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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

Economic and Environmental Assessment of Biological Conversions of Agile BioFoundry (ABF) Bio-Derived Chemicals

Bio-derived chemicals are an essential part of the growing bioeconomy. They possess the potential to boost a new domestic bioproduct industry, improve the sustainability of integrated biomanufacturing, and reduce U.S. dependence on fossil energy. The Agile BioFoundry (ABF) consortium, a Department of Energy (DOE)-sponsored collaboration, is investigating biobased pathways to produce advantaged products including advanced biofuels, fuel intermediates, and bioproducts. ABF is integrating advanced computational tools for biological engineering, process design and data analysis, and economic/sustainability modeling tools into a comprehensive and dynamic platform for biomanufacturing of microbes and using them to produce key metabolic intermediates or beachhead molecules which may be derivatized into several distinct bioproducts of industrial interest. In this presentation, we first discuss a methodology to select a single exemplar product molecule to represent each beachhead pathway based on similarities with other end-molecule options (yields/titers/rates, fermentation operation mode, oxygen requirements, general separations challenges, etc.), in order to maintain a reasonable number of cases for rigorous process simulation. We then use techno-economic analysis (TEA) and life-cycle analysis (LCA) to highlight sensitivities and trends around economic performance and environmental footprint, reflecting examples for two selected ABF technology pathways to bio-derived chemicals: 1) adipic acid production via muconic acid fermentation from mixed sugars with Pseudomonas putida and 2) cineole via geranyl diphosphate with Rhodosporidium toruloides. We present multi-variable scan plots highlighting key drivers on costs and greenhouse gas emissions in order to identify the parameter space in which each pathway could ultimately achieve economic and environmental sustainability meeting or exceeding commodity product benchmarks, thus prioritizing future R&D focus areas.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

NETL CO2U LCA Guidance Toolkit Introduction

This presentation was given on October 25, 2021 to the Fossil Energy and Carbon Management Carbon Use Welcome Session for algae-based projects. It described the LCA tools available under the NETL CO2 Utilization Guidance Toolkit.

Krynock, Michelle↗

Compatibility Of Steels At 450°-650°C In Supercritical CO2 With O2 And H2O Additions

Direct-fired supercritical CO2 (sCO2) power cycles are being commercialized to revolutionize fossil energy as a low-emission power source. However, the cycle will increase O2 and H2O in the sCO2 and the implications of these additions have not been fully studied, particularly for lower cost steels that are needed in the lower temperature segments of the plant. Representative 9 and 12%Cr ferritic-martensitic (FM) steels and conventional and advanced austenitic steels were evaluated at 450-650°C to determine the maximum use temperatures in sCO2 with 1%O2 and 0.1%H2O at 300 bar. Compared to research grade (low impurity) sCO2 in indirect-fired cycles, the mass gains and scale thickness were not significantly changed for FM steels: both formed thick duplex Fe-rich scales. For stainless steels, higher mass gains were observed in all cases with increased Fe-rich oxide nodule formation. After 1000h at 650°C, the measured bulk C content was high for all of the steels with the addition of impurities suggesting a lower maximum operating temperature for steels. The post-exposure impact of the environment on room temperature tensile properties also will be discussed.

Pint, Bruce↗

sCO2 Primary Power Large-Scale Pilot Plant FEED Summary

Echogen Power Systems and its project partners the Electric Power Research Institute, CDM Smith, Riley Power Inc. (a Babcock Power Inc. company), and the University of Missouri completed the Front-End Engineering Design (FEED) study of a nominal 10 MWe supercritical carbon dioxide (sCO2) large-scale pilot plant based on Recompression Brayton Cycle (RCBC) architecture. The FEED study was completed under Phase II of the U.S. Department of Energy Fossil Fuel Large-Scale Pilots program. The FEED study scope included the preliminary design of the combustion and environmental control systems, the primary heater, the sCO2 power cycle and its associated turbomachinery, and the balance of plant equipment to determine accurate cost and schedule requirements for fabrication and installation of the system at the University of Missouri’s Combined Cooling, Heat, and Power Plant, located in Columbia, Missouri. The RCBC sCO2 cycle presents superior thermodynamic efficiency compared to steam-Rankine cycles and is adaptable to a broad range of heat sources. The risk aversion of the power generation industry requires a successful large-scale pilot plant demonstration to enable financing and deployment of commercial-scale plants. Therefore, successful construction and demonstration of a 10 MWe RCBC sCO2 power plant would empower a transformational step forward for the efficiency of the next generation of utility power plants. This paper provides details on the primary heater, environmental control systems, and sCO2 power cycle design and performance.

