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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

Interstellar circular polarization.

This paper shows that optical observations of circular polarization produced by aligned interstellar grains could yield valuable information about the grain material. The interstellar medium is known to be linearly dichroic from observations of interstellar linear polarization. Since the same aligned grains make the medium linearly birefringent, a small component of circular polarization can result from incident linearly polarized light if the position angle of the linear polarization does not coincide with either principal axis of the medium. Calculations demonstrate that the wavelength of the circular polarization is sensitive to the imaginary part of the complex refractive index of the grain material. This provides an opportunity of investigating whether the grains are characteristically dielectric or metallic.

Martin, P. G.↗

Testing of molded high temperature plastic actuator road seals for use in advanced aircraft hydraulic systems

Molded high temperature plastic first and second stage rod seal elements were evaluated in seal assemblies to determine performance characteristics. These characteristics were compared with the performance of machined seal elements. The 6.35 cm second stage Chevron seal assembly was tested using molded Chevrons fabricated from five molding materials. Impulse screening tests conducted over a range of 311 K to 478 K revealed thermal setting deficiencies in the aromatic polyimide molding materials. Seal elements fabricated from aromatic copolyester materials structurally failed during impulse cycle calibration. Endurance testing of 3.85 million cycles at 450 K using MIL-H-83283 fluid showed poorer seal performance with the unfilled aromatic polyimide material than had been attained with seals machined from Vespel SP-21 material. The 6.35 cm first stage step-cut compression loaded seal ring fabricated from copolyester injection molding material failed structurally during impulse cycle calibration. Molding of complex shape rod seals was shown to be a potentially controllable technique, but additional molding material property testing is recommended.

Waterman, A. W.↗

Icy Satellites of the Planets, and the Work of V.I. Moroz

The satellites of the giant planets are highly varied in size and density, indicating a wide range of compositions. The principal components of these satellites are ices of many different compositions (with H2O the most abundant) and varying amounts of silicate rocky material. Many different ices have been found by spectroscopic techniques both from Earth-based observatories and from planetary spacecraft. Three of the Galilean satellites of Jupiter exhibit H2O ice on their surfaces, while small amounts of CO2 are present on Ganymede and Callisto. The volcanic satellite Io has abundant SO2 ice and frost deposits. Saturn s satellites have surfaces dominated by H2O ice, but CO2 is also present on most of them, and in the cases of the low-albedo satellites Iapetus and Phoebe, there is evidence of complex hydrocarbons mixed with the surface materials. The large Uranian satellites also have H2O-dominated surfaces, but CO2 has also been discovered on two of them. Neptune s largest satellite, Triton, show spectroscopic evidence for six different ices, including N2, CH4, CO, CO2, H2O, and C2H6. The latter ice is a photochemical product from the action of sunlight on Triton's atmosphere. Pluto is similar to Triton, although CO2 has not been found. Pluto s large satellite, Charon, shows evidence for an ammonia hydrate on part of its surface. V. I. Moroz was a pioneer in the application of near-infrared detectors to astronomical sources. Using a prism spectrometer he measured the spectra of the Galilean satellites of Jupiter, and in 1966 he published the first near-infrared spectra, noting the appearance of H2O ice as a major component of Europa and Ganymede. This discovery, and the techniques of Moroz measurements help set the stage for the broad extension of the study of planetary, satellite, and asteroid surfaces through reflectance spectroscopy in the near-infrared.

Cruikshank, Dale P.↗

Experimental characterization of composites

The experimental characterization for composite materials is generally more complicated than for ordinary homogeneous, isotropic materials because composites behave in a much more complex fashion, due to macroscopic anisotropic effects and lamination effects. Problems concerning the static uniaxial tension test for composite materials are considered along with approaches for conducting static uniaxial compression tests and static uniaxial bending tests. Studies of static shear properties are discussed, taking into account in-plane shear, twisting shear, and thickness shear. Attention is given to static multiaxial loading, systematized experimental programs for the complete characterization of static properties, and dynamic properties.

Bert, C. W.↗

Chelate-modified polymers for atmospheric gas chromatography

Chromatographic materials were developed to serve as the stationary phase of columns used in the separation of atmospheric gases. These materials consist of a crosslinked porous polymer matrix, e.g., a divinylbenzene polymer, into which has been embedded an inorganic complexed ion such as N,N'-ethylene-bis-(acetylacetoniminato)-cobalt (2). Organic nitrogenous bases, such as pyridine, may be incorporated into the chelate polymer complexes to increase their chromatographic utility. With such materials, the process of gas chromatography is greatly simplified, especially in terms of time and quantity of material needed for a gas separation.

