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NASA NTRS1997

Lithological Variation with Depth and Decoupling of Maturity Parameters in Apollo 16 Regolith Core 68001/2

Using FerroMagnetic Resonance (FMR) and Instrumental Neutron Activation Analysis (INAA), we have determined the maturity (surface exposure) parameter I(sub s)/FeO and concentrations of twenty- five chemical elements on samples taken every half centimeter down the 61-cm length of the 68001/2 regolith core (double drive tube) collected at station 8 on the Apollo 16 mission to the Moon. Contrary to premission expectations, no ejecta or other influence from South Ray crater is evident in the core, although a small inflection in the I(sub s)/FeO profile at 3 cm depth may be related the South Ray crater impact. Regolith maturity generally decreases with depth, as in several previously studied cores. We recognize five compositionally distinct units in the core, which we designate A through E, although all are similar in composition to each other and to other soils from the Cayley plains at the Apollo 16 site. Unit A (0-33 cm) is mature to submature throughout (I(sub s)/FeO: 89-34 units) and is indistinguishable in composition from surface soils collected at station 8. Unit B (33-37 cm) is enriched slightly in a component of anorthositic norite composition. Unit D (42-53 cm) is compositionally equivalent to 80 wt% Unit-A soil plus 20 wt% Apollo-16-type dimict breccia consisting of subequal parts anorthosite and impact-melt breccia. Compared to Unit A, Unit E (53-61 cm) contains a small proportion (up to 4%) of some component compositionally similar to Apollo 14 sample 14321. Unit C (37-42 cm) is unusual. For lithophile and siderophile elements, it is similar to Units A and D. However, I(sub s)/FeO is low throughout the unit (less than 30 units) and in a bluish-gray zone at 41 cm depth I(sub s)/FeO drops to 1.6 units, the lowest value that we have observed in several hundred Apollo 16 soil samples. Samples from the bluish-gray zone also have low Zn concentrations, less than 10 micro g/g, compared to 20-30 micro g/g for the rest of the core. Although both values are consistent with fragmented rock material that has received virtually no surface exposure, the abundance of agglutinates in the bluish-gray soil of Unit C is moderately high, typical of a submature soil that would ordinarily have I(sub s)/FeO - 30. We believe that the anomalously low values of I(sub s)/FeO and Zn concentration result because the soil was heated to -800-1000 'C, probably during an impact. This temperature range is sufficient to volatize the surface-correlated Zn and agglomerate the nanophase metal giving rise to the FMR signal but is not great enough to sinter the soil. Alternatively, the unusual soil interval may represent a disaggregated or incipient regolith breccia, although there is no significant difference in the texture or clast-matrix relationships between Unit C and adjacent units.

Korotev, Randy L.↗
NASA NTRS1993

Composition and Maturity of Apollo 16 Regolith Core 60013/14

Samples from every half-centimeter dissection interval of double drive tube 60013/14 (sections 60013 and 60014) were analyzed by magnetic techniques for Fe concentration and surface maturity parameter I(sub s)/ Fe(O), and by neutron activation for concentrations of 25 lithophile and siderophile elements. Core 60013/14 is one of three regolith cores taken in a triangular array 40-50 m apart on the Cayley plains during Apollo 16 mission to the Moon. The core can be divided into three zones based both on I(sub s)/FeO and composition. Unit A (0-44 cm depth) is compositionally similar to other soils from the surface of the central region of the site and is mature throughout, although maturity decreases with depth. Unit B (44-59 cm) is submature and compositionally more feldspathic than Unit A. Regions of lowest maturity in Unit B are characterized by lower Sm/Sc ratios than any soil obtained from the Cayley plains as a result of some unidentified lithologic component with low surface maturity. The component is probably some type of mafic anorthosite that does not occur in such high abundance in any of the other returned soils. Unit C (59-62 cm) is more mature than Unit B and compositionally equivalent to an 87: 13 mixture of soil such as that from Unit A and plagioclase such as found in ferroan anorthosite. Similar soils, but containing greater abundances of anorthosite (plagioclase), are found at depth in the other two cores of the array. These units of immature to submature soil enriched to varying degrees (compared to the mature surface soil) in ferroan anorthosite consisting of approx. 99% plagioclase are the only compositionally distinct subsurface similarities among the three cores. Each of the cores contains other units that are compositionally dissimilar to any soil unit in the other two cores. These compositionally distinct units probably derive from local subsurface blocks deposited by the event(s) that formed the Cayley plains. The ferroan anorthosite with approx. 99% plagioclase, however, must represent some subsurface lithology that is significant on the scale of tens of meters. The compositional uniformity of the surface soil (0-10 cm depth) over distances of kilometers reflects the large-scale uniformity of the plains deposits; the fine- structure reflects small-scale nonuniformity and the inefficiency of the impact-mixing process at depths as shallow as even one meter.

