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At least 415 records · Page 23

Subtask 1.4 - Techno-Economic Assessment of Regional Carbon Utilization Scenarios and Attendant Monitoring Technology

The U.S. Department of Energy (DOE) Carbon Storage Program seeks to develop technologies to significantly improve the effectiveness of carbon capture and storage (CCS), reduce the cost of implementation, and support the readiness of widespread commercial deployment by 2035. To accomplish this goal, technical and economic barriers must be addressed and the results used to inform regulators and industry on the safety, permanence, and viability of carbon storage. To help overcome these barriers, the Energy & Environmental Research Center (EERC) conducted three activities: 1) investigate the regional techno-economic life cycle of CO2 enhanced oil recovery (EOR) in North Dakota, 2) assist DOE in determining the prospective CO2 storage resource of residual oil zones (ROZs), and 3) develop a seismic technique for monitoring geologic storage of CO2. These three activities address two strategic goals enumerated in the DOE–EERC Cooperative Agreement, namely, 1) to advance foundational science and 2) to inform data-driven policies that enhance U.S. economic growth and job creation, energy security, and environmental quality. Activity 1 In North Dakota, there is synergistic incentive to develop and implement CO2 EOR technologies. Regional industry partners are actively seeking options that can cost-effectively improve the efficiency of power production, while also coproducing CO2 for use in EOR applications. A full-value-chain techno-economic assessment that links lignite resources, power generation, and EOR is needed to determine the implications for a state or region to continue to use these resources or look elsewhere for other energy sources and revenue streams. The integration of North Dakota’s lignite power industry with the state’s oil industry has the potential to revitalize legacy oil fields and produce up to 1 billion barrels of additional oil using CO2 EOR while providing a market for a CO2 commodity captured at coal-fired power plants. Revitalization of North Dakota’s legacy oil fields will bring new industry investment to the state, resulting in the growth of oil-related jobs and revenue through oil sales, severance tax, and associated oilfield development activities (drilling, pipelines, etc.). CO2 demand for EOR and incremental oil production were calculated for 201 conventional oil fields in North Dakota. Infrastructure development in the fields was estimated using 1) a traditional vertical well arrangement of CO2 injectors and oil producers and 2) an advanced case where horizontal wells were used exclusively. Pipeline, compression, and recycling infrastructure requirements were also estimated. When viewed from the CO2 capture and CO2 EOR sectors, the advanced case showed a positive investment scenario when including potential benefits of the 45Q tax credit policy. An economic evaluation of a full implementation of CO2 EOR showed an average $60 billion potential state economic impact estimated over the 37-year construction and production time frame could be realized with an assumed oil price of $65/bbl. Oil price ranges of $35–$90/bbl cause an estimated variation of ±$5 billion over the potential effort. The total net state government revenues were estimated over the 37-year construction and production time frame. With an assumed oil price of $65/bbl, total potential fiscal impact could average $7.4 billion. This result ranges about ±$2.5 billion for a potential EOR implementation effort for oil price ranges of $35–$90/bbl. This broad-brush assessment was focused on “magnitude-of-effect” perspectives of what CO2 capture and use for EOR could mean to the state. Whether CO2 EOR ever becomes widely adopted is not the issue at this stage of evaluation. The question being answered is, How valuable could CO2 capture and CO2 EOR be for the state and local jurisdictions in western North Dakota? The results of the current economic assessment remove any ambiguity to that question. Full implementation of CO2 EOR as modeled in this study provides substantial economic benefits to the state, even at low oil prices (i.e., $35/bbl). Job creation and government revenues could be substantial, depending on the scale of implementation. With a better understanding of what CO2 EOR might mean for the state’s economy, the focus can now shift to the policies and financial mechanisms needed to make private investment in CO2 capture and use as EOR competitive with other energy-related pursuits. Activity 2 ROZs contain remnants of oil not swept away by natural waterflooding. Although nearly all of the identified ROZs are found in West Texas, there is evidence that this category of oil reservoir can be found in other major oil-producing basins of the United States. Because the formation of these oil reservoirs is distinct from other conventional reservoirs, the method to estimate the prospective CO2 storage resource in ROZs may be equally distinct from the method used for conventional fields. As such, the EERC collaborated with DOE’s National Energy Technology Laboratory (NETL) to investigate the feasibility of CO2 storage in ROZs and determine what specific modification (if any) needs to be made to the current DOE volumetric method to estimate prospective CO2 storage resource in oil reservoirs. This activity built on a previous EERC investigation to identify ROZs in the Williston and Powder River Basins and upon collaborations between the EERC and NETL to develop storage resource estimation methods for different types of geologic CO2 storage. Review of the volumetric approach raised questions about the applicability of such an approach to hydrocarbon-bearing zones without the inclusion of potential hydrocarbon production. A production-based approach was presented by the EERC to inform the working group of additional methods of increasing the CO2 storage resource potential. Because the production-based method focuses more heavily on oil recovery than CO2 storage, it was not included in the working group manuscript. Activity 3 The EERC has used sparse and irregular seismic arrays to detect CO2 injected into a reservoir. The variability of seismic noise recorded by the sensors directly impacts the seismic interpretation. However, designing noise attenuation workflows effectively can be a more challenging task using sparse and irregular arrays for data acquisition. Based on the hypothesis that noncoherent noise is stationary during weekly data acquisition, a new machine-learning algorithm was developed to automatically estimate noise conditions using passive records, noise from active records, and ancillary information. The new noise attenuation processing workflow can improve the time-lapse detection of CO2 from sparse and irregular array acquisitions. Results show spatial and temporal noise patterns can be related to the location of the sensors and the weather conditions during the data acquisition and that our attenuation processing workflow can improve the time-lapse detection of CO2 from sparse and irregular array acquisitions. This effort was funded in part through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FE0024233. Nonfederal funding was provided by the North Dakota Department of Commerce.