01 COAL, LIGNITE, AND PEAT↗

LCA Tools Available at NETL

This presentation was given at the virtual kickoff meeting for funding opportunity announcements 2596 and 2598 - University Training and Research for Fossil Energy and Carbon Management - UCR and Minority Serving Institutions (MSIs). The presentation covered available and in progress tools that can help carbon capture projects perform environmental life cycle analyses (LCAs). The presentation also briefly covers working being performed by the NETL LCA team.

Jamieson, Matthew↗

NiCrMoNb age hardenable alloy for creep-resistant high temperature applications, and methods of making

Nickel alloys, methods of making nickel alloys, articles including the nickel alloys, uses of the alloys, and methods of treating nickel alloys are described. The inventive heat resistant structural materials are suitable for applications requiring high yield stress at room temperature and good creep strength at high temperatures, such as in gas turbines, steam turbines, fossil energy boilers, aero engines, power generation systems using fluids such as supercritical carbon dioxide (e.g., advanced ultra-supercritical power plants), concentrated solar power plants, nuclear power plants, molten salt reactors: turbine blades, casings, valves, heat exchangers and recuperators.

Detrois, Martin↗

The High Capacity Type B Waste Transport Cask to Serve Dismantling Project - 18344

The United States have already announced around 20 reactor shutdown and many more in the next 10 year. Financial constraints on plant operators and the low cost of fossil energy contribute to accelerate the shutdown of additional reactors. The industry has been gaining experience with reactor dismantling and is continuously trying to improve the cost efficiency of the upcoming projects. To do so, larger and more capacitive transport casks are needed to transport increasing volume of Low Level Waste (LLW) at a more attractive cost. Waste disposal is also a major cost element in a dismantling project. Consequently, the capacity to segment, package and transport the waste in the most optimized configuration will result in significant cost savings. While for LLW, the constraints for package requirements are limited, activated waste resulting mainly from reactor vessel and vessel internals segmentation require additional shielding to meet disposal and transportation regulations. The key element to succeed is the availability on the market of a licensed type B transport package with a larger payload that allows at the same time an optimization of the waste segmentation. AREVA TN has designed and licensed versatile high capacity type B casks for the transport of spent fuel canisters as part of the NUHOMS{sup R} system that can also be used to transport radioactive waste. While it will take a few more years to transport spent fuel to a consolidated interim storage facility and even more to a repository, the type B casks can be used to transport activated LLW from dismantled reactors to disposal sites. A first of a kind project will be performed with AREVA's partner NorthStar at Vermont Yankee Nuclear Power Plant. AREVA's team will perform the reactor segmentation and package the material into an AREVA's large capacity type B cask. This unmatched cask capacity is expected to significantly decrease the LLW disposal costs, as well as the onsite operations costs, while optimizing the schedule. The package will be transported by rail to waste disposal facilities. This paper will present the main characteristics of the package, provide an update of the overall schedule, and explain the innovations that contribute to simpler and more cost effective transport and operation. Finally, it will emphasize the benefits of using larger type B casks for immediate and future transportation needs. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

In-Situ Species Concentration Measurements in Ammonia-Mix Flames Using FTIR Spectroscopy

Hydrogen and ammonia represent two carbon-free fuel sources that could be used in place of current fossil energy sources in combustion systems. To develop optimized ammonia combustion systems, validated modeling tools are needed. In the open literature, it has been shown that the complex chemistry associated with fuel-bound nitrogen contained in ammonia differs greatly from natural gas or hydrogen combustion. As a result, several new chemical kinetic mechanisms have been developed. Many of these mechanisms have been validated experimentally, however this has primarily focused on bulk parameters such as laminar flame speed and ignition delay time. Critically, high quality measurements of species concentrations are needed under controlled conditions which are easily represented by simple models. In this paper, direct, in-situ measurements of species concentrations and gas temperature are performed in a laminar flat-flame burner. This arrangement enables comparison with 1D model predictions, better isolating chemical kinetics from the fluid dynamics. Quantitative species concentrations are determined by absorption spectroscopy using an FTIR spectrometer. Fuel compositions representative of cracked ammonia (NH3/H2) and ammonia-natural gas (NH3/CH4) are considered for rich and lean equivalence ratios. A major focus of the paper is on the selection of spectral features for nitric oxide and ammonia and correcting for large amounts of baseline H2O absorption.

Bedick, Clinton↗

NiCrMoNb age hardenable alloy for creep-resistant high temperature applications, and methods of making

Nickel alloys, methods of making nickel alloys, articles including the nickel alloys, uses of the alloys, and methods of treating nickel alloys are described. The inventive heat resistant structural materials are suitable for applications requiring high yield stress at room temperature and good creep strength at high temperatures, such as in gas turbines, steam turbines, fossil energy boilers, aero engines, power generation systems using fluids such as supercritical carbon dioxide (e.g., advanced ultra-supercritical power plants), concentrated solar power plants, nuclear power plants, molten salt reactors: turbine blades, casings, valves, heat exchangers and recuperators.

