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At least 415 records · Page 23

Integrated Hydrogen Energy Storage System (IHESS) for Power Generation (Final Report)

GTI Energy partnered with Praxair Inc., a subsidiary of Linde PLC (Praxair), the Center for Electromechanics at the University of Texas at Austin (CEM), Entergy Corporation (Entergy), Quanta Services (Quanta) and Mitsubishi Heavy Industries (MHI) to perform a feasibility study that determines the economic and technical feasibility of low-carbon hydrogen energy storage integrated with a site-specific fossil fuel asset to decarbonize electricity production using the Integrated Hydrogen Energy Storage System (IHESS). The proposed IHESS concept is novel, as it sought to leverage the existing natural gas infrastructure, hydrogen production and pipelines, existing underground hydrogen storage system and power plants in the Gulf Coast region to reduce carbon emissions and generate lowcarbon electricity. This study has shown that IHESS has a promising commercial outlook as the concept leverages existing natural gas infrastructure assets and hydrogen production and storage that are unique to the Texas gulf coast region. A key hurdle with hydrogen supply and transportation has been capital investment. By storing hydrogen in underground storage and delivering it as a fuel source during peak demand using the existing infrastructure minimizes the capital investment. Regional petrochemical producers who are actively seeking opportunities to reduce costs and lower emissions should find the IHESS concept very appealing.

03 NATURAL GAS↗

Raman spectroscopy of oxygen carrier particles in harsh environments

Fossil fuel combustion processes generate CO2, a greenhouse gas of considerable concern. To reduce this emission, the National Energy Technology Laboratory (NETL) is evaluating alternative combustion approaches, including chemical looping combustion (CLC). This technique generates relatively pure CO2, suitable for subsequent capture and storage. CLC uses oxygen-carrier particles (OCPs) such as iron oxides, copper oxides, calcium sulfates, etc. to provide oxygen for the combustion process. Optimization of the overall combustion process requires knowledge of the oxidation state (e.g., content of Fe2O3 vs. Fe3O4) of the OCPs during the different stages of the CLC process. Unfortunately, the ability to make on-line measurements of the oxidation state of OCPs in harsh environments is lacking and new sensors need to be developed. We are evaluating non-contact, stand-off Raman spectroscopy to determine the relative concentrations of the oxidized and reduced forms of OCPs at temperatures between 800 °C and 1000 °C, and pressures of about 10 atm. Using cw and pulsed Raman spectroscopy, in combination with a pressurized high-temperature sample chamber, we have optimized the operating parameters such as laser wavelength, laser intensity, collection optic design, focal spot size, etc. and measured Raman spectra of various OCP materials at high temperatures. To extract from the Raman spectra relevant information such as the concentration ratio of a material in different oxidation states, the measured data needs to be processed, and statistical modeling and multivariate calibration need to be performed.

20 FOSSIL-FUELED POWER PLANTS↗

Improving the effectiveness and equity of fuel economy regulations with sales adjustment factors

Larger vehicles, such as sports utility vehicles, consume more energy than cars. Their increasing popularity runs contrary to the goal of fuel economy regulations to reduce fossil fuel consumption and greenhouse gas emissions and can be explained by consumer preference and lower regulation stringency, which is due to footprint, truck classification, and the omission of heterogenous lifetime vehicle distance traveled among vehicle classes. This study shows that, for both the US and China, large vehicles travel more, last longer, and are owned by higher income consumers. This means large vehicles and their high-income owners use more fuel and emit more pollutants than represented by current policy and thus raises both policy effectiveness and energy equity concerns. We propose and estimate Sales Adjustment Factors that weigh fuel economy standards based on vehicle lifetime usage and demonstrate the resultant significant improvements in the effectiveness and equity of fuel economy regulations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Low oxygen levels contribute to improve photohydrogen production in mixotrophic non-stressed Chlamydomonas cultures

Currently, hydrogen fuel is derived mainly from fossil fuels, but there is an increasing interest in clean and sustainable technologies for hydrogen production. In this context, the ability of some photosynthetic microorganisms, particularly cyanobacteria and microalgae, to produce hydrogen is a promising alternative for renewable, clean-energy production. Among a diverse array of photosynthetic microorganisms able to produce hydrogen, the green algae Chlamydomonas reinhardtii is the model organism widely used to study hydrogen production. Furthermore, the well-known fact that acetate-containing medium enhances hydrogen production in this algae, little is known about the precise role of acetate during this process.

