Minority Carrier Lifetime Analysis in the Bulk of Thin-Film Absorbers Using Subbandgap (Two-Photon) Excitation
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NREL's new imaging tool could provide manufacturers with insight on their processes.
Poster to be presented to academics and STEM students from local universities during the American Association of Colleges and Universities (AAC&U) Transforming STEM Higher Education Conference: Back to Broken?, November 3–5, 2022, Arlington, VA (https://secure.aacu.org/iMIS/AACUR/Events/Event_Display.aspx?EventKey=STEM22).
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Adiabatic quantum programming defines the time-dependent mapping of a quantum algorithm into the hardware or logical fabric. An essential programming step is the embedding of problem-specific information into the logical fabric to define the quantum computational transformation. We present algorithms for embedding arbitrary instances of the adiabatic quantum optimization algorithm into a square lattice of specialized unit cells. Our methods are shown to be extensible in fabric growth, linear in time, and quadratic in logical footprint. In addition, we provide methods for accommodating hard faults in the logical fabric without invoking approximations to the original problem. These hard fault-tolerant embedding algorithms are expected to prove useful for benchmarking the adiabatic quantum optimization algorithm on existing quantum logical hardware. We illustrate this versatility through numerical studies of embeddabilty versus hard fault rates in square lattices of complete bipartite unit cells.
Poster to be presented to academics and STEM students from local universities during the American Association of Colleges and Universities (AAC&U) Transforming STEM Higher Education Conference: Back to Broken?, November 3–5, 2022, Arlington, VA (https://secure.aacu.org/iMIS/AACUR/Events/Event_Display.aspx?EventKey=STEM22).
Informative presentation on the MSIPP program. Information on the CONCISE program has been added to this version.
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Oxidation-induced degradation of structural materials employed as exhaust valves within internal combustion engines (ICEs) will be a relevant life-limiting mechanism, in addition to creep and mechanical fatigue, due to ever-increasing severity of operating temperatures and pressures. Ni–Cr-based alloys, which form external chromia-based scales at the relevant operating temperatures are being considered as suitable candidate materials. Thermal cycling of these alloys in water vapor-containing atmospheres, such as those present during hydrocarbon fuel combustion within ICEs, can considerably influence their oxidation behavior. Here, the role of typical alloying additions such as Mn, Si, Al and Ti on the cyclic oxidation behavior of model NiCr–X (X = Mn,Si,Al,Ti) alloys exposed in dry air and air + 10% H 2 O at 800°C and 950°C was investigated. Combined additions of Mn and Si reduced scaling rates compared to binary Ni–22Cr alloys. The presence of water vapor possibly suppressed formation of NiMnCr spinel and thereby the Cr depletion in the alloy. Combined Al and Ti additions mainly resulted in accelerated oxidation kinetics due to the Ti doping of chromia scales. More porous external scales were observed in water vapor leading to a much deeper depth of nitridation in the Ni–22Cr–Al–Ti alloys.
Here, the cracking behavior of a high γ' volume fraction CoNi-base superalloy fabricated via laser powder bed fusion (LPBF) is studied in relation to the content of carbon and boron. Severe cracking occurred with the increase in boron content from 0.08 to 0.16 at. pct (0.015 to 0.029 wt pct), while compositions with 0.1 to 0.36 at. pct C (0.02 to 0.076 wt pct) and 0.08 at. pct B exhibited minimal cracking. Assessment of cracks in the high-boron composition shows a variation in crack density with printing parameters, and alignment of the cracks with the build direction. Scanning electron microscopy (SEM) of the crack surfaces shows evidence of a solidification cracking mode. Differential thermal analysis (DTA) reveals a decreased incipient melting temperature for the high-boron composition, and atom probe tomography (APT) is used to measure the enrichment at grain boundaries, revealing distinct boron segregation. Scheil-Gulliver solidification simulations for the different C and B levels are consistent with the incipient melting behavior observed with DTA. Evaluation of the solidification cracking susceptibility from the simulations allow for comparison of the CoNi alloy behavior to Ni-base superalloys studied for LPBF fabrication and displays how such metrics may aid in the design of new precipitation-strengthened superalloys for additive manufacturing (AM).
This paper explores cast Mg-5Zn alloy, containing small amounts of yttrium (Y: 0.1-1.5 wt.%), through microstructure evaluation and tensile and hardness tests. The results reveal that addition of Y to the alloy refines microstructure, especially when secondary phases, Mg{sub 3}Zn{sub 6}Y (I) and Mg{sub 3}Zn{sub 3}Y{sub 2} (W), form. I-phase is detected when 0.3 wt.% Y is added to the alloy, while W-phase is only observed in Mg-5Zn-1.5Y alloy. The results also show that the addition of Y improves yield and tensile strength as well as the hardness value of the Mg-5Zn alloy at the expense of its formability. The three effects of the solid solution of Y in α-Mg, grain refinement, and the formation of I- and W-phases are the reasons for such behavior. The improvement is more pronounced when W-phase appears in the microstructure. In other words, Mg-5Zn-1.5Y alloy behaves stronger and harder than other alloys and may be considered as a potential candidate for bioimplant applications if its degradation behavior meets the requirements.
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