Search NASA⌕ Search

SEARCH · Search NASA

Results for “Atmospheric composition”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 415 records · Page 23

High-latitude ionospheric model - First step towards a predictive capability

In order to study the plasma density features associated with both weak and strong convection in the winter high-latitude F-region, a simple plasma convection model was combined with an ionospheric-atmospheric composition model. In a model calculation, a field tube of plasma is followed as it moves along a convection trajectory through a moving, neutral atmosphere. The altitude profiles of the ion densities are obtained by solving the appropriate continuity, momentum and energy equations, including many high-latitude processes. The result of following many such plasma field tubes is a time-dependent, three-dimensional ion density distribution for the ions NO(+), O2(+), O(+), N(+), and He(+). The high-latitude ionosphere is covered over one complete day above 42 deg N magnetic latitude, at altitudes of 160-800 km.

Schunk, R. W.↗

On the Assessment and Uncertainty of Atmospheric Trace Gas Burden Measurements with High Resolution Infrared Solar Occultation Spectra from Space by the ATMOS Experiment

The Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument is a high resolution Fourier transform spectrometer that measures atmospheric composition from low Earth orbit with infrared solar occultation sounding in the limb geometry. Following an initial flight in 1985, ATMOS participated in the Atmospheric Laboratory for Applications and Science (ATLAS) 1, 2, and 3 Space Shuttle missions in 1992, 1993, and 1994 yielding a total of 440 occultation measurements over a nine year period. The suite of more than thirty atmospheric trace gases profiled includes CO2, O3, N2O, CH4, H2O, NO, NO2, HNO3, HCl, HF, ClONO2, CCl3F, CCl2F2, CHF2Cl, and N2O5. The analysis method has been revised throughout the mission years culminating in the 'version 2' data set. The spectroscopic error analysis is described in the context of supporting the precision estimates reported with the profiles; in addition, systematic uncertainties assessed from the quality of the spectroscopic database are described and tabulated for comparisons with other experiments.

Abrams, M. C.↗

Exoplanet Transit Spectroscopy Using WFC3: WASP-12b, WASP-17b, and WASP-19b

We report an analysis of transit spectroscopy of the extrasolar planets WASP-12 b, WASP-17 b, and WASP-19 b using the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope (HST). We analyze the data for a single transit for each planet using a strategy similar, in certain aspects, to the techniques used by Berta et al., but we extend their methodology to allow us to correct for channel- or wavelength-dependent instrumental effects by utilizing the band-integrated time series and measurements of the drift of the spectrum on the detector over time. We achieve almost photon-limited results for individual spectral bins, but the uncertainties in the transit depth for the band-integrated data are exacerbated by the uneven sampling of the light curve imposed by the orbital phasing of HST's observations. Our final transit spectra for all three objects are consistent with the presence of a broad absorption feature at 1.4 microns most likely due to water. However, the amplitude of the absorption is less than that expected based on previous observations with Spitzer, possibly due to hazes absorbing in the NIR or non-solar compositions. The degeneracy of models with different compositions and temperature structures combined with the low amplitude of any features in the data preclude our ability to place unambiguous constraints on the atmospheric composition without additional observations with WFC3 to improve the signal-to-noise ratio and/or a comprehensive multi-wavelength analysis. Key words: planetary systems - techniques: photometric - techniques: spectroscopic

HST↗

Identifying Chemical Aerosol Signatures Using Optical Suborbital Observations: How Much Can Optical Properties Tell us about Aerosol Composition?

