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At least 415 records · Page 23

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NASA NTRS1986

Model system for studies of microbial dynamics at exuding surfaces such as the rhizosphere

An autoclavable all-glass system for studying microbial dynamics at permeable surfaces is described. Standard hydrophobic or hydrophilic membranes (46-mm diameter) of various pore sizes were supported on a glass frit through which nutrient solutions were pumped by a peristaltic pump. The pump provided a precisely controlled flow at speeds of 0.5 to 500 ml of defined or natural cell exudates per h, which passed through the membrane into a receiving vessel. The construction allowed a choice of membranes, which could be modified. The system was tested with a bacterium, isolated from rape plant roots (Brassica napus L.), that was inoculated on a hydrophilic membrane filter and allowed to develop into a biofilm. A defined medium with a composition resembling that of natural rape root exudate was pumped through the membrane at 0.5 ml/h. Scanning electron microscopic examinations indicated that the inoculum formed microcolonies embedded in exopolymers evenly distributed over the membrane surface. The lipid composition and content of poly-beta-hydroxybutyrate in free-living and adhered cells were determined by gas chromatography. The bacterial consumption of amino acids in the exudate was also studied.

NASA Discipline Number 61-10↗

DOE OSTI2021

Laponite-Incorporated UiO-66-NH2-Polyethylene Oxide Composite Membranes for Protection against Chemical Warfare Agent Simulants

A strategy is developed to enhance the barrier protection of polyethylene oxide (PEO)-metal–organic framework (MOF) composite films against chemical warfare agent simulants. To achieve enhanced protection, an impermeable high-aspect-ratio filler in the form of Laponite RD (LRD) clay platelets was incorporated into a composite PEO film containing MOF UiO-66-NH 2 . The inclusion of the platelets aids in mitigating permeation of inert hydrocarbons (octane) and toxic chemicals (2-chloroethyl ethyl sulfide, 2-CEES) of dimensions/chemistry similar to prominent vesicant threats while still maintaining high water vapor transport rates (WVTR). By utilizing small-angle neutron scattering, small-angle X-ray scattering, and wide-angle X-ray scattering, the LRD platelet alignment of the films was determined, and the structure of the films was correlated with performance as a barrier material. Performance of the membranes against toxic chemical threats was assessed using permeation testing of octane and 2-CEES, a common simulant for the vesicant mustard gas, and breathability of the membranes was assessed using WVTR measurements. To assess their robustness, chemical exposure (in situ diffuse reflectance infrared Fourier transform spectroscopy) and mechanical (tensile strength) measurements were also performed. It was demonstrated that the barrier performance of the film upon inclusion of the LRD platelets exceeds that of other MOF-polymer composites found in the literature and that this approach establishes a new path for improving permselective materials for chemical protection applications.

36 MATERIALS SCIENCE↗

NASA NTRS2005

Advanced Water Recovery Technologies for Long Duration Space Exploration Missions

Extended-duration space travel and habitation require recovering water from wastewater generated in spacecrafts and extraterrestrial outposts since the largest consumable for human life support is water. Many wastewater treatment technologies used for terrestrial applications are adoptable to extraterrestrial situations but challenges remain as constraints of space flights and habitation impose severe limitations of these technologies. Membrane-based technologies, particularly membrane filtration, have been widely studied by NASA and NASA-funded research groups for possible applications in space wastewater treatment. The advantages of membrane filtration are apparent: it is energy-efficient and compact, needs little consumable other than replacement membranes and cleaning agents, and doesn't involve multiphase flow, which is big plus for operations under microgravity environment. However, membrane lifespan and performance are affected by the phenomena of concentration polarization and membrane fouling. This article attempts to survey current status of membrane technologies related to wastewater treatment and desalination in the context of space exploration and quantify them in terms of readiness level for space exploration. This paper also makes specific recommendations and predictions on how scientist and engineers involving designing, testing, and developing space-certified membrane-based advanced water recovery technologies can improve the likelihood of successful development of an effective regenerative human life support system for long-duration space missions.