09 BIOMASS FUELS↗

Demonstrating Hybrid Heat Transport and Energy Conversion System Performance Characterization Using Intelligent Control Systems

The debate continues on the magnitude and validity of climate change caused by human activities. However, there is no debate about the need to make buildings, modes of transportation, factories, and homes as energy efficient as possible. Given that climate change could occur with the wasteful use of fossil fuel and the fact that fossil energy costs could and will swing wildly, it is imperative that every effort be made to utilize energy sources to their fullest. Hybrid energy systems (HES) are two or more separate energy producers used together to produce energy commodities. The HES this report focuses on is the use of nuclear reactor waste heat as a source of further energy utilization. Nuclear reactors use a fluid to cool the core and produce the steam needed for the production of electricity. Traditionally this steam, or coolant, is used to convert the energy then cooled elsewhere. The heat is released into the environment without being used further. By adding technologies to nuclear reactors to use the wasted heat, a system can be developed to make more than just electricity and allow for loading following capabilities.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

FLC Award: Smart Chutes and Sensors

Increasing the production and use of biofuels is a national objective for renewable, cleaner energy. A primary objective of the Department of Energy’s Bioenergy Technologies Office (BETO) Feedstock-Conversion Interface Consortium (FCIC) is to address the operational, safety, throughput, and yield of bio-refineries to revolutionize biomass processing with the goal to make bio-derived fuels cost-competitive with fossil fuels. One of the main hurdles is increasing the operational reliability of the bio-refineries. Bio-refineries convert the biomass, such as corn stover, into ethanol. Corn stover is composed of the non-edible stalks, leaves, cobs, and husks left over from harvesting. This material is known for having poor processing properties for bulk solids handling and transport. These properties, such as moisture content, cause costly system plugging and downtime at bio-refineries which limit biofuel from being cost-competitive with diesel and gasoline fuels.

09 BIOMASS FUELS↗

Cell Wall Compositions of Sorghum bicolor Leaves and Roots Remain Relatively Constant Under Drought Conditions

Renewable fuels are needed to replace fossil fuels in the immediate future. Lignocellulosic bioenergy crops provide a renewable alternative that sequesters atmospheric carbon. To prevent displacement of food crops, it would be advantageous to grow biofuel crops on marginal lands. These lands will likely face more frequent and extreme drought conditions than conventional agricultural land, so it is crucial to see how proposed bioenergy crops fare under these conditions and how that may affect lignocellulosic biomass composition and saccharification properties. We found that while drought impacts the plant cell wall of Sorghum bicolor differently according to tissue and timing of drought induction, drought-induced cell wall compositional modifications are relatively minor and produce no negative effect on biomass conversion. This contrasts with the cell wall-related transcriptome, which had a varied range of highly variable genes (HVGs) within four cell wall-related GO categories, depending on the tissues surveyed and time of drought induction. Further, many HVGs had expression changes in which putative impacts were not seen in the physical cell wall or which were in opposition to their putative impacts. Interestingly, most pre-flowering drought-induced cell wall changes occurred in the leaf, with matrix and lignin compositional changes that did not persist after recovery from drought. Most measurable physical post-flowering cell wall changes occurred in the root, affecting mainly polysaccharide composition and cross-linking. This study couples transcriptomics to cell wall chemical analyses of a C4 grass experiencing progressive and differing drought stresses in the field. As such, we can analyze the cell wall-specific response to agriculturally relevant drought stresses on the transcriptomic level and see whether those changes translate to compositional or biomass conversion differences. Our results bolster the conclusion that drought stress does not substantially affect the cell wall composition of specific aerial and subterranean biomass nor impede enzymatic hydrolysis of leaf biomass, a positive result for biorefinery processes. Coupled with previously reported results on the root microbiome and rhizosphere and whole transcriptome analyses of this study, we can formulate and test hypotheses on individual gene candidates’ function in mediating drought stress in the grass cell wall, as demonstrated in sorghum.

59 BASIC BIOLOGICAL SCIENCES↗

Process Developed for Fabricating Engineered Pore Structures for High- Fuel-Utilization Solid Oxide Fuel Cells

Solid oxide fuel cells (SOFCs) have tremendous commercial potential because of their high efficiency, high energy density, and flexible fuel capability (ability to use fossil fuels). The drive for high-power-utilizing, ultrathin electrolytes (less than 10 microns), has placed an increased demand on the anode to provide structural support, yet allow sufficient fuel entry for sustained power generation. Concentration polarization, a condition where the fuel demand exceeds the supply, is evident in all commercial-based anode-supported cells, and it presents a significant roadblock to SOFC commercialization.

