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At least 415 records · Page 23

Research in Theoretical Particle Physics: Neutrino Masses and The Origin of CP-Violation

The main goal of this project was to investigate the theories of neutrino masses at the low scale and the origin of CP-violation in physics beyond the Standard Model. The origin of neutrino masses is one of the most pressing issues in particle physics. In this proposal, we investigated the theories for neutrino masses based on local total lepton number. In these theories anomaly cancellation predicts the existence of extra fermions with lepton number, and one of them is a good dark matter (DM) candidate. The cosmological constraints on the DM relic density implies that the lepton number symmetry breaking scale must be below the multi-TeV scale. Therefore, one can hope to test the origin of neutrino masses in current or future experiments. We investigated in great detail the anomaly cancellation in these gauge theories, study the different mechanisms for neutrino masses, study the predictions for direct and indirect dark matter experiments. Since these theories predict new sources of CP violation, we investigated the predictions for the electric dipole moments (EDM). The Higgs decays and the different signatures at the Large Hadron Collider were investigated in great detail. Finally, we studied the possible baryogenesis mechanisms in these theories in agreement with the EDM, DM and collider constraints. The origin of CP violation in the Standard Model is unknown. In this proposal, we investigated the simplest mechanisms for spontaneous CP-violation to explain the CP-violation in the CKM matrix and the value of the QCD vacuum angle. We discussed the Nelson-Barr mechanism in gauge theories predicting vector-like quarks from anomaly cancellation such as theories for local baryon number. We discussed the Bento-Branco-Parada mechanism in gauge theories to explain the CP-Violation in the CKM matrix. We will investigate models with two Higgs doublets in the context of the minimal theory for quark-lepton unification. We will show the non-decoupling effects in the Higgs sector, the main constraints coming from flavour violating processes when the Yukawa couplings are related by the gauge symmetry in theories for quark-lepton unification. We will investigate the predictions for electric dipole moments in these theories. The possibility to have successful baryogenesis was investigated. Finally, we investigated the relation between CP-violation in the quark and leptonic sectors. The future results from these studies could help us to understand two main issues in physics beyond the Standard Model: The Origin of Neutrino Masses and CP-violation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Reinventing wastewater treatment plants: energy neutral treatment and enhanced fertilizer production through a novel resource recovery center

Wastewater treatment plants (WWTPs) are typically energy intensive, mainly due to the secondary treatment processes such as activated sludge (AS) for treatment of organics as well as nutrients like nitrogen. Nitrogen removal presents a big problem for WWTPs. The main form of nitrogen in wastewater is ammonium, and an AS process uses oxygen to convert ammonium into nitrite and nitrate which is then converted to nitrogen through denitrification process. During anaerobic digestion (AD), organic nitrogen gets degraded, resulting in an effluent stream (centrate) with a high nitrogen content, mostly in the form of ammonium. This contributes 15-30% of total nitrogen to the wastewater influent which further increases energy consumption for aeration. The project aims to transform this conventional municipal WWTPs into energy-neutral, resource-recovering facilities by integrating three core technologies: • Cloth Media Filtration (CMF) to replace conventional primary sedimentation (CPS) and increase the diversion of organics from the energy intensive secondary treatment to AD. This results in reduced energy demand for aeration in the secondary process while simultaneously increasing the biogas production in the anaerobic digesters. • Anerobic Digester to increase biogas and ammonia production. • Membrane Evaporation (ME) to recover ammonia from AD centrate and produce marketable fertilizer. The benefits of proposed WWTP process modifications were evaluated using techno economic analysis (TEA) and life cycle assessment (LCA). For CMF portion of the research a statistical analysis was employed to develop data-driven tools that could be used to enhance and optimize its performance in terms of energy savings and effluent quality. The main objective of this project is to reduce the energy demand for secondary treatment at municipal WWTPs by at least 50%, increase anaerobic digester (AD) biogas and ammonia production by 100% and 120%, respectively, and recover 90% of ammonia from the AD. Integrated CMF, AD, and ME was shown to work synergistically toward achieving these decarbonization targets through energy-positive treatment and fertilizer recovery techniques.

