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At least 397 records · Page 22

Feldspathic granulitic impactites and pre-final bombardment lunar evolution

It is suggested that feldspathic granulitic impactites, which are characterized by a high model plagioclase content of between 70 and 80%, all formed in the period after consolidation of the lunar crust and before the final bombardment. The granulitic impactites contain essentially no KREEP component, which suggests that KREEP appeared on the lunar surface mostly after the formation of the granulitic impactites, at about the start of the final bombardment. The granulite metamorphism indicated by the matrix textures of these samples requires 1000 C temperatures for prolonged periods of time. The apparent sequence of formation is granulitic impactites before the final bombardment, crystalline-matrix breccias during the final bombardment, and vitric-matrix breccias after the final bombardment. The sequence is consistent with a described thermal model of breccia lithification and with characteristics of the decay of the meteorite flux rate.

Warner, J. L.↗

Construction and Resource Utilization Explorer: Regolith Characterization Using a Modular Instrument Suite and Analysis Tools

The Construction Resource Utilization Explorer (CRUX) is a technology maturation project for the U.S. National Aeronautics and Space Administration to provide enabling technology for lunar and planetary surface operations (LPSO). The CRUX will have 10 instruments, a data handling function (Mapper - with features of data subscription, fusion, interpretation, and publication through geographical information system [GIs] displays), and a decision support system DSS) to provide information needed to plan and conduct LPSO. Six CRUX instruments are associated with an instrumented drill to directly measure regolith properties (thermal, electrical, mechanical, and textural) and to determine the presence of water and other hydrogen sources to a depth of about 2 m (Prospector). CRUX surface and geophysical instruments (Surveyor) are designed to determine the presence of hydrogen, delineate near subsurface properties, stratigraphy, and buried objects over a broad area through the use of neutron and seismic probes, and ground penetrating radar. Techniques to receive data from existing space qualified stereo pair cameras to determine surface topography will also be part of the CRUX. The Mapper will ingest information from CRUX instruments and other lunar and planetary data sources, and provide data handling and display features for DSS output. CRUX operation will be semi-autonomous and near real-time to allow its use for either planning or operations purposes.

Moon↗

Microstructure and Mechanical Properties of the AA7075 Tube Fabricated using Shear Assisted Processing and Extrusion (ShAPE)

Shear Assisted Processing and Extrusion (ShAPE) experimental setup and tooling were adopted for extruding thin-walled AA7075 aluminum tube from as-cast non-homogenized billet material in a single run. The mechanical and microstructural characterizations were performed on the extrudate in the as-extruded condition without subsequent heat treating. It was shown that the ShAPE process developed a significantly refined microstructure with uniform and almost equiaxed grain structure on both hoop and axial cross-sections of the extrudate as well as through the thickness of the material. The pole figures and inverse pole figures of the EBSD data showed an strong shear texture development, and it was found out that axial shear is the dominant deformation mechanism in the regions near the inner surface of the tube, while combined axial and torsional shears are the two dominant modes of deformation near the outer surface of the extrudate. As for the mechanical properties, there was an increase of 150% and 73% in the yield and ultimate strengths of the tube produced using ShAPE process, respectively, and a 18% decrease in maximum uniform plastic elongation compared to the conventionally extruded AA7075-O tube.

Shear Assisted Processing and Extrusion, Friction ↗

Analysis of convection heat transfer on multiscale rough superhydrophobic and liquid infused surfaces

Multiscale rough superhydrophobic or slippery liquid infused porous surfaces have gained much interest in recent years for their improved transport phenomena properties. While there have been several studies on drag reduction and condensation on non-wetting surfaces, convection heat transfer that is important in many thermal and thermochemical applications has not been addressed systematically. Here, this article utilizes a fractal description of rough surface topographies to develop analytical models for the Nusselt number and the thermal hydraulic factor for fluid flow and heat transfer inside a cylinder with non-wetting surfaces. For air-infused superhydrophobic surfaces, the model considers the dynamic stability of the air/fluid interface in the asperities. Using the analytical formulations and the stability criteria, systematic studies are presented on the effects of the fractal surface parameters, cylinder radius and Reynolds number on the convective heat transfer characteristics, from which surface texture design maps are developed for maximizing the convection heat transfer. It is shown that multiscale non-wetting surfaces are most effective in the range of lower Reynolds number and small cylinder radius for achieving the best convective heat transfer and thermal hydraulic performance. Applying the models to actual non-wetting surface topographies fabricated using electrodeposition and chemical etching, it is shown that contrary to prevailing notion, superhydrophobicity, characterized by the highest contact angles, does not always lead to the maximum convective heat transfer performance, and that under certain fluid flow conditions, hydrophobic surfaces may offer a greater thermal performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sensory characterization of a ready-to-eat sweetpotato breakfast cereal by descriptive analysis

