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NASA NTRSDate not supplied

The Search for Chiral Asymmetry as a Potential Biosignature in Samples from Mars

The search for evidence of extraterrestrial life in our solar system is currently guided by our understanding of terrestrial biology and its associated biosignatures. The observed homochirality in all life on Earth, that is, the predominance of “left-handed” or L-amino acids and “right-handed” or D-sugars, is a unique property of life that is crucial for molecular recognition, enzymatic function, information storage and structure and is thought to be a prerequisite for the origin or early evolution of life. Therefore, the detection of L- or D-enantiomeric excesses of chiral amino acids and sugars could be a powerful indicator of extant or extinct life on Mars or other habitable environments in our solar system. The exploration of habitable environments on Mars, including an assessment of the preservation potential for complex organics of either abiotic or biological origin, remains a key goal of both current and future Mars missions. Now with the unambiguous detection of indigenous organic matter in sedimentary rocks on Mars [1-3], NASA’s Curiosity rover has significantly advanced our understanding of the preservation of potential chemical biosignatures in the martian near surface. Although amino acids have not yet been identified by in situ measurements on Mars, if they were present, it is expected that amino acid hydrolysis and racemization would be very slow and any chiral or isotopic signatures from an extinct martian biota could be preserved for billions of years, given the extremely cold and dry surface conditions [4]. One of ESA’s Rosalind Franklin rover payload instruments called the Mars Organic Molecule Analyzer (MOMA) includes a wet chemistry package capable of measuring the enantiomeric ratios of any chiral amino acids present at part-per-million concentrations or higher [5]. The complexity and limited duration of spaceflight operations and the known analytical challenges associated with in situ extraction and characterization of trace reduced organic compounds in ancient rocks make it challenging to determine the origins of martian organic matter found to date. Coordinated state-of-the-art laboratory measurements of returned samples from Mars that include spatially resolved chemical, mineralogical, and isotopic studies and molecule-specific isotopic and enantiomeric measurements will be required to firmly establish whether the complex organic matter detected on Mars comes from biotic or abiotic sources. Ultimately, sample return may be our best chance of identifying chemical biosignatures from a past or present martian biota, if one ever existed on Mars. NASA’s Perseverance rover will collect dozens of surface sample cores for possible future return to Earth by NASA and ESA. Here we review our current knowledge of the distributions and enantiomeric and isotopic compositions of non-biological amino acids found in meteorites compared to terrestrial biochemistry and propose a set of measurement criteria that should be used to help establish the origin of any chiral asymmetry detected in samples from Mars [6].

Daniel P Glavin↗

NASA NTRS2019

Mars 2020 mission design and navigation overview

Following the exceptionally successful Mars Science Laboratory mission which placed the Curiosity rover in the interior of Gale Crater in August 2012, NASA will launch the next rover in the 2020 Earth to Mars opportunity arriving to the Red Planet in February 2021 to explore areas suspected of former habitability and look for evidence of past life. This paper details the mission and navigation requirements set by the Project and how the final mission design and navigation plan satisfies those requirements.

Wong, Mau↗

NASA NTRS2017

NASA Mars 2020 landed mission development

In January of 2014, NASA received fifty-eight proposals from U.S. and international teams for science and exploration technology investigations, for consideration for inclusion as part of NASA’s next mobile landed mission to Mars. The results of the competitive procurement were released in late July of 2014: Seven payloads were selected for the investigations that would contribute to meeting the overall objectives of the mission. The extraordinary scientific and technology development interest in the Mars 2020 mission is a direct result of NASA’s sustained and coordinated plan for the exploration of Mars, and ultimately, its search for life elsewhere in the universe. The Mars 2020 Mission will preserve the heritage and directly build upon NASA’s Mars Science Laboratory Mission and Curiosity Rover to implement its mission. In this paper, early development history leading to its development announcement, as well as key development status and design features for its implementation, is summarized.

