Search NASA⌕ Search

SEARCH · Search NASA

Results for “Ion association”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Association reactions at low pressure. IV - The HC3N(+)/HC3N system

Ion cyclotron mass spectrometry is used here to study the reactions between HC3N(+) and HC3N and between HC5N(+) and HC3N at pressures from 1 x 10 to the -7th to 0.001 Torr. The former reaction has both a bimolecular reaction path and a termolecular reaction path. The overall bimolecular reaction rate coefficient is 1.3 x 10 to the -19 cu cm/s. The primary product HC5N(+) represents 90 percent of the product ions, while HC6N2(+) and H2C6N2(+) each represent 5 percent. The termolecular association rate coefficient is 3.7 x 10 to the -24th cm exp 6/s, with He as the third body. The mean lifetime of the collision is 180 microsec. HC5N(+) reacts with HC3N to form the adduct ion H2C8N2(+) through both bimolecular and termolecular reactions. The bimolecular rate coefficient is 5.0 x 10 to the -10th cu cm/s and the termolecular one is 1.2 x 10 to the -22nd cm exp 6/s, with HC3N as the third body.

Sen, Atish D.↗
NASA NTRS1973

Comet Encke: Meteor metallic ion identification by mass spectrometer

Positive metallic ions have been measured in the earth's atmosphere between 85 and 120 km, during the period of the beta Taurids meteor shower, which is associated with Comet Encke. The ions originate during and following ablation of extraterrestrial debris by the earth's atmosphere. The enhancement of metal ion density during meteor showers is primary evidence for their extraterrestrial origin. The present results were obtained from a rocket-borne ion mass spectrometer.

Goldberg, R. A.↗
NASA NTRS1987

The ionotail of Venus - Its configuration and evidence for ion escape

The configuration and morphology of the plasma clouds in the ionotail of Venus (revealed by the Pioneer Venus Orbiter) are studied, and the rate of planetary ion escape, which may be associated with the dissipation and removal of the ionospheric plasma, is estimated. The data supplied by the Orbiter's instruments, the Orbiter electron temperature probe, the ion mass spectrometer, the neutral mass spectrometer, the magnetometer, and the plasma analyzer, are analyzed, and the results of the observations are discussed.

Brace, L. H.↗
NASA NTRS1973

Spacecraft integration of an ion propulsion system

This paper describes the development and integration of a one millipound thrust ion thruster system on the NASA Goddard ATS-F spacecraft with the objective of outlining for the propulsion system engineer: (1) system interactions or potential problems associated with the application of ion thruster systems, and (2) progress which has been made and is being made in identifying and solving these problems. Principal areas of concern are the compatibility of the thruster exhaust (ions and atoms) with sensitive spacecraft surfaces and possible electromagnetic interactions of the thruster and its exhaust with other spacecraft subsystems.

Worlock, R. M.↗
NASA NTRS1987

Parabolic heavy ion flow in the polar magnetosphere

Recent observations by the Dynamics Explorer 1 satellite over the dayside polar cap magnetosphere have indicated downward flows of heavy ions such as O(+), O(2+), N(+), and N(2+) with flow velocities of the order 1 km/s (Lockwood et al., 1985). These downward flows were interpreted as the result of 'parabolic' flow of these heavy ionospheric ions from a source region associated with the polar cleft topside ionosphere. Here, a two-dimensional kinetic model is utilized to elicit features of the transport of very low energy O(+) ions from the cleft ionosphere. Bulk parameter (density, flux, thermal energies, etc.) distributions in the noon-midnight meridian plane illustrate the effects of varying convection electric fields and source energies. The results illustrate that, particularly under conditions of weak convection electric fields and weak ion heating in the cleft region, much of the intermediate altitude polar cap magnetosphere may be populated by downward flowing heavy ions. It is further shown how two-dimensional transport effects may alter the characteristic vertical profiles of densities and fluxes from ordinary profiles computed in one-dimensional steady-state models.

