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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Table and Charts of Equilibrium Normal-shock Properties for Pure Hydrogen with Velocities to 70 km/sec. Revised.

Errors found in the original edition are corrected. Refinement was made in procedures for solving the conservation relations for an incident (moving), standing, and reflected normal shock, as well as in computational methods for determining thermochemical-equilibrium hydrogen properties. A six-species hydrogen model replaces the original four-species model, and the heat of formation and spectroscopic constants used in this six-species model are listed in appendix A. In appendix B, comparisons are made between a number of methods for determining equilibrium thermodynamic properties for hydrogen for several values of pressure and temperatures to 50000 K. A comparison is also performed between the present method and a second method for determining thermodynamic properties and flow velocity behind an incident shock into pure hydrogen and behind a reflected shock.

Miller, C. G., III↗
NASA NTRS1977

Gaseous sodium sulfate formation in flames and flowing gas environments

Formation of Na2SO4(g) in flames and hot flowing gas systems was studied by high pressure, free-jet expansion, modulated molecular beam mass spectrometric sampling. Fuel-lean CH4-O2 flames doped with SO2, H2O and NaCl yielded the gaseous Na2SO4 molecule in residence times of less than one millisecond. Intermediate species NaSO2(g) and NaSO3(g) were also observed and measured. Composition profiles were obtained for all reaction products. Nonflame flowing gas experiments showed that Na2SO4 and NaSO3 gaseous molecules were formed at 1140 C in mixtures of O2, H2O(g), SO2 and NaCl(g). Experimental results are compared with calculated equilibrium thermodynamic predictions.

Stearns, C. A.↗
NASA NTRS1976

The relation between carbon monoxide emission and visual extinction in cloud L134

Emission from the J = 1-0 transition of carbon monoxide has been mapped over an area of 40 by 55 arcmin in cloud L134, and visual extinctions over the entire cloud have been obtained by means of star counts. Line intensities of at least 2 K are observable down to an extinction level of about one magnitude. From observations of the J = 1-0 transition of the (C-13)O isotopic species at 18 locations in the cloud, a linear correlation is found between the local thermodynamic equilibrium (LTE) column densities of (C-13)O and magnitudes of visual extinction.

Tucker, K. D.↗
NASA NTRS1977

Can the ordinary chondrites have condensed from a gas phase

The conditions under which ordinary chondrites containing iron in three different chemical states can form in thermodynamic equilibrium with a gas phase are calculated. Hydrogen depletion factors of 100-1000 are obtained and the formation of liquid condensates from residual gases occurs at pressures (prior to hydrogen depletion) of roughly equal to or greater than 1 atm.

Herndon, J. M.↗
NASA NTRS1977

Gaseous sodium sulfate formation in flames and flowing gas environments

Formation of Na2SO4(g) in flames and hot flowing gas systems was studied by high pressure, free-jet expansion, modulated molecular beam mass spectrometric sampling. Fuel-lean CH4-O2 flames doped with SO2, H2O and NaCl yielded the gaseous Na2SO4 molecule in residence times of less than one millisecond. Intermediate species NaSO2(g) and NaSO3(g) were also observed and measured. Composition profiles were obtained for all reaction products. Non-flame flowing gas experiments showed that Na2SO4 and NaSO3 gaseous molecules were formed at 1140 C in mixtures of O2, H2O(g), SO2 and and NaCl(g). Experimental results are compared with calculated equilibrium thermodynamic predictions.

Stearns, C. A.↗
NASA NTRS1977

Formation of Na2SO4 and K2SO4 in flames doped with sulfur and alkali chlorides and carbonates

High pressure, free-jet expansion, mass spectrometric sampling was used to identify directly and to measure reaction products formed in doped methane-oxygen flames. Flames were doped with SO2 or CH3SH and sodium or potassium chlorides or carbonates. Gaseous NA2SO4 or K2S04 molecules were formed in residence times on the order of msec for each combination of dopants used. Composition profiles of combustion products were measured and compared with equilibrium thermodynamic calculations of product composition.