Detrois, Martin↗

Market analysis for the integration of new power technologies: A case study of the deployment of hybrid fossil-based generator plus energy storage (ES-FE)

This study examines the national landscape of hybridized fossil energy (FE) power plants with energy storage (ES) technologies (“ES-FE”) and presents the compilation of an ES-FE dataset, which includes over 65 ES-FE projects and concepts in the United States, comprising approximately 500 MWh of co-located ES capacity with FE power plants. This study also estimates the economic feasibility of adding ES to existing FE power plants by characterizing the potential revenues that can be generated by the ES component through flexibility and capacity value. The analysis focuses on ES technologies with 2- to 10-h. durations located in four U.S. independent system operators (ISOs): Midcontinent ISO (MISO), Electric Reliability Council of Texas (ERCOT), PJM Interconnection (PJM), and California ISO (CAISO), which have +70,000 MW of combined FE power capacity that could add ES. Annual revenues are estimated for the ES component using a what-if-analysis approach, for capacity value, price arbitrage, or ancillary services provision. The results show that annual revenues depend on the end-use storage service, wholesale electricity and capacity market prices, and ES technology operation parameters such as discharging duration and cycling frequency. When performing a sensitivity analysis, ES accrues $7–178/kW-yr. via price arbitrage and ancillary services provision in the four ISOs, and $13–92/kW-yr. when providing capacity value only in MISO and PJM. A cash flow analysis is performed to estimate the net present value (NPV) of the ES addition using a range of ES costs. The study finds that for most ES technologies considered, these revenues alone are insufficient to achieve economic feasibility. In conclusion, of the 1645 total runs analyzed, 115 had positive NPVs (7%). Therefore, other revenue streams or monetizable benefits are necessary to achieve the break-even point.

20 FOSSIL-FUELED POWER PLANTS↗

Reversible Methane Electrochemical Reactors as Efficient Energy Storage for Fossil Power

The overall objective of the project was to conduct a comprehensive Research & Development (R&D) program to demonstrate the suitability and future advancement and integration of reversible methane protonic ceramic electrochemical reactors (PCERs) as an efficient Energy Storage System (ESS) with fossil fuel power plants. Fundamental process and system models are developed to conduct a preliminary conceptual study and investigate the power plant system integration requirements, performance requirements, and technical and non-technical gaps for eventual implementation at system level. Technology maturation requirements is also investigated through identifying the critical technical elements and networking with industrial technology developers and end-users.

08 HYDROGEN↗

Geothermal Power Production: Alternative Scenarios and Critical Issues

This is the last in a series of reports that completes the life cycle analyses (LCAs) of geothermal power production technologies conducted by Argonne National Laboratory. It addresses the remaining critical issues pertaining to the LCAs of geothermal electricity production: the relative contributions from plant operations and maintenance (O&M), from decommissioning (dcm), from well field exploration, and from plant operational greenhouse gas (GHG) emissions to the total life cycle performance of geothermal power plants. Contributions from O&M and dcm to the performance of other power generating technologies are also discussed. Also included in this study are LCA results for a new series of scenarios for geothermal power production. Our analysis uses fossil fuel energy consumption and GHG emissions per unit of lifetime electricity output (referred to as the fossil energy and GHG ratios, respectively) as the life cycle metrics for quantifying life cycle stage contributions to their corresponding totals, which were subsequently used for comparing the environmental performance of geothermal and other electric power production plants. Based on literature results, we concluded that the contribution from dcm to both ratios is negligible for power plants in general. Further, we found that the contribution from O&M to both ratios is generally significant for facilities with no fuel cycle (fuel production and use) burdens. In the case of geothermal power production, O&M contributes about 20% to the total for enhanced geothermal power plants, 10% for geothermal binary plants, and about 25% of the energy ratio for geothermal flash and dry steam plants. However, due to operational GHG emissions that are unique among geothermal power plants, O&M contributes only about 1% of total GHG ratios for flash and dry steam plants. These GHG emissions arise when the geofluids of these plants become exposed to the atmosphere, thus releasing dissolved GHGs. The amount of GHG emissions from these plants had a wide range. However, we found that 85% of California’s running capacity in flash and dry steam plants released 160 grams or less per kilowatt-hour of electricity produced. We developed an exploration model to account for core hole, slim hole, and confirmation well drilling that includes a probability of success for confirmation well drilling. The model shows that well field exploration represents about 20% of the total life cycle burden for large geothermal plants with numerous wells and 32% of the burden for small plants with few wells. We also analyzed a set of geothermal scenario pairs. The objective was to identify geothermal scenarios with a lower levelized cost of electricity and lower life cycle burdens. A comparison of reference with improved cases within each pair revealed that the improved cases demonstrated a lower levelized cost of electricity and lower fossil energy consumption and GHG metrics. The scenario pairs covered a range of plant capacities, well numbers and depths, resource temperatures, and plant lifetimes. Finally, we found that compared to fossil-fuel generation of electricity, both flash and dry steam geothermal electricity generation result in fewer GHG emissions: on average, only one-fifth of the GHG emissions per kilowatt-hour from a natural gas combined-cycle plant, and one-tenth of those from a coal-fired plant. Moreover, these fractions were much smaller when the fossil plants were compared with plants that use geothermal binary technology.

