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NASA NTRS2013

Abundance and Isotopic Composition of Gases in the Martian Atmosphere: First Results from the Mars Curiosity Rover

Repeated measurements of the composition of the Mars atmosphere from Curiosity Rover yield a (40)Ar/N2 ratio 1.7 times greater and the (40)Ar/(36)Ar ratio 1.6 times smaller than the Viking Lander values in 1976. The unexpected change in (40)Ar/N2 ratio probably results from different instrument characteristics although we cannot yet rule out some unknown atmospheric process. The new (40)Ar/(36)Ar ratio is more aligned with Martian meteoritic values. Besides Ar and N2 the Sample Analysis at Mars instrument suite on the Curiosity Rover has measured the other principal components of the atmosphere and the isotopes. The resulting volume mixing ratios are: CO2 0.960(+/- 0.007); (40)Ar 0.0193(+/- 0.0001); N2 0.0189(+/- 0.0003); O2 1.45(+/- 0.09) x 10(exp -3); and CO 5.45(+/- 3.62) x 10(exp 4); and the isotopes (40)Ar/(36)Ar 1.9(+/- 0.3) x 10(exp 3), and delta (13)C and delta (18)O from CO2 that are both several tens of per mil more positive than the terrestrial averages. Heavy isotope enrichments support the hypothesis of large atmospheric loss. Moreover, the data are consistent with values measured in Martian meteorites, providing additional strong support for a Martian origin for these rocks.

Results from Curiosity↗

NASA NTRS2013

Time Variations of Cosmic-Ray Helium Isotopes with BESS-Polar I

The Balloon-borne Experiment with a Superconducting Spectrometer (BESS) is configured with a solenoidal superconducting magnet and a suite of precision particle detectors, including time-of-flight hodoscopes based on plastic scintillators, a silica-aerogel Cherenkov detector, and a high resolution tracking system with a central jet-type drift chamber. The charges of incident particles are determined from energy losses in the scintillators. Their magnetic rigidities (momentum/charge) are measured by reconstructing each particle trajectory in the magnetic field, and their velocities are obtained by using the time-of-flight system. Together, these measurements can accurately identify helium isotopes among the incoming cosmic-ray helium nuclei up to energies in the GeV per nucleon region. The BESS-Polar I instrument flew for 8.5 days over Antarctica from December 13th to December 21st, 2004. Its long-duration flight and large geometric acceptance allow the time variations of isotopic fluxes to be studied for the first time. The time variations of helium isotope fluxes are presented here for rigidities from 1.2 to 2.5 GV and results are compared to previously reported proton data and neutron monitor data.

Cosmic-ray flux time variations↗

NASA NTRS2021

The effects of terrestrial weathering on samarium-neodymium isotopic composition of ordinary chondrites

Following their fall to Earth, meteorites experience weathering. In this systematic study, we evaluate the trace element composition of ordinary chondrites from the Antarctic cold desert, and Atacama (Chile) and Lut (Iran) hot deserts, with an emphasis on rare earth elements (REE). Our data confirms that terrestrial weathering of meteorites in hot deserts changes their trace element (Sr, Ba, REE, Hf, Th, and U) concentrations. However, weathering effects in majority of Antarctic samples are limited to slight Ba, REE, Hf, and Th depletions and in some case to U enrichment. In comparison to the Antarctic meteorites, hot desert samples show greater disturbances and REE fractionation relative to the average fall values. We measured the Sm-Nd isotopic composition of the hot desert meteorites that have heavily affected REE compositions. Our Sm-Nd isotopic data show a significant effect of terrestrial weathering evidenced by non-CHUR (147)Sm/(144)Nd and (143)Nd/(144)Nd ratios. Measurements show a higher variation and lower values of (147)Sm/(144)Nd for the Atacama samples than those from the Lut Desert. Deviations from CHUR (147)Sm/(144)Nd value are in positive accordance with the degree of La/Lu fractionation caused by weathering. The ɛNd values of Atacama and Lut deserts meteorites range from −2.20 to +1.61, which is wider than the −1.07 to +0.64 range for falls. We suggest that disturbance of primary Sm/Nd ratios resulting from mixing with terrestrial components originating from soil during weathering is responsible for lower (147)Sm/(144)Nd ratio in these meteorites. The majority of the Atacama meteorites regardless of their weathering degrees have their REE compositions and ɛNd affected by terrestrial contamination. Both (147)Sm/(144)Nd ratio and ɛNd values show no straightforward relationship with weathering degree. However, in both cases the samples with the highest negative isotopic disturbances are H chondrites from the Atacama and Lut deserts. In addition, Ba concentration shows a negative correlation with (147)Sm/(144)Nd ratio. Care must be taken into account while dealing with samples collected from hot deserts, even fresh-looking ones.

