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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1960

Pressure Transients for Boron-Potassium Nitrate Igniters in Inert, Vented Chambers

Equations which will describe the pressure-time curves for the ignition of cylindrical, boron-potassium nitrate, igniter pellets in vented, inert chambers are derived on the assumption that the burning rate is independent of pressure. This assumption is justified on the basis of closed chamber experiments. Experimental firings were conducted over a considerable range of igniter weights and nozzle throat sizes. Smooth, reproducible pressure- time histories were obtained which showed excellent agreement with the analytically predicted curves.

Scheier, W.↗
NASA NTRS2016

The Potassium-Argon Laser Experiment (KArLE): In Situ Geochronology for Planetary Robotic Missions

The Potassium (K) - Argon (Ar) Laser Experiment (KArLE) will make in situ noble-gas geochronology measurements aboard planetary robotic landers and roverss. Laser-Induced Breakdown Spectroscopy (LIBS) is used to measure the K abun-dance in a sample and to release its noble gases; the evolved Ar is measured by mass spectrometry (MS); and rela-tive K content is related to absolute Ar abundance by sample mass, determined by optical measurement of the ablated volume. KArLE measures a whole-rock K-Ar age to 10% or better for rocks 2 Ga or older, sufficient to resolve the absolute age of many planetary samples. The LIBS-MS approach is attractive because the analytical components have been flight proven, do not require further technical development, and provide complementary measurements as well as in situ geochronology.

KArLE↗
NASA NTRS2016

Continued Development of in Situ Geochronology for Planetary Using KArLE (Potassium-Argon Laser Experiment)

Geochronology is a fundamental measurement for planetary samples, providing the ability to establish an absolute chronology for geological events, including crystallization history, magmatic evolution, and alteration events, and providing global and solar system context for such events. The capability for in situ geochronology will open up the ability for geochronology to be accomplished as part of lander or rover complement, on multiple samples rather than just those returned. An in situ geochronology package can also complement sample return missions by identifying the most interesting rocks to cache or return to Earth. The K-Ar radiometric dating approach to in situ dating has been validated by the Curiosity rover on Mars as well as several laboratories on Earth. Several independent projects developing in situ rock dating for planetary samples, based on the K-Ar method, are giving promising results. Among them, the Potassium (K)-Argon Laser Experiment (KArLE) at MSFC is based on techniques already in use for in planetary exploration, specifically, Laser-induced Breakdown Spectroscopy (LIBS, used on the Curiosity Chemcam), mass spectroscopy (used on multiple planetary missions, including Curiosity, ExoMars, and Rosetta), and optical imaging (used on most missions).

In SITU Geochronology↗
NASA NTRS2016

Free-Space Quantum Key Distribution with a High Generation Rate Potassium Titanyl Phosphate Waveguide Photon-Pair Source

A high generation rate photon-pair source using a dual element periodically-poled potassium titanyl phosphate (PP KTP) waveguide is described. The fully integrated photon-pair source consists of a 1064-nanometer pump diode laser, fiber-coupled to a dual element waveguide within which a pair of 1064-nanometer photons are up-converted to a single 532-nanometer photon in the first stage. In the second stage, the 532-nanometer photon is down-converted to an entangled photon-pair at 800 nanometer and 1600 nanometer which are fiber-coupled at the waveguide output. The photon-pair source features a high pair generation rate, a compact power-efficient package, and continuous wave (CW) or pulsed operation. This is a significant step towards the long term goal of developing sources for high-rate Quantum Key Distribution (QKD) to enable Earth-space secure communications. Characterization and test results are presented. Details and preliminary results of a laboratory free-space QKD experiment with the B92 protocol are also presented.