Abilleira, Fernando↗

NASA NTRS2018

Detecting Spacecraft Anomalies Using LSTMs and Nonparametric Dynamic Thresholding

As spacecraft send back increasing amounts of telemetry data, improved anomaly detection systems are needed to lessen the monitoring burden placed on operations engineers and reduce operational risk. Current spacecraft monitoring systems only target a subset of anomaly types and often require costly expert knowledge to develop and maintain due to challenges involving scale and complexity. We demonstrate the effectiveness of Long Short-Term Memory (LSTMs) networks, a type of Recurrent Neural Network (RNN), in overcoming these issues using expert-labeled telemetry anomaly data from the Soil Moisture Active Passive (SMAP) satellite and the Mars Science Laboratory (MSL) rover, Curiosity. We also propose a complementary unsupervised and nonparametric anomaly thresholding approach developed during a pilot implementation of an anomaly detection system for SMAP, and offer false positive mitigation strategies along with other key improvements and lessons learned during development.

Soderstrom, Tom↗

NASA NTRS2018

Plans and Concepts for a New Generation of RTGs for Planetary Science Missions

Of the six types of radioisotope thermoelectric generators NASA has flown in space, only the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) is currently available for spaceflight, and it relies on technology first used for RTGs in the 1970s. The MMRTG is a rugged power system capable of delivering 110W at launch. NASA is considering future missions with higher power demands however, and sponsored a study to identify concepts and plans to address those needs. The Director of NASA’s Planetary Sciences Division was briefed on a potential enhancement to the MMRTG in late-2012, just a couple of days after the landing of the Mars Science Laboratory rover, Curiosity, on Mars. NASA subsequently funded system-level engineering and technology maturation tasks for a proposed enhanced MMRTG, or eMMRTG, in fiscal year 2013. There was no plan to build a complete generator, rather the engineering of one, and the transfer of technology from laboratories at the Jet Propulsion Laboratory to industry were begun. NASA has now formed a Project to take the eMMRTG from technology to a qualification unit. This would form the first of a new generation of RTGs in 50 years. NASA has also formed a Project for a Next-Generation RTG concept based upon a study led by this author and a large team. NASA’s Radioisotope Power Systems (RPS) Program set the objective for the study to explore what possible options NASA has for Next-Generation-RTGs. The scope and breadth of the study included many possible destinations within the solar system, and traded a variety of RTG conceptual designs, and risk rated a variety of thermoelectric materials and couple configurations. Requirements were defined for the RTG concepts, a variety of thermoelectric materials were evaluated to find the most mature candidates, and performance was estimated for each RTG concept that could use the most mature of these new thermoelectric materials. The study relied upon mission concepts outlined in the latest Planetary Science Decadal Survey (2011), other more recent mission studies completed throughout the agency, and recent analyses of potential missions to ocean worlds to identify requirements that were not applied to previous RTGs but might prove valuable to these NG-RTGs. RTG concepts with maximal potential utility were identified as being modular and ranging in power output from 50 to 500W. A variety of RTG design concepts with several distinguishing characteristics were formulated. The plans and concepts for a new generation of RTGs (the eMMRTG and NG-RTG) will be discussed.

Woerner, David F.↗

NASA NTRS2016

Design of an Excavation Robot: Regolith Advanced Surface Systems Operations Robot (RASSOR) 2.0

To continue on a sustainable and flexible path, NASA needs to address the challenge of collecting and moving large amounts of regolith at the destination. Acquiring the water resources on Mars will require mining significant quantities of regolith and this is not possible with the state-of-the-art low mass excavation systems. Low gravity environments (Mars = 3/8 G) and launch mass restrictions limit the traction and the resulting reaction force of the vehicle, making current terrestrial techniques impractical. This project addressed this challenge by developing a completely new technology that can mine large quantities of regolith on Mars. Recent measurements by the “Curiosity” rover on Mars have found that the regolith contains ~ 2% water by weight globally, ~4% in Jezero Crater (Human Architecture Team’s reference landing site), and much more at the poles(Leshin et al, 2013). RASSOR 2.0 is a planetary excavator, which has a mass of 66 kg, with a 0.38 kg vehicle mass per kilogram, per hour of excavation rate and power usage of 4 W per kg of regolith excavation rate. A single RASSOR 2.0 can excavate a minimum of 2.7 metric tons of regolith per day.This is accomplished by using counteracting excavation forces on two opposing digging implements called bucket drums and an autonomous mining control system. This work has addressed several major research areas outlined in the NASA Technology Area (TA) 04 Robotics & Autonomous Systems and TA 07 Human Destination Systems roadmaps. This project started at Technology Readiness Level (TRL) 4 as a low fidelity “proof of concept” prototype which has successfully demonstrated basic regolith simulant excavation functionality in a lab-scale gravity off load test. The foundational technology described here was awarded US patent number: US 9027265 for a “Zero horizontal reaction force excavator” on May 12, 2015.