Horwitz, J. L.↗
DOE OSTI2020

Evidence for a Solid-Electrolyte Inductive Effect in the Superionic Conductor Li 10 Ge 1– x Sn x P 2 S 12

Strategies to enhance ionic conductivities in solid electrolytes typically focus on the effects of modifying their crystal structures or of tuning mobile-ion stoichiometries. A less-explored approach is to modulate the chemical bonding interactions within a material to promote fast lithium-ion diffusion. Recently, the idea of a solid-electrolyte inductive effect has been proposed, whereby changes in bonding within the solid-electrolyte host framework modify the potential energy landscape for the mobile ions, resulting in an enhanced ionic conductivity. Direct evidence for a solid-electrolyte inductive effect, however, is lacking—in part because of the challenge of quantifying changes in local bonding interactions within a solid-electrolyte host framework. Here, we consider the evidence for a solid-electrolyte inductive effect in the archetypal superionic lithium-ion conductor Li 10 Ge 1–x Sn x P 2 S 12 . Substituting Ge for Sn weakens the {Ge,Sn}–S bonding interactions and increases the charge density associated with the S 2– ions. This charge redistribution modifies the Li + substructure causing Li + ions to bind more strongly to the host framework S 2– anions, which in turn modulates the Li + ion potential energy surface, increasing local barriers for Li + ion diffusion. Each of these effects is consistent with the predictions of the solid-electrolyte inductive effect model. Density functional theory calculations predict that this inductive effect occurs even in the absence of changes to the host framework geometry due to Ge → Sn substitution. These results provide direct evidence in support of a measurable solid–electrolyte inductive effect and demonstrate its application as a practical strategy for tuning ionic conductivities in superionic lithium-ion conductors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1989

Interplanetary energetic particle observations of the March 1989 events

The IMP-8 spacecraft placed in an elongated orbit of approximately R(sub E) x R(sub E) orbit around the Earth was the only monitor of the energetic particle environment of the near interplanetary space during the period of the solar particle events associated with the Active Region 5395 in March 1989. Measurements of energetic ion and electron intensities were obtained in a series of channels within the energy range: 0.3 to 440 MeV for photons, 0.6 to 52 MeV/nuc for alpha particles, 0.7 to 3.3 MeV/nuc for nuclei with Z greater than or equal to 3, 3 to 9 MeV/nuc with Z greater than or equal to 20, and 0.2 to 2.5 MeV for electrons. The responses of selected energy channels during the period 5 to 23 March 1989 are displayed. It is clearly noted that the most prominent energetic ion intensity enhancements in that time interval were associated with the interplanetary shock wave of March 13 (07:42 UT) as well as that of March 8 (17:56 UT), which have distinct particle acceleration signatures. These shock waves play a major role in determining the near Earth energetic ion intensities during the above period by accelerating and modulating the ambient solar energetic particle population, which was already present in high intensities in the interplanetary medium due to the superposition of a series of solar flare particle events originating in AR 5395. The differential ion intensities at the lowest energy channel of the CPME experiment, which were associated with the March 13 shock wave, reached the highest level in the life of the IMP-8 spacecraft at this energy. At high energies, the shock associated intensity peak was smaller by less than a factor of 3 than the maxima of solar flare particle intensities from some other major flares, in particular from those with sites well connected to the Earth's magnetic flux tubes.

Sarris, E. T.↗
NASA NTRS1985

Nonresonant interaction of heavy ions with electromagnetic ion cyclotron waves

The motion of a heavy ion in the presence of an intense ultralow-frequency electromagnetic wave propagating along the dc magnetic field is analyzed. Starting from the basic equations of motion and from their associated two invariants, the heavy ion velocity-space trajectories are drawn. It is shown that after a certain time, particles whose initial phase angles are randomly distributed tend to bunch together, provided that the wave intensity b-sub-1 is sufficiently large. The importance of these results for the interpretation of the recently observed acceleration of singly charged He ions in conjunction with the occurrence of large-amplitude ion cyclotron waves in the equatorial magnetosphere is discussed.