Peck, Wesly↗

Conceptual Model Update of Mercury Sources and Flux at Y-12 and Upper East Fork Poplar Creek, Oak Ridge,Tennessee

The interactions between the key processes that control the fate and transport of mercury (Hg) in the sediments, groundwater, and stream water within the Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee are complex, and many aspects are not well understood. In contaminated environments such as Y-12, conceptual models are frequently developed to aid in visualizing and understanding the dynamic nature of the hydrologic, geochemical, and physical environment. These conceptual models integrate data in an internally consistent manner to understand processes that control the fate and transport of contaminants. Over the past few decades of environmental investigation at Y-12, a number of conceptual models have been developed to identify and define various technical processes at various scales. The main purpose of the activities described in this report is to update the 2011 conceptual model for Upper East Fork Poplar Creek using the most recent Hg concentration and flux data and informed scientific interpretation. Emphasis was placed on improving the previous model by implementing a more detailed spatial and temporal approach to visualize transport pathways in the watershed and trends in flux and concentration over time, and to compare baseflow and stormflow system dynamics. Detailed descriptions of historical and current Hg sources and transport pathways are also provided for the east and west ends of the facility. This conceptual model will allow the US Department of Energy to evaluate past and present remedial activities and provide a strong technical basis for prioritizing and optimizing remedial responses in a cost-effective and efficient manner. Twenty years ago, Hg flux from Outfall (OF) 200 at the headwaters of East Fork Poplar Creek represented approximately 20% of the overall flux leaving Y-12. By the time of the 2011 conceptual model report, that percentage had increased to 70%–80%. Flux estimates compiled for this report using data from 2009 to 2018 show that OF200 accounted for roughly 60% of the flux leaving Y-12. The relative role of the four storm drain conduits to OF200 appeared similar to 2011, with OF163 being the greatest contributor to downstream flux. An increase in Hg concentrations and flux occurred throughout and downstream of west end storm drains in 2011 in response to a storm drain cleanout. Leading up to the 2011 storm drain cleanout, annual baseflow flux was higher at OF200A6 than at Station 17. From 2011 to 2018, the trend reversed with concentrations and flux being higher at Station 17 than at OF200A6. A spike in concentrations occurred in July 2018, potentially due to a one-time influx of Hg that occurred during COLEX decontamination and decommissioning activities at Y-12. This report includes recommendations for improving our conceptual understanding of Hg sources, transport pathways, and flux at Y-12. Important recommendations include further evaluation of transport pathways, concurrent measurement of Hg concentration and flux under baseflow and stormflow conditions at multiple sites, and research to understand the connections among periphyton and methylmercury concentration, bioavailability, and bioaccumulation. Ongoing facility decontamination and decommissioning efforts, site characterization, remedial actions, and research are facilitating the collection of new Hg data at Y-12. The conceptual model update provided herein takes advantage of the extensive recent Hg sampling to provide an updated assessment of Hg mass balance and support a refined understanding of Hg behavior at or near Y-12. This assessment should assist in future environmental management decisions and in mitigating the impacts of Hg on the surrounding environment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Strategy for Maturing Active Radiation Shielding Concepts

