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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Relative Water Content, Bidirectional Reflectance and Bidirectional Transmittance of the Interior of Detached Leaves During Dry Down.

Remotely sensing the water status of plants and the water content of canopies remain long-term goals of remote sensing research [1]. Estimates of canopy water content commonly involve measurements in the 900nm to 2000nm portion of the optical spectrum [1]. We have used optical polarization techniques to remove leaf surface reflection and to demonstrate that the visible light reflected by the interior of green healthy corn leaves measured in situ inversely depends upon the leaf relative water content (RWC) [2]. In the research reported here, we again used optical polarization techniques in order to remove the leaf surface reflection from our measurements. This allowed us to monitor the interiors of detached corn leaf samples during leaf dry down measuring for each sample the RWC, bidirectional spectral reflectance and bidirectional spectral transmittance over the wavelength range 450nm to 2,500nm. Our new results like our earlier results show light scattered by the leaf interior measured in the visible wavelength region generally increased as leaf RWC decreased. However, the spectral character and the much improved signal noise of our new results shows the RWC-linked visible light scattering changes are due to leaf structural changes. Our new results show that scattering changes that occur with changing leaf RWC are not attributable to molecular configuration changes in cellular pigments.

Corn↗
NASA NTRS2017

Aseptic Handling of the MOMA Mass Spectrometer After Dry Heat Microbial Reduction

Mars Organic Molecule Analyzer Mass Spectrometer (MOMA-MS) is an instrument in the larger MOMA instrument suite for the European Space Agency (ESA) ExoMars 2020 Rover. As a life-detection instrument on a Mars landing mission, MOMA-MS has very stringent Planetary Protection (PP) bioburden requirements. Within the MOMA instrument suite, the hardware surfaces of the sample path must be cleaned to a level of 0.03 spore/sq m. To meet this requirement, a process called Dry Heat Microbial Reduction (DHMR) is used to decrease the number of viable spores by 4 orders of magnitude. Before DHMR, the hardware is handled using standard cleanroom practices, while after DHMR, all sample path surfaces must be handled aseptically when exposed. Aseptic handling of the sample path involves a number of strategies and protocols including working only in an aseptic ISO class 5 work space, limiting the amount of time of exposure, using sterile garmenting with sterile gloves, and using sterile tools. Before work begins, the aseptic workspace will be tested for bioburden and particle fallout, and all tools that will contact sample path surfaces must be sterilized. During the exposure activity, sterile garments will be worn, sterile tools will be handled in a 2 person set up so that the operator touches only the sterile tool and not the exterior surfaces of the sterile pouch, and the environment will be monitored with active and passive fallout for bioburden and particle levels. Any breach in the planetary protection cleanliness can necessitate repeating DHMR, which not only has significant cost and schedule implications, it also become a risk to hardware that is not rated for repeated long exposures to high temperatures.

Life Detection↗
NASA NTRS2017

Prebiotic Peptide (Amide) Bond Synthesis Accelerated by Glycerol and Bicarbonate Under Neutral to Alkaline Dry-Down Conditions

Past studies of prebiotic peptide bond synthesis have generally been carried out in the acidic to neutral pH range [1, 2]. Here we report a new process for peptide bond (amide) synthesis in the neutral to alkaline pH range that involves simple dry-down heating of amino acids in the presence of glycerol and bicarbonate. Glycerol was included in the reaction mixture as a solvent and to provide hydroxyl groups for possible formation of ester intermediates previously implicated in peptide bond synthesis under acidic to neutral conditions [1]. Bicarbonate was added to raise the reaction pH to 8-9.

Forsythe, J. G.↗
NASA NTRS2018

Dried Plum as a Candidate Radiomitigant

This presentation will focus on data obtained from that authors' studies that test the efficacy of dried plum as a countermeasure against radiation-induced bone loss.