RASSOR↗

NASA NTRS2020

Evidence for Multiple Diagenetic Episodes in Ancient Fluvial‐Lacustrine Sedimentary Rocks in Gale Crater, Mars

The Curiosity rover's exploration of rocks and soils in Gale crater has provided diverse geochemical and mineralogical data sets, underscoring the complex geological history of the region. We report the crystalline, clay mineral, and amorphous phase distributions of four Gale crater rocks from an 80‐m stratigraphic interval. The mineralogy of the four samples is strongly influenced by aqueous alteration processes, including variations in water chemistries, redox, pH, and temperature. Localized hydrothermal events are evidenced by gray hematite and maturation of amorphous SiO 2 to opal‐CT. Low‐temperature diagenetic events are associated with fluctuating lake levels, evaporative events, and ground water infiltration. Among all mudstones analyzed in Gale crater, the diversity in diagenetic processes is primarily captured by the mineralogy and X‐ray amorphous chemistry of the drilled rocks. Variations indicate a transition from magnetite to hematite and an increase in matrix‐associated sulfates suggesting intensifying influence from oxic, diagenetic fluids up section. Furthermore, diagenetic fluid pathways are shown to be strongly affected by unconformities and sedimentary transitions, as evidenced by the intensity of alteration inferred from the mineralogy of sediments sampled adjacent to stratigraphic contacts.

C N Achilles↗

NASA NTRS2020

Communications with Curiosity during solar conjunction

This study examines the methodology for operating and communicating with NASA's Curiosity Rover (MSL) during the 2019 solar conjunction. For MSL, solar conjunction occurs when the viewing angle between the Sun and Mars from Earth's perspective falls below 3 degrees, which occurs roughly every two Earth years and lasts for about two weeks. This presents a challenge for engineers operating a vehicle on Mars because the degraded signal to noise ratio disrupts data flow between Earth and the spacecraft. As a result, operators designate a command moratorium in which no commands are sent to the rover and instead design long-term plans that are uplinked weeks in advance (rather than the nominal case of daily uplinks). Coordinating communications with the rover leading up to and following conjunction requires negotiations with several orbiters, another lander, and the Deep Space Network (DSN) each with their own set of constraints. It is the Strategic Comm Planning T coordination, which acts as a baseline for the conjunction Comm team faced additional complications such as the arrival of two new spacecraft at Mars - Roscosmos ExoMars Trace Gas Orbiter (TGO).

Laubach, Sharon↗

NASA NTRSDate not supplied

X-ray Amorphous Materials in Soils from the Antarctica Dry Valleys: Insights into Aqueous Alteration Processes on Mars

The CheMin XRD instrument onboard the Curiosity rover has discovered abundant quantities of X-ray amorphous materials (25-40 wt. %) in windblown deposits and sedimentary rocks on Mars. The large amounts of X-ray amorphous materials on Mars is surprising because these materials are usually not found in large abundances in terrestrial soils. We have previously identified short-range ordered or X-ray amorphous materials in Antarctica Dry Valleys (ADV) soils. The ADV are one of the driest and coldest environments on Earth and provide an ideal process analog environment for Mars. The objective of this study was to further characterize the chemistry and mineralogy of ADV soils, specifically to quantify and characterize the X-ray amorphous materials. Two soils were characterized from different elevations in the ADV - a low elevation, coastal, subxerous soil in Taylor Valley and a high elevation, ultraxerous soil in University Valley. Rietveld analysis of XRD patterns generated with a CheMin-like analog instrument indicated up to 40 and 15 wt. % X-ray amorphous materials in the Taylor and University Valley soils, respectively. The high abundance of X-ray amorphous materials in Taylor Valley is surprising for one of the driest places on Earth. These materials may have been physically and chemical altered during soil formation, however, the limited interaction with water and low temperatures may have resulted in the formation of “immature” X-ray amorphous or SRO materials. Perhaps, a similar process contributes to the formation of the high content of X-ray amorphous materials detected on Mars.