42 ENGINEERING↗

BOTTLE: Hybrid Chemical-Mechanical Separation and Upcycling of Mixed Plastic Waste

The main objective of this project is to develop a hybrid mechanical-chemical recycling technology for multilayered and laminated plastics. We aimed to separate and upcycle up to more than 80% of the two main constituents of such structures, polyolefins and polyesters, for a significantly lower cost and at higher energetic efficiency and much larger throughputs than chemical recycling. At the end of the project, the team was able to: a) Develop an extrusion-based separation technology that resorts to polyester depolymerizaton and extraction and allows for more than 90% of the polyester to be separated in the melt from the main polyolefin stream. b) Depolymerize the separated PET to more than 90%, which facilitates its posterior repolymerization and guarantees its retention in the polymer value-chain. c) Develop a zeolite-induced extrusion-based technology able to conduct continuous catalytic cracking of polyolefins, including highly contaminated PCR streams, at temperatures as low as 350 OC. d) Show, using LCA/TEA analysis that the two technologies are much more advantageous techno-economically and over the material’s life cycle than existing recycling technologies.

36 MATERIALS SCIENCE↗

Life Cycle Assessment of Bioethanol Production: A Case Study from Poplar Biomass Growth in the U.S. Pacific Northwest

Biomass appears to be one of the most prominent renewable resources for biofuels such as bioethanol, mainly due to its better environmental performance compared with fossil fuels. This study addresses a comprehensive environmental performance of bioethanol production, employing empirical data from hybrid poplar grown in the U.S. The study considers 1 MJ as a functional unit and employs a cradle-to-grave approach, which entails the feedstock and harvesting production of poplar, transport to a biorefinery, bioconversion of the biomass process, and fuel use. On average, bioconversion is the main contributor to environmental degradation in all the categories evaluated (77%). The second main contributor is either the feedstock and harvesting production of poplar (17%) or fuel use (6%), depending on the environmental category. Thus, focusing on only one category may induce a misinterpretation of the environmental performance of bioethanol production. Finally, environmental credits in the global warming potential (GWP) category were obtained from the carbon sequestered in the biomass during the growing period and from avoided fossil fuel emissions due to electricity production from a renewable source. This means that the net GWP of the life cycle of bioethanol from poplar biomass is slightly negative (–1.05 × 10 –3 kg CO 2 -eq·MJ –1 ).

09 BIOMASS FUELS↗

Ultra-short-period Planets Are Stable against Tidal Inspiral

It has been unambiguously shown both in individual systems and at the population level that hot Jupiters experience tidal inspiral before the end of their host stars’ main-sequence lifetimes. Ultra-short-period (USP) planets have orbital periods P < 1 day, rocky compositions, and are expected to experience tidal decay on similar timescales to hot Jupiters if the efficiency of tidal dissipation inside their host stars parameterized as Q{sub ∗}{sup ′} is independent of P and/or secondary mass M {sub p}. Any difference between the two classes of systems would reveal that a model with constant Q{sub ∗}{sup ′} is insufficient. If USP planets experience tidal inspiral, then USP planet systems will be relatively young compared to similar stars without USP planets. Because it is a proxy for relative age, we calculate the Galactic velocity dispersions of USP planet candidate host and non-host stars using data from Gaia Data Release 2 supplemented with ground-based radial velocities. We find that main-sequence USP planet candidate host stars have kinematics consistent with similar stars in the Kepler field without observed USP planets. This indicates that USP planet hosts have similar ages to field stars and that USP planets do not experience tidal inspiral during the main-sequence lifetimes of their host stars. The survival of USP planets requires that Q{sub ∗}{sup ′} ≳ 10{sup 7} at P ≈ 0.7 day and M{sub p}≈2.6 M{sub ⊕}. This result demands that Q{sub ∗}{sup ′} depend on the orbital period and/or mass of the secondary in the range 0.5 day≲P≲5 days and 1 M{sub ⊕}≲M{sub p}≲1000 M{sub ⊕}.

79 ASTRONOMY AND ASTROPHYSICS↗

KELT-11 b: Abundances of Water and Constraints on Carbon-bearing Molecules from the Hubble Transmission Spectrum

In the past decade, the analysis of exoplanet atmospheric spectra has revealed the presence of water vapor in almost all the planets observed, with the exception of a fraction of overcast planets. Indeed, water vapor presents a large absorption signature in the wavelength coverage of the Hubble Space Telescope’s (HST) Wide Field Camera 3 (WFC3), which is the main space-based observatory for atmospheric studies of exoplanets, making its detection very robust. However, while carbon-bearing species such as methane, carbon monoxide, and carbon dioxide are also predicted from current chemical models, their direct detection and abundance characterization has remained a challenge. Here we analyze the transmission spectrum of the puffy, clear hot-Jupiter KELT-11 b from the HST WFC3 camera. We find that the spectrum is consistent with the presence of water vapor and an additional absorption at longer wavelengths than 1.5 μm, which could well be explained by a mix of carbon bearing molecules. CO{sub 2}, when included is systematically detected. One of the main difficulties to constrain the abundance of those molecules is their weak signatures across the HST WFC3 wavelength coverage, particularly when compared to those of water. Through a comprehensive retrieval analysis, we attempt to explain the main degeneracies present in this data set and explore some of the recurrent challenges that are occurring in retrieval studies (e.g., the impact of model selection, the use of free versus self-consistent chemistry, and the combination of instrument observations). Our results make this planet an exceptional example of a chemical laboratory to test current physical and chemical models of the atmospheres of hot Jupiters.