Schreurs, Ann-Sofie↗
NASA NTRS2016

Dried Plum Diet Prevents Bone Loss Caused by Ionizating Radiation: Reduces Pro-Resorption Cytokine Expression, and Protects Marrow-Derived Osteoprogenitors

Future long duration missions outside the protection of the Earth's magnetosphere, or unshielded exposures to solar particle events, achieves total doses capable of causing cancellous bone loss. Cancellous bone loss caused by ionizing radiation occurs quite rapidly in rodents: Initially, radiation increases the number and activity of bone-resorbing osteoclasts, followed by decrease in bone forming osteoblast cells. Here we report that Dried Plum (DP) diet completely prevented cancellous bone loss caused by ionizing radiation (Figure 1). DP attenuated marrow expression of genes related to bone resorption (Figure 2), and protected the bone marrow-derived pre-osteoblasts ex vivo from total body irradiation (Figure 3). DP is known to inhibit resorption in models of aging and ovariectomy-induced osteopenia; this is the first report that dietary DP is radioprotective.

Radioprotective↗
NASA NTRS2020

X-ray Amorphous Components of Antarctica Dry Valley Soils: Weathering Implications for Mars

The Antarctic Dry Valleys (ADV) comprise the largest ice-free region of Antarctica. Precipitation usually occurs as snow, relative humidity is frequently low, and mean annual temperatures are about -20°C [1]. Substantial work has focused on soil formation in the ADVs [2], however, little work has focused on the mineralogy of secondary alteration phases. The dominant weathering process in the ADV region is physical weathering, however, chemical weathering has been well documented [3]. The occurrence of chemical weathering processes are suggested by the presence of clay minerals and iron and titanium oxides in soil. Previously we have investigated soils from two sites in the ADV’s and have shown evidence of chemical weathering by the presence of clay minerals (vermiculite, smectite), short-range ordered (SRO) and/or X-ray amorphous materials, and Fe- and Tioxides as well as the presence of discrete calcite crystals [4, 5]. The Chemistry and Mineralogy (CheMin) instrument onboard the Mars Curiosity rover has detected abundant amounts (approx. 25-30 wt. %) of X-ray amorphous materials in a windblown deposit or “soil” (Rocknest) and in a sedimentary rocks [6,7,8]. The occurrence of large amounts of X-ray amorphous materials in Mars sediments is surprising because these materials are usually present in small quantities in terrestrial environments. The objective of this study is to further characterize the chemistry and mineralogy, specifically the secondary alteration mineralogy and the presence of X-ray amorphous material, of soils from two sites we have previously studied, a subxerous soil in Taylor Valley, and an ultraxerous soil in University Valley. While the chemical alteration processes and mineralogy of the ADV has been documented previously, there has been limited discussion on the occurrence and formation of X-ray amorphous and SRO materials in Antarctica soils. The process of aqueous alteration in the ADVs may have implications for pedogenic processes on Mars, and may lead to a better understanding to the abundance of amorphous material found in sediments in Gale crater.

Quinn, J. E.↗
NASA NTRSDate not supplied

Solvent-Free Preparation of High Energy, Binder-Free Electrodes Enabled by Dry Compressible Holey Graphene

Graphene is an atomically thick sheet consisting of a graphitic carbon network with excellent mechanical strength, electrical and thermal conductivity, and chemical stability. Holey graphene, a structural derivative of graphene, has an array of through-the-thickness holes across the lateral surface of the nanosheet. The presence of these holes has minimal detrimental effect on the graphene properties and leads to enhanced performance in applications such as electronics, sensors, and energy storage. For example, these holes allow more facile cross-plane ion and gas transport than intact graphene, making holey graphene an ideal electrode material for electrochemical energy storage. This presentation will focus on the ability of holey graphene to be compression molded into robust articles or architectures under solvent-free conditions without the need for potentially parasitic binders. The unique dry compressibility of holey graphene has enabled facile fabrication of high mass loading electrodes with both high density and high porosity, which have found use in supercapacitors and various high-energy battery systems such as lithium-oxygen, lithium-sulfur, and lithium-selenium batteries.