Active shielding strategies for protecting astronauts on exploration missions has long been a dream that proved evasive. Study after study since the early 1970’s has shown that solutions are both mass and power prohibitive. This talk will give an overview of current NASA work aimed at making advancements in the area of active shielding. The basic project premise is that we may have a better chance at success if we: (1) remove the constraint of having to reduce the exposure to zero, and instead focus on how to increase the number of ‘safe’ days in space according to the current NASA risk posture; (2) sub-divide the proton and heavy ion energy spectrum to identify a starting point in energy that may yield a non-negligible reduction in ion flux at power levels achievable with current technology, and; (3) develop methods to use scaling to build, test and mature small-scale shielding structures on the ground as a pathway to identifying technology development investment strategies. A top-level overview of these strategies will be presented during this talk.

Radiation Protection↗

Self-evolving atomistic kinetic Monte Carlo simulations of defects in materials

The recent development of on-the-fly atomistic kinetic Monte Carlo methods has led to an increased amount attention on the methods and their corresponding capabilities and applications. In this review, the framework and current status of Self-Evolving Atomistic Kinetic Monte Carlo (SEAKMC) are discussed. SEAKMC particularly focuses on defect interaction and evolution with atomistic details without assuming potential defect migration/interaction mechanisms and energies. The strength and limitation of using an active volume, the key concept introduced in SEAKMC, are discussed. Potential criteria for characterizing an active volume are discussed and the influence of active volume size on saddle point energies is illustrated. A procedure starting with a small active volume followed by larger active volumes was found to possess higher efficiency. Applications of SEAKMC, ranging from point defect diffusion, to complex interstitial cluster evolution, to helium interaction with tungsten surfaces, are summarized. A comparison of SEAKMC with molecular dynamics and conventional object kinetic Monte Carlo is demonstrated. Overall, SEAKMC is found to be complimentary to conventional molecular dynamics, especially when the harmonic approximation of transition state theory is accurate. However it is capable of reaching longer time scales than molecular dynamics and it can be used to systematically increase the accuracy of other methods such as object kinetic Monte Carlo. Furthermore, the challenges and potential development directions are also outlined.

36 MATERIALS SCIENCE↗

Is the Distribution Grid Ready to Accept Large Scale Photovoltaic Deployment? - State of the Art, Progress and Future Prospects

The installed capacity of photovoltaic systems has recently increased at a much faster rate than the development of grid codes to effectively and efficiently manage high penetrations of PV within the distribution system. In a number of countries, PV penetrations in some regions are now raising growing concerns regarding integration. Management strategies vary considerably by country - some still have an approach that photovoltaic systems should behave as passive as possible while others demand an active participation in grid control. This variety of grid codes also causes challenges in learning from 'best practice'. This paper provides a review of current grid codes in some countries with high PV penetrations. In addition, the paper presents a number of country-specific case studies on different approaches for improved integration of photovoltaic systems in the distribution grid. In particular, we consider integration approaches using active and reactive power control that can reduce or defer expensive grid reinforcement while supporting higher PV penetrations.