Isotope geochemistry↗

NASA NTRS2021

Probing the Atmospheric Cl Isotopic Ratio on Mars: Implications for Planetary Evolution and Atmospheric Chemistry

Following the recent detection of HCl in the atmosphere of Mars by ExoMars/Trace Gas Orbiter, we present here the first measurement of the 37Cl/35Cl isotopic ratio in the Martian atmosphere using a set of NOMAD observations. We determine an isotopic anomaly of -6 ±78‰ compared to Earth standard, consistent with the -51‰ to -1‰ measured on Mars’ surface by Curiosity. The measured isotopic ratio is also consistent with surface measurements, and suggests that Cl reservoirs may have undergone limited processing since formation in the Solar Nebula. The examination of possible sources and sinks of HCl shows only limited pathways to short-term efficient Cl fractionation and many plausible reservoirs of “light” Cl.

Exomars NOMAD↗

NASA NTRS2021

Towards a holistic sulfate-water-O2 triple oxygen isotope systematics

Triple oxygen isotope (∆^(17)O with δ^(18)O) signals of H2O and O2 found in sulfate of oxidative weathering origin offer promising constraints on modern and ancient weathering, hydrology, atmospheric gas concentrations, and bioproductivity. However, interpretations of the sulfate-water-O2 system rely on assuming fixed oxygen-isotope fractionations between sulfate and water, which, contrastingly, are shown to vary widely in sign and amplitude. Instead, here we anchor sulfate-water-O2 triple oxygen isotope systematics on the homogeneous composition of atmospheric O2 with empirical constraints and modeling. Our resulting framework does not require a priori assumptions of the O2- versus H2O-oxygen ratio in sulfate and accounts for the signals of mass dependent and mass independent fractionation in the ∆^(17)O and δ^(18)O of sulfate's O2-oxygen source. Within this framework, new ∆^(17)O measurements of sulfate constrain ~2.3Ga Paleoproterozoic gross primary productivity to between 6 and 160 times present-day levels, with important implications for the biological carbon cycle response to high CO2concentrations prevalent on the early Earth.

sulfate, oxygen isotopes, atmospheric oxygen, sulf↗

NASA NTRS2022

Noble Gases and Stable Isotopes Track the Origin and Early Evolution of the Venus Atmosphere

The composition the atmosphere of Venus results from the integration of many processes entering into play over the entire geological history of the planet. Determining the elemental abundances and isotopic ratios of noble gases (He, Ne, Ar, Kr, Xe) and stable isotopes (H, C, N, O, S) in the Venus atmosphere is a high priority scientific target since it could open a window on the origin and early evolution of the entire planet. This chapter provides an overview of the existing dataset on noble gases and stable isotopes in the Venus atmosphere. The current state of knowledge on the origin and early and long-term evolution of the Venus atmosphere deduced from this dataset is summarized. A list of persistent and new unsolved scientific questions stemming from recent studies of planetary atmospheres (Venus, Earth and Mars) are described. Important mission requirements pertaining to the measurement of volatile elements in the atmosphere of Venus as well as potential technical difficulties are outlined.

noble gases↗

NASA NTRSDate not supplied

Early Aqueous Alteration of Ryugu’s Parent Body – Insight from In-situ Isotopic Analyses

The Hayabusa2 mission returned approximately 5.4 g of highly aqueously-altered material resembling the CI (Ivuna-type) chondrites from the C-type asteroid Ryugu. To understand the timing and duration of aqueous alteration on Ryugu’s parent body, we measured the 53Mn-53Cr (t1/2 = 3.7 Myr) ages of dolomite, breunnerite, and Ca-carbonate minerals in Ryugu particles A0037 and C0009 using secondary ion mass spectrometry (SIMS) with the UCLA CAMECA ims-1290 instrument with Hyperion II oxygen plasma source. Using these carbonate formation ages, we estimate the accretion time and size of Ryugu’s parent body to have been within the first 1.8 million years of Solar System history in a planetesimal less than ~20 km in diameter, or within a larger body which was disrupted and reassembled. To further constrain the conditions of aqueous alteration, we measured the δ13C, δ18O, and Δ17O of Ryugu dolomite, Ca-carbonate, and magnetite using the UCLA CAMECA ims-1290. The results of our stable isotopic analyses show that the earliest stages of aqueous alteration occurred at low temperatures (between 0 and 20 °C), that the initial fluid was enriched in the heavy 13C, 17O and 18O isotopes, and that the fluid evolved towards lighter carbon and oxygen isotopic compositions as alteration proceeded.