Berchem, J.↗
NASA NTRS1994

Ion velocity distributions in the vicinity of the current sheet in Earth's distant magnetotail

Observations of the three-dimensional velocity distributions of positive ions and electrons have been recently gained for the first time in Earth's distant magnetotail with the Galileo and Geotail spacecraft. For this brief discussion of these exciting results the focus is on the overall character of the ion velocity distributions during substorm activity. The ion velocity distributions within and near the magnetotail current sheet are not accurately described as convecting, isotropic Maxwellians. The observed velocity distributions are characterized by at least two robust types. The first type is similar to the 'lima bean'-shaped velocity distributions that are expected from the nonadiabatic acceleration of ions which execute Speiser-type trajectories in the current sheet. The second distribution is associated with the presence of cold ion beams that presumably also arise from the acceleration of plasma mantle ions in the electric and weak magnetic fields in the current sheet. The ion velocity distributions in a magnetic field structure that is similar to that for plasmoids are also examined. Again the velocity distributions are not Maxwellian but are indicative of nonadiabatic acceleration. An example of the pressure tensor within the plasmoid-like event is also presented because it is anticipated that the off-diagonal elements are important in a description of magnetotail dynamics. Thus our concept of magnetotail dynamics must advance from the present assumption of co-moving electron and ion Maxwellian distributions into reformulations in terms of global kinematical models and nonadiabatic particle motion.

Frank, L. A.↗
DOE OSTI2022

A chiral alkali metal capped Ni 4 cubane complex: Synthesis, structure, magnetic and catalytic bromination studies

A new chiral NaO 2 Ni 4 O 2 N 2 cluster has been developed with a distorted capped cubane-type structure. The structure was determined by single crystal X-ray diffraction. The tetradentate Schiff-base ligand was synthesized by the condensation of o-vanillin and $\textit{D}$-(-)–threo-2-amino-1-(4-nitrophenyl)-1,3-propanediol. X-ray structure reveals that the complex possesses a Ni 4 cubane cluster where sodium ion is anchored on the face of the cubane structure. Continuous shape measurement studies revealed that all the Ni centres are in distorted octahedral geometry and sodium ion adopts the spherical square pyramidal geometry. Further structural exploration reveals that the complex shows local distortions of the coordination geometries at each metal site, and these distortions govern the magnetic anisotropy associated with each Ni II ion. For the present case, an elongation ($d_{str}$ > 0) of the octahedral coordination sphere results in a local easy-plane anisotropy, with a positive $D_{Ni(II)}$ parameter. Temperature dependant magnetization measurements showed a predominant ferromagnetic interaction amongst the four Ni centres. This complex is also catalytically active towards bromination of aromatic phenolic compounds. Initial catalytic activity was verified with the conversion of phenol red to bromophenol blue. Different phenolic substances show good conversion to their corresponding bromo derivatives. The complex showed good catalytic activity towards bromination of aromatic phenolic compounds, offering up to 99% conversion with 100% selectively to their corresponding bromo derivatives.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

Association reactions at low pressure. III - The C2H2(+)/C2H2 system

An ion cyclotron resonance mass spectrometer is used to examine the association reactions, C4H2(+) + C2H2 and C4H3(+) + C2H2, at pressures in the range of 8 x 10 to the -8 to 1 x 10 to the -4 Torr at 298 K. The association of C4H2(+) and C4H3(+) with C2H2 was found to exhibit classical behavior in the pressure range of 5 x 10 to the -8 Torr to 0.4 Torr. It is found that an efficient route via radiative association exists for unsaturated hydrocarbon cations to convert to aromatic structures in the presence of acetylene.

Anicich, Vincent G.↗
DOE OSTI2024

MARS-F/K modeling of plasma response and fast ion losses due to RMP in KSTAR

Abstract The toroidal single-fluid magnetohydrodynamic (MHD) code MARS-F (Liu et al 2000 Phys. Plasmas 7 3681) and the MHD-kinetic hybrid code MARS-K (Liu et al 2008 Phys. Plasmas 15 112503) are utilized to study the plasma response to the n = 1 ( n is the toroidal mode number) resonant magnetic perturbation (RMP), applied to suppress the type-I edge localized mode (ELM) in a KSTAR discharge. Both the resistive-rotating and ideal-static plasma models identify strong screening of the resonant radial field harmonics of the applied RMP due to the plasma response, and predict a strong edge-peeling response of the plasma which is consistent with the optimal ELM control coil current configuration adopted in experiment. The RMP-induced radial displacement of the plasma, computed by the resistive-rotating plasma model, agrees reasonably well with that reconstructed from the measured data in the plasma core. Taking into account the drift kinetic response of fast ions, MARS-K hybrid modeling also finds quantitative agreement of the plasma core fluid pressure perturbation with experiment. Based on the MARS-F computed plasma response, a guiding-center orbit-tracing simulation finds about 0.3% of fast ion losses due the n = 1 RMP in the KSTAR ELM control experiment considered. Most losses are associated with counter-current fast ions located near the plasma edge.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1986