14 SOLAR ENERGY↗

Aspects of Crystal Growth and Atomic-Scale Characterization of U/Th Age-Dating Particles

Trace analysis of particulate material collected on environmental swipe samples continues to be one of the cornerstones of the IAEA’s process of verifying member state compliance as part of the Non-Proliferation Treaty (NPT). While complementary to traditional bulk analysis, the ability to measure individual particles can be far more impactful from a radiochronometry perspective. The 234U/230Th radiochronometer is being evaluated as a means of establishing model ages for discrete particles with sufficient confidence. To support the extension of current capabilities, reference materials with a suitable particle form factor and well-documented purification date are actively sought for development with large geometry secondary ion mass spectroscopy.

Nuclear Safeguards, IAEA, Particle Standards↗

Evolution of systems concepts for a 100 kWe class Space Nuclear Power System

Conceptual designs for the SP-100 Space Nuclear Power System have been prepared that meet baseline, backup and growth program scenarios. Near-term advancement in technology was considered in the design of the Baseline Concept. An improved silicon-germanium thermoelectric technique is used to convert the heat from a fast-spectrum, liquid lithium cooled reactor. This system produces a net power of 100 kWe with a 10-year end of life, under the specific constraints of area and volume. Output of the Backup Concept is estimated to be 60 kWe for a 10-year end of life. This system differs from the Baseline Concept because currently available thermoelectric conversion is used from energy supplied by a liquid sodium cooled reactor. The Growth Concept uses Stirling engine conversion to produce 100 kWe within the constraints of mass and volume. The Growth Concept can be scaled up to produce a 1 MWe output that uses the same type reactor developed for the Baseline Concept. Assessments made for each of the program scenarios indicate the key development efforts needed to initiate detailed design and hardware program phases. Development plans were prepared for each scenario that detail the work elements and show the program activities leading to a state of flight readiness.

Katucki, R.↗

Midtail plasma flows and the relationship to near-Earth substorm activity: A case study

Recent simulations of magnetotail reconnection have pointed to a link between plasma flows, dipolarization, and the substorm current wedge. In particular, Hesse and Birn (1991) have proposed that earthward jetting of plasma from the reconnection region transports flux into the near-Earth region. At the inner edge of the plasma sheet this flux piles up, producing a dipolarization of the magnetic field. The vorticity produced by the east-west deflection of the flow at the inner edge of the plasma sheet gives rise to field-aligned currents that have region 1 polarity. Thus in this scenario the earthward flow from the reconnection region produces the dipolarization ad the current wedge in a self-consistent fashion. In this study we examine observations made on April 8, 1985 by the Active Magnetospheric Particle Tracer Explorers (AMPTE)/Ion Release Module (IRM), the geosynchronous satellites 1979-053, 1983-019, and 1984-037, and Syowa station, as well as AE. This event is unique because IRM was located near the neutral sheet in the midnight sector for am extended period of time. Ground data show that there was ongoing activity in the IRM local time sector for several hours, beginning at 1800 UT and reaching a crescendo at 2300 UT. This activity was also accompanied by energetic particle variations, including injections, at geosynchronous orbit in the nighttime sector. Significantly, there were no fast flows at the neutral sheet until the great intensification of activity at 2300 UT. At that time, IRM recorded fast eartheard flow simultaneous with a dipolatization of the magetic field. We conclude that while the aforementioned scenario for the creation of the current wedge encounters serious problems explaining the earlier activity, the observations at 2300 UT are consistent with the scenario of Hesse and Birn (1191). On that basis it is argued that the physics of substorms is not exclusively rooted in the development of a global tearing mode. Processes at the inner edge of the cross-tail current that cause a disruption of the current and a consequent dipolarization and current wedge may be unrelated to the formation of a macroscale reconnection region. Thus the global evolution of a substorm is probably a complicated superposition of such processes operating on a very localized scale and a global macroscale process that allows for such things as releasing te energy stored in lobe flux and creation of plasmoids.