Sofie, Stephen W.↗

Solid-State Thermionic Nuclear Power for Megawatt Propulsion, Planetary Surface and Commercial Power Project

Thermionic (TI) power conversion is a promising technology first investigated for power conversion in the 1960's, and of renewed interest due to modern advances in nanotechnology, MEMS, materials and manufacturing. Benefits include high conversion efficiency (20%), static operation with no moving parts and potential for high reliability, greatly reduced plant complexity, and the potential for reduced development costs. Thermionic emission, credited to Edison in 1880, forms the basis of vacuum tubes and much of 20th century electronics. Heat can be converted into electricity when electrons emitted from a hot surface are collected across a small gap. For example, two "small" (6 kWe) Thermionic Space Reactors were flown by the USSR in 1987-88 for ocean radar reconnaissance. Higher powered Nuclear-Thermionic power systems driving Electric Propulsion (Q-thruster, VASIMR, etc.) may offer the breakthrough necessary for human Mars missions of < 1 yr round trip. Power generation on Earth could benefit from simpler, moe economical nuclear plants, and "topping" of more fuel and emission efficient fossil-fuel plants.

George, Jeffrey↗

Postscript: Future Perspectives

Over the past 20 years, a hydrogen economy has often been proposed by the media, as well as by scientists, as a means to mitigate the environmental problems caused by the use of fossil fuels.

08 HYDROGEN↗

Reversible Methane Electrochemical Reactors as Efficient Energy Storage for Fossil Power

The overall objective of the project was to conduct a comprehensive Research & Development (R&D) program to demonstrate the suitability and future advancement and integration of reversible methane protonic ceramic electrochemical reactors (PCERs) as an efficient Energy Storage System (ESS) with fossil fuel power plants. Fundamental process and system models are developed to conduct a preliminary conceptual study and investigate the power plant system integration requirements, performance requirements, and technical and non-technical gaps for eventual implementation at system level. Technology maturation requirements is also investigated through identifying the critical technical elements and networking with industrial technology developers and end-users.

08 HYDROGEN↗

Electrochemical Membrane for Carbon Dioxide Capture and Power Generation

FuelCell Energy, Inc. (FCE), in collaboration with AECOM Corporation (formerly URS Corporation) and Pacific Northwest National Laboratory, has been developing a novel Combined Electric Power and Carbon-dioxide Separation (CEPACS) system. The CEPACS system is based on electrochemical membrane (ECM) technology derived from FCE’s carbonate fuel cell products featuring internal (methane steam) reforming and carrying the trade name of Direct FuelCell®. The unique chemistry of carbonate fuel cells offers an innovative approach for separation of CO 2 from existing fossil-fuel power plant exhaust streams (flue gases). The ECM-based CEPACS system has the potential to become a transformational CO 2 -separation technology by working as two devices in one: it separates the CO 2 from the exhaust of other plants such as an existing coal-fired plant and simultaneously produces clean electric power at high efficiency using a supplementary fuel. The development effort was carried out under the U.S. Department of Energy (DOE) cooperative agreement DE-FE0007634. The overall objective of this project was to successfully demonstrate the ability of FCE’s ECM-based CEPACS system technology to separate ≥90% of the CO 2 from a simulated Pulverized Coal (PC) power plant flue gas stream and to compress the captured CO2 to a state that can be easily transported for sequestration or beneficial use. In addition, a key objective was to show, through the technical and economic feasibility study and bench scale testing, that the ECM-based CEPACS system is an economical alternative for CO 2 capture in PC power plants, and that it meets DOE’s objective related to the incremental cost of electricity (COE) for post-combustion CO 2 capture (no more than 35% increase in COE). The project was performed in three budget periods (BP). The specific objective for BP1 was to complete the Preliminary Technical and Economic Feasibility Study. The T&EF study was based on the carbon capture system size suitable for a reference 550 MW PC power plant. The specific objectives for BP2 were to perform (flue gas) contaminant effect evaluation tests, small area membrane tests using clean simulated flue gas, design a flue gas pretreatment system for processing of the gas feed to ECM, update the Technical & Economic Feasibility Study (T&EFS) incorporating results of contaminant effect tests and small area membrane tests, and to prepare a test facility for bench scale testing. The specific objectives for BP3 were to perform bench scale testing (parametric and long-duration testing) of a 11.7 m 2 ECM-based CO 2 capture, purification and compression system, and update (as final) the Technical and Economic Feasibility Study. In addition, an Environmental Health and Safety evaluation (assessment) of the ECM technology was included. This final technical report presents the progress made under the project.