Ion acceleration in laboratory plasmas

Recent experiments which investigate ion acceleration in 'collisionless' laboratory plasmas are described. The experiments fall into two classes - those involving stationary and those involving time dependent processes.Among the stationary structures which accelerate ions are sheaths, presheaths, double layers, multiple double layers and ambipolar potentials. RF is an example of time dependent processes. Both classes of experiments are considered. Experiments with 'collisionless' plasmas in multidipole triple plasma-type devices and novel phenomena associated with the use of Ion Cyclotron Resonance Heating in the inhomogeneous magnetic field of a tandem mirror 'fusion' plasma are described. New RF phenomenon include RF pitch angle scattering, RF electron pumping, and ICRF ponderomotive force.

Hershkowitz, Noah↗
NASA NTRS1993

Magnetosheath-ionospheric plasma interactions in the cusp/cleft. 1: Observations of modulated injections and upwelling ion fluxes

In situ observations of the cusp/cleft are important as they allow a direct investigation of coupling solar wind energy to the ionosphere, plus they provide an opportunity for the remote sensing of the magnetopause. High time resolution observations from Dynamic Explorer 1 are used to investigate these processes. It is shown that in the spacecraft frame the injection is modulated or pulsating with a period of approximately 18-30 s with the injection duration possibly being as short as 6 s. This modulation indicates that there may be fast time scale and/or short scale length processes modulating the injection of the magnetosheath plasma across the magnetopause. In addition, the pulsating injection is seen to modulate the outflow of upwelling ionospheric ions to the magnetosphere. These upwelling ions are seen prior to the magnetosheath ion injection and therefore are not directly created by the injection. During the injection itself, the intensity of the upwelling ions is seen to dramatically decrease but their average energy increases. At end of the magnetosheath injections, the intensity of the upwelling ion flux is seen to increase to levels comparable to levels prior to the magnetosheath injection. On two occasions during the encounter, the particle fluxes are sufficiently high that enhanced downward flows of perpendicularly heated ions, of presumably ionospheric origin, are observed in association with a reduction in the intensity of the upwelling ions. These observations are probably the first detection of downward conics and suggest that there is momentum transfer between the magnetosheath and ionospheric ions. This momentum transfer eventually leads to an enhanced outflow of heated ionospheric plasma where their energy has been raised from a few tens of eV to a few hundred eV.

Winglee, R. M.↗
NASA NTRS2011

Wind Observations of Wave Heating and/or Particle Energization at Supercritical Interplanetary Shocks

We present the first observations at supercritical interplanetary shocks of large amplitude (> 100 mV/m pk-pk) solitary waves, approx.30 mV/m pk-pk waves exhibiting characteristics consistent with electron Bernstein waves, and > 20 nT pk-pk electromagnetic lower hybrid-like waves, with simultaneous evidence for wave heating and particle energization. The solitary waves and the Bernstein-like waves were likely due to instabilities driven by the free energy provided by reflected ions [Wilson III et al., 2010]. They were associated with strong particle heating in both the electrons and ions. We also show a case example of parallel electron energization and perpendicular ion heating due to a electromagnetic lower hybrid-like wave. Both studies provide the first experimental evidence of wave heating and/or particle energization at interplanetary shocks. Our experimental results, together with the results of recent Vlasov [Petkaki and Freeman, 2008] and PIC [Matsukyo and Scholer, 2006] simulations using realistic mass ratios provide new evidence to suggest that the importance of wave-particle dissipation at shocks may be greater than previously thought.