Improvements in air quality and Earth’s climate predictions require improvements of the aerosol speciation in chemical transport models, using observational constraints. Aerosol speciation (e.g., organic aerosols, black carbon, sulfate, nitrate, ammonium, dust or sea salt) is typically determined using in situ instrumentation. Continuous, routine surface network aerosol composition measurements are not uniformly widespread over the globe. Satellites, on the other hand, can provide a maximum coverage of the horizontal and vertical atmosphere but observe aerosol optical properties (and not aerosol speciation) based on remote sensing instrumentation. Combinations of satellite-derived aerosol optical properties can inform on air mass aerosol types (AMTs e.g., clean marine, dust, polluted continental). However, these AMTs are subjectively defined, might often be misclassified and are hard to relate to the critical parameters that need to be refined in models. In this paper, we derive AMTs that are more directly related to sources and hence to speciation. They are defined, characterized, and derived using simultaneous in situ gas-phase, chemical and optical instruments on the same aircraft during the Study of Emissions and Atmospheric Composition, Clouds, and Climate Coupling by Regional Surveys (SEAC4RS, US, summer of 2013). First, we prescribe well-informed AMTs that display distinct aerosol chemical and optical signatures to act as a training AMT dataset. These in situ observations reduce the errors and ambiguities in the selection of the AMT training dataset. We also investigate the relative skill of various combinations of aerosol optical properties to define AMTs and how much these optical properties can capture dominant aerosol speciation. We find distinct optical signatures for biomass burning (from agricultural or wildfires), biogenic and dust-influence AMTs. Useful aerosol optical properties to characterize these signatures are the extinction angstrom exponent (EAE), the single scattering albedo, the difference of single scattering albedo in two wavelengths, the absorption coefficient, the absorption angstrom exponent (AAE), and the real part of the refractive index (RRI). We find that all four AMTs studied when prescribed using mostly airborne in situ gas measurements, can be successfully extracted from at least three combinations of airborne in situ aerosol optical properties (e.g., EAE, AAE and RRI) over the US during SEAC4RS. However, we find that the optically based classifications for BB from agricultural fires and polluted dust include a large percentage of misclassifications that limit the usefulness of results relating to those classes. The technique and results presented in this study are suitable to develop a representative, robust and diverse source-based AMT database. This database could then be used for widespread retrievals of AMTs using existing and future remote sensing suborbital instruments/networks. Ultimately, it has the potential to provide a much broader observational aerosol data set to evaluate chemical transport and air quality models than is currently available by direct in situ measurements. This study illustrates how essential it is to explore existing airborne datasets to bridge chemical and optical signatures of different AMTs, before the implementation of future spaceborne missions (e.g., the next generation of Earth Observing System (EOS) satellites addressing Aerosol, Cloud, Convection and Precipitation (ACCP) designated observables).

Meloe S F Kacenelenbogen↗

Atmospheric Escape and Planetary Atmosphere Evolution. the Complex Role of Magnetization

Exoplanetary research is currently steered by investigations into the characteristics and evolution of their atmospheres. The fundamental inquiries encompass whether a given exoplanet possesses an atmosphere and, if so, how its attributes have evolved over time. The atmospheric composition reflects a delicate equilibrium between the inbound and outbound flows of volatiles, whether between space, surface, or between liquid and solid phases. Understanding atmospheric escape is, therefore, a critical facet of such studies. Especially, exoplanets that are relatively light and situated near their host stars are prone to substantial atmospheric loss, potentially resulting in barren celestial bodies. Thus, it becomes vital to comprehend the atmospheric responses to the host stars' activities, alongside other factors influencing atmospheric evolution. In that context, there persists a common narrative in the scientific community that frames a planetary magnetic field as a 'shield' against atmospheric escape. However, this study challenges the oversimplification of this premise, taking a closer look at the nuanced role magnetization plays in planetary atmospheric defense mechanisms. We will review the escape processes in the light of the different mechanisms and of the recent observations to highlight which processes have to carefully be taken into account.

Guillaume Gronoff↗

Structure and variations of the heterosphere

Atmospheric composition is kept almost homogeneous to a height of approximately 90 km (the homosphere) by mixing; above 100 km (the heterosphere), diffusive separation of the atmospheric constituents occurs. The heterosphere is dominated by two energy sources: solar extreme ultraviolet radiation and the solar wind. Many large variations are observed in this region and they can all be related, directly or indirectly, to variations in the intrinsic intensity of these two sources and to variations in the location of the sources relative to the observer. Atmospheric models can be successfully constructed in which the temperature and density variations are empirically related to solar and geomagnetic parameters. Some of the more recent findings concerning the structure and variations in the heterosphere are presented.