Yi Lin↗
NASA NTRSDate not supplied

Ultrahigh Mass Loading Batteries with Holey Graphene-Enabled Dry-Pressed Cathode Architectures

Holey graphene is a structural derivative of graphene with arrays of nanometer-sized, through-thickness holes across the lateral surface of the atomically thin nanosheet. It has been widely acknowledged that the presence of holes improves ion transport through the graphene planes, making holey graphene an ideal electrode material for electrochemical energy storage. We recently discovered another unique attribute of holey graphene in that it can be directly compressed from powder into electrode in a single step without the use of solvent or binder. In addition to neat holey graphene electrodes, composite electrodes with holey graphene as an ultralightweight scaffold host filled with various active materials can also be readily prepared in a similar solvent-free and binder-free fashion. The active materials can be metal-containing catalysts for lithium-oxygen batteries, lithium-ion battery electrode materials, or high energy density components such as sulfur. Compared to the conventional slurry-based process, the dry-press method is comparably much more suitable toward the facile and scalable preparation of ultrahigh mass loading electrodes with ultrahigh areal capacities.

holey graphene, cathode scaffold, lithium metal, h↗
NASA NTRSDate not supplied

The Mineralogy and Cation Exchange of Sediments in Don Juan Pond, Antarctica Dry Valley: Implications for Mars

Located in the McMurdo Dry Valleys of Antarctica (MDV) is among of the saltiest bodies of water of Earth, Don Juan Pond (DJP)[1]. DJP pond waters are unique in that they contain nearly 40% salt by weight including 95% CaCl2 [1-5] and they never evaporate or freeze entirely due to the high hygroscopicity and low eutectic temperature of the CaCl2 brine (-52 ̊C) [6]. The source of DJP water is suggested to be due to groundwater upwelling through a weathered dolerite aquifer and/or near-surface runoff, including salt deliquescence in the pond’s watershed [7,8], however the source of water is still a topic of study. During the 2017-2018 field season, we collected soil samples and altered sediments on hillslopes and drainage basins near the pond (Fig. 1). Two drill bores were also acquired in Don Juan Pond sediments in a episodically flooded area of the pond basin. This study's objectives were to characterize the mineralogy of these soils and sediments to determine if there are mineralogical indicators and/or controls for the delivery of salts to DJP and understand the role of salts on Mars on these analog studies.

V M Tu↗
NASA NTRSDate not supplied

X-ray Amorphous Materials in Soils from the Antarctica Dry Valleys: Insights into Aqueous Alteration Processes on Mars

The CheMin XRD instrument onboard the Curiosity rover has discovered abundant quantities of X-ray amorphous materials (25-40 wt. %) in windblown deposits and sedimentary rocks on Mars. The large amounts of X-ray amorphous materials on Mars is surprising because these materials are usually not found in large abundances in terrestrial soils. We have previously identified short-range ordered or X-ray amorphous materials in Antarctica Dry Valleys (ADV) soils. The ADV are one of the driest and coldest environments on Earth and provide an ideal process analog environment for Mars. The objective of this study was to further characterize the chemistry and mineralogy of ADV soils, specifically to quantify and characterize the X-ray amorphous materials. Two soils were characterized from different elevations in the ADV - a low elevation, coastal, subxerous soil in Taylor Valley and a high elevation, ultraxerous soil in University Valley. Rietveld analysis of XRD patterns generated with a CheMin-like analog instrument indicated up to 40 and 15 wt. % X-ray amorphous materials in the Taylor and University Valley soils, respectively. The high abundance of X-ray amorphous materials in Taylor Valley is surprising for one of the driest places on Earth. These materials may have been physically and chemical altered during soil formation, however, the limited interaction with water and low temperatures may have resulted in the formation of “immature” X-ray amorphous or SRO materials. Perhaps, a similar process contributes to the formation of the high content of X-ray amorphous materials detected on Mars.

Antarctica↗
NASA NTRS2021

Land Surface Modeling Over the Dry Chaco: The Impact of Model Structures, and Soil, Vegetation and Land Cover Parameters

