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At least 415 records · Page 23

Creep Properties of Shale and Predicted Impact on Proppant Embedment for the Caney Shale, Oklahoma

The Caney shale is an emerging hydrocarbon play located in southwest Oklahoma, USA. Within the Caney shale exist facies which were initially dubbed “reservoir” and “ductile” based on evaluation of well logging data. While past work has shown the distinction of “brittle” and “ductile” is not mechanically justifiable according to formal definitions, here the current work shows some important differences between nominally ductile and reservoir zones. First, the “ductile” zones are more clay rich and have textural differences which can be expected to lead to differences in mechanical properties. One important impact of these differences is observed in triaxial creep experiments showing the “ductile” zones are more prone to creep deformation. Numerical simulations predict the “reservoir” zones will experience very little proppant embedment due to creep deformation of hydraulic fractures around proppant particles. On the other hand, “ductile” zones can be expected to undergo creep-driven proppant embedment leading to loss of fracture aperture ranging up to 100% loss, depending upon the spatial density of the proppant distribution. Hence, this research shows the identification of nominally “ductile” zones from well logs, while a misnomer, can be useful in finding clay-rich, creep-prone zones which will be the most prone to proppant embedment and hence vulnerable to greater production decline over time.

58 GEOSCIENCES↗

Water-Weakening and Time-Dependent Deformation of Organic-Rich Chalks

Abstract The Ghareb Formation is a shallowly buried porous chalk in southern Israel that is being considered as a host rock for a geologic nuclear waste repository. Setup and operation of a repository will induce significant mechanical, hydrological and chemical perturbations in the Ghareb. Developing a secure repository requires careful characterization of the rock behavior to different loads. To characterize hydromechanical behavior of the Ghareb, several short- and long-term deformation experiments were conducted. Hydrostatic loading tests were conducted both dry and water-saturated, using different setups to measure elastic properties, time-dependent behavior, and permeability. A set of triaxial tests were conducted to measure the elastic properties and rock strength under differential loading at dry and water-saturated conditions. The hydrostatic tests showed the Ghareb began to deform inelastically around 12–15 MPa, a relatively low effective pressure. Long-term permeability measurements demonstrated that permeability declined with increasing effective pressure and was permanently reduced by ~ 1 order of magnitude after unloading pressure. Triaxial tests showed that water saturation significantly degrades the rock properties of the Ghareb, indicating water-weakening is a significant risk during repository operation. Time-dependent deformation is observed during hold periods of both the hydrostatic and triaxial tests, with deformation being primarily visco-plastic. The rate of deformation and permeability loss is strongly controlled by the effective pressure as well. Additionally, during holds of both hydrostatic and triaxial tests, it is observed that when water-saturated, radial strain surpassed axial strain when above effective pressures of 13–20 MPa. Thus, deformation anisotropy may occur in situ during operations even if the stress conditions are hydrostatic when above this pressure range.

58 GEOSCIENCES↗

Energy Budget of Brittle Fracturing in Granite Under Stress Relaxation and Creep

Creep and relaxation are the two major time-dependent fracturing processes in rocks. While a considerable amount of research has been done in understanding these two mechanisms, critical gaps remain regarding how different energy components evolve during time-dependent fracturing processes in rocks. In this study, a series of relaxation and creep experiments were conducted on prismatic Barre granite specimens in the laboratory to estimate the energy budget of brittle fracturing in granite. For the input energy, the work done by the machine (W) is calculated and for the output energy the radiated seismic energy (E R ), released in the form of acoustic emissions (AEs), is calculated as the only measurable output energy component in the conducted experiments. The low-frequency plateau (Ω 0 ) and corner frequency (f 0 ) for each AE waveform was estimated by fitting the observed AE spectra with the theoretical spectra using the Omega model. These parameters were used to estimate the seismic moments (M 0 ) based on the radiation pattern for the double couple (shear) and non-double-couple (non-shear) events. The range of f 0 and M 0 varied from 150 to 750 kHz and 10 –4 to 10 –1 N m, respectively. Moment magnitude (M w ) varied in a wider range from –9 to –6 in creep and –8.5 to –7 in relaxation. Stress drops (Δ σ ) and source radius (r) were estimated for the AEs using Brune’s model. Here, the results report on three primary observations: (1) the effects of different source mechanisms on the estimated source parameters showed that M 0 and Δ σ were higher for DC events as compared to NDC in both relaxation and creep. (2) The radiation efficiency in the case of creep is 70% higher as compared to relaxation and, (3) the stress drop estimated in relaxation and creep demonstrated a breakdown in scaling with the seismic moment.