Korotev, Randy T.↗
NASA NTRS1996

Lunar Meteorite Queen Alexandra Range 93069 and the Iron Concentration of the Lunar Highlands Surface

Lunar meteorite Queen Alexandra Range 93069 is a clast-rich, glassy-matrix regolith breccia of ferroan, highly aluminous bulk composition. It is similar in composition to other feldspathic lunar meteorites but differs in having higher concentrations of siderophile elements and incompatible trace elements. Based on electron microprobe analyses of the fusion crust, glassy matrix, and clasts, and instrumental neutron activation analysis of breccia fragments, QUE 93069 is dominated by nonmare components of ferroan, noritic- anorthosite bulk composition. Thin section QUE 93069,31 also contains a large, impact-melted, partially devitrified clast of magnesian, anorthositic-norite composition. The enrichment in Fe, Sc, and Cr and lower Mg/Fe ratio of lunar meteorites Yamato 791197 and Yamato 82192/3 compared to other feldspathic lunar meteorites can be attributed to a small proportion (5-10%) of low-Ti mare basalt. It is likely that the non- mare components of Yamato 82192/3 are similar to and occur in similar abundance to those of Yamato 86032, with which it is paired. There is a significant difference between the average FeO concentration of the lunar highlands surface as inferred from the feldspathic lunar meteorites (mean: approx. 5.0%; range: 4.3-6.1 %) and a recent estimate based on data from the Clementine mission (3.6%).

Korotev, Randy L.↗
NASA NTRS1999

Looking for Fossil Bacteria in Martian Materials

The rationale for looking for prokaryote fossils in Martian materials is based on our present understanding of the environmental evolution of that planet in comparison to the history of the terrestrial environments and the development and evolution of life on Earth. On Earth we have clear, albeit indirect, evidence of life in 3.8 b.y.-old rocks from Greenland and the first morphological fossils in 3.3-3.5 b.y.-old cherts from South Africa and Australia. In comparison, Mars, being smaller, probably cooled down after initial aggregation faster than the Earth. Consequently, there could have been liquid water on its surface earlier than on Earth. With a similar exogenous and endogenous input of organics and life-sustaining nutrients as is proposed for the Earth, life could have arisen on that planet, possibly slightly earlier dm it did on Earth. Whereas on Earth liquid water has remained at the surface of the planet since about 4.4 b.y. (with some possible interregnums caused by planet-sterilising impacts before 3.8. b.y. and perhaps a number of periods of a totally frozen Earth, this was not the case with Mars. Although it is not known exactly when surficial water disappeared from the surface, there would have been sufficient time for life to have developed into something similar to the terrestrial prokaryote stage. However, given the earlier environmental deterioration, it is unlikely that it evolved into the eukaryote stage and even evolution of oxygenic photosynthesis may not have been reached. Thus, the impetus of research is on single celled life simnilar to prokaryotes. We are investigating a number of methods of trace element analysis with respect to the Early Archaean microbial fossils. Preliminary neutron activation analysis of carbonaceous layers in the Early Archaean cherts from South Africa and Australia shows some partitioning of elements such as As, Sb, Cr with an especial enrichment of lanthanides in a carbonaceous-rich banded iron sediment . More significantly, preliminary TOF-SIMS investigations of organics in the cherts reveals the presence of a biomarker, which appears to be a derivative of bacterial polymer, in the carbonaceous parts of the rocks. We conclude that a combination of morphological, isotope and biogeochemical methods can be used to successfully identify signs of life in terrestrial material, and that these methods will be useful in searching for signs of life in extraterrestrial materials.