Fryburg, G. C.↗
NASA NTRS1978

Temperature distributions of a cesium-seeded hydrogen-oxygen supersonic free jet

The hydrogen-oxygen plasma was generated at combustion chamber pressures ranging from 0.5 to 2.0 megapascals and for various seed ratios (1 to 10 percent). The plasma was observed as the atmospheric exhaust from a Mach 2 rocket test facility. Transverse profiles of the absolute integrated intensity were measured with the optically thin CsI lines (0.5664 and 0.5636 microns) at a range of axial positions downstream of the 5-cm-diameter combustor nozzle exit. Radial profiles of the emission coefficient were obtained from the measured transverse profiles of intensity by Abel inversion. Temperatures were then determined from the emission coefficients for conditions of local thermodynamic equilibrium using particle densities generated by a two-dimensional free jet computer program. Temperature results show the inherent effects of compression and expansion pressure waves characteristic of a free jet exiting from a supersonic nozzle.

Wang, S. Y.↗
NASA NTRS1977

Thermal radiation model for solid rocket booster plumes

The Monte Carlo method is used to model the thermal radiation field of the plumes for the dual solid rocket boosters astride the Space Shuttle launch configuration. The model accounts for axial and radial variations in radiative properties of the plumes. The plumes are considered to be composed of a dispersion of aluminum oxide (Al2O3) particles immersed in the gaseous products of combustion. The principal emitting gases are taken to be CO, CO2, H2O, and HCl. The thermal model is based on local thermodynamic equilibrium. Scattering of radiant energy by Al2O3 particles may be treated as isotropic or anisotropic. Sample radiant heating rates to the base region of the Space Shuttle are shown. Space Shuttle geometries are simulated as combinations of quadric surfaces.

Watson, G. H.↗
NASA NTRS1977

Interpretation of Beta Lyrae. III - A study of the disk around the secondary component

Light curves of Beta Lyrae available in the far-ultraviolet, visual, and infrared regions of the spectrum at numerous phases in eclipse are analyzed in order to investigate the physical and radiative nature of the disk surrounding the secondary component. The results of this analysis together with those of other investigators lead to the proposal that the outer regions of the disk are dominated by free electrons. This electron-scattering envelope is most likely the source of infrared radiation as well as the cause of the observed polarization. However, the radiation in the region from the optical to the far-ultraviolet comes mainly from submerged layers where local thermodynamic equilibrium prevails. These layers represent the photosphere of either the disk or the secondary component itself.

Brown, D. A.↗
NASA NTRS1977

High-temperature condensates in carbonaceous chondrites

Equilibrium thermodynamic calculations of the sequence of condensation of minerals from a cooling gas of solar composition play an important role in explaining the mineralogy and trace element content of different types of inclusions in carbonaceous chondrites. Group IV B iron meteorites and enstatite chondrites may also be direct condensates from the solar nebula. Condensation theory provides a framework within which chemical fractionations between different classes of chondrites may be understood.

Grossman, L.↗
NASA NTRS1977

Formation of Na2SO4 and K2SO4 in flames doped with sulfur and alkali chlorides and carbonates

High pressure, free-jet expansion, mass spectrometric sampling was used to identify directly and to measure reaction products formed in doped methane-oxygen flames. Flames were doped with SO2 or CH3SH and sodium or potassium chlorides or carbonates. Gaseous Na2SO4 or K2SO4 molecules were formed in residence times on the order of 1 msec for each combination of dopants used. Composition profiles of combustion products were measured and compared with equilibrium thermodynamic calculations of product composition.

Fryburg, G. C.↗
NASA NTRS1978

Radiative shock dynamics. II - Hydrogen continua

The interaction between radiation and a shock wave propagating through a stellar atmosphere is investigated. Departures from local thermodynamic equilibrium (LTE) are permitted in the first two levels of a 10-level hydrogen atom; levels 3-10 are in LTE. A piston moving at constant velocity into the bottom of the atmosphere drives a shock wave. This shock produces precursor radiation that diffuses through the gas well ahead of the shock and causes a mild luminosity flash in the emergent Balmer and free-free radiation when it reaches the surface. The precursor wave deposits a large amount of radiative energy in the outer layers of the atmosphere, initiating a radiation-induced pressure wave. The process of energy transfer from the radiation field to the compression wave is similar to the Eddington valve mechanism which drives stellar pulsations. Material is accelerated outward by the radiation-induced wave; eventually it free-falls inward, hits the quasistationary atmosphere, and forms an accretion shock. The piston driven shock is weakened by radiative energy losses. When it reaches the surface, the shock is invisible in the continuum radiation.