58 GEOSCIENCES↗

Thermo-Hydro-Mechanical Modeling of Brine Migration in a Heated Borehole Test in Bedded Salt

Abstract This research paper focuses on the thermo-hydro-mechanical (THM) modeling of brine migration in a heated borehole test conducted as part of the ongoing Brine Availability Test in Salt (BATS) at the Waste Isolation Pilot Plant (WIPP) in New Mexico. It is a component of the international collaboration project DECOVALEX-2023 (DEvelopment of COupled models and their VALidation against EXperiments), which aims to understand the THM processes governing brine flow in heated rock salt repositories through collaborative analysis by multiple research teams. Using the TOUGH–FLAC simulator, THM simulations were performed and compared with data from the BATS phase 1a. This experiment involved two identical horizontal-borehole arrays, one heated and one serving as a control, both equipped with sensor arrays. Analysis of measurements revealed water flow rate surges during heater power transitions, with the highest jump observed during cooling. Acoustic emission activity exhibited distinct patterns in response to heater power changes, suggesting that damage to rock salt is particularly pronounced during the cooling phase. The THM simulations successfully captured these phenomena, highlighting the significance of thermal effects, brine migration, and mechanical behavior in predicting brine availability in heated and damaged rock salt. Our modeling also revealed the critical interplay between heating and cooling-induced damage and its influence on flow properties, particularly affecting brine inflow estimation. Notably, we found that cooling-induced brine inflow spikes result from increased permeability due to tensile dilatancy. These findings have important implications for the development of robust containment strategies and enhance our understanding of the complex processes involved in repository performance.

58 GEOSCIENCES↗

Microseismic Monitoring of Laboratory Hydraulic Fracturing Experiments in Granitic Rocks for Different Fracture Propagation Regimes

While hydraulic fracturing (HF) is a widely employed process, the underlying fracturing processes are still heavily contested. The attributes of the HF generated fracture network can exhibit substantial variation when dealing with specific HF propagation regimes encountered in the field. In this study, HF experiments were performed on true-triaxially loaded Barre granite cubes, with microseismic monitoring, to identify and characterize the fracturing mechanisms associated with different viscosity injection fluids. Utilizing fluids with high (oil/1450 cP) and low (water/1 cP) viscosity represented two key HF propagation regimes: viscosity- and toughness-dominated. The experiments conducted with oil involved higher breakdown pressures, larger fluid volumes, and slower fracture propagation speeds. Furthermore, the frequency–magnitude distribution (b value) for all experiments (1.9–2.3) was similar to those encountered for large-scale operations. Slightly larger b values were encountered during the initiation phase (2.4–2.7) relative to the fracture propagation and post-fracturing phases (1.9–2.2). Techniques such as polarity and moment-tensor inversion were utilized to characterize the source mechanisms. For the HF experiments with oil, tensile fractures were most dominant (92%) in the initiation phase compared to fracture propagation and post-fracturing phases (70–75%). Similar tensile fracturing dominancy was not observed with water, attributable to fluid permeation and leak-off. Regardless of the injection fluid or classification criteria employed, tensile fractures were the dominant type consistently, with fewer occurring in water experiments but the specific ratio of crack types varied with different source mechanism criteria employed.

58 GEOSCIENCES↗

Coupled Thermo-Hydro-Mechanical Processes in Fractured Rocks: Some Past Scientific Highlights and Future Research Directions