Westall, F.↗
NASA NTRS1999

Iron Meteorites from Antarctica: More Specimens, Still 40% Ungrouped

I summarize the data obtained to date on independent Antarctic iron meteorites by our UCLA neutron-activation laboratory. With about 5 exceptions, the listed values are the means of duplicate determinations. We have now analyzed 40 independent iron meteorites; I list 8 other irons that proved to be paired with meteorites. Because of the close relationship between pallasites and iron meteorites, I also list our data for two Antarctic pallasites that were studied at UCLA. Our new results confirm the previously reached conclusion about the abundance of ungrouped irons. In fact, the ungrouped fraction has increased slightly; of the 40 irons 16 are ungrouped, a fraction of 0.40. The two meteorites with pallasite structures are both small (approx. 50 g); one is ungrouped, the other a high-Ir anomalous member of the main-group pallasites (PMG).

Wasson, J. T.↗
NASA NTRS2000

Iron Meteorites from Antarctica: More Specimens, Still 40% Ungrouped

Clarke (1986) was the first to recognize that ungrouped irons are more common in Antarctica than in the regions where most irons have been collected; his conclusion was based on the first 21 irons collected in Antarctica. Wasson et al. (1989) reported compositional data for 24 Antarctic irons and reported that 8 were ungrouped; the ungrouped fraction of 0.33 was found to be about twice that (0.153) observed in irons from the remainder of the world. Wasson (1990) reported data for 7 additional Antarctic irons, and reported that 12 of 31 were ungrouped, a fraction of 0.39. In Table 1 I summarize the data obtained to date on independent Antarctic iron meteorites by our UCLA neutron-activation laboratory. With about 5 exceptions, the listed values are the means of duplicate determinations. We have now analyzed 40 independent iron meteorites; in Table 2 I list 8 other irons that proved to be paired with meteorites listed in Table 1. Because of the close relationship between pallasites and iron meteorites, in Table 3 I also list our data for two Antarctic pallasites that were studied at UCLA. Our new results confirm the previously reached conclusion about the abundance of ungrouped irons. In fact, the ungrouped fraction has increased slightly; of the 40 irons 16 are ungrouped, a fraction of 0.40. The two meteorites with pallasite structures are both small (approx. equals 50 g); one is ungrouped, the other a high-Ir anomalous member of the main-group pallasites (PMG).

Wasson, J. T.↗
NASA NTRS1999

Iron Meteorites from Antarctica: More Specimens, Still 40% Ungrouped

Clarke was the first to recognize that ungrouped irons are more common in Antarctica than in the regions where most irons have been collected; his conclusion was based on the first 21 irons collected in Antarctica. Wasson et al. reported compositional data for 24 Antarctic irons and reported that eight were ungrouped; the ungrouped fraction of 0.33 was found to be about twice that (0.153) observed in irons from the remainder of the world. Wasson reported data for seven additional Antarctic irons, and reported that 12 of 31 were ungrouped, a fraction of 0.39. I summarize the data obtained to date on independent Antarctic iron meteorites by our UCLA neutron-activation laboratory. With about five exceptions, the listed values are the means of duplicate determinations. We have now analyzed 40 independent iron meteorites; I list eight other irons that proved to be paired with meteorites listed. Because of the close relationship between pallasites and iron meteorites, I also list our data for two Antarctic pallasites that were studied at UCLA. Our new results confirm the previously reached conclusion about the abundance of ungrouped irons. In fact, the ungrouped fraction has increased slightly; of the 40 irons 16 are ungrouped, a fraction of 0.40. The two meteorites with pallasite structures are both small (= 50 g); one is ungrouped, the other a high-Ir anomalous member of the main-group pallasites (PMG).