Klein, R. I.↗
NASA NTRS1978

The Stratospheric and Mesospheric Sounder (SAMS) experiment

Thermal emission and solar resonance fluorescence from the atmospheric limb are reported. Global measurements are made of radiation from the molecular species. The gas correlation spectroscopy technique based on the use of gas cells to select emission from chosen spectral lines or from particular parts of spectral lines is used. The source function and departure from the thermodynamic equilibrium between 80 and 130 kilometers associated with CO2 emission bands were investigated. The zonal wind velocity component along the line of sight is measured.

Drummond, J. R.↗
NASA NTRS1979

A marching method for calculating line and continuum radiation in high energy flow fields

A method is presented for calculating nongrey radiative fluxes and intensities in a highly ionized, low temperature plasma with extreme line broadening. The method was developed to study radiative heating phenomena in the mass-injected hypersonic shock-layer environments characteristic of outer planet atmospheric entry, although it is not limited to such studies. The radiative properties model assumed local thermodynamic equilibrium and used standard continuum and molecular band models. The atomic line model, however, used a frequency-marching method for the frequency integration, which not only accounted completely for line overlapping (reabsorption) effects, but compared favorably in economy with the best equivalent-width methods. An assessment of hydrogen line-far-wing treatments, with recommendations for engineering models, is also presented.

Bolz, C. W., Jr.↗
NASA NTRS1979

Spray combustion models - A review

Due to recent theoretical and experimental advances, modeling spray combustion can be contemplated as a means of supplementing traditional cut and try combustor development methods. This review describes spray models that are currently being developed and their validation. The review is limited to steady, turbulent two- and three-dimensional systems typified by furnaces and gas turbine combustors. Both locally homogeneous flow models, where the phases are assumed to be in kinematic and thermodynamic equilibrium at each point in the flow, and more complete two-phase flow models, which allow for finite rate processes between the phases, are considered.

Faeth, G. M.↗
NASA NTRS1979

The 63 micron radiation field in the earth's thermosphere and its influence on the atomic hydrogen temperature

The thermal escape of hydrogen from the earth's atmosphere is strongly affected by its temperature at the exobase. It has been suggested recently that the hydrogen temperature might be significantly lower than the thermospheric temperature as a result of a collisional exchange of energy with atomic oxygen. The tendency is to cool the hydrogen since the energy of the excited 3P1 level of oxygen can be lost from the atmosphere via magnetic dipole emission of the micron line (3P2-3P1). A detailed calculation of the net cooling effect as a function of altitude throughout the thermosphere is presented. The calculations have been performed for both day and night conditions and for periods of maximum and minimum solar activity conditions. It is found that its effect on Delta T/T varies from a very small value to a maximum of about 3%. The theoretical framework for describing deviations of the 63 micron emission from local thermodynamic equilibrium is given and it is shown that these effects can cause the emission to be reduced by as much as 40% near 500 km.

Durrance, S. T.↗
NASA NTRS1979

Effects of probe shape change on flow phenomena during Jovian entry

The effects of probe shape change on the flow phenomena around a Jovian entry body is investigated. The initial body shapes considered are: 45-degree sphere cone, 35-degree hyperboloid, and 45-degree ellipsoid. The radiating shock-layer flow is assumed to be axisymmetric, inviscid, and in chemical and local thermodynamic equilibrium. The radiative transfer is calculated with an existing nongray radiation model that accounts for molecular band, atomic line, and continuum transitions. The results indicate that the shock-standoff distance, shock temperature and density, wall pressure distribution and radiative heating to the body are influenced significantly because of the probe shape change. The effect of shape change on radiative heating of the afterbody was considerably larger for the sphere cone and ellipsoid than for the hyperboloid. For the peak heating conditions, the net radiative heating to the body was found to be highest for the ellipsoid

Tiwari, S. N.↗
NASA NTRS1980

Wake flowfields for Jovian probe

The wake flow field developed by the Galileo probe as it enters the Jovian atmosphere was modeled. The wake produced by the probe is highly energetic, yielding both convective and radiative heat inputs to the base of the probe. A component mathematical model for the inviscid near and far wake, the viscous near and far wake, and near wake recirculation zone was developed. Equilibrium thermodynamics were used for both the ablation and atmospheric species. Flow fields for three entry conditions were calculated. The near viscous wave was found to exhibit a variable axial pressure distribution with the neck pressure approximately three times the base pressure. Peak wake flow field temperatures were found to be in proportion to forebody post shock temperatures.

Engel, C. D.↗