) state of the catalyst, and carbon formation on the catalyst surface during chemical looping is explored to drive superior reaction kinetics, conversions, selectivity, and syngas ratios (H2/CO). The bulk and surface structure of the catalyst, along with carbon deposition features were characterized by electron microscopy, X-Ray diffraction, and ex situ Raman spectroscopy. The dynamic evolution of catalysts under CLR reaction conditions and the intrinsic reaction mechanisms were probed with in situ Raman spectroscopy, in situ Fourier transform spectroscopy, dynamic oxygen storage capacity (DOSC), and the Temporal Analysis of Products (TAP) reactor studies. Intrinsic kinetics of syngas production via CLR was correlated to the redox state of catalyst and the participation of nickel-catalyzed multiwalled carbon nanotube (CNT) growth, allowing enhanced CLR reaction performance.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Metallic Environmentally Resistant Coating Rapid Innovation Initiative Under Extreme Space Environments

Mission concepts such as JPL’s Endurance-A campaign will utilize rovers such as Astrolab’s FLEX concept to explore the lunar surface. For these types of systems, lightweight alloys such as aluminum (Al) and titanium (Ti) are often specified to minimize mass while maintaining structural integrity [1,2,3]. Such alloys, however, exhibit poor tribological response in the form of high friction and wear, especially in extreme space environments and with the additional presence of lunar regolith. This shortens the lifetimes of these systems which have a requirement to traverse 1,00km/year [2,3]. The MERCRII project is ad-dressing the technology need of this and future rover missions by developing advanced wear- and radiation-resistant coatings for lightweight parts to extend the lifetime and sustainability of both lunar and Martian assets. The MERCRII project focuses on the technology taxonomies of exploration destination systems, mission infrastructure, and sustainability and supportability to explore both new and existing coating technologies, including material formulations and application methods. Several material formulations were considered for their wear resistance and fracture toughness and the following were chosen for Phase I testing: Nickle Titani-um (NiTi), Aluminum Oxide (AlO), and Ti64 with hBN at two and ten vol percent (Ti-2vol%hBN and Ti-10vol%hBN).

S. Rengifo↗