Wasson, J. T.↗
NASA NTRS2000

Chondrules in the LEW85332 Ungrouped Carbonaceous Chondrite: Fractionation Processes in the Solar Nebula

We studied 14 chondrules separated from LEW85332, an ungrouped type-3 carbonaceous chondrite related to CR chondrites; 23 elements were determined by neutron activation and the chondrules were characterized petrographically. Oxygen isotopic compositions were determined by R. N. Clayton and T. K. Mayeda for seven chondrules. Chondrule abundance ratios tend to form one of two distinct patterns. In low FeO chondrules, refractory lithophile patterns are flat (i.e., unfractionated); siderophile abundances are high and show a small decrease with increasing volatility. Although high FeO chondrules also have flat refractory lithophile abundance patterns, siderophile abundances are highly fractionated; refractory Ir is very low and Fe is very high relative to other siderophiles. We suggest that the low FeO chondrules in LEW85332 formed early in nebular history when metal was intimately mixed with silicates in the chondrule precursors, and that the viscosity of the liquid-solid mix was too high to permit expulsion of the metal by centrifugal action; their porphyritic structures are consistent with incomplete melting, which would result in relatively high viscosities. When the high FeO chondrules formed somewhat later, much of the Fe was oxidized and the melting of precursors was more extensive, FeO and other oxidized siderophiles were retained in the silicate liquid, and metal was lost, possibly expelled from low viscosity chondrule melts. The O isotopic compositions of the chondrules form a linear array of slope 0.93 +/- 0.05 on a three-isotope diagram, parallel to the carbonaceous chondrite anhydrous minerals (CCAM) line and a CR chondrule array, but offset from the latter by -1% in (delta)O-18. Some or all of this offset may reflect incorporation of O from Antarctic water during weathering. Chondrule (Delta)O-17 values correlate positively with FeO, possibly indicating that the (Delta)O-17 of the nebular gas composition increased with time. The chemical and O isotopic data suggest a temporal sequence extending from early, low FeO to late high FeO chondrules.

Wasson, John T.↗
NASA NTRS2001

Gas-Phase Combustion Synthesis of Nonoxide Nanoparticles in Microgravity

Gas-phase combustion synthesis is a promising process for creating nanoparticles for the growing nanostructure materials industry. The challenges that must be addressed are controlling particle size, preventing hard agglomerates, maintaining purity, and, if nonoxides are synthesized, protecting the particles from oxidation and/or hydrolysis during post-processing. Sodium-halide Flame Encapsulation (SFE) is a unique methodology for producing nonoxide nanoparticles that addresses these challenges. This flame synthesis process incorporates sodium and metal-halide chemistry, resulting in nanoparticles that are encapsulated in salt during the early stages of their growth in the flame. Salt encapsulation has been shown to allow control of particle size and morphology, while serving as an effective protective coating for preserving the purity of the core particles. Metals and compounds that have been produced using this technology include Al, W, Ti, TiB2, AlN, and composites of W-Ti and Al-AlN. Oxygen content in SFE synthesized nano- AlN has been measured by neutron activation analysis to be as low as 0.54wt.%, as compared to over 5wt.% for unprotected AlN of comparable size. The overall objective of this work is to study the SFE process and nano-encapsulation so that they can be used to produce novel and superior materials. SFE experiments in microgravity allow the study of flame and particle dynamics without the influence of buoyancy forces. Spherical sodium-halide flames are produced in microgravity by ejecting the halide from a spherical porous burner into a quiescent atmosphere of sodium vapor and argon. Experiments are performed in the 2.2 sec Drop Tower at the NASA-Glenn Research Center. Numerical models of the flame and particle dynamics were developed and are compared with the experimental results.