Sullivan, J. L.↗

Optimal design and integration of decentralized electrochemical energy storage with renewables and fossil plants

Increasing renewable energy requires improving the electricity grid flexibility. Existing measures include power plant cycling and grid-level energy storage, but they incur high operational and investment costs. Using a systems modeling and optimization framework, we study the integration of electrochemical energy storage with individual power plants at various renewable penetration levels. Furthermore, our techno-economic analysis includes both Li-ion and NaS batteries to encompass different technology maturity levels. A California case-study indicates localized integration to be cost-effective for greater grid flexibility. Li-ion batteries can mitigate the residual demand fluctuations of small to medium-sized plants, while NaS batteries would be best-suited for larger storage with higher renewable penetration. Overall, the battery-enabled renewable integration could reduce the unmet grid demand by 75%, the renewable curtailment by 58%, and the CO 2 emission intensity by 16% while including the life cycle emissions of the battery and the renewable farm. Our scenario-based analysis also indicates that rather than replacing all fossil power plants, it is more economical to combine batteries and renewables with individual fossil plants to achieve a clean energy grid.

25 ENERGY STORAGE↗

Determinants of CO{sub 2} emissions in ASEAN countries using energy and mining indicators

Carbon dioxide (CO{sub 2}) is the main greenhouse gas emitted from human activities. Industrial revolution is one of the triggers to accelerate the quantity of CO{sub 2} in the atmosphere which lead to undesirable changes in the cycle of carbon. Like China and United States which are affected by the economic development growth, the atmospheric CO{sub 2} level in ASEAN countries is expected to be higher from year to year. This study focuses on energy and mining indicators, namely alternative and nuclear energy, energy production, combustible renewables and waste, fossil fuel energy consumption and the pump price for diesel fuel that contribute to CO{sub 2} emissions. Six ASEAN countries were examined from 1970 to 2010 using panel data approach. The result shows that model of cross section-fixed effect is the most appropriate model with the value of R-squared is about 86%. Energy production and fossil fuel energy consumption are found to be significantly influenced to CO{sub 2} emissions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Annual Technology Baseline: The 2024 Electricity Update

Consistent cost and performance data for various electricity generation technologies can be difficult to find and may change frequently for certain technologies. With the Annual Technology Baseline (ATB), the National Renewable Energy Laboratory annually provides an organized and centralized set of such cost and performance data. The ATB uses the best information from the Department of Energy national laboratories' energy analysts. The ATB has been reviewed by experts and it includes the following electricity generation and storage technologies: land-based wind, offshore wind, distributed wind, utility-scale solar photovoltaics (PV), commercial-scale solar PV, residential-scale solar PV, concentrating solar power, geothermal power, hydropower, utility-scale battery storage, commercial battery storage, residential battery storage, pumped storage hydropower, nuclear, coal, and natural gas. EIA data for conventional biopower are included for reference. This webinar presentation introduces the 2024 update to the ATB Electricity data and documentation.

battery storage↗

Resource Assessment for Hydrogen Production: Hydrogen Production Potential from Fossil and Renewable Energy Resources

This study examines the energy resources required to produce 4-10 million metric tonnes of domestic, low-carbon hydrogen in order to fuel approximately 20-50 million fuel cell electric vehicles. These projected energy resource requirements are compared to current consumption levels, projected 2040 business as usual consumptions levels, and projected 2040 consumption levels within a carbonconstrained future for the following energy resources: coal (assuming carbon capture and storage), natural gas, nuclear (uranium), biomass, wind (on- and offshore), and solar (photovoltaics and concentrating solar power). The analysis framework builds upon previous analysis results estimating hydrogen production potentials and drawing comparisons with economy-wide resource production projections

30 DIRECT ENERGY CONVERSION↗