20 FOSSIL-FUELED POWER PLANTS↗

2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Volume 2: Environmental Sustainability Effects of Select Scenarios from Volume 1

With the goal of understanding environmental effects of a growing bioeconomy, the U.S. Department of Energy (DOE), national laboratories, and U.S. Forest Service research laboratories, together with academic and industry collaborators, undertook a study to estimate environmental effects of potential biomass production scenarios in the United States, with an emphasis on agricultural and forest biomass. Potential effects investigated include changes in soil organic carbon (SOC), greenhouse gas (GHG) emissions, water quality and quantity, air emissions, and biodiversity. Effects of altered land-management regimes were analyzed based on select county-level biomass-production scenarios for 2017 and 2040 taken from the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy (BT16), volume 1, which assumes that the land bases for agricultural and forestry would not change over time. The scenarios reflect constraints on biomass supply (e.g., excluded areas; implementation of management practices; and consideration of food, feed, forage, and fiber demands and exports) that intend to address sustainability concerns. Nonetheless, both beneficial and adverse environmental effects might be expected. To characterize these potential effects, this research sought to estimate where and under what modeled scenarios or conditions positive and negative environmental effects could occur nationwide. The report also includes a discussion of land-use change (LUC) (i.e., land management change) assumptions associated with the scenario transitions (but not including analysis of indirect LUC [ILUC]), analyses of climate sensitivity of feedstock productivity under a set of potential scenarios, and a qualitative environmental effects analysis of algae production under carbon dioxide (CO 2 ) co-location scenarios. Because BT16 biomass supplies are simulated independent of a defined end use, most analyses do not include benefits from displacing fossil fuels or other products, with the exception of including a few illustrative cases on potential reductions in GHG emissions and fossil energy consumption associated with using biomass supplies for fuel, power, heat, and chemicals. Most analyses in volume 2 show potential for a substantial increase in biomass production with minimal or negligible environmental effects under the biomass supply constraints assumed in BT16. Although corn ethanol has been shown to achieve GHG emissions improvements over fossil fuels, cellulosic biomass shows further improvements in certain environmental indicators covered in this report. The harvest of agricultural and forestry residues generally shows the smallest contributions to changes in certain environmental indicators investigated. The scenarios show national-level net SOC gains. When expanding the system boundary in illustrative cases that consider biomass end use, reductions in GHG emissions are estimated for scenarios in which biomass—rather than oil, coal, and natural gas—is used to produce fuel, power, heat, and chemicals. Analyses of water quality reveal that there could be tradeoffs between biomass productivity and some water quality indicators, but better outcomes for both biomass productivity and water quality can be achieved with selected conservation practices. Biodiversity analyses show possible habitat benefits to some species, with other species showing potential adverse effects that may require additional safeguards. Increasing productivity of algae can reduce GHG emissions and water consumption associated with producing algal biomass, though the effects of water consumption are likely of greater concern in some regions than in others. Moreover, the effects of climate change on potential biomass production show gains and losses in yield among feedstocks across the continental United States. Key research gaps and priorities include actions that can enhance benefits and reduce potential for negative effects of increased biomass production. The results from this report will help DOE, the bioenergy industry, and other institutions continue important discussions on environmental effects and will help chart a path toward a more environmentally sustainable bioeconomy.

54 ENVIRONMENTAL SCIENCES↗

Electrochemical conversion of coal-derived CO 2 into fuels and chemicals using a modified PEM electrolyzer. Final report

Opus 12 is developing an electrochemical process to convert CO 2 into chemicals and fuels. Using only CO 2 , water, and electricity as inputs, the electrochemical reduction of CO 2 could form the basis of an artificial carbon cycle that replaces a wide range of products that are currently derived from fossil fuel resources. We have developed a prototype that demonstrates high selectivity and current density for CO 2 conversion to CO, which can be used to make high-value products including methanol, acetic acid, polymers, and pharmaceuticals.