Christensen, W. W.↗

Electrostatic Separator for Beneficiation of Lunar Soil

A charge separator has been constructed for use in a lunar environment that will allow for separation of minerals from lunar soil. In the present experiments, whole lunar dust as received was used. The approach taken here was that beneficiation of ores into an industrial feedstock grade may be more efficient. Refinement or enrichment of specific minerals in the soil before it is chemically processed may be more desirable as it would reduce the size and energy requirements necessary to produce the virgin material, and it may significantly reduce the process complexity. The principle is that minerals of different composition and work function will charge differently when tribocharged against different materials, and hence be separated in an electric field.

Quinn, Jacqueline↗

Interstellar circular polarization and the composition of interstellar dust

This paper shows that optical observations of circular polarization produced by aligned interstellar grains could yield valuable information about the grain material. The interstellar medium is known to be linearly dichroic from observations of interstellar linear polarization; many different grain models using a large variety of compositions can be found to reproduce these observations. Since the same aligned grains make the medium linearly birefringent, a small component of circular polarization can result from incident linearly polarized light if the position angle of the linear polarization does not coincide with either principal axis of the medium. Here calculations are presented to demonstrate that the wavelength of the circular polarization is sensitive to the imaginary part of the complex refractive index of the grain material. This provides an opportunity of investigating whether the grains are characteristically dielectric or metallic. Some possible observations are suggested.

Martin, P. G.↗

XANES Analysis of Organic Residues Produced from the UV Irradiation of Astrophysical Ice Analogs

Organic residues formed in the laboratory from the ultraviolet (UV) photo-irradiation or ion bombardment of astrophysical ice analogs have been extensively studied for the last 15 years with a broad suite of techniques, including infrared (IR) and UV spectroscopies, as well as mass spectrometry. Analyses of these materials show that they consist of complex mixtures of organic compounds stable at room temperature, mostly soluble, that have not been fully characterized. However, the hydrolysis products of these residues have been partly identified using chromatography techniques, which indicate that they contain molecular precursors of prebiotic interest such as amino acids, nitrile-bearing compounds, and amphiphilic compounds. In this study, we present the first X-ray absorption near-edge structure (XANES) spectroscopy measurements of three organic residues made from the UV irradiation of ices having different starting compositions. XANES spectra confirm the presence of different chemical functions in these residues, and indicate that they are rich in nitrogenand oxygen-bearing species. These data can be compared with XANES measurements of extraterrestrial materials. Finally, this study also shows how soft X rays can alter the chemical composition of samples.

XANES(X-RAY ABSORPTION NEAR-EDGE STRUCTURE)↗

Automated Guided-Wave Scanning Developed to Characterize Materials and Detect Defects

The Nondestructive Evaluation (NDE) Group of the Optical Instrumentation Technology Branch at the NASA Glenn Research Center has developed a scanning system that uses guided waves to characterize materials and detect defects. The technique uses two ultrasonic transducers to interrogate the condition of a material. The sending transducer introduces an ultrasonic pulse at a point on the surface of the specimen, and the receiving transducer detects the signal after it has passed through the material. The aim of the method is to correlate certain parameters in both the time and frequency domains of the detected waveform to characteristics of the material between the two transducers. The scanning system is shown. The waveform parameters of interest include the attenuation due to internal damping, waveform shape parameters, and frequency shifts due to material changes. For the most part, guided waves are used to gauge the damage state and defect growth of materials subjected to various mechanical or environmental loads. The technique has been applied to polymer matrix composites, ceramic matrix composites, and metal matrix composites as well as metallic alloys. Historically, guided wave analysis has been a point-by-point, manual technique with waveforms collected at discrete locations and postprocessed. Data collection and analysis of this type limits the amount of detail that can be obtained. Also, the manual movement of the sensors is prone to user error and is time consuming. The development of an automated guided-wave scanning system has allowed the method to be applied to a wide variety of materials in a consistent, repeatable manner. Experimental studies have been conducted to determine the repeatability of the system as well as compare the results obtained using more traditional NDE methods. The following screen capture shows guided-wave scan results for a ceramic matrix composite plate, including images for each of nine calculated parameters. The system can display up to 18 different wave parameters. Multiple scans of the test specimen demonstrated excellent repeatability in the measurement of all the guided-wave parameters, far exceeding the traditional point-by-point technique. In addition, the scan was able to detect a subsurface defect that was confirmed using flash thermography This technology is being further refined to provide a more robust and efficient software environment. Future hardware upgrades will allow for multiple receiving transducers and the ability to scan more complex surfaces. This work supports composite materials development and testing under the Ultra-Efficient Engine Technology (UEET) Project, but it also will be applied to other material systems under development for a wide range of applications.