In this study, we tested the impact of a revised set of soil, vegetation and land cover parameters on the performance of three different state-of-the-art land surface models (LSMs) within the NASA Land Information System (LIS). The impact of this revision was tested over the South American Dry Chaco, an ecoregion characterized by deforestation and forest degradation since the 1980s. Most large-scale LSMs may lack the ability to correctly represent the ongoing deforestation processes in this region, because most LSMs use climatological vegetation indices and static land cover information. The default LIS parameters were revised with improved soil parameters, satellite-based interannually varying vegetation indices (leaf area index and green vegetation fraction) instead of climatological vegetation indices, and yearly land cover information instead of static land cover. A relative comparison in terms of water budget components and “efficiency space” for various baseline and revised experiments showed that large regional and long-term differences in the simulated water budget partitioning relate to different LSM structures, whereas smaller local differences resulted from updated soil, vegetation and land cover parameters. Furthermore, the different LSM structures redistributed water differently in response to these parameter updates. A time-series comparison of the simulations to independent satellite-based estimates of evapotranspiration and brightness temperature (Tb) showed that no LSM setup significantly outperformed another for the entire region and that not all LSM simulations improved with updated parameter values. However, the revised soil parameters generally reduced the bias between simulated surface soil moisture and pixel-scale in situ observations and the bias between simulated Tb and regional Soil Moisture Ocean Salinity (SMOS) observations. Our results suggest that the different hydrological responses of various LSMs to vegetation changes may need further attention to gain benefits from vegetation data assimilation.

Michiel Maertens↗
NASA NTRS2022

Assessment of ICESat-2’s Horizontal Accuracy Using Precisely Surveyed Terrains in McMurdo Dry Valleys, Antarctica

This article presents an assessment of the horizontal accuracy and precision of the laser altimetry observations collected by NASA’s Ice, Cloud, and Land Elevation Satellite-2 (ICESat-2) mission. We selected the terrain-matching method to determine the position of laser altimeter profiles within a precisely known surface, represented by a digital elevation model (DEM). We took this classical approach a step further, approximated the DEM by planar surfaces, and calculated the optimal position of the laser profile by minimizing the square sum of the elevation differences between reference DEMs and ICESat-2 profiles. We found the highly accurate DEMs of the McMurdo Dry Valleys (DV), Antarctica, ideal for this research because of their stable landscape and rugged topography. We computed the 3-D shift parameters of 379 different laser altimeter profiles along two reference ground tracks collected within the first two years of the mission. Analyzing these results revealed a total geolocation error (mean +1 σ ) of 4.93 m for version 3 and 4.66 m for version 4 data. These numbers are the averages of the six beams, expressed as mean +1 σ and lie well within the mission requirement of 6.5 m.

calibration↗
NASA NTRS2023

Wetting and Drying Trends Under Climate Change

The geography and timing of changes in water availability under climate change are of considerable societal interest. Characterizing these changes in a robust and meaningful manner, however, has not been easy. In the past decade, studies have engaged two provocative hypotheses to explain and predict large-scale trends in water availability. One hypothesis holds that there will be increased contrasts in available water, as wet places become wetter and dry places become drier. Another hypothesis states that there will be global aridification, as widespread increases in evapotranspiration overwhelm changes in precipitation in most terrestrial regions. There is an extensive and sometimes contentious literature on the evidence for each. In some cases, these debates reflect direct disagreement, but the appearance of disagreement is exaggerated by the diversity of methods and terminologies employed in different studies. Herein we examine the applicability and limits of both hypotheses across different frameworks, scales and contexts, yielding insights on hydrologic change and the future of water availability.

Benjamin F. Zaitchik↗
NASA NTRSDate not supplied

Lithium Nucleation of Anode-Free Solid-State Batteries with a Dry Compressible Interlayer

Anode-free lithium batteries offer promising advantages, including increased energy density and the ability to address common mechanistic failures within the cell, thus increasing safety. One way that can make this possible is to control lithium nucleation. This could be achieved by reducing the overpotential required and implanting lithophilic nucleation sites in an anodic interlayer to aid in lithium ion transport and plating. The concept has been utilized in solid-state battery systems where electrolytes are solids with further improved safety and structural longevity. In this presentation, we discuss the use of a silver-holey graphene-based anodic interlayer that can be fabricated via direct dry compression without the use of solvent or binder. The addition of silver to the holey graphene matrix creates a route to lithium plating via a lower-energy intermediate. This idea is supported by the presence of a lithium-silver alloy that forms during the activation step. It is understood that the embedded silver acts as a nucleation site for lithium ions, thereby assisting in even plating. This control, combined with the added cushion of the holey graphene itself, can help reduce dendrite formation, ultimately increasing the safety and lifetime of the solid-state batteries.