Liu, Scan X.↗

DOE OSTI2021

Collaboration on SBIR/TTO Phase II Project for Optical QC Device and Collaboration on SBIR/TTO Phase II-b Project for Advanced Quality Inspection Device Development: Cooperative Research and Development CRADA Number CRD-16-00652 (Final Report)

The overall goal of this program is to develop and commercialize a turnkey quality control solution for the entire PEM fuel cell manufacturing process including membrane, gas diffusion layers, catalyst, and assembled systems. This quality control solution is unique to each customer’s specific needs but includes a suite of in-line quality control systems for roll-to-roll manufacturing that can target thin, transparent membrane as well as opaque membrane, catalyst, and GDLs. The Phase II developed the CPNUVV system for thin, transparent membrane that operates using polarized filters to enhance defect resolution and determine thickness. However, PEM material manufacturers want a complete, turnkey solution for all components of the PEM fuel cell. In the Phase IIB, Mainstream will partner with NREL, and transition reflectance technology NREL developed (US Patent 9,234,843) to operate in real-time on a web-line to develop a total solution to PEM quality control. The device will identify and mark defects as well as monitor materials thickness in real-time to improve line efficiency and to reduce waste. The research performed at NREL under this CRADA increases the basis of knowledge about optical inspection methods, how they perform with regards to fuel cell component materials, and how they can be implemented in in-line, real-time configurations to provide quality inspection for roll-to-roll (R2R) manufacturing. Methods explored were found to be sensitive to catalyst loading in electrodes on both membrane and gas diffusion media substrates and to membrane thickness, across a broad range of thickness. The latter capability is novel and now patented and provides a previously unstudied and undemonstrated capability for R2R manufacturing of membranes.

30 DIRECT ENERGY CONVERSION↗

NASA NTRS1984

A novel reverse-osmosis wash water recycle system for manned space stations

The preliminary development of a wash water recycle system utilizing an inside-skinned hollow-fiber membrane is described. This module configuration is based on tube-side feed and is highly resistant to fouling with a minimum of pretreatment. During an ongoing research program for NASA, these modules were operated on actual wash waters with no significant fouling for a period of 40 days. Due to the tube-side-feed flow in these hollow-fiber membranes, the fibers themselves become the pressure vessels, allowing the development of extremely lightweight membrane modules. During the NASA research program, a pre-prototype membrane module capable of processing 6 gallons per day of wash water at 97 percent recovery was developed that can be dry-stored and that weighs 120 g.

Ray, R. J.↗

NASA NTRS2013

Selection and Manufacturing of Membrane Materials for Solar Sails

Commercial metallized polyimide or polyester films and hand-assembly techniques are acceptable for small solar sail technology demonstrations, although scaling this approach to large sail areas is impractical. Opportunities now exist to use new polymeric materials specifically designed for solar sailing applications, and take advantage of integrated sail manufacturing to enable large-scale solar sail construction. This approach has, in part, been demonstrated on the JAXA IKAROS solar sail demonstrator, and NASA Langley Research Center is now developing capabilities to produce ultrathin membranes for solar sails by integrating resin synthesis with film forming and sail manufacturing processes. This paper will discuss the selection and development of polymer material systems for space, and these new processes for producing ultrathin high-performance solar sail membrane films.

Bryant, Robert G.↗

DOE OSTI2026

Hydrogen from Carbonaceous Waste Material - Hydrogen Fuel Cells Prize Phase 2 Voucher: Cooperative Research and Development (Final Report)

NLR conducted a conceptual design study for scaling up biomass conversion technology from Green Fortress Engineering (GFE). GFE has proprietary technology where cellulosic biomass is thermally converted to a tar-free syngas. A ceramic membrane separation unit (MSU) previously developed with NLR can extract high-purity hydrogen from the syngas. The energy content of the retentate stream is sufficient to power the process with a gas-powered genset. Design details including mass and energy balances, process and instrumentation diagrams (P&ID), and major equipment schedules were delivered.