Antarctica↗

NASA NTRSDate not supplied

Mars 2020 Reconstructed Aerothermal Environments and Design Margins

The Mars 2020 aeroshell's thermal protection system was nearly identical to the Mars Science Laboratory system that successfully completed its mission for the Curiosity rover's landing in 2012. It was predicted that, like Mars Science Laboratory, the Mars 2020 heatshield would experience boundary layer transition and that the thermal protection system would provide sufficient material thickness margins against the aerothermal environments, even after adding radiative heating that was not included for Mars Science Laboratory. The Mars 2020 flight instrumentation suite included heatshield sensors similar to Mars Science Laboratory and new backshell measurements. A full set of surface pressure and in-depth temperature data were collected during atmospheric entry. This paper provides an initial analysis of the flight data and focuses on the reconstructed total surface heat flux inferred from the measured temperatures. Turbulent boundary layer conditions again were observed on the Mars 2020 heatshield, and the temperatures at all eleven heatshield and six backshell thermocouple in-depth sensor locations were well within system capabilities due to favorable entry conditions and conservative uncertainties. New computational fluid dynamics results on the reconstructed entry trajectory are compared to the measured surface pressures and reconstructed total heat fluxes. The predicted heatshield surface pressures at six locations match the data qualitatively and quantitatively well, as expected. Smooth-wall laminar heating predictions prior to boundary layer transition fall above the reconstructed heating on the heatshield. After the observed boundary layer transition time, total heat flux based on algebraic turbulence model calculations generally match the heat flux trends relative to one another. The convective heat flux was predicted to constitute the majority of the total heating. On the backshell, smooth-wall laminar total heat flux predictions generally exceed the reconstructed total heating at six locations. At each of these locations, it is estimated that radiative heating provided almost all of the total heating. The Mars 2020 as-flown aerothermal environments were well below the design levels for all measurement locations due to conservative design assumptions and a stressing design trajectory.

Mars 2020↗

NASA NTRSDate not supplied

Mars 2020 Reconstructed Aerothermal Environments and Design Margins

Mars 2020↗

NASA NTRSDate not supplied

Formation of Fe(III) (hydr)oxides from Fe(II) Sulfides: Implications for Akaganeite Detection on Mars

Akaganeite (Cl-bearing Fe(III) (hydr)oxide) was identified by the Chemistry and Mineralogy X-ray diffraction (XRD) instrument onboard the Mars Science Laboratory (MSL) Curiosity Rover in mudstones drilled at Yellowknife Bay and Vera Ru-bin Ridge in Gale crater [1,2]. The mineral likely formed in chloride-bearing solutions of variable pH[3]but progenitor Fe-bearing phases for martian akaganeite are not well constrained. Akaganeite in Gale crater has been proposed to form through oxidation of Fe(II) sulfide minerals [2,3]. The objectives of this study was to constrain akaganeite formation conditions from Fe(II) sulfide pyrrhotite.