Axelbaum, R. L.↗
NASA NTRS2001

Fractionation Trends Among IVA Iron Meteorites: Contrasts with IIIAB Trends

A neutron-activation study of 49 group-IVA irons shows much lower negative slopes on Ir-Au and Ir-As diagrams than observed in the larger magmatic group IIIAB. This difference seems to reflect the tendency of D(sub Ir), D(sub Au), and D(sub As) to increase with increasing S content. Contents of S and other volatiles are much lower in IVA irons than IIIAB irons. We show that both groups can be fit with Dx values that depend quadratically on S, with initial IVA S contents about 6X lower than those in IIIAB. The IVA scatter fields show a spread in Au or As at constant Ir that appears to reflect variations in the fraction of trapped melt between 0% and 30%. Copper shows an S-shaped trend that may reflect moderate positive and negative changes in D(sub Cu) as the magma evolved or, less likely, sampling variations in a broad band reflecting fractionation and trapping of melt. Gibeon, the largest IVA iron with a mass greater than 30 tons, shows an appreciable range in compositions consistent either with differences in the degree of magma crystallization or with differences in the content of trapped melt. A striking difference between IVA and IIIAB is observed in the Ir/Au ratios in the most Ir-rich irons in the groups; that in IVA is 40% lower than the IIIAB ratio, and lower than those in other iron-meteorite groups, The IVA Ir/Au ratio is about half the ratios in the chondrite groups. We examined three possible explanations of this anomaly: (1) the high-Ir irons contain large amounts of trapped melt: or (2) half of the IVA core (i.e., the first 50% to crystallize) is missing from the terrestrial set of IVA irons; or (3) the IVA magma formed by incomplete melting of the metal in the chondritic precursor material, with the metal that remained in the mantle having high Ir and low Au contents. Plausibility arguments favor the third possibility. The third scenario is the most plausible, but the second cannot be ruled out. We review recent evidence regarding the cooling rates in group IVA. In contrast to recent interpretations, we note several lines of evidence that indicate constant cooling rates independent of composition, as expected if all IVA meteorites were in the same core when cooling between 900 and 650 K occurred.

Wasson, J. T.↗
NASA NTRS2003

Osmium Isotope and Highly Siderophile Element Compositions of Lunar Orange and Green Glasses

The absolute and relative abundances of the highly siderophile elements (HSE) present in planetary mantles are primarily controlled by: 1) silicate-metal partitioning during core-mantle differentiation, 2) the subsequent addition of HSE to mantles via continued planetary accretion. Consequently, constraints on the absolute and relative abundances of the HSE in the lunar mantle will provide unique insights to the formation and late accretionary history of not only the Moon, but also Earth. Determining the HSE content of the lunar mantle, however, has proven difficult, because no bona fide mantle rocks have been collected from the moon. The only materials presently available for constraining mantle abundances are lunar volcanic rocks. Lunar basalts typically have very low concentrations of HSE and highly fractionated HSE patterns. Because of our extremely limited understanding of mantle melt partitioning of the HSE, even for terrestrial systems, extrapolations to mantle compositions from basaltic compositions are difficult, except possibly for the less compatible HSE Pt and Pd. Primitive, presumably less fractionated materials, such as picritic glasses are potentially more diagnostic of the lunar interior. Here we report Os isotopic composition data and Re, Os, Ir, Ru, Pt and Pd concentration data for green glass (15426,164) and orange glass (74001,1217). As with previous studies utilizing neutron activation analysis, we are examining different size fractions of the spherules to assess the role of surface condensation in the generation of the HSE abundances.

Walker, R. J.↗
NASA NTRS2003

A Central X-ray Source in the Non-thermal Radio Nebula DA 495

We report the detection, in archival ROSAT and ASCA observations, of X-ray emission from the direction of DA 495 (G65.7+1.2), a likely supernova remnant of uncertain classification but with similarities to the Crab Nebula. An unusual feature of the radio nebula is its annular morphology, with a flux minimum at the geometrical center. In the soft X-ray band, the ROSAT data resolve a compact source near the edge of the central radio hole ; the hard X-ray morphology, at the limit of ASCA's spatial resolution, is suggestive of extended plerionic emission dropping off from a central flux maximum coincident with the ROSAT source. The spectrum is well-described by a power-law with photon index approximately 1.7, and the X-ray flux is roughly constant with time. Taken together, this evidence suggests identification of the X-ray source with a magnetospherically active neutron star and its associated wind nebula. Timing analysis of the ASCA data yields only a weak upper bound on pulsations with periods longer than approximately 30 ms. These results reveal for the first time the high-energy engine that powers the synchrotron nebula, and strengthen the classification of DA 495 as a plerionic supernova remnant, one that may represent a late evolutionary stage of Crab-like nebulae.