The sweetpotato [Ipomoea batatas (L.) Lam], an important industry in the United States, has been selected as a candidate crop to be grown on future long-duration space missions by NASA. Raw sweetpotato roots were processed into flour, which was used to formulate ready-to-eat breakfast cereal (RTEBC). Twelve trained panelists evaluated the sensory attributes of the extruded RTEBC using descriptive analysis. The samples were significantly different (P<0.05) for all attributes. Twelve perceived sensory attributes, which could be used to differentiate the appearance, texture, and flavor of sweetpotato RTEBC, were described. The data could be used to optimize the RTEBC and for designing studies to test its consumer acceptance.

NASA Discipline Life Support Systems↗

Connecting Lunar Meteorites to Source Terrains on the Moon

The number of named stones found on Earth that have proven to be meteorites from the Moon is approx. 180 so far. Since the Moon has been mapped globally in composition and mineralogy from orbit, it has become possible to speculate broadly on the region of origin on the basis of distinctive compositional characteristics of some of the lunar meteorites. In particular, Lunar Prospector in 1998 [1,2] mapped Fe and Th at 0.5 degree/pixel and major elements at 5 degree/pixel using gamma ray spectroscopy. Also, various multispectral datasets have been used to derive FeO and TiO2 concentrations at 100 m/pixel spatial resolution or better using UV-VIS spectral features [e.g., 3]. Using these data, several lunar meteorite bulk compositions can be related to regions of the Moon that share their distinctive compositional characteristics. We then use EPMA to characterize the petrographic characteristics, including lithic clast components of the meteorites, which typically are breccias. In this way, we can extend knowledge of the Moon's crust to regions beyond the Apollo and Luna sample-return sites, including sites on the lunar farside. Feldspathic Regolith Breccias. One of the most distinctive general characteristics of many lunar meteorites is that they have highly feldspathic compositions (Al2O3 approx. 28% wt.%, FeO <5 wt.%, Th <1 ppm). These compositions are significant because they are similar to a vast region of the Moon's farside highlands, the Feldspathic Highlands Terrane, which are characterized by low Fe and Th in remotely sensed data [4]. The meteorites provide a perspective on the lithologic makeup of this part of the Moon, specifically, how anorthositic is the surface and what, if any, are the mafic lithic components? These meteorites are mostly regolith breccias dominated by anorthositic lithic clasts and feldspathic glasses, but they do also contain a variety of more mafic clasts. On the basis of textures, we infer these clasts to have formed by large impacts that excavated and mixed rocks from depth within the lunar crust and possibly the upper mantle. One of the key questions is whether the mafic materials are ferroan or magnesian, which remote sensing does not clearly distinguish, and if mafic, whether they might contain mantlederived components such as olivine (dunite). Many but not all have mainly ferroan mafic components, consistent with a ferroan crustal source that is complementary to the ferroan anorthositic suite and that represents primary magma-ocean-derived feldspathic crust. Meteorites such as ALH 81005 [5] and Shişr 161 [6], however, contain coarse-grained magnesian mafic clasts (Fig. 1a) derived from deeply seated and melted material associated with impact basins. Comparison to LP gamma-ray data [2] supports an origin for magnesian feldspathic meteorites such as these (e.g., Shişr 161) as shown in Fig. 1b. Sayh al Uhaymir (SaU) 169. Another distinctive but much less common composition is represented by relatively mafic impact-melt breccia that is rich in incompatible elements known as KREEP. These meteorites can be related to the western nearside Procellarum KREEP Terrane, especially through a combination of Fe and Th contents. Among the most enriched is SaU 169, which has been related to high- Th impact-melt breccia found at the Apollo 12 site [7]. Through detailed EPMA and ion microprobe analysis we have shown that these two rock types are related in age and origin.