79 ASTRONOMY AND ASTROPHYSICS↗

Stellar Radial Velocities in the Old Open Cluster M67 (NGC 2682). II. The Spectroscopic Binary Population

We present and analyze 120 spectroscopic binary and triple cluster members of the old (4 Gyr) open cluster M67 (NGC 2682). As a cornerstone of stellar astrophysics, M67 is a key cluster in the WIYN Open Cluster Study (WOCS); radial-velocity (RV) observations of M67 are ongoing and extend back over 45 yr, incorporating data from seven different telescopes, and allowing us to detect binaries with orbital periods ≲10{sup 4} days. Our sample contains 1296 stars (604 cluster members) with magnitudes of 10 ≤ V ≤ 16.5 (about 1.3–0.7 M {sub ⊙}), from the giants down to ∼4 mag below the main-sequence turnoff, and extends in radius to 30′ (7.4 pc at a distance of 850 pc, or ∼7 core radii). This paper focuses primarily on the main-sequence binaries, but orbital solutions are also presented for red giants, yellow giants, and sub-subgiants. Out to our period detection limit and within our magnitude and spatial domain, we find a global main-sequence incompleteness-corrected binary fraction of 34% ± 3%, which rises to 70% ± 17% in the cluster center. We derive a tidal circularization period of P{sub circ}=11.0{sub −1.0}{sup +1.1} days. We also analyze the incompleteness-corrected distributions of binary orbital elements and masses. The period distribution rises toward longer periods. The eccentricity distribution, beyond P {sub circ}, is consistent with a uniform distribution. The mass-ratio distribution is also consistent with a uniform distribution. Overall, these M67 binaries are closely consistent with similar binaries in the galactic field, as well as with the old (7 Gyr) open cluster NGC 188. WOCS. 83.

47 OTHER INSTRUMENTATION↗

Efficient Detection of Emission-line Galaxies in the Cl0016+1609 and MACSJ1621.4+3810 Supercluster Filaments Using SITELLE

We observe a system of filaments and clusters around Cl0016+1609 and MACSJ1621.4+3810 using the SITELLE Fourier transform spectrograph at the Canada–France–Hawaii Telescope. For Cl0016+1609 (z = 0.546), the observations span an 11.8 Mpc × 4.3 Mpc region along an eastern filament that covers the main cluster core, as well as two 4.3 Mpc × 4.3 Mpc regions that each cover southern subclumps. For MACSJ1621.4+3810 (z = 0.465), 3.9 Mpc × 3.9 Mpc around the main cluster core is covered. We present the frequency and location of the emission-line galaxies and their emission-line images, and calculate the star formation rates, specific star formation rates, and merger statistics. In Cl0016+1609, we find 13 [O ii] 3727 Å emitting galaxies with star formation rates between 0.2 and 14.0 M {sub ⊙} yr{sup −1}. Of these, 91{sub −10}{sup +3}% are found in regions with moderate local galaxy density, avoiding the dense cluster cores. These galaxies follow the main filament of the superstructure and are mostly blue and disky, with several showing close companions and merging morphologies. In MACSJ1621.4+3810, we find 10 emission-line sources. All are blue (100{sub −15}{sup +0}%), with 40{sub −12}{sup +16}% classified as disky and 60{sub −16}{sup +12}% as merging systems. Eight avoid the cluster core (80{sub −17}{sup +7}%), but two (20{sub −7}{sup +17}%) are found near high-density regions, including the brightest cluster galaxy (BCG). These observations push the spectroscopic study of galaxies in filaments beyond z ∼ 0.3 to z ∼ 0.5. Their efficient confirmation is paramount to their usefulness as more galaxy surveys come online.