01 COAL, LIGNITE, AND PEAT↗

Regulators’ Energy Transition Primer: Economic Impacts of the Energy Transition on Energy Communities, Environmental Justice Considerations, and Implications on Clean Energy Jobs

Applications of new technology, such as horizontal drilling and hydraulic fracturing, enabled the United States to significantly increase its production of oil and natural gas during the last decade—the “Shale Gas Revolution.” As natural gas began to dominate the market with abundant supply and low prices, coal production and consumption have declined. Concurrently, the competitiveness of renewable energy and energy storage has climbed sharply, and analysts expect to see continued reductions in fossil fuel use in the coming decades. Many of these changes have been driven by market forces (i.e., low-cost natural gas and renewables), but current and future policy decisions aimed at tackling climate change concerns and reducing greenhouse gas emissions will also shape the future of the energy sector. This transition to low-carbon fuels has created both opportunities for clean energy technologies and challenges for communities traditionally dependent on fossil fuel-related industries. The power sector’s ongoing shift away from coal has left many coal miners and coal-fired power plant employees unemployed and often unprepared for jobs in other industries, including growing clean energy fields. This primer focuses on the declining coal industry, impacts on communities and workers, opportunities to transition workers who have lost their jobs to clean energy and other related sectors (including hydrogen-oriented jobs), recruitment and training strategies, and available programs and actions to make the shift to a low-carbon economy in a fair, just, and equitable manner by engaging the resources of federal and state governments, as well as the private sector.

01 COAL, LIGNITE, AND PEAT↗

Pilot-Scale Demonstration of a Fully Integrated Commercial Process for Converting Woody Biomass into Clean Biomass Diesel Fuel

The economic recovery of petroleum, like other fossil fuels, is limited. Although the current price of oil has dramatically dropped due to increased production and new production methods, it is not expected to remain low for an extended period of time as demand increases. While new methods of obtaining these fossil energy reserves are constantly being invented and introduced, the cost of production generally continues to increase. New sources of energy such as fracking and oil shale or oil sands recovery can produce enormous amounts of energy, but at a severe cost. The current estimate on energy return for energy invested for oil shale for instance is just barely over 1, meaning that for every barrel of energy produced by oil shale there was nearly a barrel of energy invested to recover it. Furthermore, these new technologies are often constantly under attack for environmental concerns (especially given the poor ratio of energy conversion), while conventional oil is regarded as dangerous due to lack of domestic supply and susceptibility to foreign intervention that compromises overall national security. Alternatives to a petroleum-based supply of fuel are a potential route to address these issues, although they must also be economically feasible. The fuels industry is forced to consider these issues in addition to federal mandates intended to gradually diversify our fuel sources.

09 BIOMASS FUELS↗

Techno-Economic Analysis and Life-Cycle Assessment for Gas Phase Catalytic Oxidation of Lignin to Produce Phenolic Compounds

Displacing fossil fuels with biofuels is an effective way to sustainably mitigate greenhouse gas (GHG) emissions and natural resource consumption. As DOE's only national laboratory solely dedicated to researching and developing clean energy and energy efficiency technologies, NREL has been developing conceptual biomass-to-fuels conversion processes. To improve the economic feasibility of biofuels production from lignocellulosic biomass, NREL's researchers have been exploring various design options. Our team has developed a vapor phase selective oxidation process that will convert lignin streams from biofuels production into high-value chemicals and thereby improve the economics and GHG emissions of biofuels plants. This approach is directed towards valorizing lignin, which is often treated as waste or burnt for low value process heat. For techno-economic analysis (TEA) and life-cycle assessment (LCA), we have developed and modeled this hybrid process: 1) biochemically converting C5/C6 sugars from biomass to a hydrocarbon blendstock, and 2) thermochemically converting lignin from biomass, via selective partial oxidation of lignin pyrolysis vapor, to phenols. Results from the TEA and LCA for this process will be presented and discussed. The lignin valorization readily improves the biofuel production cost and reduces the life cycle carbon footprint. Even though more electricity is required as lignin is used for coproduct production instead of for heat and power generation, the GHG coproduct credit from phenols is more than enough to compensate for the GHG associated with the additional import electricity use. These analyses show that our process to produce phenol has significant economic and environmental impacts, which will enable biofuel production.

09 BIOMASS FUELS↗