Arzoumanian, Z.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Meteorites

The session "Meteorites" included the following reports:Description of a New Stony Meteorite Find from Bulloch County, Georgia; Meteorite Ablation Derived from Cosmic Ray Track Data Dhofar 732: A Mg-rich Orthopyroxenitic Achondrite Halogens, Carbon and Sulfur in the Tagish Lake Meteorite: Implications for Classification and Terrestrial Alteration; Electromagnetic Scrape of Meteorites and Probably Columbia Tiles; Pre-Atmospheric Sizes and Orbits of Several Chondrites; Research of Shock-Thermal History of the Enstatite Chondrites by Track, Thermoluminescence and Neutron-Activation (NAA) Methods; Radiation and Shock-thermal History of the Kaidun CR2 Chondrite Glass Inclusions; On the Problem of Search for Super-Heavy Element Traces in the Meteorites: Probability of Their Discovery by Three-Prong Tracks due to Nuclear Spontaneous Fission Trace Element Abundances in Separated Phases of Pesyanoe, Enstatite Achondrite; Evaluation of Cooling Rate Calculated by Diffusional Modification of Chemical Zoning: Different Initial Profiles for Diffusion Calculation; Mineralogical Features and REE Distribution in Ortho- and Clinopyroxenes of the HaH 317 Enstatite Chondrite Dhofar 311, 730 and 731: New Lunar Meteorites from Oman; The Deuterium Content of Individual Murchison Amino Acids; Clues to the Formation of PV1, an Enigmatic Carbon-rich Chondritic Clast from the Plainview H-Chondrite Regolith Breccia ;Numerical Simulations of the Production of Extinct Radionuclides and ProtoCAIs by Magnetic Flaring.

Source record↗
NASA NTRS1993

Pigmenting agents in Martian soils: inferences from spectral, Mossbauer, and magnetic properties of nanophase and other iron oxides in Hawaiian palagonitic soil PN-9

We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars.

Minerals/analysis↗
NASA NTRS2001

Mercury Abundances and Isotopic Compositions in the Murchison (CM) and Allende (CV)Carbonaceous Chondrites

The abundance and isotopic composition of Hg was determined in bulk samples of both the Murchison (CM) and Allende (CV) carbonaceous chondrites using single- and multi-collector inductively coupled plasma mass spectrometry (ICP-MS). The bulk abundances of Hg are 294 6 15 ng/g in Murchison and 30.0 6 1.5 ng/g in Allende. These values are within the range of previous measurements of bulk Hg abundances by neutron activation analysis (NAA). Prior studies suggested that both meteorites contain isotopically anomalous Hg, with d l 96/202Hg values for the anomalous, thermal-release components from bulk samples ranging from 2260 %o to 1440 9/00 in Murchison and from 2620 9/00 to 1540 9/00 in Allende (Jovanovic and Reed, 1976a; 1976b; Kumar and Goel, 1992). Our multi-collector ICP-MS measurements suggest that the relative abundances of all seven stable Hg isotopes in both meteorites are identical to terrestrial values within 0.2 to 0.5 9/00m. On-line thermal-release experiments were performed by coupling a programmable oven with the singlecollector ICP-MS. Powdered aliquots of each meteorite were linearly heated from room temperature to 900 C over twenty-five minutes under an Ar atmosphere to measure the isotopic composition of Hg released fiom the meteorites as a h c t i o n of temperature. In separate experiments, the release profiles of S and Se were determined simultaneously with Hg to constrain the Hg distribution within the meteorites and to evaluate the possibility of Se interferences in previous NAA studies. The Hg-release patterns differ between Allende and Murchison. The Hg-release profile for Allende contains two distinct peaks, at 225" and 343"C, whereas the profile for Murchison has only one peak, at 344 C. No isotopically anomalous Hg was detected in the thermal-release experiments at a precision level of 5 to 30 9/00, depending on the isotope ratio. In both meteorites the Hg peak at ;340"C correlates with a peak in the S-release profile. This correlation suggests that Hg is associated with S-bearing phases and, thus, that HgS is a major Hg-bearing phase in both meteorites. The Hg peak at 225 C for Allende is similar to release patterns of physically adsorbed Hg on silicate and metal grains.