47 OTHER INSTRUMENTATION↗

High-resolution Near-infrared Spectroscopy of Diffuse Sources around MWC 1080

To reveal the origins of diffuse Hα emissions observed around the Herbig star MWC 1080, we have performed a high-resolution near-infrared (NIR) spectroscopic observation using the Immersion Grating Infrared Spectrograph. In the NIR H and K bands, we detected various emission lines (six hydrogen Brackett lines, seven H{sub 2} lines, and an [Fe ii] line) and compared their spatial locations with the optical (Hα and [S ii]) and radio ({sup 13}CO and CS) line maps. The shock-induced H{sub 2} and [Fe ii] lines indicate the presence of multiple outflows, consisting of at least three associated young stars in this region. The kinematics of H{sub 2} and [Fe ii] near the northeast (NE) cavity edge supports the idea that the NE main outflow from MWC 1080A is the blueshifted one with a low inclination angle. The H{sub 2} and [Fe ii] lines near the southeast molecular region newly reveal that additional highly blueshifted outflows originate from other young stars. The fluorescent H{sub 2} lines were found to trace photodissociation regions formed on the cylindrical surfaces of the main outflow cavity, which are expanding outward with a velocity of about 10–15 km s{sup −1}. For the Hα emission, we identify its components associated with two stellar outflows and two young stars in addition to the dominant component of MWC 1080A scattered by dust. We also report a few faint Hα features located ∼0.4 pc away in the southwest direction from MWC 1080A, which lie near the axes of the NE main outflow and one of the newly identified outflows.

74 ATOMIC AND MOLECULAR PHYSICS↗

The Backup Program of the Dark Energy Spectroscopic Instrument’s Milky Way Survey

The Milky Way Backup Program (MWBP), a survey currently underway with the Dark Energy Spectroscopic Instrument (DESI) on the Nicholas U. Mayall 4 m Telescope, works at the margins of the DESI Main surveys to obtain spectra of millions of additional stars from the Gaia catalog. Efficiently utilizing times between ∼12° and 18° twilight and poor weather conditions, the MWBP extends the range of stellar sources studied to both brighter magnitudes and lower Galactic latitude and declination than the stars studied in DESI’s Main Milky Way Survey. While the MWBP prioritizes candidate giant stars selected from the Gaia catalog (using color and parallax criteria), it also includes an unbiased sample of bright stars (i.e., 11.2 ≲ G < 16 mag) as well as fainter sources (to G ≲ 19 mag). As of 2025 March 1, the survey had obtained spectra of ∼7 million stars, approximately 1.2 million of which are included in the DESI Data Release 1. The DESI spectra cover the wavelength range from 3600 to 9800 Å at a resolution λ/Δλ varying from 2000 to 5000. The full survey, when completed, will cover an area of more than 21,000 deg 2 and include approximately 10 million Gaia sources, roughly equal to the number of stellar spectra obtained through the DESI Main Survey, while only utilizing ≈9% of all DESI observing time. This paper provides an overview of the MWBP, describing the target selection, observing strategy, and an introduction to the resulting data.

79 ASTRONOMY AND ASTROPHYSICS↗

The X-shaped Radio Galaxy J0725+5835 is Associated with an AGN Pair

X-shaped radio galaxies (XRGs) are those that exhibit two pairs of unaligned radio lobes (main radio lobes and wings). One of the promising models for the peculiar morphology is jet reorientation. To clarify this, we conducted a 5 GHz observation with the European VLBI Network (EVN) of XRG J0725+5835, which resembles the archetypal binary active galactic nuclei (AGNs) 0402+379 in radio morphology, but it is larger in angular size. In our observation, two milliarcsecond-scale radio components with nonthermal radio emission are detected. Each of them coincides with an optical counterpart with similar photometric redshift and (optical and infrared) magnitude, corresponding to dual active nuclei. Furthermore, with the improved Very Large Array (VLA) images, we find a bridge between the two radio cores and a jet bending in the region surrounding the companion galaxy. This further supports the interplay between the main and companion galaxies. In addition, we also report the discovery of an arcsecond-scale jet in the companion. Given the projected separation of ~100 kpc between the main and companion galaxies, XRG J0725+5835 is likely associated with a dual jetted-AGN system. In both EVN and VLA observations, we find signatures that the jet is changing its direction, which is likely responsible for the X-shaped morphology. For the origin of jet reorientation, several scenarios are discussed.

79 ASTRONOMY AND ASTROPHYSICS↗

Overview of the DESI Milky Way Survey

Abstract We describe the Milky Way Survey (MWS) that will be undertaken with the Dark Energy Spectroscopic Instrument (DESI) on the Mayall 4 m telescope at the Kitt Peak National Observatory. Over the next 5 yr DESI MWS will observe approximately seven million stars at Galactic latitudes ∣ b ∣ > 20°, with an inclusive target selection scheme focused on the thick disk and stellar halo. MWS will also include several high-completeness samples of rare stellar types, including white dwarfs, low-mass stars within 100 pc of the Sun, and horizontal branch stars. We summarize the potential of DESI to advance understanding of the Galactic structure and stellar evolution. We introduce the final definitions of the main MWS target classes and estimate the number of stars in each class that will be observed. We describe our pipelines for deriving radial velocities, atmospheric parameters, and chemical abundances. We use ≃500,000 spectra of unique stellar targets from the DESI Survey Validation program (SV) to demonstrate that our pipelines can measure radial velocities to ≃1 km s −1 and [Fe/H] accurate to ≃0.2 dex for typical stars in our main sample. We find the stellar parameter distributions from ≈100 deg 2 of SV observations with ≳90% completeness on our main sample are in good agreement with expectations from mock catalogs and previous surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