Lopez, R. E.↗

4 kW Test of Solid Oxide Electrolysis Stacks with Advanced Electrode-Supported Cells

A new test stand has been developed at the Idaho National Laboratory for multi-kW testing of solid oxide electrolysis stacks. This test stand will initially be operated at the 4 KW scale. The 4 kW tests will include two 60-cell stacks operating in parallel in a single hot zone. The stacks are internally manifolded with an inverted-U flow pattern and an active area of 100 cm2 per cell. Process gases to and from the two stacks are distributed from common inlet/outlet tubing using a custom base manifold unit that also serves as the bottom current collector plate. The solid oxide cells incorporate a negative-electrode-supported multi-layer design with nickel-zirconia cermet negative electrodes, thin-film yttria-stabilized zirconia electrolytes, and multi-layer lanthanum ferrite-based positive electrodes. Treated metallic interconnects with integral flow channels separate the cells and electrode gases. Sealing is accomplished with compliant mica-glass seals. A spring-loaded test fixture is used for mechanical stack compression. Due to the power level and the large number of cells in the hot zone, process gas flow rates are high and heat recuperation is required to preheat the cold inlet gases upstream of the furnace. Heat recuperation is achieved by means of two inconel tube-in-tube counter-flow heat exchangers. A current density of 0.3 A/cm2 will be used for these tests, resulting in a hydrogen production rate of 25 NL/min. Inlet steam flow rates will be set to achieve a steam utilization value of 50%. The 4 kW test will be performed for a minimum duration of 1000 hours in order to document the long-term durability of the stacks. Details of the test apparatus and initial results will be provided.

08 HYDROGEN↗

FY 2007 LDRD Director's R&D Progress SummaryProposal Title: Developing a Science Base for Fuel Reprocessing Separations in the Global Nuclear Energy Program

This work is aimed at developing an experimentally validated computational capability for understanding the complex processes governing the performance of solvent extraction devices used for separations in nuclear fuel reprocessing. These applications pose a grand challenge due to the combination of complicating factors in a three-dimensional, turbulent, reactive, multicomponent, multiphase/interface fluid flow system. The currently limited process simulation and scale-up capabilities provides uncertainty in the ability to select and design the separations technology for the demonstration plan of the Global Nuclear Energy Partnership (GNEP) program. We anticipate the development of science-based models for technology development and design. This project will position ORNL to address the emerging opportunity by creating an expandable process model validated experimentally. This project has three major thrusts, namely, a prototype experimental station, a continuum modeling and simulation effort, and molecular modeling and kinetics support. Excellent progress has been made in corresponding activities in this first year in: (1) defining, assembling, and operating a relevant prototype system for model validation; (2) establishing a mathematical model for fluid flow and transport; (3) deploying sub-scale molecular modeling.

de Almeida, Valmor F↗

Solar Decarbonization of Paraffin Dehydrogenation Through Particle Heat Carriers (Final Technical Report)

This project focuses on solutions to decarbonize high-temperature catalytic processes using solar thermal heat. The primary project goal is to show the validity of a moving packed bed reactor for propane dehydrogenation using catalyst particles as the heat carrier for the reaction, which can be heated by concentrated solar energy in a particle receiver. This concept, if further developed, may provide a cost-effective pathway for converting lower value gases to important chemical precursors for industrial materials using only renewable energy. The project was divided into six tasks. In Task 1, DFT calculations were performed to understand the role of Pt and Sn in the catalytic dehydrogenation reaction. In Task 2 chemical kinetics measurements were made for several catalyst formulations at high temperatures. In Task 3, the solar absorptance of catalyst particles was compared to the absorptance of commonly used materials in particle receivers. In Task 4, numerical models were developed which could predict performance of the complete system and predict specific temperatures in the system. In Task 5, a prototype system was designed, fabricated, and tested to show the validity of the concept. Task 6 concerned project management activities. Experiments with the prototype showed repeatable thermal performance at temperatures targeted for the reaction. A limited set of tests were done with active catalyst and propane dehydrogenation, showing conversion of propane to propylene with a range of conversions and selectivities. The results are promising, and the prototype designed was reliable during testing, and the team expects that further development of the prototype would yield improved results. A numerical model framework based on coupled fluid and particle mechanics was developed with high computational efficiency using GPU calculations. The model may prove highly useful for evaluating other high-temperature particle systems. However, it was determined that simpler porous media models were good fits for the needs of the current moving packed bed concept. Data showing strong solar absorption of the particles validates the plan of using existing solar particle receivers with only a change in the particle type. Catalyst investigation showed that Pt 1 Sn 3 is the most viable candidate for developing PtSn catalysts for high temperature propane dehydrogenation, considering the balance of activity, selectivity, and deactivation. This project completed an initial study of various factors needed to incorporate a moving bed catalytic reactor for propane dehydrogenation into a concentrated solar thermal particle system. Future developments may allow this technology to be scaled up and help to use solar thermal energy to decarbonize not only the propane dehydrogenation reaction, but other gas-solid catalytic reactions at similar temperatures.