photons↗
NASA NTRS2017

The Potassium-Argon Laser Experiment (KArLE): Design Concepts

The absolute ages of geologic events are fundamental information for understanding the timing and duration of surface processes on planetary bodies. Absolute ages can place a planet's history in the context of the solar system evolution. For example, "when was Mars warm and wet?" is one of the key questions of planetary science. If Mars was warm and wet until 3.7 billion years ago, for instance, it suggests that Mars was still warm and wet when life appeared on Earth. Mars history has been discussed so far based on crater chronology, but the current constraints for Martian chronology models come from the cratering history of the Moon [1]. Moreover, the lunar chronology model itself is fraught with uncertainty because our understanding of lunar chronology is constrained only in a few time periods and itself needs further investigation relating crater-counting ages to absolute ages [2]. Although sample return missions would provide highly accurate radiometric ages of returned samples, they are very expensive and technically challenging. In situ geochronology is highly valuable because they would have larger number of mission opportunities and the capability of iterative measurements for multiple rocks from multiple geologic units. The capability of flight instruments to perform in situ dating is required in the NASA Planetary Science Decadal Survey and the NASA Technology Roadmap. Beagle 2 is the only mission launched to date with the explicit aim to perform in situ potassium-argon (K-Ar) dating [3], but it did not happen because of the communication failure to the spacecraft. The first in situ K-Ar dating on Mars, using SAM and APXS measurements on the Cumberland mudstone [4], yielded an age of 4.21 +/- 0.35 Ga and validated the idea of K-Ar dating on other planets. However, the Curiosity method is not purposebuilt for dating and requires many assumptions that degrade its accuracy. To obtain more accurate and meaningful ages, multiple groups are developing dedicated in situ dating instruments [5-8].

design↗
NASA NTRS2018

Dating Igneous Rocks Using the Potassium-Argon Laser Experiment (KArLE) Instrument: A Case Study for ~380 Ma Basaltic Rocks

We report new K-Ar isochron data for two approximately 380 million-years-old basaltic rocks, using an updated version of the Potassium-Argon Laser Experiment (KArLE), which is being developed for future in situ dating of planetary materials. These basalts have K contents comparable with those of lunar KREEP basalts or igneous lithologies found by Mars rovers, whereas previous proof-of-concept studies focused primarily on more K-rich rocks. We aim to measure these analogous samples to show the advancing capability of in situ K-Ar geochronology.

Cho, Yuichiro↗
NASA NTRS2019

Chemistry and Crystallography of Diagenetic, Authigenic, and Igneous Potassium Feldspar: Implications for Sedimentary Petrology in Gale Crater, Mars

The Mars Science Laboratory Curiosity’s Chemistry and Mineralogy (CheMin) instrument performed X-ray diffraction (XRD) analysis of Gale Crater drill sample Windjana and found 21 wt.% nearly pure potassium feldspar in the disordered structural state of high-sanidine. The source of sanidine in Windjana is not clear – it could be detrital igneous, hydrothermal, or authigenic, with each possible source representing widely different implications for the sedimentary history of Gale Crater and igneous evolution of sediment sources. Here, we try to constrain the origin of the Windjana sanidine by determining unit-cell (UC) parameters and compositions of sanidines from a range of environments on Earth.

Ott, J. P.↗
NASA NTRS2018

Dating Igneous Rocks Using the Potassium–Argon Laser Experiment (KArLE) Instrument: A Case Study for ~380 Ma Basaltic Rocks

We report new K–Ar isochron data for two ~380 Ma basaltic rocks, using an updated version of the Potassium–Argon Laser Experiment (KArLE), which is being developed for future in situ dating of planetary materials. These basalts have K contents comparable with those of lunar KREEP basalts or igneous lithologies found by Mars rovers, whereas previous proof‐of‐concept studies focused primarily on more K‐rich rocks. We aim to measure these analogous samples to show the advancing capability of in situ K–Ar geochronology. Combining laser‐induced breakdown spectroscopy (LIBS), mass spectrometry (MS), and microscopic analyses, we measured the abundance of K and 40Ar from 23 spots on the basalt samples. We then constructed K–Ar isochron plots from these rocks. The breadboard instrument consists of flight‐equivalent devices including a 30‐mJ Nd:YAG laser and a quadrupole mass spectrometer. Despite much lower K abundances than in previous studies, the isochron slopes yielded 380 ± 44 Ma and 398 ± 50 Ma for 380.7‐Ma and 373.5‐Ma rocks, respectively, indicating that accuracy better than 25 Ma (<7%) is achievable with our instrument. The isochron intercepts both yielded trapped 40Ar approximately 1 × 10−6 cm3 STP/g. Our experimental results demonstrate that accurate and precise measurements are possible using the KArLE approach on basaltic rocks, which are ubiquitous on planetary surfaces, and are useful in addressing a wide range of questions in planetary science.