Target Selection and Validation of DESI Quasars

The Dark Energy Spectroscopic Instrument (DESI) survey will measure large-scale structures using quasars as direct tracers of dark matter in the redshift range 0.9 < z < 2.1 and using Lyα forests in quasar spectra at z > 2.1. We present several methods to select candidate quasars for DESI, using input photometric imaging in three optical bands (g, r, z) from the DESI Legacy Imaging Surveys and two infrared bands (W1, W2) from the Wide-field Infrared Survey Explorer. These methods were extensively tested during the Survey Validation of DESI. In this paper, we report on the results obtained with the different methods and present the selection we optimized for the DESI main survey. The final quasar target selection is based on a random forest algorithm and selects quasars in the magnitude range of 16.5 < r < 23. Visual selection of ultra-deep observations indicates that the main selection consists of 71% quasars, 16% galaxies, 6% stars, and 7% inconclusive spectra. Using the spectra based on this selection, we build an automated quasar catalog that achieves a fraction of true QSOs higher than 99% for a nominal effective exposure time of ~1000 s. With a 310 deg -2 target density, the main selection allows DESI to select more than 200 deg -2 quasars (including 60 deg -2 quasars with z > 2.1), exceeding the project requirements by 20%. The redshift distribution of the selected quasars is in excellent agreement with quasar luminosity function predictions.

79 ASTRONOMY AND ASTROPHYSICS↗

Three-dimensional Simulations of Massive Stars. II. Age Dependence

We present 3D full star simulations, reaching up to 90% of the total stellar radius, for three 7 M⊙ stars of different ages: zero-age main sequence (ZAMS), mid–main sequence (midMS), and terminal-age main sequence (TAMS). A comparison with several theoretical prescriptions shows that the generation spectra for all three ages are dominated by convective plumes. Two distinct overshooting layers are observed, with most plumes stopped within the layer situated directly above the convective boundary; overshooting to the second, deeper layer becomes progressively more infrequent with increasing stellar age. Internal gravity wave (IGW) propagation is significantly impacted in the midMS and TAMS models as a result of some IGWs getting trapped within their Brunt–Väisälä frequency spikes. A fundamental change in the wave structure across radius is also observed, driven by the effect of density stratification on IGW propagation causing waves to become evanescent within the radiative zone, with older stars being affected more strongly. We find that the steepness of the frequency spectrum at the surface increases from ZAMS to the older models, with older stars also showing more modes in their spectra.

79 ASTRONOMY AND ASTROPHYSICS↗

PROVABGS: The Probabilistic Stellar Mass Function of the BGS One-percent Survey

We present the probabilistic stellar mass function (pSMF) of galaxies in the DESI Bright Galaxy Survey (BGS), observed during the One-percent Survey. The One-percent Survey was one of DESI's survey validation programs conducted from 2021 April to May, before the start of the main survey. It used the same target selection and similar observing strategy as the main survey and successfully observed the spectra and redshifts of 143,017 galaxies in the r < 19.5 magnitude-limited BGS Bright sample and 95,499 galaxies in the fainter surface-brightness- and color-selected BGS Faint sample over z < 0.6. We derive pSMFs from posteriors of stellar mass, M*, inferred from DESI photometry and spectroscopy using the Hahn et al. PRObabilistic Value-Added BGS (PROVABGS) Bayesian spectral energy distribution modeling framework. We use a hierarchical population inference framework that statistically and rigorously propagates the M* uncertainties. Furthermore, we include correction weights that account for the selection effects and incompleteness of the BGS observations. We present the redshift evolution of the pSMF in BGS, as well as the pSMFs of star-forming and quiescent galaxies classified using average specific star formation rates from PROVABGS. Overall, the pSMFs show good agreement with previous stellar mass function measurements in the literature. Our pSMFs showcase the potential and statistical power of BGS, which in its main survey will observe >100 × more galaxies. Moreover, we present the statistical framework for subsequent population statistics measurements using BGS, which will characterize the global galaxy population and scaling relations at low redshifts with unprecedented precision.