Jolliff, B. L.↗

High-Energy X-Ray Diffraction Microscopy in Materials Science

High-energy diffraction microscopy (HEDM) is an implementation of three-dimensional X-ray diffraction microscopy. HEDM yields maps of internal crystal orientation fields, strain states, grain shapes and locations as well as intragranular orientation distributions, and grain boundary character. Because it is nondestructive in hard materials, notably metals and ceramics, HEDM has been used to study responses of these materials to external fields including high temperature and mechanical loading. Currently available sources and detectors lead to a spatial resolution of ~1 μm and an orientation resolution of <0.1°. With the penetration characteristic of high energies ( E ≥ 50 keV), sample cross-section dimensions of ~1 mm can be studied in materials containing elements across much of the Periodic Table. This review describes hardware and software associated with HEDM as well as examples of applications. Overall, these applications include studies of grain growth, recrystallization, texture development, orientation gradients, deformation twinning, annealing twinning, plastic deformation, and additive manufacturing. We also describe relationships to other X-ray-based methods as well as prospects for further development.

36 MATERIALS SCIENCE↗

Boundary characterization using 3D mapping of geometrically necessary dislocations in AM Ta microstructure

Additive manufacturing (AM) of high strength metallic materials produces microstructures and defects that deviate substantially from those created through conventional manufacturing methods. It has recently been demonstrated that with application of extreme energy densities, a high-temperature refractory metal, tantalum (Ta), can be printed to a fully dense state with exceptionally low porosity. Here we employ a combination of three-dimensional electron backscattered diffraction (EBSD) TriBeam technology and crystallographic geometrically necessary dislocation (GND) theory to characterize the microstructure and defect boundaries of this unusual AM product. Two-dimensional (2D) EBSD and these three-dimensional (3D) measurements indicate that the microstructure of AM Ta is highly oriented <111> along the build direction, yet at the same time contains large crystallographic orientation gradients that span mm’s across the build. Crystallographic GND density analysis of the 3D microstructure reveals that highly misoriented subboundaries exist within this strongly textured microstructure that have large dislocation densities of 1×10 16 m –2 , just as large as those comprising the high-angle grain boundaries (HAGBs) in the same material. The 3D crystallographic GND density mapping reveals these subboundaries are part of a complex, finely spaced network that extends throughout the entire microstructure. Here, the orientation of these boundaries can be related to the scan strategy used during printing. TEM measurements corroborate an extremely high dislocation density at the microscale and indicate a cell-like dislocation network structure existing in the AM Ta at the sub-μm scale.

36 MATERIALS SCIENCE↗

Correlation of critical current density to quasi-biaxial texture and grain boundary cleanliness in fully dense Bi-2212 wires

The distinctive quasi-biaxial texture of Bi 2 Sr 2 CaCu 2 O x (Bi-2212) plays an important role in enabling high critical current density ($J_c$) in Bi-2212 round wires (RWs). Here we studied three over pressure heat treated wires with $J_c$ varying by a factor of ~10, all being fully dense. Using electron backscatter diffraction, we observed the differences in biaxial texture in these three wires. Transmission electron microscopy also revealed differences in grain boundary (GB) cleanliness and connectivity. These analyses showed that high $J_c$ is unambiguously correlated to the best biaxial texture, which is in turn correlated to slow cooling from the liquid melt into solid Bi-2212. However, at 4.2 K, there is a negligible difference in intragrain pinning in the three wires, suggesting that the $J_c$ variation by a factor of ~10 is primarily due to variable filament and intergrain connectivity. In this work, the principal determinants of intergrain connectivity is the quasi-biaxial texture and GB cleanliness. Overall, $J_c$ optimization of the Bi-2212 RW is a complex multi-variable process, but this study shows that maximizing the biaxial texture quality is an important first step in such an optimization process.

36 MATERIALS SCIENCE↗

Production of Creep-Resistant FeCrAl-ODS

Four ODS FeCrAl alloys with base alloy composition Fe-16Cr-4Al-2Mo-0.2Y (wt.%) were mechanically alloyed with minor additions of CeO 2 and Y 2 O 3 additions and were successfully extruded into rectangular-shaped bars. Two oxide compositions were explored, which were designated NC with oxide addition of 0.5CeO 2 plus 0.2Yin solution of the base alloy powder and PC with additions of 0.5CeO 2 and 0.7Y 2 O 3 to elevate the O level. The microstructure of both alloys revealed by SEM and EBSD to consist of very small grains with sizes of ~450-520 nm and weak texture components. Sub-size tensile specimens fabricated from both alloys were tensile tested from room temperature to 800ºC. The results for both alloys from room temperature to 400ºC showed very high strengths, but low ductilities, especially uniform strain. From 500ºC to 800ºC, the strengths decreased rapidly, and the ductilities increased significantly. The reason for the rapid decreases in tensile strengths above 500ºC for both alloys is not clear, but will require advanced characterization techniques including atom probe tomography, to determine the size and number density of the nano-size oxide particles, and TEM/EFTEM, for investigating the dispersion of nano-size oxide particles on grain boundaries to assess the Zener grain boundary pinning effect, which will hinder grain coarsening at high temperatures that may enhance the Hall Petch strengthening mechanism.