Yuichiro Cho↗
NASA NTRS2000

Distinct abscisic acid signaling pathways for modulation of guard cell versus mesophyll cell potassium channels revealed by expression studies in Xenopus laevis oocytes

Regulation of guard cell ion transport by abscisic acid (ABA) and in particular ABA inhibition of a guard cell inward K(+) current (I(Kin)) is well documented. However, little is known concerning ABA effects on ion transport in other plant cell types. Here we applied patch clamp techniques to mesophyll cell protoplasts of fava bean (Vicia faba cv Long Pod) plants and demonstrated ABA inhibition of an outward K(+) current (I(Kout)). When mesophyll cell protoplast mRNA (mesophyll mRNA) was expressed in Xenopus laevis oocytes, I(Kout) was generated that displayed similar properties to I(Kout) observed from direct analysis of mesophyll cell protoplasts. I(Kout) expressed by mesophyll mRNA-injected oocytes was inhibited by ABA, indicating that the ABA signal transduction pathway observed in mesophyll cells was preserved in the frog oocytes. Co-injection of oocytes with guard cell protoplast mRNA and cRNA for KAT1, an inward K(+) channel expressed in guard cells, resulted in I(Kin) that was similarly inhibited by ABA. However, oocytes co-injected with mesophyll mRNA and KAT1 cRNA produced I(Kin) that was not inhibited by ABA. These results demonstrate that the mesophyll-encoded signaling mechanism could not substitute for the guard cell pathway. These findings indicate that mesophyll cells and guard cells use distinct and different receptor types and/or signal transduction pathways in ABA regulation of K(+) channels.

NASA Discipline Plant Biology↗
DOE OSTI2023

Impact of lowering potassium contamination in liquid scintillation cocktails for ultra-sensitive radiation detection

Intrinsic 40 K radioactive backgrounds from impurities of natural K in liquid scintillation cocktails have previously been demonstrated to limit their use in ultra-sensitive applications. Here, this work explores two methodologies in parallel for the reduction of 40 K backgrounds in the cocktails, and lays the groundwork for use in ultra-sensitive applications. In one method, alternative low-K liquid scintillation matrix constituents were identified and in the other, a simple purification method for single components and finished cocktails was developed. Both methods were verified via ICP-MS analysis. Liquid scintillation counting of selected purified cocktails demonstrated background reduction, improved stability, and enhanced performance. The best performing purified cocktail was also counted on a custom-built ultra-low background liquid scintillation counter, with results below the detector background.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2023

Electrospraying deposition and characterization of potassium chloride targets for nuclear science measurements

Natural and isotopically enriched KCl targets were prepared using specially formulated KCl solutions, deposited by electrospraying on thin (1.5 μm) gold backings, followed by a short annealing in a preheated (350-450 °C) furnace. Various techniques, such as X-ray fluorescence (XRF), scanning electron microscopy (SEM) imaging, and energy-dispersive X-ray spectroscopy (EDS), were used to characterize the produced targets. A white neutron beam at the Los Alamos Neutron Science Center (LANSCE) facility was also used to verify the estimated atomic percentages of the enriched 40 KCl targets. KCl was deposited relatively uniformly as large particles rather than films on the gold surface. As a result, this method can be broadly extended to make stable targets that are difficult to produce with other methods and more exotic radioactive targets required for research in fundamental sciences and applications.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Density Measurements of Various Molten Sodium, Magnesium, Potassium, and Uranium Chloride Salt Compositions Using Neutron Imaging

With an increased interest in the use of molten salts for energy generation, obtaining thermophysical properties of salt mixtures becomes critical for the understanding of salt performance and behavior. Density is one of the significant thermophysical properties of salt systems. This work presents the density measurement of molten chloride salt mixtures using neutron imaging. This work was performed at the Oak Ridge National Laboratory High-Flux Isotope Reactor. Here, resulting densities as a function of temperature for different molten chloride salts from this work were compared with calculated values using Redlich–Kister modeling. Agreement between the calculated and measured values was within 1–10%, with the exception of the ternary UCl 3 –NaCl–KCl salt that showed a 32% discrepancy between several literature reports; however, the results did align well with another neutron radiography article. Analysis of the radiographs suggests that microbubbles in the ternary mixture might have biased the density measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Deactivation by Potassium Accumulation on a Pt/TiO 2 Bifunctional Catalyst for Biomass Catalytic Fast Pyrolysis