79 ASTRONOMY AND ASTROPHYSICS↗

Collapsar Black Holes Are Likely Born Slowly Spinning

Collapsing stars constitute the main black hole (BH) formation channel, and are occasionally associated with the launch of relativistic jets that power γ-ray bursts (GRBs). Thus, collapsars offer an opportunity to infer the natal (before spin-up/down by accretion) BH spin directly from observations. We show that once the BH saturates with a large-scale magnetic flux, the jet power is dictated by the BH spin and mass accretion rate. Core-collapse simulations by Halevi et al. and GRB observations favor stellar density profiles that yield an accretion rate of $\dot m\approx 10^{-2} M_{\odot}s^{-1}$, weakly dependent on time. This leaves the spin as the main factor that governs the jet power. By comparing the jet power to characteristic GRB luminosities, we find that the majority of BHs associated with jets are likely born slowly spinning with a dimensionless spin of a ≃ 0.2, or a ≃ 0.5 for wobbling jets, with the main uncertainty originating in the unknown γ-ray radiative efficiency. This result could be applied to the entire core-collapse BH population, unless an anticorrelation between the stellar magnetic field and angular momentum is present. In a companion paper, Jacquemin-Ide et al., we show that regardless of the natal spin, the extraction of BH rotational energy leads to spin-down to a ≲ 0.2, consistent with gravitational-wave observations. We verify our results by performing the first 3D general-relativistic magnetohydrodynamic simulations of collapsar jets with characteristic GRB energies, powered by slowly spinning BHs. We find that jets of typical GRB power struggle to escape from the star, providing the first numerical indication that many jets fail to generate a GRB.

79 ASTRONOMY AND ASTROPHYSICS↗

Annual cycle of aerosol properties over the central Arctic during MOSAiC 2019–2020 – light-extinction, CCN, and INP levels from the boundary layer to the tropopause

Abstract. The MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) expedition was the largest Arctic field campaign ever conducted. MOSAiC offered the unique opportunity to monitor and characterize aerosols and clouds with high vertical resolution up to 30 km height at latitudes from 80 to 90∘ N over an entire year (October 2019 to September 2020). Without a clear knowledge of the complex aerosol layering, vertical structures, and dominant aerosol types and their impact on cloud formation, a full understanding of the meteorological processes in the Arctic, and thus advanced climate change research, is impossible. Widespread ground-based in situ observations in the Arctic are insufficient to provide these required aerosol and cloud data. In this article, a summary of our MOSAiC observations of tropospheric aerosol profiles with a state-of-the-art multiwavelength polarization Raman lidar aboard the icebreaker Polarstern is presented. Particle optical properties, i.e., light-extinction profiles and aerosol optical thickness (AOT), and estimates of cloud-relevant aerosol properties such as the number concentration of cloud condensation nuclei (CCN) and ice-nucleating particles (INPs) are discussed, separately for the lowest part of the troposphere (atmospheric boundary layer, ABL), within the lower free troposphere (around 2000 m height), and at the cirrus level close to the tropopause. In situ observations of the particle number concentration and INPs aboard Polarstern are included in the study. A strong decrease in the aerosol amount with height in winter and moderate vertical variations in summer were observed in terms of the particle extinction coefficient. The 532 nm light-extinction values dropped from >50 Mm−1 close to the surface to <5 Mm−1 at 4–6 km height in the winter months. Lofted, aged wildfire smoke layers caused a re-increase in the aerosol concentration towards the tropopause. In summer (June to August 2020), much lower particle extinction coefficients, frequently as low as 1–5 Mm−1, were observed in the ABL. Aerosol removal, controlled by in-cloud and below-cloud scavenging processes (widely suppressed in winter and very efficient in summer) in the lowermost 1–2 km of the atmosphere, seems to be the main reason for the strong differences between winter and summer aerosol conditions. A complete annual cycle of the AOT in the central Arctic could be measured. This is a valuable addition to the summertime observations with the sun photometers of the Arctic Aerosol Robotic Network (AERONET). In line with the pronounced annual cycle in the aerosol optical properties, typical CCN number concentrations (0.2 % supersaturation level) ranged from 50–500 cm−3 in winter to 10–100 cm−3 in summer in the ABL. In the lower free troposphere (at 2000 m), however, the CCN level was roughly constant throughout the year, with values mostly from 30 to 100 cm−3. A strong contrast between winter and summer was also given in terms of ABL INPs which control ice production in low-level clouds. While soil dust (from surrounding continents) is probably the main INP type during the autumn, winter, and spring months, local sea spray aerosol (with a biogenic aerosol component) seems to dominate the ice nucleation in the ABL during the summer months (June–August). The strong winter vs. summer contrast in the INP number concentration by roughly 2–3 orders of magnitude in the lower troposphere is, however, mainly caused by the strong cloud temperature contrast. A unique event of the MOSAiC expedition was the occurrence of a long-lasting wildfire smoke layer in the upper troposphere and lower stratosphere. Our observations suggest that the smoke particles frequently triggered cirrus formation close to the tropopause from October 2019 to May 2020.