Mars↗

NASA NTRSDate not supplied

The Search for Chiral Asymmetry as a Potential Biosignature in Samples from Mars

The search for evidence of extraterrestrial life in our solar system has been guided by our under-standing of terrestrial biology and its associated biosignatures. The observed homochirality in all life on Earth, that is, the predominance of “left-handed” or L-amino acids and “right-handed” or D-sugars, is a unique property of life that is crucial for molecular recognition, enzymatic function, information storage and structure, and is thought to be a prerequisite for the origin or early evolution of life. Therefore, the detection of L- or D-excesses of chiral amino acids or sugars could be a powerful indicator of extant or extinct life on Mars or other habitable environments in our solar system. However, studies of primitive meteorites have revealed that they contain extraterrestrial amino acids and sugar acids with large enantiomeric excesses (60% and higher) that resulted from non-biological processes [1], complicating the use of chiral asymmetry by itself as a definitive biosignature. The exploration of habitable environments on Mars, including an assessment of the preservation potential for complex organics of either abiotic or biological origin, is an objective of both current and future Mars missions. Now with the unambiguous detection of indigenous organic matter in sedimentary rocks by the Sample Analysis at Mars (SAM) instrument suite on Mars [2-5], NASA’s Curiosity rover has found evidence of the preservation of potential chemical biosignatures in the martian near surface. Although amino acids have not yet been identified by in situ measurements on Mars [5], indigenous achiral amino acids have been identified in one martian meteorite [6]. It is expected that amino acid racemization would be very slow and any chiral or isotopic signatures from an extinct martian biota could be preserved for billions of years, given the extremely cold and dry surface conditions [7]. The ESA/Roscosmos ExoMars mission scheduled for launch next year includes the Rosalind Franklin rover designed to acquire samples from a depth of ~2 m and deliver them to a suite of instruments, including the Mars Organic Molecule Analyzer (MOMA). The MOMA instrument contains a wet chemistry experiment designed specifically for the detection of amino acids and measurement of their enantiomeric compositions [8]. The complexity and limited duration of spaceflight operations, and the known analytical challenges associated with in situ extraction and characterization of trace reduced organic com-pounds in ancient rocks, make it challenging to determine the origins of martian organic matter found to date. Coordinated state-of-the-art laboratory measurements of returned samples from Mars that include spatially resolved chemical, mineralogical, bulk and molecule-specific isotopic, and enantiomeric measurements will be required to firmly establish whether the complex organic matter detected on Mars derives from bio-tic or abiotic processes. Ultimately, Mars Sample Return of rock cores collected by NASA’s Perseverance rover may be our best chance of identifying chemical biosignatures, including any chiral amino acid asymmetry resulting from a past or present martian biota, if one ever existed on Mars. Here we review our current knowledge of the distributions, and enantiomeric and isotopic com-positions of amino acids found in meteorites compared to terrestrial biochemistry. We also propose a set of measurement criteria that should be used to help establish the sources of any amino acids detected in samples returned from Mars using state-of-the-art gas and liquid chromatography mass spectrometry techniques [1].

D P Glavin↗

NASA NTRSDate not supplied

Overview and Initial Results of DIGMARS: Digging Iceland Geology for Mars Analog Research Science

Preserved in the sedimentary rocks of Mars is a rich record of ancient surface environments and burial diagenesis. Sequences of sandstones and mudstones that indicate sedimentation in deltaic and lacustrine environments have been encountered by the Curiosity rover in Gale crater and likely will be by the Perseverance rover in Jezero crater [1-3]. The compositional variability in these sedimentary rocks points to a complex diagenetic story that bears significantly on the basin history and early martian environment. Because interaction of percolating groundwaters and with unconsolidated sediments is a process commonly observed in lacustrine environments on Earth [4], groundwater has been invoked to develop a sedimentary history for Gale crater [e.g., 5-9]. Unique conceptual models, each with their own implications for the paleoenvironment and hydrologic conditions have been put forward. However, we currently lack a terrestrial reference frame for groundwater-driven diagenesis in a basalt dominated watersheds on Earth. The Digging Iceland Geology for Mars Analog Research Science (DIGMARS) project aims to close this research gap, with the goal of exploring groundwater-sediment interaction from lakes around Iceland. Here, we present the initial results for the 2021 field campaign and the laboratory analysis of aqueous and sediment samples.

M T Thorpe↗

NASA NTRS2013

Mars Hand Lens Imager (MAHLI) efforts and observations at the “Rocknest” Eolian sand shadow in Curiosity’s Gale Crater field site

The Mars Science Laboratory (MSL) mission is focused on assessing the past or present habitability of Mars, through interrogation of environment and environmental records at the Curiosity rover field site in Gale crater. The MSL team has two methods available to collect, process and deliver samples to onboard analytical laboratories, the Chemistry and Mineralogy instrument (CheMin) and the Sample Analysis at Mars (SAM) instrument suite. One approach obtains samples by drilling into a rock, the other uses a scoop to collect loose regolith fines.