Abstract Coupled thermo-hydro-mechanical (THM) processes in fractured rocks have been a topic of intense scientific research for more than 30 years. The present paper takes a look into the past and highlights some scientific advances which are of an unusual “out-of-the-box” nature, and then looks forward and discusses possible directions of future research in this interesting field of study. Concerning future research directions, we see a trend from a focus on coupled THM processes in single fractures or a few interacting fractures, to the study of coupled THM behavior in complex fracture network systems where the fractures act collectively giving rise to local stress concentration points and points of large pressure gradients. Three examples of future research directions are presented. First is an effort towards identifying characterizing parameters of a fracture network that play a direct controlling role in major coupled THM phenomena (such as induced seismicity and flow channeling), rather than parameters of stochastic distributions of fractures in the network. The second example of research direction is accounting for the heterogeneity and hierarchy of fractures in a fault or fracture zone which has been associated with major THM events in a number of geo-energy projects. The third example is at the opposite end of the first; here it is recognized that in some cases, the coupled THM processes in fractured rocks may be controlled dominantly by only a few key bridges. Identification, characterization, and evaluation of these key bridges should be one of the important research directions in the coming days.

58 GEOSCIENCES↗

Intermediate Principal Stress Effects on the 3D Cracking Behavior of Flawed Rocks Under True Triaxial Compression

Crack initiation, growth, and coalescence in flawed rocks have been extensively studied for 2D (planar, penetrating) flaws under uniaxial/biaxial compression. However, little is known as to the mechanisms and processes of cracking from 3D flaws under true triaxial compression, where the intermediate principal stress (σ 2 ) is distinguished from the major and minor principal stresses. In this work, we systematically investigate the effects of σ 2 on the 3D cracking behavior of rock specimens with preexisting flaws, through the use of mechanistic simulations of mixed-mode fracture in rocks. We explore how two characteristics of σ 2 , namely, (i) its orientation with respect to the flaw and (ii) its magnitude, affect two aspects of the cracking behavior, namely, (i) the cracking pattern and (ii) the peak stress. Results show that the orientation of σ 2 exerts more control over the cracking pattern than the flaw inclination angle. The peak stress becomes highest when σ 1 is parallel to the flaw, whereas it becomes lowest when σ 2 is parallel to the flaw. Also, the effects of σ 2 magnitude are more significant when σ 2 becomes more oblique to the flaw plane. On the basis of our observations, we propose mechanisms underlying the cracking behavior of 3D flawed rocks under true triaxial compression.

58 GEOSCIENCES↗

A New Simplified Discrete Fracture Model for Shearing of Intersecting Fractures and Faults

Abstract Shearing of fractures and faults is important because it can result in permeability change or even induce seismicity—both are keys for efficient and safe energy recovery and storage in Earth systems. Quantitative analysis of shearing of intersecting fractures and faults is challenging because it can involve dynamic frictional contacts that are complicated by deformation of the rock matrix. To predict the shearing of intersecting fractures/faults, we attempt to answer the question of how intersections impact the shearing of a fracture network and whether we can simplify the description as compared to classical discrete fracture network (DFN) models. To answer these questions, we conducted a series of numerical simulations on scenarios for variable numbers of intersecting fractures. All these examples yield consistent results: the results of using DFNs are consistent with those of using hypothetical major paths. This leads to a new model, which we name simplified discrete fracture network model , to analyze shearing of intersecting fractures/faults using major path(s). We found that the intersections of fractures do not fundamentally change the shearing of two intersecting fractures if the intersecting angles are small. Furthermore, increasing the number of fractures/faults may relax the stress as more fractures/faults become available for shearing and distributing the stress. The simplified DFN model, which can capture efficiently the shearing behavior of each major paths from a large number of intersecting fractures/faults, will be a promising conceptual model that is complementary to existing equivalent continuum and discrete fracture models to analyze shearing of intersecting fractures/faults.

58 GEOSCIENCES↗

Simulation of Multiphase Flow and Poromechanical Effects Around Injection Wells in CO 2 Storage Sites