36 MATERIALS SCIENCE↗

BOREAS TE-2 NSA Soil Lab Data

This data set contains the major soil properties of soil samples collected in 1994 at the tower flux sites in the Northern Study Area (NSA). The soil samples were collected by Hugo Veldhuis and his staff from the University of Manitoba. The mineral soil samples were largely analyzed by Barry Goetz, under the supervision of Dr. Harold Rostad at the University of Saskatchewan. The organic soil samples were largely analyzed by Peter Haluschak, under the supervision of Hugo Veldhuis at the Centre for Land and Biological Resources Research in Winnipeg, Manitoba. During the course of field investigation and mapping, selected surface and subsurface soil samples were collected for laboratory analysis. These samples were used as benchmark references for specific soil attributes in general soil characterization. Detailed soil sampling, description, and laboratory analysis were performed on selected modal soils to provide examples of common soil physical and chemical characteristics in the study area. The soil properties that were determined include soil horizon; dry soil color; pH; bulk density; total, organic, and inorganic carbon; electric conductivity; cation exchange capacity; exchangeable sodium, potassium, calcium, magnesium, and hydrogen; water content at 0.01, 0.033, and 1.5 MPascals; nitrogen; phosphorus: particle size distribution; texture; pH of the mineral soil and of the organic soil; extractable acid; and sulfur. These data are stored in ASCII text files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Veldhuis, Hugo↗

Quality comparison of hydroponic tomatoes (Lycopersicon esculentum) ripened on and off vine

There is a general belief that the quality of tomatoes ripened on vine is better than tomatoes ripened off the vine, influencing among other parameters, the price of this commodity. We compared the quality of hydroponic tomatoes ripened on and off vine by chemical, physical, and sensory evaluation to find what attributes are affected and to what extent. Lycopene, beta-carotene, total and soluble solids, moisture content, ascorbic acid, acidity, pH, texture, and color were analyzed. Tomatoes ripened on vine had significantly more lycopene, beta-carotene, soluble and total solids, higher a* and lower L*, and were firmer. However, a 100-judge panel rated only the color and overall liking of the vine-ripened tomatoes as more intense than the fruit ripened off vine. Therefore, the chemical and physical differences were mostly not large enough to influence the panelist's perception. The characterization of tomatoes ripened on and off vine may help to guide post-harvest handling and treatment and to improve the quality of tomatoes ripened off vine.

Non-NASA Center↗

In-situ integrated processing and characterization of thin films of high temperature superconductors, dielectrics and semiconductors by MOCVD

In this strategy of depositing the basic building blocks of superconductors, semiconductors, and dielectrics having common elements, researchers deposited superconducting films of Y-Ba-Cu-O, semiconductor films of Cu2O, and dielectric films of BaF2 and Y2O3 by metal oxide chemical vapor deposition (MOCVD). By switching source materials entering the chamber, and by using direct writing capability, complex device structures like three terminal hybrid semiconductor/superconductor transistors can be fabricated. The Y-Ba-Cu-O superconducting thin films on BaF2/YSZ substrates show a T(sub c) of 80 K and are textured with most of the grains having their c-axis or a-axis perpendicular to the substrate. Electrical characteristics as well as structural characteristics of superconductors and related materials obtained by x-ray deffraction, electron microscopy, and energy dispersive x-ray analysis are discussed.

Singh, R.↗

In-situ integrated processing and characterization of thin films of high temperature superconductors, dielectrics and semiconductors by MOCVD

In this strategy of depositing the basic building blocks of superconductors, semiconductors, and dielectric having common elements, researchers deposited superconducting films of Y-Ba-Cu-O, semiconductor films of Cu2O, and dielectric films of BaF2 and Y2O3 by metal oxide chemical vapor deposition (MOCVD). By switching source materials entering the chamber, and by using direct writting capability, complex device structures like three-terminal hybrid semiconductors/superconductors transistors can be fabricated. The Y-Ba-Cu-O superconducting thin films on BaF2/YSZ substrates show a T(sub c) of 80 K and are textured with most of the grains having their c-axis or a-axis perpendicular to the substrate. Electrical characteristics as well as structural characteristics of superconductors and related materials obtained by x-ray defraction, electron microscopy, and energy dispersive x-ray analysis are discussed.