Martin, Richard E.↗

On Structural Design of a Mobile Lunar Habitat With Multi- Layered Environmental Shielding

This report presents an overview of a Mobile Lunar Habitat (MLH) structural design consisting of advanced composite materials. The habitat design is derived from the cylindrical-shaped U.S. Lab module aboard the International Space Station (ISS) and includes two lateral ports and a hatch at each end that geometrically match those of the ISS Nodes. Thus, several MLH units can be connected together to form a larger lunar outpost of various architectures. For enhanced mobility over the lunar terrain, the MLH uses six articulated insect-like robotic, retractable legs enabling the habitat to .t aboard a launch vehicle. The carbon-composite shell is sandwiched between two layers of hydrogen-rich polyethylene for enhanced radiation shielding. The pressure vessel is covered by modular double-wall panels for meteoroid impact shielding supported by externally mounted stiffeners. The habitat s structure is an assembly of multiple parts manufactured separately and bonded together. Based on the geometric complexity of a part and its material system, an appropriate fabrication process is proposed.

Pruitt, J. R.↗

Using ABAQUS Scripting Interface for Materials Evaluation and Life Prediction

An ABAQUS script has been written to aid in the evaluation of the mechanical behavior of viscoplastic materials. The purposes of the script are to: handle complex load histories; control load/displacement with alternate stopping criteria; predict failure and life; and verify constitutive models. Material models from the ABAQUS library may be used or the UMAT routine may specify mechanical behavior. User subroutines implemented include: UMAT for the constitutive model; UEXTERNALDB for file manipulation; DISP for boundary conditions; and URDFIL for results processing. Examples presented include load, strain and displacement control tests on a single element model. The tests are creep with a life limiting strain criterion, strain control with a stress limiting cycle and a complex interrupted cyclic relaxation test. The techniques implemented in this paper enable complex load conditions to be solved efficiently with ABAQUS.

Powers, Lynn M.↗

High performance alloy electroforming

Electroformed copper and nickel are used in structural applications for advanced propellant combustion chambers. An improved process has been developed by Bell Aerospace Textron, Inc. wherein electroformed nickel-manganese alloy has demonstrated superior mechanical and thermal stability when compared to previously reported deposits from known nickel plating processes. Solution chemistry and parametric operating procedures are now established and material property data is established for deposition of thick, large complex shapes such as the Space Shuttle Main Engine. The critical operating variables are those governing the ratio of codeposited nickel and manganese. The deposition uniformity which in turn affects the manganese concentration distribution is affected by solution resistance and geometric effects as well as solution agitation. The manganese concentration in the deposit must be between 2000 and 3000 ppm for optimum physical properties to be realized. The study also includes data regarding deposition procedures for achieving excellent bond strength at an interface with copper, nickel-manganese or INCONEL 718. Applications for this electroformed material include fabrication of complex or re-entry shapes which would be difficult or impossible to form from high strength alloys such as INCONEL 718.

Malone, G. A.↗

Automated time-resolved data acquisition during static and dynamic loading of composite materials

This paper reports the development of two new nondestructive techniques for precise determination of the nature and extent of complex damage and the consequent redistribution of stress in composite materials during quasi-static and cyclic or dynamic loading. The two methods incorporate video-thermography and four-component tensor elastic modulus determination. The experimental and analytical aspects of these two methods are discussed and data is presented.

Reifsnieder, K. L.↗

The Formation of Charon's Red Poles from Seasonally Cold-Trapped Volatiles

A unique feature of Plutos large satellite Charon is its dark red northern polar cap. Similar colours on Plutos surface have been attributed to tholin-like organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location on Charon implicates the temperature extremes that result from Charons high obliquity and long seasons in the production of this material. The escape of Pluto's atmosphere provides a potential feedstock for a complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation for the dark coloration on the basis of an image of Charon's northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase that show the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon and the supply and temporary cold-trapping of material escaping from Pluto, as well as the photolytic processing of this material into more complex and less volatile molecules while cold-trapped. The model results are consistent with the proposed mechanism for producing the observed colour pattern on Charon.