08 HYDROGEN↗

NASA NTRSDate not supplied

Zero-G Experiments of the BionicWingsat - A 2U-Cubesat with Deployable, Biologically-Inspired Wings

In this paper, recent testing of a novel deployable structure with several potential applications in space will be described, with the focus on performed deployment experiments in a DLR Zero-g flight campaign and in ground tests. Through a cooperative effort of the German Aerospace Center (DLR) and the National Aeronautics and Space Administration (NASA), a biologically-inspired structurally-integrated membrane featuring distributed functional elements has been developed and integrated into the 2U CubeSat called BionicWingSat. Such a membrane structure could be useful for all sorts of applications in which a relatively flat area is desirable such as solar sails, drag sails, or solar shades. For SmallSats and CubeSats, the design proposed also has the desirable property of being self-deploying without the need for powered deployment mechanisms. Building on previous work inspired by the wings of earwigs, the research presented in this paper focuses on testing of developed design concepts for such structural systems. To do so 24 fully integrated wings on two BionicWingSats in 2U Cubesat format were experimentally deployed in a microgravity environment during a dedicated DLR Zero-g flight campaign in 2021. The results of these experiments, the built hardware and test articles, the test arrangement, as well as a comparison to ground tests are discussed in this paper.

Spacecraft structures↗

NASA NTRS2007

NASA's First Year Progress with Fuel Cell Advanced Development in Support of the Exploration Vision

NASA Glenn Research Center (GRC), in collaboration with Johnson Space Center (JSC), the Jet Propulsion Laboratory (JPL), Kennedy Space Center (KSC), and industry partners, is leading a proton-exchange-membrane fuel cell (PEMFC) advanced development effort to support the vision for Exploration. This effort encompasses the fuel cell portion of the Energy Storage Project under the Exploration Technology Development Program, and is directed at multiple power levels for both primary and regenerative fuel cell systems. The major emphasis is the replacement of active mechanical ancillary components with passive components in order to reduce mass and parasitic power requirements, and to improve system reliability. A dual approach directed at both flow-through and non flow-through PEMFC system technologies is underway. A brief overview of the overall PEMFC project and its constituent tasks will be presented, along with in-depth technical accomplishments for the past year. Future potential technology development paths will also be discussed.

Hoberecht, Mark↗

NASA NTRS2002

Simulation and Flight Control of an Aeroelastic Fixed Wing Micro Aerial Vehicle

Micro aerial vehicles have been the subject of continued interest and development over the last several years. The majority of current vehicle concepts rely on rigid fixed wings or rotors. An alternate design based on an aeroelastic membrane wing has also been developed that exhibits desired characteristics in flight test demonstrations, competition, and in prior aerodynamics studies. This paper presents a simulation model and an assessment of flight control characteristics of the vehicle. Linear state space models of the vehicle associated with typical trimmed level flight conditions and which are suitable for control system design are presented as well. The simulation is used as the basis for the design of a measurement based nonlinear dynamic inversion control system and outer loop guidance system. The vehicle/controller system is the subject of ongoing investigations of autonomous and collaborative control schemes. The results indicate that the design represents a good basis for further development of the micro aerial vehicle for autonomous and collaborative controls research.

Waszak, Martin↗

DOE OSTI2020

Zeolite Membrane Reactor for Pre-Combustion Carbon Dioxide Capture (Final Scientific/Technical Report)