Singh, R.↗

Microstructural and Mechanical Property Characterization of Shear Formed Aerospace Aluminum Alloys

Advanced manufacturing processes such as near-net-shape forming can reduce production costs and increase the reliability of launch vehicle and airframe structural components through the reduction of material scrap and part count and the minimization of joints. The current research is an investigation of the processing-microstructure-property relationships for shear formed cylinders of the Al-Cu-Li-Mg-Ag alloy 2195 for space applications and the Al-Cu-Mg-Ag alloy C415 for airframe applications. Cylinders which had undergone various amounts of shear-forming strain were studied to correlate the grain structure, texture, and mechanical properties developed during and after shear forming.

Troeger, Lillianne P.↗

Characterization of low thermal conductivity PAN-based carbon fibers

The microstructure and surface chemistry of eight low thermal conductivity (LTC) PAN-based carbon fibers were determined and compared with PAN-based fibers heat treated to higher temperatures. Based on wide-angle x ray diffraction, the LTC PAN fibers all appear to have a similar turbostratic structure with large 002 d-spacings, small crystallite sizes, and moderate preferred orientation. Limited small-angle x ray scattering (SAXS) results indicate that, with the exception of LTC fibers made by BASF, the LTC fibers do not have well developed pores. Transmission electron microscopy shows that the texture of the two LTC PAN-based fibers studied (Amoco T350/23X and /25X) consists of multiple sets of parallel, wavy, bent layers that interweave with each other forming a complex three dimensional network oriented randomly around the fiber axis. X ray photoelectron spectroscopy (XPS) analysis finds correlations between heat treated temperatures and the surface composition chemistry of the carbon fiber samples.

Katzman, Howard A.↗

Through-Thickness Microstructure Characterization in a Centrifugally Cast Austenitic Stainless Steel Nuclear Reactor Primary Loop Pipe Using Time-of-Flight Neutron Diffraction

The US code of Federal Regulations mandates regular inspection of centrifugally cast austenitic stainless steel pipe, commonly used in primary cooling loops in light-water nuclear power plants. These pipes typically have a wall thickness of ~8 cm. Unfortunately, inspection using conventional ultrasonic techniques is not reliable as the microstructure strongly attenuates ultrasonic waves. Work is ongoing to simulate the behavior of acoustic waves in this microstructure and ultimately develop an acoustic inspection method for reactor inspections. In order to account for elastic anisotropy in the material, the texture in the steel was measured as a function of radial distance though the pipe wall. Experiments were conducted on two 10 × 12.7 × 80 mm radial sections of a cast pipe using neutron diffraction scans of 2 mm slices using the HIPPO time-of-flight neutron diffractometer at the Los Alamos Neutron Science Center (LANSCE, Los Alamos, NM, USA). Strong textures dominated by a small number of austenite grains with their (100) direction aligned in the radial direction of the pipe were observed. ODF analysis indicated that up to 70% of the probed volume was occupied by just three single-grain orientations, consistent with grain sizes of almost 1 cm. Texture and phase fraction of both ferrite and austenite phases were measured along the length of the samples. These results will inform the development of a more robust diagnostic tool for regular inspection of this material.

42 ENGINEERING↗

Developing an experimental-computational framework to investigate the deformation mechanisms and mechanical properties of Al-8Ce-10Mg alloys at micro and macroscales

There is a promising future for the use of aluminum-cerium-magnesium alloys in a broad range of applications, including devices that operate at high temperatures. With cerium currently considered a waste product of rare earth mining validation studies of possible applications are essential to reduce the environmental waste. Here, a computational-experimental framework is developed to investigate the role both the intermetallic and matrix have on the mechanical properties of these alloys. A set of experiments, including SEM/EBSD imaging, nanoindentation, in-situ SEM tensile testing, and in-situ SEM-DIC tests are performed to characterize the microstructure and mechanical properties of these alloys. Furthermore, the elastic, plastic, and failure deformation mechanisms of the microstructure, and their correlation with the bulk scale mechanical properties are investigated. Experimental results are also used to calibrate parameters for a crystal plasticity finite element model, by performing a computational framework that minimizes the error between the computational and experimental results. This model is then utilized to investigate how the area percentage of intermetallics and the crystallographic texture control the mechanical properties of the alloy. Simulation results show that an increase in the percentage of intermetallics increase the strength but decrease the ductility of the alloy. Also, a change in material texture improves strength and reduces damage that leads to material failure. The development of the crystal plasticity model, as discussed in this work, opens opportunities for future investigations of similar aluminum-cerium-magnesium alloys.

36 MATERIALS SCIENCE↗