In geological CO 2 storage operations, wellbore deformations and leakage pathways formations can occur around injection and abandoned wells subjected to high rates and long-term CO 2 injection. To guide engineering design and prevent CO 2 leakage risks, a full understanding of the underlying physics and robust numerical models is necessary to evaluate the response of underground formations in the near wellbore region and in the reservoir. In this study, a multi-scale and multi-physics open-source simulator (GEOS) is used to simulate multiphase flow and poromechanical deformations over time in three dimensions. The governing equations for mechanical deformations of the rock body and multiphase compositional fluid flow within the rock matrix are solved with a fully coupled finite element and finite volume approach. The Drucker–Prager model with friction hardening is applied to simulate elastoplastic deformation and a multiphase fluid model with power-law correlations for relative permeability is used to model the migration of CO 2 plume, which are coupled with numerical implicit scheme. Simulation results are verified against multiple analytical solutions for multiphase flow and wellbore problems, thus demonstrating the accuracy of this advanced simulator. In two engineering applications, here we highlight the impact of elastoplastic deformation and coupled modeling for assessing induced displacements and stress perturbations, which are more pronounced in the near wellbore regions. This work focuses on short-term processes in the vicinity of injection wells where stress evolutions, rock deformations and multiphase compositional flow and transport are simulated jointly to ensure wellbore stability and prevent damage. This fully coupled geomechanical model can simulate multiphase flow and any associated poromechanical effects within the CO 2 storage site and in the surrounding formations. Such a large-scale, long-term, multi-physics simulation model is useful in many ways: it can guide operational decisions for CO 2 injection, assess the containment potential and risks of a site, and analyze the wellbore stability and integrity during and after CO 2 injection.

58 GEOSCIENCES↗

Temporal and Spatial Evolution of Non-Elastic Strain Accumulation in Stanstead Granite During Brittle Creep

Understanding the long-term behavior of brittle rocks requires fundamental consideration of time-dependent strain evolution and brittle creep processes. Previous studies have evaluated sub-critical crack growth during time-dependent deformation and damage evolution in brittle rocks; however, there is an incomplete knowledge of how damage evolves spatially and temporally within the body of intact rocks, where distributed regions of damage interact and coalesce during creep. This paper presents laboratory research focusing on evaluating brittle creep damage processes in Stanstead granite (SG) using 2-dimensional digital image correlation (2D-DIC). In the laboratory, the prismatic SG specimens were loaded beyond an estimated Crack Damage stress threshold (CD) level and then maintained a constant stress to initiate the creep process. DIC was used to characterize full-field spatiotemporal strain evolution, which was then interpreted in the context of local regions of “damage”, determined according to a strain-based criterion. Here, a method was proposed for identifying “existing” and “new” damage regions over specified intervals during the test, followed by spatial clustering of these regions to assess their spatiotemporal evolution. The clustering analysis results demonstrated the extension of existing damage regions was the main damage process during brittle creep, which is consistent with existing models of sub-critical crack growth. In addition, temporal analysis of tensile and shear strains on a point-by-point basis revealed both new damage formation and the strain concentration within existing damaged regions significantly contribute to overall specimen strain during primary creep. In contrast, during secondary creep, increases in specimen deformation are influenced by the accumulation of strains within already damaged regions.

58 GEOSCIENCES↗

Detecting impacts of surface development near weather stations since 1895 in the San Joaquin Valley of California

Abstract Temperature readings observed at surface weather stations have been used for detecting changes in climate due to their long period of observations. The most common temperature metrics recorded are the daily maximum (TMax) and minimum (TMin) extremes. Unfortunately, influences besides background climate variations impact these measurements such as changes in (1) instruments, (2) location, (3) time of observation, and (4) the surrounding artifacts of human civilization (buildings, farms, streets, etc.) Quantifying (4) is difficult because the surrounding infrastructure, unique to each site, often changes slowly and variably and is thus resistant to general algorithms for adjustment. We explore a direct method of detecting this impact by comparing a single station that experienced significant development from 1895 to 2019, and especially since 1970, relative to several other stations with lesser degrees of such development (after adjustments for the (1) to (3) are applied). The target station is Fresno, California (metro population ~ 15,000 in 1900 and ~ 1 million in 2019) situated on the eastern side of the broad, flat San Joaquin Valley in which several other stations reside. A unique component of this study is the use of pentad (5-day averages) as the test metric. Results indicate that Fresno experienced + 0.4 °C decade −1 more nighttime warming (TMin) since 1970 than its neighbors—a time when population grew almost 300%. There was little difference seen in TMax trends between Fresno and non-Fresno stations since 1895 with TMax trends being near zero. A case is made for the use of TMax as the preferred climate metric relative to TMin for a variety of physical reasons. Additionally, temperatures measured at systematic times of the day (i.e., hourly) show promise as climate indicators as compared with TMax and especially TMin (and thus TAvg) due to several complicating factors involved with daily high and low measurements.