Solid state batteries↗
DOE OSTI2025

ECAR-8823 Rev 0 Structural Evaluation of the MARVEL Support Frame in Dry Critical Configuration

The purpose of this ECAR is to structurally evaluate the MARVEL reactor support frame during the dry critical (DryCrit) start-up testing. The ECAR includes evaluation of the DryCrit configuration for tip-over of the frame during a seismic event, floor loading of the frame on the MFC-720 (TREAT) operating floor, stress analysis of the adapter ring, and stress analysis of the frame itself for gravity and seismic loads.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗
DOE OSTI2026

Flaw Tolerance Assessment for DOE Standard SNF Dry Storage Canisters - 26550

The U.S. DOE has designed four spent nuclear fuel (SNF) dry storage canisters for storing DOE standardized SNFs. The DOE standard canisters are cylindrical shells with a diameter of 24 inches (610 m) or 18 inches (457 m), a wall thickness of 0.5 inches (12.7 m) or 0.375 inches (9.53 m), and a length of 15 feet (4.57 m) or 10 feet (3.05 m). These DOE canister geometries are completely different from commercial canisters. The latter may experience chloride-induced stress cracking corrosion (CI-SCC) because they are stored near coastal regions. The former may not experience CI-SCC but face different challenges because they are stored in the SNF storage facilities. Because of large residual stresses, mechanical flaws may occur in the DOE canisters during long-distance transportation or lifting handling. To date, only limited structural integrity analyses were carried out through drop tests on the DOE canisters, but a more general flaw tolerance assessment has not been performed. Therefore, the failure assessment diagram (FAD)-based fracture mechanics method, as codified by the latest API 579-1/ASME FFS-1-2021 Edition, is adopted in this work to assess surface flaw tolerance for DOE canisters under operation loading and welding residual stresses (WRS), where the new code-recommended WRS distributions are used. To more adequately consider the transverse distribution of WRS, an equivalent WRS distribution is proposed to account for the WRS reduction with distance from the weld centerline. Moreover, the closed-form solutions of stress intensity factor K, which serves as the crack driving force during subcritical crack growth, are developed from the tabular data of the K factors provided in API 579-1/ASME FFS-1 and used to determine more accurate flaw sizes at flaw instability. Subsequently, the Level 2 assessment procedures with 12 assessment steps, as codified and detailed in API 579-1 and ASME FFS-1, are followed to assess the flaw tolerance for the surface flaws in the DOE standard canisters with consideration of normal or accident operation loads combined with WRS. The assessment results show that the four designs of DOE standard canisters can tolerate all surface flaws that meet the code permitted maximum sizes of a flaw length of 8 inches (i.e., 200 mm) and a flaw depth of 80% wall thickness. This demonstrates that all designs of DOE standard canisters are robust and reliable.

DOE standard canister↗
DOE OSTI2025

Seismic DAS observations of a large underground chemical explosion in dry tuff

On 18 October 2023 a 16.3-ton TNT equivalent chemical explosion was detonated underground at the Nevada National Security Site, generating a seismic event with a magnitude of 1.7 (Meyers et al., 2024). The associated seismic wavefield was measured on a Distributed Acoustic Sensing (DAS) array with slant range distances from 27 m – 1123 m. The first arriving phase traveled at an apparent velocity of about 2640 m s -1 from 27 m to 420 m slant range and about 2470 m s -1 from 505 m to 1123 m slant range according to the first arrival moveouts on the DAS data. The first arrival from the explosion temporarily saturated the cable from a slant range of 27 m – 186 m and 0.009 s to 0.084 s post detonation. From 186 m slant range to 420 m slant range, peak strain rates of 5.6 x 10 6 nm m -1 s -1 were observed for the first arrival phase. For the first arrival from 505 m slant range to 1123 m slant range, peak strain rates reduced to 8.0 x 104 nm m -1 s -1 . A comparison of the scaled accelerations computed from DAS, the geophone pairs, and the measurements of co-located accelerometer pairs show common agreement at the scaled ranges of the single point sensors. This study adds to the body of work reporting near-source DAS observations of the seismic wavefields generated by underground chemical explosions. These results indicate that near-source DAS observations can refine interpretations of phase identification from single-point sensor observations. Phase identification could be one mechanism that contributes scatter to single point seismic measurements which would confound the performance of empirical relationships for small explosions. Removing that mechanism may therefore reduce interstation variability and increase empirical relationship performance for small explosions.

58 GEOSCIENCES↗