Astromaterials↗

NASA NTRS2026

The Significance of Water Vapor Isotopes in Improving Weather Prediction

Water vapor isotopes carry the integrated history of evaporation, condensation, mixing, and transport. Although previous studies have shown potential to improve forecasts under controlled conditions, real-world applications have been limited by systematic biases in both models and satellite retrievals arising from sparse measurements in the free troposphere. Here we assimilate mid‑tropospheric δD retrievals (peak sensitivity ~4.2 km) from the Infrared Atmospheric Sounding Interferometer into the Isotope‑incorporated Global Spectral Model and evaluate the added value beyond co‑assimilated temperature and specific humidity with identical spatial and temporal coverage. Assimilating δD improves 0–120 h forecasts of wind, temperature, specific humidity, and geopotential height, with the largest gains in the midlatitudes; heavy‑precipitation skill also increases for thresholds >3 mm per 6 h. Demonstrated in a coarse‑resolution configuration with limited observations, the results indicate that isotopic information strengthens transport tracking and hydrological constraints, motivating evaluation in operational high‑resolution forecasting systems.

Hydrology↗

NASA NTRS1996

Stable light isotope biogeochemistry of hydrothermal systems

The stable isotopic composition of the elements O, H, S and C in minerals and other chemical species can indicate the existence, extent, conditions and the processes (including biological activity) of hydrothermal systems. Hydrothermal alteration of the 18O/16O and D/H values of minerals can be used to detect fossil systems and delineate their areal extent. Water-rock interactions create isotopic signatures which indicate fluid composition, temperature, water-rock ratios, etc. The 18O/16O values of silica and carbonate deposits tend to increase with declining temperature and thus help to map thermal gradients. Measurements of D/H values can help to decipher the origin(s) of hydrothermal fluids. The 34S/32S and 13C/12C values of fluids and minerals reflect the origin of the S and C as well as oxygen fugacities and key redox processes. For example, a wide range of 34S/32S values which are consistent with equilibration below 100 degrees C between sulfide and sulfate can be attributed to sulfur metabolizing bacteria. Depending on its magnitude, the difference in the 13C/12C value of CO2 and carbonates versus organic carbon might be attributed either to equilibrium at hydrothermal temperatures or, if the difference exceeds 1% (10/1000), to organic biosynthesis. Along the thermal gradients of thermal spring outflows, the 13C/12C value of carbonates and 13C-depleted microbial organic carbon increases, principally due to the outgassing of relatively 13C-depleted CO2.

Review, Tutorial↗

NASA NTRS1969

Substitution of stable isotopes in Chlorella

Replacement of biologically important isotopes in the alga Chlorella by corresponding heavier stable isotopes produces increasingly greater deviations from the normal cell size and changes the quality and distribution of certain cellular components. The usefulness of isotopically altered organisms increases interest in the study of such permuted organisms.

Flaumenhaft, E.↗

NASA NTRS1972

Safe atmosphere entry of an isotope heat source with a single stable trim attitude at hypersonic speeds

A theoretical investigation has been made to design an isotope heat source capable of satisfying the conflicting thermal requirements of steady-state operation and atmosphere entry. The isotope heat source must transfer heat efficiently to a heat exchange during normal operation with a power system in space, and in the event of a mission abort, it must survive the thermal environment of atmosphere entry and ground impact without releasing radioactive material. A successful design requires a compatible integration of the internal components of the heat source with the external aerodynamic shape. To this end, configurational, aerodynamic, motion, and thermal analyses were coupled and iterated during atmosphere entries at suborbital through superorbital velocities at very shallow and very steep entry angles. Results indicate that both thermal requirements can be satisfied by a heat source which has a single stable aerodynamic orientation at hypersonic speeds. For such a design, the insulation material required to adequately protect the isotope fuel from entry heating need extend only half way around the fuel capsule on the aerodynamically stable (wind-ward) side of the heat source. Thus, a low-thermal-resistance, conducting heat path is provided on the opposite side of the heat source through which heat can be transferred to an adjacent heat exchanger during normal operation without exceeding specified temperature limits.

Levy, L. L., Jr.↗

NASA NTRS1972

Oxygen isotope temperatures of 'equilibrated' ordinary chondrites.