14 SOLAR ENERGY↗

Subsurface Temperature, Moisture, Thermal Conductivity and Heat Flux, Area A, B, C, and D, Utqiagvik (Barrow), Alaska, Ongoing from 2012

Subsurface soil monitoring stations are located across each of the four NGEE Arctic, Utqiagvik (Barrow), Alaska, intensive study Areas: (A) low-centered polygons with well-defined troughs, (B) high-centered polygons, (C) flat-centered or transitional polygons, and (D) inundated low-centered polygons with no troughs. Two data products are being generated - both with high temporal (hourly) and spatial resolution (within polygon and with depth): (1) soil profile temperature measurements and (2) active layer and permafrost temperature and moisture measurements from instrumented soil pits. This data package currently contains seventy-nine .csv files, one .xlsx (with complimentary .csv file), and one .pdf. Data from September 2012 through August 2022 are available as annual files. Additional data will be added annually after quality checks have been completed. These data are being collected to better understand the thermal dynamics of the active layer and permafrost. Together this information serves as calibration and evaluation data for fine-scale simulations of polygons. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

A Self-Consistent Model of the Interacting Ring Current Ions with Electromagnetic ICWs

Initial results from a newly developed model of the interacting ring current ions and ion cyclotron waves are presented. The model is based on the system of two bound kinetic equations: one equation describes the ring current ion dynamics, and another equation describes wave evolution. The system gives a self-consistent description of ring current ions and ion cyclotron waves in a quasilinear approach. These two equations were solved on a global scale under non steady-state conditions during the May 2-5, 1998 storm. The structure and dynamics of the ring current proton precipitating flux regions and the wave active zones at three time cuts around initial, main, and late recovery phases of the May 4, 1998 storm phase are presented and discussed in detail. Comparisons of the model wave-ion data with the Polar/HYDRA and Polar/MFE instruments results are presented..

Khazanov, G. V.↗

Benchmarking Planning Applications on the Qualcomm Snapdragon

We benchmark several space planning/scheduling applications on the Qualcomm Snapdragon 855 Handheld Development Kit (HDK), a high performance embedded processor used in many mobile phones.We are flying 2 Snapdragon HDKs onboard the International Space Station (ISS) where they are hosted by the the Spaceborne Computer-2 by Hewlett Packard Enterprise linked by USB and 12V power delivery. We run computational benchmarks using three planner/ schedulers that are used for several space missions: Multi- Mission Executive (MEXEC), Compressed Large-scale Activity Scheduling and Planning (CLASP), and M2020 Ground Scheduler (Surrogate). We compare the Snapdragon performance to a performance baseline on Linux workstations. In addition, we are currently working on benchmarking the same applications on other space flight processors, such as the LEON4 Processor on the Sabertooth card, the LEON3 Processor on the Sphinx card, and the RAD750 processor.

Chien, Steve↗

Knowledge based ranking algorithm for comparative assessment of post-closure care needs of closed landfills

Post-closure care (PCC) activities at landfills include cap maintenance; water quality monitoring; maintenance and monitoring of the gas collection/control system, leachate collection system, groundwater monitoring wells, and surface water management system; and general site maintenance. The objective of this study was to develop an integrated data and knowledge based decision making tool for preliminary estimation of PCC needs at closed landfills. To develop the decision making tool, 11 categories of parameters were identified as critical areas which could affect future PCC needs. Each category was further analyzed by detailed questions which could be answered with limited data and knowledge about the site, its history, location, and site specific characteristics. Depending on the existing knowledge base, a score was assigned to each question (on a scale 1-10, as 1 being the best and 10 being the worst). Each category was also assigned a weight based on its relative importance on the site conditions and PCC needs. The overall landfill score was obtained from the total weighted sum attained. Based on the overall score, landfill conditions could be categorized as critical, acceptable, or good. Critical condition indicates that the landfill may be a threat to the human health and the environment and necessary steps should be taken. Acceptable condition indicates that the landfill is currently stable and the monitoring should be continued. Good condition indicates that the landfill is stable and the monitoring activities can be reduced in the future. The knowledge base algorithm was applied to two case study landfills for preliminary assessment of PCC performance.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