54 ENVIRONMENTAL SCIENCES↗

HarDWR - Harmonized Water Rights Records

A dataset within the Harmonized Database of Western U.S. Water Rights (HarDWR). For a detailed description of the database, please see the meta-record v2.0. Changelog v2.0 - Recalculated based on data sourced from WestDAAT - Changed using a Site ID column to identify unique records to using aa combination of Site ID and Allocation ID - Removed the Water Management Area (WMA) column from the harmonized records. The replacement is a separate file which stores the relationship between allocations and WMAs. This allows for allocations to contribute to water right amounts to multiple WMAs during the subsequent cumulative process. - Added a column describing a water rights legal status - Added "Unspecified" was a water source category - Added an acre-foot (AF) column - Added a column for the classification of the right's owner v1.02 - Added a .RData file to the dataset as a convenience for anyone exploring our code. This is an internal file, and the one referenced in analysis scripts as the data objects are already in R data objects. v1.01 - Updated the names of each file with an ID number less than 3 digits to include leading 0s v1.0 - Initial public release Description Here we present an updated database of Western U.S. water right records. This database provides consistent unique identifiers for each water right record, and a consistent categorization scheme that puts each water right record into one of seven broad use categories. These data were instrumental in conducting a study of the multi-sector dynamics of inter-sectoral water allocation changes though water markets (Grogan et al., *in review*). Specifically, the data were formatted for use as input to a process-based hydrologic model, Water Balance Model (WBM), with a water rights module (Grogan et al., *in review*). While this specific study motivated the development of the database presented here, water management in the U.S. West is a rich area of study (e.g., Anderson and Woosly, 2005; Tidwell, 2014; Null and Prudencio, 2016; Carney et al., 2021) so releasing this database publicly with documentation and usage notes will enable other researchers to do further work on water management in the U.S. West. We produced the water rights database presented here in four main steps: (1) data collection, (2) data quality control, (3) data harmonization, and (4) generation of cumulative water rights curves. Each of steps (1)-(3) had to be completed in order to produce (4), the final product that was used in the modeling exercise in Grogan et al. (*in review*). All data in each step is associated with a spatial unit called a Water Management Area (WMA), which is the unit of water right administration utilized by the state in which the right came from. Steps (2) and (3) required use to make assumptions and interpretation, and to remove records from the raw data collection. We describe each of these assumptions and interpretations below so that other researchers can choose to implement alternative assumptions an interpretation as fits their research aims. Motivation for Changing Data Sources The most significant change has been a switch from collecting the raw water rights directly from each state to using the water rights records presented in WestDAAT, a product of the Water Data Exchange (WaDE) Program under the Western States Water Council (WSWC). One of the main reasons for this is that each state of interest is a member of the WSWC, meaning that WaDE is partially funded by these states, as well as many universities. As WestDAAT is also a database with consistent categorization, it has allowed us to spend less time on data collection and quality control and more time on answering research questions. This has included records from water right sources we had previously not known about when creating v1.0 of this database. The only major downside to utilizing the WestDAAT records as our raw data is that further updates are tied to when WestDAAT is updated, as some states update their public water right records daily. However, as our focus is on cumulative water amounts at the regional scale, it is unlikely most records updates would have a significant effect on our results. The structure of WestDAAT led to several important changes to how HarWR is formatted. The most significant change is that WaDE has calculated a field known as `SiteUUID`, which is a unique identifier for the Point of Diversion (POD), or where the water is drawn from. This separate from `AllocationNativeID`, which is the identifier for the allocation of water, or the amount of water associated with the water right. It should be noted that it is possible for a single site to have multiple allocations associated with it and for an allocation to be able to be extracted from multiple sites. The site-allocation structure has allowed us to adapt a more consistent, and hopefully more realistic, approach in organizing the water right records than we had with HarDWR v1.0. This was incredibly helpful as the raw data from many states had multiple water uses within a single field within a single row of their raw data, and it was not always clear if the first water use was the most important, or simply first alphabetically. WestDAAT has already addressed this data quality issue. Furthermore, with v1.0, when there were multiple records with the same water right ID, we selected the largest volume or flow amount and disregarded the rest. As WestDAAT was already a common structure for disparate data formats, we were better able to identify sites with multiple allocations and, perhaps more importantly, allocations with multiple sites. This is particularly helpful when an allocation has sites which cross WMA boundaries, instead of just assigning the full water amount to a single WMA we are now able to divide the amount of water between the number of relevant WMAs. As it is now possible to identify allocations with water used in multiple WMAs, it is no longer practical to store this