Water-gas shift (WGS) reaction followed by carbon dioxide (CO 2 ) separation is a critical step in the integrated gasification combined cycle (IGCC) process for fossil-fuel-fired electrical power generation with CO 2 capture. To intensify the IGCC process hydrogen-permselective zeolite membrane reactor offers promise to replace the conventional energy-intensive fixed-bed reactors and solvent-based CO 2 capture units. The objectives of this project were to develop a bench-scale zeolite membrane reactor (total membrane area: 932 cm 2 for a 21-tube membrane bundle) for the water-gas-shift reaction of raw syngas from an oxygen-blown coal-gasifier for H 2 production with simultaneous CO 2 separation at the capability of about 2 kilograms H 2 per day (equivalent to 2 kW IGCC power plant) and to demonstrate significant progress toward achieving overall performance goal of 90% CO 2 capture rate with 95% CO 2 purity at the cost of electricity 30% less than the baseline carbon capture approaches. This report summarizes results obtained in this project on scaling up the zeolite membrane reactor by a factor of 200 in membrane area, tests of the bench-scale zeolite membrane reactor for the water-gas-shift reaction at high temperature and high-pressure, and techno-economic analysis of the integration of the zeolite membrane reactor in IGCC power plant for the electrical generation with CO 2 capture. With effective pore modification by catalytic cracking deposition of MDES (methyldiethoxysilane), fabrication of MFI-type zeolite membranes was successfully scaled-up from a lab-scale disk type to bench-scale multiple-tube bundles on low-cost alumina supports. A Co-Mo based sour shift catalyst was evaluated and used in the zeolite membrane reactors for water-gas-shift reaction. The reaction kinetic and gas-permeation equations were developed and employed in mathematic models to guide/predict experiments/performance of zeolite membrane reactors for water-gas shift reaction. Multiple-tube zeolite membrane bundles and reactors were designed, fabricated and tested for gas separation and water-gas-shift reactions with real raw syngas from a coal-fired gasifier operated at high temperature and pressure. The zeolite membrane reactors demonstrated good long-term thermal and chemical stability and constant H 2 permeance (>300 GPU) together with a Knudsen selectivity (~4.7) for H 2 over CO 2 in the field test (cumulative time >28 hours) with high-sulfur coal-derived syngas. The zeolite-membrane-reactor integrated IGCC process was designed using the performance experimentally measured by the University of Cincinnati team with a single-tube zeolite membrane reactor that offers a CO conversion >98% with more than 90% of CO 2 and H 2 captured. With the above integrative approaches, a techno-economic analysis for a cost-benefit comparison was performed to uncover features that determine the power output, capital expenditure, operating expenditure, cost of electricity and cost of CO 2 capture in a 550-MW zeolite-membrane-reactor integrated IGCC process. The integration of the zeolite membrane reactor in IGCC could provide a significant reduction of 80% and 27% in the power consumption for Selexol™ Acid Gas Removal and CO 2 compression, respectively, which lowers the total auxiliary power consumption by 12.5%. However, the low pressure required at permeate stream for maintaining the driving force of hydrogen permeation through the zeolite membrane costs a huge power in permeate compressor, compensating the power consumption reduction achieved with the membrane reactor. Thus, for coal-fired IGCC for electricity generation with 90% CO 2 captured, the integration of the membrane reactor could provide a CO conversion ~99% and a significant drop in cost-of-electricity using zeolite membrane with H 2 permeance >600 GPU and the H 2 /CO 2 selectivity over 70.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2023

Molecular dynamics study of carbon dioxide and nitrogen selectivity through poly[bis((methoxyethoxy)ethoxy)phosphazene] (MEEP) membrane

Here, a molecular dynamics simulation model was developed to comprehensively understand carbon dioxide over nitrogen (CO 2 /N 2 ) selectivity through polyphosphazene-based membrane comprising of poly[bis((methoxyethoxy)ethoxy)phosphazene] (MEEP) selective layer at the molecular level. The effects of temperature, pressure, and initial feed gas composition on the CO 2 transport on a polymer membrane were studied. The computed free energy and density profile of the permeating gas mixture exhibited that CO 2 molecules express higher interactions with the membrane than N 2 molecules, resulting in higher CO 2 /N 2 selectivity. Statistical analysis of gas molecules (CO 2 , water (H 2 O), and N 2 ) transportation suggested that hydro- and CO 2 -philic functional groups in the membrane significantly impact CO 2 permeability and CO 2 /N 2 selectivity. This study suggested that Lewis acid–base and hydrogen bonding combinations contribute to CO 2 permeation and CO 2 /N 2 selectivity. An equal CO 2 /N 2 selectivity was observed with and without water vapor in the feed gas suggesting that water does not hinder CO 2 transport through the membrane.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Chloroplast phosphatases LPPγ and LPPε1 facilitate conversion of extraplastidic phospholipids to galactolipids