Jacchia, L. G.↗

The ultraviolet dayglow at solar maximum. III - Photoelectron-excited emissions of N2 and O

Rocket observations of the far ultraviolet dayglow spectrum near solar cycle maximum are analyzed using laboratory cross sections, atmospheric composition models, and photoelectron production models. Photoelectron-excited emissions of N2 and O are used to derive a self-consistent description of the atmosphere at solar maximum. Spectral synthesis of the N2 Lyman-Birge-Hopfield bands shows a departure of a 1Pi(q) state vibrational populations from the direct excitation theory. Observations of the N2 second positive (0, 0) 3371-A band and O I 1356-A emission indicate an exospheric temperature of 1600 K, 200 K higher than predicted by empirical models. The empirical models are also found to overestimate the O and O2 densities required to fit the data by a factor of 2 and 1.4, respectively. These results are compared to the results of an analysis of similar observations made in 1978 near solar minimum.

Meier, R. R.↗

The UARS and EOS Microwave Limb Sounder (MLS) Experiments

The Microwave Limb Sounder (MLlS) experiments obtain measurements of atmospheric composition, temperature and pressure by observations of millimeter and submillimeter-wavelength thermal emission as the instrument field-of-view is scanned through the atmospheric limb.

Microwave Limb Sounder Temperature Pressure↗

The case for a Martian origin of the shergottites. II - Trapped and indigenous gas components in EETA 79001 glass

The isotopic composition of N, Ar, Ne, and He, trapped in an uncrushed sample of the antarctic shergottite EETA 79001, was analyzed by subjecting the evacuated sample to stepped heating in the presence of 100 mtorr of oxygen. The isotopic composition of nitrogen (with the delta-N-15 value of greater than 300 percent) and the elemental ratios Ar-36/N-14 and Ar-40/N-14 were covariant along mixing lines passing through the Martian atmospheric composition. The results of this and previous analyses are consistent with a two-component nitrogen system in which about 84 ppb of trapped Martian atmospheric N is mixed in variable proportions with another, more thermally labile N component during stepped heating. The isotopic Ar-36/Ar-38 ratio of the EETA 79001 is different from that of the earth atmosphere by about 25 percent.

Wiens, R. C.↗

Processes Associated with Boundary Layer Cloud Ice Phase Precipitation in the High Southern Latitudes (Final Technical Report)

This is a final technical report for DOE Award No. DE-SC0018995. Using data collected during the MARCUS deployment of the 2nd ARM mobile facility, this project sought to address the following scientific questions: 1. What are the conditions that govern phase partitioning in supercooled boundary layer clouds over the high latitude Southern Oceans? 2. To what extent are supercooled mixed phase clouds responsible for the high cloud fractions over the Southern Ocean and do these mixed phase clouds contribute to the model biases in absorbed shortwave radiation? 3. Can the cloud properties and phase partitioning over the Southern Ocean be linked to the underlying aerosol environment? 4. How do the aerosol properties at the surface vary spatially and seasonally over the high latitude Southern Ocean and what processes control these features? 5. How well defined are the atmospheric compositional boundaries between Southern Ocean marine, Antarctic free tropospheric, and Antarctic surface airmasses, and how does this influence the chemistry and physics of the Southern Ocean atmosphere? In this project we published three peer review journal articles that address these questions.