information within a single column. Instead the stAllocationToWMATab.csv file was created, which is an allocation by WMA matrix containing the percent Place of Use area overlap with each WMA. We then use this percentage to divide the allocation's flow amount between the given WMAs during the cumulation process to hopefully provide more realistic totals of water use in each area. However, not every state provides areas of water use, so like HarDWR v1.0, a hierarchical decision tree was used to assign each allocation to a WMA. First, if a WMA could be identified based on the allocation ID, then that WMA was used; typically, when available, this applied to the entire state and no further steps were needed. Second was the spatial analysis of Place of Use to WMAs. Third was a spatial analysis of the POD locations to WMAs, with the assumption that allocation's POD is within the WMA it should belong to; if an allocation still had multiple WMAs based on its POD locations, then the allocation's flow amount would be divided equally between all WMAs. The fourth, and final, process was to include water allocations which spatially fell outside of the state WMA boundaries. This could be due to several reasons, such as coordinate errors / imprecision in the POD location, imprecision in the WMA boundaries, or rights attached with features, such as a reservoir, which crosses state boundaries. To include these records, we decided for any POD which was within one kilometer of the state's edge would be assigned to the nearest WMA. Other Changes WestDAAT has Allowed In addition to a more nuanced and consistent method of assigning water right's data to WMAs, there are other benefits gained from using the WestDAAT dataset. Among those is a consistent categorization of a water right's legal status. In HarDWR v1.0, legal status was effectively ignored, which led to many valid concerns about the quality of the database related to the amounts of water the rights allowed to be claimed. The main issue was that rights with legal status' such as "application withdrawn", "non-active", or "cancelled" were included within HarDWR v1.0. These, and other water rights status' which were deemed to not be in use have been removed from this version of the database. Another major change has been the addition of the "unspecified water source category. This is water that can come from either surface water or groundwater, or the source of which is unknown. The addition of this source category brings the total number of categories to three. Due to reviewer feedback, we decided to add the acre-foot (AF) column so that the data may be more applicable to a wider audience. We added the ownerClassification column so that the data may be more applicable to a wider audience. File Descriptions The dataset is a series of various files organized by state sub-directories. In addition, each file begins with the state's name, in case the file is separate from its sub-directory for some reason. After the state name is the text which describes the contents of the file. Here is each file described in detail. Note that st is a placeholder for the state's name. stFullRecords_HarmonizedRights.csv: A file of the complete water records for each state. The column headers for each of this type of file are: state - The name of the state to which the allocations belong to. FIPS - The two digit numeric state ID code. siteID - The site location ID for POD locations. A site may have multiple allocations, which are the actual amount of water which can be drawn. In a simplified hypothetical, a farm stead may have an allocation for "irrigation" and an allocation for "domestic" water use, but the water is drawn from the same pumping equipment. It should be noted that many of the site ID appear to have been added by WaDE, and therefore may not be recognized by a given state's water rights database. allocationID - The allocation ID for the water right. For most states this is the water right ID, and what is recommended to use should a right be looked up on a given state's water rights database. The water amounts associated with these IDs tend to be finer scaled than those associated with siteID. It should be noted that some allocations may be extracted from multiple sites, particularly for larger Places of Use. ownerClassification - A classification of the types of owners for water rights. The most common is `Private` which incorporates a wide range of entities. Several classifications would be grouped into a government category, most of which are for the U.S. Federal Government. These allocations could be listed as "Federal", "United States of America", or as the names of any number of federal agencies. The last major grouping of entities is for "Native American"s. priorityDate - The date we use as the water right priority date for our modeling analysis. This is the legal priority date when it is available. However, for some rights, specifically from California and New Mexico, we used a pseudo priority date (e.g. well completion date or start of well drilling date) when a legal priority date was not available. The most questionable dates come from New Mexico, where the only date associated with certain water right records was the date the allocation was recorded in the database. As the allocation record creation tended to be within a few months of the filing of the application of the water right, from manually double checking the water rights, and our analysis focuses on aggregating water rights on the timescale of years, we determined it was acceptable to use such dates to include as many records as possible. primaryBeneficialUse - From the numerous state water use categories, WaDE categorized them into 21 categories WestDAAT. This column is the original WaDE category for the primary water use at the PoD site. allocationBeneficialUse - From the numerous state water use categories, WaDE categorized them into 21 categories for WestDAAT. This column is the original WaDE category

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