Measurements have been made of O-18/O-16 ratios of coexisting minerals (plagioclase, pyroxene, olivine) from nine ordinary chondrites. The O-18 content of a given mineral increases systematically from H through L to LL group. Isotope fractionations for mineral pairs fall on a concordancy line, suggesting that these minerals were crystallized in oxygen isotope equilibrium. The isotopic temperature is estimated to be 950 (plus or minus 100) C for seven of the type 5 and type 6 chondrites.

Onuma, N.↗

NASA NTRS1972

Elemental and isotopic abundances in the solar wind

The use of collecting foils and lunar material to assay the isotopic composition of the solar wind is reviewed. Arguments are given to show that lunar surface correlated gases are likely to be most useful in studying the history of the solar wind, though the isotopic abundances are thought to give a good approximation to the solar wind composition. The results of the analysis of Surveyor material are also given. The conditions leading to a significant component of the interstellar gas entering the inner solar system are reviewed and suggestions made for experimental searches for this fraction. A critical discussion is given of the different ways in which the basic solar composition could be modified by fractionation taking place between the sun's surface and points of observation such as on the Moon or in interplanetary space. An extended review is made of the relation of isotopic and elemental composition of the interplanetary gas to the dynamic behavior of the solar corona, especially processes leading to fractionation. Lastly, connection is made between the subject of composition, nucleosynthesis and the convective zone of the sun, and processes leading to modification of initial accretion of certain gases on the Earth and Moon.

Geiss, J.↗

NASA NTRS1973

Cosmic ray isotopes

The isotopic composition of cosmic rays is studied in order to develop the relationship between cosmic rays and stellar processes. Cross section and model calculations are reported on isotopes of H, He, Be, Al and Fe. Satellite instrument measuring techniques separate only the isotopes of the lighter elements.

Stone, E. C.↗

NASA NTRS1974

Regolith history from cosmic-ray-produced isotopes

A statistical model is given for soil development relating meteoroid impacts on the moon to cosmic-ray-produced isotopes in the soil. By means of this model, the average lunar mass loss rate during the past 1.4 aeons is determined to be 170g/sq cm aeon and the soil mixing rate to be approximately 200 cm/aeon from the gadolinium isotope data for the Apollo 15 and 16 drill stems. The isotope data also restrict the time variation of the meteoroid flux during the past 1.4 aeons.

Fireman, E. L.↗

NASA NTRS1973

The relative abundance of the isotopes of Li, Be and B and the age of cosmic rays

Using a balloon borne double dE/dx total energy telescope, we have determined the isotopic composition of cosmic ray Li, Be and B nuclei in the energy range 100-250 MeV/nuc. The measured mass resolution for these nuclei is about 0.3 AMU. The observed isotopic composition is in agreement with that predicted on the basis of interstellar fragmentation with the exception of a deficiency of Be-10. If the low abundance of Be-10 is attributed to the decay of this radioactive isotope, we obtain a mean cosmic ray lifetime of 3.4 (plus 3.4 or minus 1.3) m.y.

Webber, W. R.↗

NASA NTRS1974

Cosmic ray isotope resolution obtained using a new Cerenkov-total energy telescope

The details of a recent measurement of the cosmic ray isotopic composition of Z equals or exceeds 10 nuclei are given, using a new technique combining a Cerenkov and total energy counter. In terms of sigma, the characteristic width of a Gaussian distribution of mass measurement, values of mass resolution have been obtained ranging from about 0.4 AMU at a Z about 14, to about 0.8 AMU at a Z about 26, using the Cerenkov-total energy (C x E) technique. It is customary to claim that two equal Gaussian distributions may be resolved for values of sigma less than 0.4 x the separation of their means. With these criteria isotopes separated by delta A = 2 are being resolved up to a Z about 26 using the C x E technique. An important source of error in these measurements is the determination of the mass of each of the isotopes on an absolute scale.

Webber, W. R.↗

NASA NTRS1974

A large area multi-element telescope for measuring the cosmic ray isotope composition

To measure the isotopic composition of cosmic rays up to Fe an instrument is needed with good isotopic resolution and a large exposure. The large geometry needed for a balloon-borne detector has been obtained with large mapped detectors and a trajectory determining spark chamber. The instrument achieves isotopic resolution only for stopping particles. For low charge particles where there is no Cerenkov response the detector works as a multiple dE/dx-Range-Energy detector. For higher charges where scintillator saturation becomes important it becomes a Cerenkov-range measurement.

Fisher, A. J.↗