54 ENVIRONMENTAL SCIENCES↗

Dispersion and Aging of Volcanic Aerosols after the La Soufriere Eruption in April 2021

Volcanic aerosols change the atmospheric composition and thereby affect weather and climate. Aerosol dynamic processes such as nucleation, condensation, and coagulation modify the shape, size, and mass of aerosol particles, which influence their atmospheric lifetime and radiative properties. Nevertheless, most models omit these processes for ash particles. In this work, we explore the ash aerosol aging and sulfate production during the first 4 days following the 2021 La Soufrière (St. Vincent) eruption with the ICON-ART model (ICOsahedral Nonhydrostatic model with Aerosol and Reactive Trace gases). Online coupling of ICON-ART with a one-dimensional volcanic plume model calculates volcanic emission, which makes it possible to resolve the different eruption phases of the noncontinuous La Soufrière eruption. We compared our simulated aerosol distribution and composition with observations from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument, the Multiangle Imaging SpectroRadiometer (MISR) Research Aerosol (RA) Algorithm, and the Barbados Cloud Observatory (BCO). We show that online coupling is essential to adequately model the emissions and plume development close to the volcano. The modeled aerosol aging is in very good agreement with observations from MISR near the emission source and with CALIOP at larger distances. Furthermore, particle aging occurs faster in the troposphere than in the stratosphere due to the availability of water vapor and OH, but a layer of coated ash appears at the plume top due to faster oxidation of SO2 and lofting by aerosol-radiation interaction. This paper gives the first direct comparison of aerosol aging in volcanic eruption plumes between simulations and observations

volcanic aerosols↗

Models of Venus neutral upper atmosphere - Structure and composition

Models of the Venus neutral upper atmosphere, based on both in situ and remote sensing measurements, are provided for the height interval from 100 to 3500 km. The general approach in model formulation was to divide the atmosphere into three regions: 100-150 km, 150-250 km, and 250-3500 km. Boundary conditions at 150 km are consistent with both drag and mass spectrometer measurements. A paramount consideration was to keep the models simple enough to be used conveniently. Available observations are reviewed.

Keating, G. M.↗

Remote sensing of the earth's atmosphere by infrared absorption spectroscopy - An update of the ATMOS program

The NASA's Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment was designed to address the requirements of the remote sensing of atmospheric composition on a four-dimensional basis (latitude, longitude, altitude, and time), necessary for understanding and predicting the effect of changes on the chemical balance of the atmosphere. This paper describes the ATMOS program, overviews the ATMOS instrument and its performance, and presents the results obtained during its first flight as part of the Spacelab 3 Space Shuttle mission (April 29 through May 6, 1985). Also discussed are prospects for further missions.

Zander, R.↗

An Advanced Open-Source Platform for Air Quality Analysis, Visualization, and Prediction

Ambient air pollution is the largest environmental health risk factor, leading to several million premature deaths globally per year. The challenge of combating poor air quality is exacerbated by growing urban populations, changing emissions, and a warming climate. While there have been many advances monitoring and modeling of atmospheric composition, reflected in the dramatic increase in archived Earth Observations, there is no single measurement or method that alone can provide an accurate depiction of the entire atmosphere. The rapidly growing collections of observational and modeling data require us to be smarter about what data to include, and how such data is used. In recent years, NASA has invested significantly in advancing the concepts for Analytics Collaborative Framework (ACF) [5] and New Observing Strategies (NOS) [4] to tackle our software infrastructure need for harmonized data management and dynamic acquisition of diverse measurements for on-demand, interactive, multivariate analysis, and access [3]. It is not enough to have a big data, standalone analytics solution; it is critical that we start integrating data from remote sensing, modeling, and in-situ networks in a harmonized manner that enables timely and data-driven decision-making for air quality management. This work presents the design and development of an Air Quality Analytics Collaborative Framework (AQ ACF), as part of NASA’s Advanced Information Systems Technology (AIST) effort, to establish a data, machine-learning, and numerically driven platform for air quality analysis, visualization, and prediction.