Lauretta, D. S.↗
NASA NTRS2005

Compositions of Three Lunar Meteorites: Meteorite Hills 01210, Northeast Africa 001, and Northwest Africa 3136

We report on compositions obtained by instrumental neutron activation analysis on three new lunar meteorites, MET 01210 (Meteorite Hills, Antarctica; 23 g), NEA 001 (Northeast Africa, Sudan; 262 g), and NWA 3136 (Northwest Africa, Algeria or Morocco; 95 g). As in previous similar studies, we divided our samples into many (8-9) small (approximately 30 mg) subsamples prior to analysis.

Korotev, R. L.↗
NASA NTRS2005

Method for Determination of Less Than 5 ppm Oxygen in Sodium Samples

Alkali metals used in pumped loops or heat pipes must be sufficiently free of nonmetallic impurities to ensure long heat rejection system life. Life issues are well established for alkali metal systems. Impurities can form ternary compounds between the container and working fluid, leading to corrosion. This Technical Memorandum discusses the consequences of impurities and candidate measurement techniques to determine whether impurities have been reduced to suf.ciently low levels within a single-phase liquid metal loop or a closed two-phase heat transfer system, such as a heat pipe. These techniques include the vanadium wire equilibration, neutron activation analysis, plug traps, distillation, and chemical analysis. Conceptual procedures for performing vanadium wire equilibration purity measurements on sodium contained in a heat pipe are discussed in detail.

Reid, R. S.↗
NASA NTRS2009

Sulfur Speciation in the Martian Regolith Component in Shergottite Glasses

We have shown that Gas-Rich Impact-Melt (GRIM) glasses in Shergotty, Zagami, and EET79001 (Lith A and Lith B) contain Martian regolith components that were molten during impact and quenched into glasses in voids of host rock materials based on neutron-capture isotopes, i.e., Sm-150 excesses and Sm-149 deficits in Sm, and Kr-80 excesses produced from Br [1, 2]. These GRIM glasses are rich in S-bearing secondary minerals [3.4]. Evidence for the occurrence of CaSO4 and S-rich aluminosilicates in these glasses is provided by CaO-SO3 and Al2O3-SO3 correlations, which are consistent with the finding of gypsum laths protruding from the molten glass in EET79001 (Lith A) [5]. However, in the case of GRIM glasses from EET79001 (Lith B), Shergotty and Zagami, we find a different set of secondary minerals that show a FeO-SO3 correlation (but no MgOSO3 correlation), instead of CaO-SO3 and Al2O3-SO3 correlations observed in Lith A. These results might indicate different fluidrock interactions near the shergottite source region on Mars. The speciation of sulfur in these salt assemblages was earlier studied by us using XANES techniques [6], where we found that Lith B predominantly contains Fe-sulfide globules (with some sulfate). On the other hand, Lith A showed predominantly Casulfite/ sulfate with some FeS. Furthermore, we found Fe to be present as Fe2+ indicating little oxidation, if any, in these glasses. To examine the sulfide-sulfate association in these glasses, we studied their Fe/Ni ratios with a view to find diagnostic clues for the source fluid. The Fe-sulfide mineral (Fe(0.93)Ni(0.3)S) in EET79001, Lith A is pyrrhotite [7, 8]. It yields an Fe/Ni ratio of 31. In Shergotty, pyrrhotite occurs with a molar ratio of Fe:S of 0.94 and a Ni abundance of 0.12% yielding a Fe/Ni ratio of approx.500 [8]. In this study, we determined a NiO content of approx.0.1% and FeO/NiO ratio of approx.420 in S-rich globules in #507 (EET79001, Lith B) sample using FE-SEM. In the same sample (bulk), using EMPA, we determined a FeO/NiO ratio of approx.700 (raster mode). Using similar techniques, we determined a NiO content of approx.0.015% and a FeO/NiO ratio of approx.800 in #506 (EET79001, Lith A). Moreover, a NiO content of approx.150 ppm and 6.1% FeO were found in Lith A GRIM glasses using neutron activation analysis [9] yielding a FeO/NiO ratio of approx.420. The FeO/NiO ratios in secondary mineral phases in S-rich pockets of EET79001 (Lith A/B) and Shergotty are high (approx.400) compared to the FeO/NiO ratio of 31 in Lith A pyrrhotite. These results suggest similar kind of fluids interacted with different rock materials to yield the observed variations in GRIM glasses in EET79001 Lith A and B.

Rao, M. N.↗