Biomass-derived feedstocks bring significant challenges to the longevity of the catalysts used for their conversion, and alkali metals, for example, K, in the feedstock have been widely ascribed as one of the important factors causing catalyst deactivation. To address this challenge, it is critical to understand the mechanism of catalyst deactivation caused by K accumulation to guide the improvement of catalysts and processes and the development of catalyst regeneration strategies. In this work, we report a deep understanding of the impact of K on a bifunctional Pt/TiO 2 catalyst, which is an efficient catalyst for the ex situ catalytic fast pyrolysis of biomass. We simulated the K-poisoning of Pt/TiO 2 catalysts by purposely loading different amounts of K (100-6000 ppm by weight) on the catalysts. A series of characterization approaches, including scanning transmission electron microscopy, Fourier transform infrared spectroscopy, and chemical titration, were combined with a kinetic assessment of multiple probe reactions to elucidate the mechanism of Pt/TiO 2 deactivation by K accumulation. At low K loadings (<800 ppm), K preferentially poisons the strong Lewis acid sites, leading to significantly reduced activity for acid-catalyzed alcohol dehydration. However, acetone condensation is less sensitive to the poisoning of strong Lewis acid sites. Reactions that occur on Pt sites or at the metal-support interface, including alkene hydrogenation, m-cresol hydrodeoxygenation (HDO), and CO oxidation, were not impacted. At high K loadings (>800 ppm), K starts to accumulate on the Pt-TiO 2 interfacial area, poisoning the interfacial active sites for HDO and CO oxidation reactions. We further found that the poisoning of the Pt/TiO 2 catalyst by K is reversible, and water washing can successfully remove the accumulated K and recover the activities for both alcohol dehydration and m-cresol HDO reactions.

09 BIOMASS FUELS↗
DOE OSTI2020

Distinguishing Potassium Channel Resting State Conformations in Live Cells with Environment-Sensitive Fluorescence

Ion channels are polymorphic membrane proteins whose high-resolution structures offer images of individual conformations, giving us starting points for identifying the complex and transient allosteric changes that give rise to channel physiology. Here, we report live-cell imaging of voltage-dependent structural changes of voltage-gated Kv2.1 channels using peptidyl tarantula toxins labeled with an environment-sensitive fluorophore, whose spectral shifts enable identification of voltage-dependent conformation changes in the resting voltage sensing domain (VSD) of the channel. We synthesize a new environment-sensitive, far-red fluorophore, julolidine phenoxazone (JP) azide, and conjugate it to tarantula toxin GxTX to characterize Kv2.1 VSD allostery during membrane depolarization. JP has an inherent response to the polarity of its immediate surroundings, offering site-specific structural insight into each channel conformation. Using voltage-clamp spectroscopy to collect emission spectra as a function of membrane potential, we find that they vary with toxin labeling site, the presence of Kv2 channels, and changes in membrane potential. With a high-affinity conjugate in which the fluorophore itself interacts closely with the channel, the emission shift midpoint is 50 mV more negative than the Kv2.1 gating current midpoint. This suggests that substantial conformational changes at the toxin-channel interface are associated with early gating charge transitions and these are not concerted with VSD motions at more depolarized potentials. These fluorescent probes enable study of conformational changes that can be correlated with electrophysiology, putting channel structures and models into a context of live-cell membranes and physiological states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Comparison of Single-Ion Conducting Polymer Gel Electrolytes for Sodium, Potassium, and Calcium Batteries: Influence of Polymer Chemistry, Cation Identity, Charge Density, and Solvent on Conductivity

From the standpoint of material diversification and sustainability, the development of so-called “beyond lithium-ion” battery chemistries is important for the future of energy storage. Na, K, and Ca are promising as the basis for battery chemistries in that these elements are highly abundant. Here, a series of single-ion conducting polymer electrolytes (SIPEs) for Na, K, and Ca batteries are synthesized and investigated. The two classes of metal cation neutralized SIPEs compared are crosslinked poly(ethylene glycol) dimethacrylate-x-styrene sulfonate (PEGDMA-SS) and poly(tetrahydrofuran) diacrylate-x-4-styrenesulfonyl (trifluoromethylsulfonyl)imide (PTHFDA-STFSI); three cation types, three charge densities, and four swelling states are examined. The impact on conductivity of all of these parameters is studied, and in conjunction with small angle X-ray scattering (SAXS), it is found that promoting ion dissociation and preventing the formation of dense ionic aggregates facilitates ion transport. These results indicate many of the lessons learned from the Li SIPE literature can be translated to beyond Li chemistries. At 25 °C, the best performing Na/K and Ca exchanged polymers yield active cation conductivity on the order of 10 –4 S/cm and 10 –6 S/cm, respectively, for ethylene carbonate:propylene carbonate gelled SIPEs, and 10 –5 S/cm and 10 –7 S/cm, respectively, for glyme gelled SIPEs.

X-ray scattering↗