Abstract Galactolipids comprise the majority of chloroplast membranes in plants, and their biosynthesis requires dephosphorylation of phosphatidic acid at the chloroplast envelope membranes. In Arabidopsis (Arabidopsis thaliana), the lipid phosphate phosphatases LPPγ, LPPε1, and LPPε2 have been previously implicated in chloroplast lipid assembly, with LPPγ being essential, as null mutants were reported to exhibit embryo lethality. Here, we show that lppγ mutants are in fact viable and that LPPγ, LPPε1, and LPPε2 do not appear to have central roles in the plastid pathway of membrane lipid biosynthesis. Redundant LPPγ and LPPε1 activity at the outer envelope membrane is important for plant development, and the respective lppγ lppε1 double mutant exhibits reduced flux through the ER pathway of galactolipid synthesis. While LPPε2 is imported and associated with interior chloroplast membranes, its role remains elusive and does not include basal nor phosphate limitation-induced biosynthesis of glycolipids. The specific physiological roles of LPPγ, LPPε1, and LPPε2 are yet to be uncovered, as does the identity of the phosphatidic acid phosphatase required for plastid galactolipid biosynthesis.

Cook, Ron (ORCID:0000000198356205)↗

DOE OSTI2025

Exergy Analysis of a Convective Heat Pump Dryer Integrated with a Membrane Energy Recovery Ventilator

To increase energy efficiency, heat pump dryers and membrane dryers have been proposed to replace conventional fossil fuel dryers. Both conventional and heat pump dryers require substantial energy for condensing and reheating, while “active” membrane systems require vacuum pumps that are insufficiently developed. Lower temperature dehumidification systems make efficient use of membrane energy recovery ventilators (MERVs) that do not need vacuum pumps, but their high heat losses and lack of vapor selectivity have prevented their use in industrial drying. In this work, we propose an insulating membrane energy recovery ventilator for moisture removal from drying exhaust air, thereby reducing sensible heat loss from the dehumidification process and reheating energy. The second law analysis of the proposed system is carried out and compared with a baseline convective heat pump dryer. Irreversibilities in each component under different ambient temperatures (5–35 °C) and relative humidity (5–95%) are identified. At an ambient temperature of 35 °C, the proposed system substantially reduces sensible heat loss (47–60%) in the dehumidification process, resulting in a large reduction in condenser load (45–50%) compared to the baseline system. The evaporator in the proposed system accounts for up to 59% less irreversibility than the baseline system. A maximum of 24.5% reduction in overall exergy input is also observed. The highest exergy efficiency of 10.2% is obtained at an ambient condition of 35 °C and 5% relative humidity, which is more than twice the efficiency of the baseline system under the same operating condition.

Balaraman, Anand (ORCID:0000000218355788)↗

NASA NTRS1992

A membrane-based subsystem for water-vapor recovery from plant-growth chambers

Bioregenerative systems--life-support systems to regenerate oxygen, food, and water--are the key to establishing man's permanent presence in space. NASA is investigating the use of plant-growth chambers (PGC's) for space missions and for bases on the moon and Mars. PGC's serve several important purposes, including the following: (1) oxygen and food production; (2) carbon-dioxide removal; and (3) water purification and reuse. The key to the successful development of PGC's is a system to recover and reuse the water vapor that is transpired by the leaves of the growing plants. In this program we propose to develop a simple, reliable, membrane-based system that allows the recovery, purification, and reuse of the transpired water vapor through control of temperature and humidity levels in the PGC. This system has characteristics that make it ideally suited to use in space: (1) minimal power requirements; (2) small volume and mass; (3) simplicity; (4) reliability; and (5) versatility. In Phase 1 we will do the following: (1) develop an accurate, predictive model of our temperature- and humidity-control system, based on parametric tests of membrane modules; and (2) use this model to design systems for selected PGC's. In Phase 2, we will seek to design, fabricate, test, and deliver a breadboard unit to NASA for testing on a PGC.