On the mechanisms of stress relaxation and intensification at the lithium/solid-state electrolyte interface

Under electrochemical cycling, stress intensification and relaxation within small volumes at the lithium/solid-state electrolyte (SSE) interface are thought to be critical factors contributing to mechanical failure of the SSE and subsequent short-circuiting of the device. Nanoindentation has been used to examine the diffusion-limited pressure lithium can support in the absence of active dislocation sources at high homologous temperatures. Based on the underlying physics of this deformation mechanism, a simple perturbation model coupling local current density, elastic stress, and diffusional creep relaxation is introduced. Combining this analysis with the indentation results, it is possible to describe a defect length scale which is too large for effective diffusional creep relaxation, but too small for efficient dislocation multiplication. In this instance, the properties of the SSE may become critical, and relevant indentation results of the SSE are described. Lastly, the final outcome of the proposed analysis is a newly developed deformation mechanism map.

36 MATERIALS SCIENCE↗

Integrated Refrigeration and Storage for Advanced Liquid Hydrogen Operations

NASA has used liquefied hydrogen (LH2) on a large scale since the beginning of the space program as fuel for the Centaur and Apollo upper stages, and more recently to feed the three space shuttle main engines. The LH2 systems currently in place at the Kennedy Space Center (KSC) launch pads are aging and inefficient compared to the state-of-the-art. Therefore, the need exists to explore advanced technologies and operations that can drive commodity costs down, and provide increased capabilities. The Ground Operations Demonstration Unit for Liquid Hydrogen (GODU-LH2) was developed at KSC to pursue these goals by demonstrating active thermal control of the propellant state by direct removal of heat using a cryocooler. The project has multiple objectives including zero loss storage and transfer, liquefaction of gaseous hydrogen, and densification of liquid hydrogen. The key technology challenge was efficiently integrating the cryogenic refrigerator into the LH2 storage tank. A Linde LR1620 Brayton cycle refrigerator is used to produce up to 900W cooling at 20K, circulating approximately 22 g/s gaseous helium through the hydrogen via approximately 300 m of heat exchanger tubing. The GODU-LH2 system is fully operational, and is currently under test. This paper will discuss the design features of the refrigerator and storage system, as well as the current test results.

Liquefaction↗

Mid-Latitude Circulation and Extremes in a Changing Climate

Mid-latitude extreme weather events are responsible for a large part of climate-related damage. Yet large uncertainties remain in climate model projections of heat waves, droughts, and heavy rain/snow events on regional scales, limiting our ability to effectively use these projections for climate adaptation and mitigation. These uncertainties can be attributed to both the lack of spatial resolution in the models, and to the lack of a dynamical understanding of these extremes. The approach of this project is to relate the fine-scale features to the large scales in current climate simulations, seasonal re-forecasts, and climate change projections in a very wide range of models, including the atmospheric and coupled models of ECMWF over a range of horizontal resolutions (125 to 10 km), aqua-planet configuration of the Model for Prediction Across Scales and High Order Method Modeling Environments (resolutions ranging from 240 km – 7.5 km) with various physics suites, and selected CMIP5 model simulations. The large scale circulation will be quantified both on the basis of the well tested preferred circulation regime approach, and very recently developed measures, the finite amplitude Wave Activity (FAWA) and its spectrum. The fine scale structures related to extremes will be diagnosed following the latest approaches in the literature. The goal is to use the large scale measures as indicators of the probability of occurrence of the finer scale structures, and hence extreme events. These indicators will then be applied to the CMIP5 models and time-slice projections of a future climate.

54 ENVIRONMENTAL SCIENCES↗