Edgett, K. S.↗

NASA NTRS2020

Tuning a variational autoencoder for data accountability problem in the Mars Science Laboratory ground data system

The Mars Curiosity rover is frequently sending back engineering and science data that goes through a pipeline of systems before reaching its final destination at the mission operations center making it prone to volume loss and data corruption. A ground data system analysis (GDSA) team is charged with the monitoring of this flow of information and the detection of anomalies in that data in order to request a re-transmission when necessary. This work presents ∆-MADS, a derivative-free optimization method applied for tuning the architecture and hyperparameters of a variational autoencoder trained to detect the data with missing patches in order to assist the GDSA team in their mission.

Lakhmiri, Dounia↗

NASA NTRSDate not supplied

Importance of Sulfur for Phosphorus Mobility on the Martian Surface

Sulfur and phosphorus were mobile on the martian surface, and we present evidence that sulfate was likely a control on phosphate mobility. Mobility of the two elements on the martian surface is crucial for the habitability of Mars because their availability for biochemical reactions and biological structures is a major constraint on life. In the sedimentary rocks of Gale crater, the rover Curiosity has discovered evidence of mobile S and P with the alpha particle X-ray spectrometer (APXS). Sulfur-rich fluids are evident in ubiquitous Ca-sulfate veins that crosscut the bedrock. Compelling evidence of P mobility is in nodules, veins, crusts, and haloes with P2O5 enrichments (1.5-7.5 wt%) relative to the median bedrock (0.9-1.2 wt%) and average basaltic crust (~0.9 wt%). We have investigated phosphorus mobility in Hawaiian analogues, where the primary P2O5 (0.2-2.1 wt%) is contained in Ca-apatite. Four relevant processes have emerged: (1) In open-system, circumneutral regolith weathering profiles, we found up to 40% of the P was leached over 10s-100s ka. (2) Natural acid-sulfate alteration at the Maunakea summit resulted in the dissolution of apatite and mobilization of phosphate 10s-1000s µm to rock surfaces where it formed Al-phosphates and substituted into crystalline sulfates (alunite and jarosite). (3) Experimental results indicate that basaltic sediment chemisorbs phosphate (pH < 7). (4) In experimental systems containing water, basaltic sediment, and a starting pH = 2-7, phosphate has higher solubility in chloride-rich fluids, but significantly lower solubility in sulfate-rich fluids. For example, in water doped with phosphate (~100-500 mg/L), ~60-80% of the PO43- was removed from the sulfate-rich fluid, whereas ~20% of the PO43- was removed from the Cl-rich and pure water fluids (likely via adsorption). Gypsum precipitated from the sulfate-rich fluids; the fate of phosphate in the solid residue is unconfirmed. The potential for phosphate incorporation in martian sulfates is reflected in the enrichment of P2O5 in Gale Ca-sulfate veins, based on preliminary analyses of APXS data. Models for the mobility of phosphorus in Gale crater should consider these conflicting P characteristics: (1) P solubility may have been inhibited by sulfate and (2) P¬ is enriched in diagenetic features and was therefore mobile.

Jeff A. Berger↗

NASA NTRSDate not supplied

MastCam Multispectral Examination of Rocks in the Sulfate-Bearing Terrain of Marker Band Valley, Gale Crater, Mars

A primary objective of the 4th extended mission of the Mars Science Laboratory rover Curiosity is to characterize the sulfate-bearing beds exposed on the slopes of Mt. Sharp (Aeolis Mons) above the clay-bearing beds of the Glen Torridon region characterized in the 3rd extended mission. Orbital reflectance spectroscopy from CRISM has indicated the presence of polyhydrated Mg sulfates in the portion of Mt. Sharp dubbed “Marker Band Valley” (MBV). The Marker Band is a darker toned, high-Ca pyroxene bearing unit that extends around much of Mt. Sharp above the first exposures of sulfate-bearing beds. Standoff imaging of the Marker Band indicates that it is not monolithic, but contains at least two subunits. Curiosity measures multispectral reflectance in the 430 to 1012 nm range with its Mastcam. While diagnostic spectral features of Mg-sulfates are not present in the Mastcam spectral range, a water overtone feature of some polyhydrated sulfates can be observed as a drop in reflectance in the longest wavelength one to three bands of Mastcam multispectral data. Other minerals associated with sulfate-generating alteration processes, most notably Fe-bearing minerals, are more readily detectable in Mastcam multispectral data.

W H Farrand↗