54 ENVIRONMENTAL SCIENCES↗

Correction to: Investigating the rheology of fluidized and non-fluidized gas-particle beds: implications for the dynamics of geophysical flows and substrate entrainment

We report natural geophysical mass flows are among the most complex granular systems and their dynamics are often modified by the presence of an interstitial fluid. Prediction of their runout requires the development of models estimating the solid stresses in these hazardous currents wherein excess pore-fluid pressure can develop. We use discrete element modelling (DEM-CFD) with a Coarse-Graining post-processing technique (CG) to investigate the rheology of unsteady gas-particle fluidized to non-fluidized granular beds placed on horizontal and inclined planes. Similar to fluidized beds immersed in viscous fluids, the effective friction coefficient of air-fluidized beds can be defined as a function of the classic μ(I)-rheology and the non-dimensional fluid or solid pressure to explain the failure and dynamics of granular flows with excess pore pressure on inclines. However, dilation imposed by fluid drag and particle collisions in gas-particle fluidized beds can drastically change its effective frictional properties. In contrast with the common assumption in water-particle flows that granular temperature is negligible, in our gas-particle simulations, the contribution of the velocity fluctuations to the stress tensor is significant. Hence, the shear stress is found to be non-zero even when the flow is fully fluidized in the inertial regime. These results suggest the need to better understand velocity fluctuations to predict the effective viscosity of sheared fluidized mixtures and are relevant for many applications. Notably, a unified approach is useful for many geophysical flows that encompass a range of fluidization conditions in a single flow such as pyroclastic density currents and snow avalanches.

58 GEOSCIENCES↗

Understanding long-term groundwater flow at Pahute Mesa and vicinity, Nevada National Security Site, USA, from naturally occurring geochemical and isotopic tracers

Abstract Recently collected naturally occurring geochemical and isotopic groundwater tracers were combined with historic data from the Pahute Mesa area of the Nevada National Security Site (NNSS), Nevada, USA, to provide insights into long-term regional groundwater flow patterns, mixing and recharge. Pahute Mesa was the site of 85 nuclear detonations between 1965 and 1992, many of them deeply buried devices that introduced radionuclides directly into groundwater. The dataset examined included major ions and field measurements, stable isotopes of hydrogen (δ 2 H), oxygen (δ 18 O), carbon (δ 13 C) and sulfur (δ 34 S), and radioisotopes of carbon ( 14 C) and chloride ( 36 Cl). Analysis of the patterns of groundwater 14 C data and the δ 2 H and δ 18 O signatures indicates that groundwater recharge is predominantly of Pleistocene age, except for a few localized areas near major ephemeral drainages. Steep gradients in sulfate (SO 4 ) and chloride (Cl) define a region near the western edge of the NNSS where high-concentration groundwater flowing south from north of the NNSS merges with dilute groundwater flowing west from eastern Pahute Mesa in a mixing zone that coincides with a groundwater trough associated with major faults. The 36 Cl/Cl and δ 34 S data suggest that the source of the high Cl and SO 4 in the groundwater was a now-dry, pluvial-age playa lake north of the NNSS. Patterns of groundwater flow indicated by the combined data sets show that groundwater is flowing around the northwest margin of the now extinct Timber Mountain Caldera Complex toward regional discharge areas in Oasis Valley.

58 GEOSCIENCES↗

Review: Pre-Darcy flows in low-permeability porous media

The widely used Darcy’s law specifies a linear relation between the Darcy velocity of fluid flow and the pressure gradient that drives the flow. However, studies have shown that Darcy velocity can exhibit a nonlinear dependence on the pressure gradient in low-permeability porous media such as clay and shale when the pressure gradient is adequately low. This phenomenon is referred to as low-velocity non-Darcian flow or pre-Darcy flow. This paper provides a comprehensive review of the theories, experimental data, and modeling methods for pre-Darcy flow in low-permeability porous media. The review begins by outlining the fundamental mechanisms underlying pre-Darcy flow that regulate the unique characteristics such as nonlinear dependence of the Darcy velocity on the pressure gradient and its relevance to fluid–rock interactions. The review then proceeds to present a thorough compilation of experimental investigations performed in various low-permeability geomaterials including tight sandstones, shales, and clays. Next, empirical and theoretical models and simulation methods that have been developed to fit and interpret experimental data are reviewed. Finally, the review underscores the challenges encountered in conducting and interpreting pre-Darcy flow experiments and suggests future research directions. By analyzing previous experimental investigations, this review aims to offer a valuable resource for researchers and practitioners seeking to enhance their understanding of fluid dynamics in low-permeability geomaterials. This provides insights into the application of pre-Darcy flow in numerous natural and engineered processes such as shale oil and gas recovery, contaminant transport in low-permeability aquifers, and geological disposal of nuclear waste.