Liu, Qian↗

Pioneer Venus 1978

An orbiter and a multiprobe spacecraft will be sent to Venus in 1978 to conduct a detailed examination of the planet's atmosphere and weather. The spin-stabilized multiprobe spacecraft consists of a bus, a large probe and three identical small probes, each carrying a complement of scientific instruments. The large probe will conduct a detailed sounding of the lower atmosphere, obtaining measurements of the clouds, atmospheric structure, wind speed, and atmospheric composition. Primary emphasis will be placed on the planet's energy balance and clouds. The three small probes will provide information on the circulation pattern of the lower atmosphere. The probe bus will provide data on the upper atmosphere and ionosphere down to an altitude of about 120 km. The orbiter is designed to globally map the atmosphere, ionosphere, and the solar wind/ionosphere interaction. In addition, it will utilize radar mapping techniques to study the surface.

Source record↗

Amplifier Module for 260-GHz Band Using Quartz Waveguide Transitions

Packaging of MMIC LNA (monolithic microwave integrated circuit low-noise amplifier) chips at frequencies over 200 GHz has always been problematic due to the high loss in the transition between the MMIC chip and the waveguide medium in which the chip will typically be used. In addition, above 200 GHz, wire-bond inductance between the LNA and the waveguide can severely limit the RF matching and bandwidth of the final waveguide amplifier module. This work resulted in the development of a low-loss quartz waveguide transition that includes a capacitive transmission line between the MMIC and the waveguide probe element. This capacitive transmission line tunes out the wirebond inductance (where the wire-bond is required to bond between the MMIC and the probe element). This inductance can severely limit the RF matching and bandwidth of the final waveguide amplifier module. The amplifier module consists of a quartz E-plane waveguide probe transition, a short capacitive tuning element, a short wire-bond to the MMIC, and the MMIC LNA. The output structure is similar, with a short wire-bond at the output of the MMIC, a quartz E-plane waveguide probe transition, and the output waveguide. The quartz probe element is made of 3-mil quartz, which is the thinnest commercially available material. The waveguide band used is WR4, from 170 to 260 GHz. This new transition and block design is an improvement over prior art because it provides for better RF matching, and will likely yield lower loss and better noise figure. The development of high-performance, low-noise amplifiers in the 180-to- 700-GHz range has applications for future earth science and planetary instruments with low power and volume, and astrophysics array instruments for molecular spectroscopy. This frequency band, while suitable for homeland security and commercial applications (such as millimeter-wave imaging, hidden weapons detection, crowd scanning, airport security, and communications), also has applications to future NASA missions. The Global Atmospheric Composition Mission (GACM) in the NRC Decadel Survey will need low-noise amplifiers with extremely low noise temperatures, either at room temperature or for cryogenic applications, for atmospheric remote sensing.

Padmanabhan, Sharmila↗

Multi-Decadal Records of Stratospheric Composition and Their Relationship to Stratospheric Circulation Change

Constituent evolution for 1990-2015 simulated using the Global Modeling Initiative chemistry and transport model driven by meteorological fields from the Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA-2) is compared with three sources of observations: ground-based column measurements of HNO3 and HCl from two stations in the Network for the Detection of Atmospheric Composition Change (NDACC, 1990- ongoing), profiles of CH4 from the Halogen Occultation Experiment (HALOE) on the Upper Atmosphere Research Satellite (UARS, 1992-2005), and profiles of N2O from the Microwave Limb Sounder on the Earth Observing System satellite Aura (2005- ongoing). The differences between observed and simulated values are shown to be time dependent, with better agreement after 2000 compared with the prior decade. Furthermore, the differences between observed and simulated HNO3 and HCl columns are shown to be correlated with each other, suggesting that issues with the simulated transport and mixing cause the differences during the 1990s and that these issues are less important during the later years. Because the simulated fields are related to mean age in the lower stratosphere, we use these comparisons to evaluate the time dependence of mean age. The ongoing NDACC column observations provide critical information necessary to substantiate trends in mean age obtained using fields from MERRA-2 or any other reanalysis products.

Profiles of N2O from the Microwave Limb Sounde↗