Ray, R. J.↗

DOE OSTI2026

Membrane Composition Influences Expression Yield of Plant Cytochrome P450s in E. coli Lysate-Based Cell-Free Systems

Plant cytochrome P450 enzymes are central to natural product biosynthesis, but remain difficult to express in microbial hosts due to their transmembrane nature. Lysate-based, cell-free expression systems allow supplementation with artificial membranes to support the expression and translocation of transmembrane proteins. We developed a framework to systematically test liposomal membrane compositions to enhance the plant P450 expression yield. Adjustments to common phospholipid ratios or the addition of plant galactolipids had minimal impact on expression. In contrast, blended liposomes containing Egg PC, sterol-conjugated phospholipids, and PEGylated lipids produced concentration-dependent increases in expression. Expression of an Escherichia coli mechanosensitive channel and three plant P450s improved more than 2-fold, with some P450s showing up to 14-fold enhancement. Furthermore, these findings highlight membrane composition as a key determinant of the P450 expression yield in cell-free expression systems. While P450 activity was not measured, these findings provide a framework for future workflows toward achieving functional plant transmembrane enzymes for the bioproduction of natural products.

TXTL↗

DOE OSTI2021

Development of a universal nanobody-binding Fab module for fiducial-assisted cryo-EM studies of membrane proteins

Structural studies of membrane proteins by cryogenic electron microscopy (cryo-EM) often require antibody fragments (Fabs) to facilitate particle alignments and achieve high resolution. While conformational nanobodies have been developed to lock specific states of many membrane proteins, they only add 15 kDa of mass to the complex. We developed a synthetic Fab (NabFab) that rigidly binds the conserved scaffold of nanobodies, providing a universally applicable fiducial for cryo-EM studies of protein–nanobody complexes. Additionally, we demonstrate the concept by determining two high-resolution structures of membrane proteins bound to specific nanobodies and NabFab. As the structural epitope for NabFab can be incorporated into the scaffold of virtually any nanobody, this raises the prospect of facile structure determination of many nanobody–protein complexes.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2021

Upregulation of PPPDE1 contributes to anorectal malformations via the mitochondrial apoptosis pathway during hindgut development in rats

Congenital anorectal malformations (ARMs) are among the most prominent deformities of the gastrointestinal tract; however, their precise aetiology remains obscure. Immunohistochemistry demonstrated that, in the ARM group, the PPPDE1-positive cells were widely distributed in the hindgut epithelial tissue from GD13 to GD16. Immunofluorescence revealed that most TUNEL-, Bax-, and Cytochrome C (Cyt C)-positive cells overlapped with PPPDE1-positive cells in the urorectal septum (URS). Western blotting and quantitative real-time RT-PCR revealed that PPPDE1 levels were significantly higher in the ARM group from GD13 to GD14 (p < 0.05). IEC-6 cells were transfected with PPPDE1 overexpression plasmid/NC (negative control) or si-PPPDE1/si-NC. Flow cytometry analysis and CCK-8 assay (used to detect apoptosis and proliferation, respectively), as well as western blotting, showed that the levels of PPPDE1 were positively correlated with the pro-apoptotic molecules Bax and Cyt C. Accordingly, aberrantly high expression of PPPDE1 caused a spatiotemporal imbalance in foetal rats with ARMs during hindgut development. Therefore, the upregulation of PPPDE1 may promote epithelial apoptosis and reduce proliferation in the hindgut via the mitochondrial apoptotic pathway. This could affect the fusion of the URS and cloacal membrane, ultimately inhibiting the hindgut development and resulting in ARMs.

60 APPLIED LIFE SCIENCES↗