58 GEOSCIENCES↗

Mechanical and poroelastic behavior of porous tuff under drained and undrained conditions

A series of drained and undrained water-saturated constant mean-stress tests were performed to investigate the strength, elasticity, and poroelastic response of a water-saturated high porosity nonwelded tuff. Drained strengths are found to increase with increasing effective confining pressures. Elastic moduli increase with increasing mean stress. Undrained strengths are small due to development of high pore pressures that generate low effective confining pressures. Skempton’s values are pressure dependent and appear to reflect the onset of inelastic deformation. Permeabilities decrease after deformation from ~ 10 –14 to ~ 10 –16 m 2 and are a function of the applied confining pressure. Deformation is dominated by pore collapse, compaction, and intense microfracturing, with the undrained tests favoring microfracture-dominant deformation and the drained tests favoring compaction-dominant deformation. These property determinations and observations are used to develop/parameterize physics-based models for underground explosives testing.

58 GEOSCIENCES↗

Phosphorus recycling by mineral-catalyzed ribonucleotide cleavage on iron and manganese oxides

Abstract Phosphorus is an essential element influencing both food security via plant fertilization, and water pollution through excessive phosphorus use, yet the phosphorus cycle in ecosystems is poorly known. In particular, beyond adsorption, the role of iron and manganese oxides in catalyzing the abiotic dephosphorylation of biomolecules is debated. Here, we studied the reactions of ribonucleotides, containing different phosphate bonding, with goethite, hematite, and birnessite. We employed both high-resolution mass spectrometry of solution species and molecular modeling simulations of ribonucleotide-mineral complexes. Results disclose an up to fivefold preferential hydrolytic cleavage of a phosphoanhydride bond over a phosphoester bond, indicating that mineral-catalyzed reactions reflect the hierarchy reported for the activity of phosphatase enzymes. The fourfold higher catalytic reactivity of goethite and birnessite versus hematite is explained by mineral-specific binding rather than surface area differences. Corresponding simulated adsorbate conformations at the water–mineral interfaces are proposed. Overall, our findings provide new insights on the catalytic recycling of organic phosphorus species by mineral oxides.

58 GEOSCIENCES↗

The age and potential causes of the giant Green Lake Landslide, Fiordland, New Zealand

Abstract Landslide deposits preserved in the geological record afford opportunities to better inform hillslope and seismic hazard and risk models, particularly in regions where observational records are short. In the Southern Alps of New Zealand, small coseismic landslides are frequent, but the geological record preserves several instances of more substantial (> 1 km 3 ) but infrequent mass failures. With an estimated volume of 27 km 3 , the giant Green Lake Landslide represents one of the largest subaerial landslides on Earth. Previous work has suggested this deep-seated mass movement was most likely triggered by high-intensity seismic shaking, but that local structural weakness and/or glacial debuttressing may help to explain the anomalously large failure volume. Resolving the potential contribution of the latter is important given predictions concerning alpine deglaciation in the coming decades to centuries. Key to resolution are secure chronologies of landslide emplacement and past glacier change. Here we present in situ cosmogenic 10 Be exposure ages from the Green Lake Landslide that suggest an emplacement age of 15.5 ± 0.7 ka. Recent work shows that glacial retreat in the region was underway by 19 ka, indicating that the Green Lake Landslide was emplaced 3–4 kyr after the onset of glacier retreat. Given the geometry of the former confining valley glacier, we expect that the deglaciation-landslide age gap is closer to the upper end of this estimate. If correct, this conclusion places greater weight on the roles of local geological structure and/or a great earthquake as factors contributing to the exceptionally large volume of this event.

58 GEOSCIENCES↗