Wilson, Lynn Bruce, III↗
DOE OSTI2026

Mixed-anion electrolytes: from bulk speciation to interfacial dynamics in divalent metal electrodeposition

Mixing anions is emerging as a promising strategy for multivalent electrolyte design, allowing for adjustment of the solvation structure of bulk cations and enhancing the efficiency of electrochemical processes (e.g. metal deposition for batteries and catalysis). Further progress in electrolyte development requires a fundamental understanding of how tailored electrolyte speciation in mixed anion systems can modify the dynamic electrochemical interface during metal cycling. In this study, we present an anode-focused mechanistic study of exemplar Mg electrolytes containing three different secondary anions, correlating electrochemical behavior with bulk speciation and operando interfacial dynamics. Electrospray Ionization-Mass Spectrometry (ESI-MS) results reveal a general trend of forming mixed anion contact ion pairs (CIPs) across various anions, with the extent of ion pairing influenced by the association strength of the secondary anion. Operando multiharmonic electrochemical quartz crystal microbalance with dissipation (EQCM-D) reveals how these bulk species influence interfacial mass uptake, viscoelasticity, and solvent-coupled hydrodynamic behavior during deposition and stripping. The results indicate that Mg-containing ion pairs and solvated complexes shape adsorption, nucleation, and deposit growth, leading to distinct anion-dependent interphases ranging from more permeable, solvent-coupled layers to relatively compact and rigid deposits. This work establishes a quantitative link between bulk speciation and interfacial dynamics in divalent metal electrodeposition and provides mechanistic guidance for electrolyte design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

Ion Viscosity Mediated by Tangled Magnetic Fields: An Application to Black Hole Accretion Disks

We examine the viscosity associated with the shear stress exerted by ions in the presence of a tangled magnetic field. As an application, we consider the effect of this mechanism on the structure of black hole accretion disks. We do not attempt to include a self-consistent description of the magnetic field. Instead, we assume the existence of a tangled field with coherence length lambda(sub coh), which is the average distance between the magnetic 'kinks' that scatter the particles. For simplicity, we assume that the field is self-similar, and take lambda(sub coh) to be a fixed fraction zeta of the local disk height H. Ion viscosity in the presence of magnetic fields is generally taken to be the cross-field viscosity, wherein the effective mean free path is the ion Larmor radius lambda(sub L), which is much less than the ion-ion Coulomb mean free path A(sub ii) in hot accretion disks. However, we arrive at a formulation for a 'hybrid' viscosity in which the tangled magnetic field acts as an intermediary in the transfer of momentum between different layers in the shear flow. The hybrid viscosity greatly exceeds the standard cross-field viscosity when (lambda/lambda(sub L)) much greater than (lambda(sub L)/lambda(sub ii)), where lambda = ((lambda(sub ii)(sup -1) + lambda(sub (coh)(sup -1))(sup -1) is the effective mean free path for the ions. This inequality is well satisfied in hot accretion disks, which suggests that the ions may play a much larger role in the momentum transfer process in the presence of magnetic fields than was previously thought. The effect of the hybrid viscosity on the structure of a steady-state, two-temperature, quasi-Keplerian accretion disk is analyzed. The hybrid viscosity is influenced by the degree to which the magnetic field is tangled (represented by zeta = lambda(sub coh)), and also by the relative accretion rate M/M(sub E), where M(sub E) = L(sub E)/c(sup 2) and L(sub E) is the Eddington luminosity. We find that ion viscosity in the presence of magnetic fields (hybrid viscosity) can dominate over conventional magnetic viscosity for fields that are tangled on sufficiently small scales.

Subramanian, Prasad↗
NASA NTRS1993

Corotating MeV/amu ion enhancements at 1 AU or less from 1978 to 1986

The properties of MeV/amu ions in 64 corotating streams at and inside 1 AU associated with corotating high-speed streams from 1978 to 1986 during presolar maximum to near solar minimum conditions are discussed. Around 50 percent of the streams include significant ion intensity enhancements not associated with solar particle events or traveling interplanetary shocks. The ions stream nearly along the E x B drift direction in the spacecraft frame, corresponding to a weak sunward field-aligned streaming in the solar wind frame. The sunward streaming is consistent with particle acceleration in the outer heliosphere followed by diffusion into the inner heliosphere. The ion intensity is not correlated with the stream solar wind speed or with the increase in solar wind speed at the leading edge of the high-speed stream, suggesting that the local shock strength alone may not play a dominant role in determining the intensity.

Richardson, I. G.↗