Grundy, W. M.↗

High Speed Thermal Imaging on Ballistic Impact of Triaxially Braided Composites

Ballistic impact experiments were performed on triaxially braided polymer matrix composites to study the heat generated in the material due to projectile velocity and penetration damage. Quantifying the heat generation phenomenon is crucial for attaining a better understanding of composite behavior and failure under impact loading. The knowledge gained can also be used to improve physics-based models which can numerically simulate impact of composites. Triaxially braided (0/+60/-60) composite panels were manufactured with T700S standard modulus carbon fiber and two epoxy resins. The PR520 (toughened) and 3502 (untoughened) resin systems were used to make different panels to study the effects of resin properties on temperature rise. Ballistic impact tests were conducted on these composite panels using a gas gun, and different projectile velocities were applied to study the effect on the temperature results. Temperature contours were obtained from the rear surface of the panel during the test through a high speed, infrared (IR) thermal imaging system. The contours show that high temperatures were locally generated and more pronounced along the axial tows for the T700S/PR520 composite specimens; whereas, tests performed on T700S/3502 composite panels using similar impact velocities demonstrated a widespread area of lower temperature rises. Nondestructive, ultrasonic C-scan analyses were performed to observe and verify the failure patterns in the impacted panels. Overall, the impact experimentation showed temperatures exceeding 525 K (485degF) in both composites which is well above the respective glass transition temperatures for the polymer constituents. This expresses the need for further high strain rate testing and measurement of the temperature and deformation fields to fully understand the complex behavior and failure of the material in order to improve the confidence in designing aerospace components with these materials.

thermal imaging↗

Ultrasonic Polishing

The ultrasonic polishing process makes use of the high-frequency (ultrasonic) vibrations of an abradable tool which automatically conforms to the work piece and an abrasive slurry to finish surfaces and edges on complex, highly detailed, close tolerance cavities in materials from beryllium copper to carbide. Applications range from critical deburring of guidance system components to removing EDM recast layers from aircraft engine components to polishing molds for forming carbide cutting tool inserts or injection molding plastics. A variety of materials including tool steels, carbides, and even ceramics can be successfully processed. Since the abradable tool automatically conforms to the work piece geometry, the ultrasonic finishing method described offers a number of important benefits in finishing components with complex geometries.

Gilmore, Randy↗

Acousto-ultrasonic characterization of fiber reinforced composites

The acousto-ultrasonic technique combines advantageous aspects of acoustic emission and ultrasonic methodologies. Acousto-ultrasonics operates by introducing a repeating series of ultrasonic pulses into a material. The waves introduced simulate the spontaneous stress waves that would arise if the material were put under stress as in the case of acoustic emission measurements. These benign stress waves are detected by an acoustic emission sensor. The physical arrangement of the ultrasonic (input) transducer and acoustic emission (output) sensor is such that the resultant waveform carries an imprint of morphological factors that govern or contribute to material performance. The output waveform is quite complex, but it can be quantitized in terms of a 'stress wave factor'. The stress wave factor, which can be defined in a number of ways, is essentially a relative measure of the efficiency of energy dissipation in a material. If flaws or other material anomalies exist in the volume being examined, their combined effect will appear in the stress wave factor.

Vary, A.↗

Acousto-ultrasonic characterization of fiber reinforced composites

The advantageous aspects of acoustic emission and ultrasonic methodologies are combined in a technique which operates by introducing a repeating series of ultrasonic pulses into a material. The waves introduced simulate the spontaneous stress waves that would arise if the material were put under stress as in the case of acoustic emission measurements. These benign stress waves are detected by an acoustic emission sensor. The physical arrangement of the ultrasonic (input) transducer and acoustic emission (output) sensor is such that the resultant waveform carries an imprint of morphological factors that govern or contribute to material performance. The output waveform is quite complex, but it can be quantitized in terms of a "stress wave factor". The stress wave factor, which can be defined in a number of ways, is essentially a relative measure of the efficiency of energy dissipation in a material. If flaws or other material anomalies exist in the volume being examined, their combined effect will appear in the stress wave factor.

Vary, A.↗