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Ultrasonic Nondestructive Evaluation Techniques Applied to the Quantitative Characterization of Textile Composite Materials

In this Progress Report, we describe our recent developments of advanced ultrasonic nondestructive evaluation methods applied to the characterization of anisotropic materials. We present images obtained from experimental measurements of ultrasonic diffraction patterns for a thin woven composite in an immersion setup. In addition, we compare apparent signal loss measurements of the thin woven composite for phase-sensitive and phase-insensitive detection methods. All images of diffraction patterns have been included on the accompanying CD-ROM in the Adobe(Trademark) Portable Document Format (PDF). Due to the extensive amount of data, however, hardcopies of only a small representative selection of the images are included within the printed report. This Progress Report presents experimental results that support successful implementation of single element as well as one and two-dimensional ultrasonic array technologies for the inspection of textile composite structures. In our previous reports, we have addressed issues regarding beam profiles of ultrasonic pressure fields transmitted through a water reference path and transmitted through a thin woven composite sample path. Furthermore, we presented experimental results of the effect of a thin woven composite on the magnitude of an insonifying ultrasonic pressure field. In addition to the study of ultrasonic beam profiles, we consider issues relevant to the application of single-element, one-dimensional, and two-dimensional array technologies towards probing the mechanical properties of advanced engineering composites and structures. We provide comparisons between phase-sensitive and phase-insensitive detection methods for determination of textile composite structure parameters. We also compare phase-sensitive and phase-insensitive - - ---- ----- apparent signal loss measurements in an effort to study the phenomenon of phase cancellation at the face of a finite-aperture single-element receiver. Furthermore, in this Progress Report we extend our work on ultrasonic beam profile issues through investigation of the phase fronts of the pressure field. In Section H of this Progress Report we briefly describe the experimental arrangement and methods for data acquisition of the ultrasonic diffraction patterns upon transmission through a thin woven composite. Section III details the analysis of the experimental data followed by the experimental results in Section IV. Finally, a discussion of the observations and conclusions is found in Section V.

Miller, James G.↗

Star formation in grand design and flocculent spiral galaxies

An examination is conducted of the colors and neutral hydrogen contents of spiral galaxies which have been classified in the Elmegreen and Elmegreen arm morphology system. Using these data, possible differences between the star formation activity in spiral galaxies with and without classic spiral arms are delineated. At the same revised Hubble type, spiral galaxies with regular global arm patterns (the grand design spirals) are bluer than spiral galaxies lacking such patterns (the flocculent spirals) by a small, but statistically significant amount (approximately 0.05 in B-V and approximately 0.15 in U-V). The neutral hydrogen contents of the two groups are roughly similar, implying the star formation rate averaged over a Hubble time has been approximately the same in grand design and flocculent systems. The color differences can be explained either by using an initial mass function in the flocculent spiral galaxies which is deficient in massive stars by a factor of 2 compared with the grand design systems, or by a decrease of 30 percent in the ratio of recent to past star formation rates in flocculent galaxies. The possibility is discussed that systematic Hubble type misclassifications significantly affect these conclusions.

Romanishin, W.↗

Rocks, resolution, and the record at the terrestrial K/T boundary, eastern Montana and western North Dakota

Reconstructions of mass extinction events are based upon faunal patterns, reconstructed from numerical and diversity data ultimately derived from rocks. It follows that geological complexity must not be subsumed in the desire to establish patterns. This is exemplified at the Terrestrial Cretaceous-Tertiary (K/T) boundary in eastern Montana and western North Dakota, where there are represented all of the major indicators of the terrestrial K/T transition: dinosaurian and non-dinosaurian vertebrate faunas, pollen, a megaflora, iridium, and shocked quartz. It is the patterns of these indicators that shape ideas about the terrestrial K/T transition. In eastern Montana and western North Dakota, the K/T transition is represented lithostratigraphically by the Cretaceous Hell Creek Formation, and the Tertiary Tullock Formation. Both of these are the result of aggrading, meandering, fluvial systems, a fact that has important consequences for interpretations of fossils they contain. Direct consequences of the fluvial depositional environments are: facies are lenticular, interfingering, and laterally discontinuous; the occurrence of fossils in the Hell Creek and Tullock formations is facies-dependent; and the K/T sequence in eastern Montana and western North Dakota is incomplete, as indicated by repetitive erosional contacts and soil successions. The significance for faunal patterns of lenticular facies, facies-dependent preservation, and incompleteness is discussed. A project attempting to reconstruct vertebrate evolution in a reproducible manner in Hell Creek-type sediments must be based upon a reliable scale of correlations, given the lenticular nature of the deposits, and a recognition of the fact that disparate facies are not comparable in terms of either numbers of preserved vertebrates or depositional rates.

Fastovsky, D. E.↗

Microarray Data Analysis of Space Grown Arabidopsis Leaves for Genes Important in Vascular Patterning

Venation patterning in leaves is a major determinant of photosynthesis efficiency because of its dependency on vascular transport of photoassimilates, water, and minerals. Arabidopsis thaliana grown in microgravity show delayed growth and leaf maturation. Gene expression data from the roots, hypocotyl, and leaves of A. thaliana grown during spaceflight vs. ground control analyzed by Affymetrix microarray are available through NASAs GeneLab (GLDS-7). We analyzed the data for differential expression of genes in leaves resulting from the effects of spaceflight on vascular patterning. Two genes were found by preliminary analysis to be upregulated during spaceflight that may be related to vascular formation. The genes are responsible for coding an ARGOS like protein (potentially affecting cell elongation in the leaves), and an F-boxkelch-repeat protein (possibly contributing to protoxylem specification). Further analysis that will focus on raw data quality assessment and a moderated t-test may further confirm upregulation of the two genes and/or identify other gene candidates. Plants defective in these genes will then be assessed for phenotype by the mapping and quantification of leaf vascular patterning by NASAs VESsel GENeration (VESGEN) software to model specific vascular differences of plants grown in spaceflight.

Weitzeal, A. J.↗

Microarray Data Analysis of Space Grown Arabidopsis Leaves for Genes Important in Vascular Patterning

Venation patterning in leaves is a major determinant of photosynthesis efficiency because of its dependency on vascular transport of photoassimilates, water, and minerals. Arabidopsis thaliana grown in microgravity show delayed growth and leaf maturation. Gene expression data from the roots, hypocotyl, and leaves of A. thaliana grown during spaceflight vs. ground control analyzed by Affymetrix microarray are available through NASA's GeneLab (GLDS-7). We analyzed the data for differential expression of genes in leaves resulting from the effects of spaceflight on vascular patterning. Two genes were found by preliminary analysis to be upregulated during spaceflight that may be related to vascular formation. The genes are responsible for coding an ARGOS like protein (potentially affecting cell elongation in the leaves), and an F-box/kelch-repeat protein (possibly contributing to protoxylem specification). Further analysis that will focus on raw data quality assessment and a moderated t-test may further confirm upregulation of the two genes and/or identify other gene candidates. Plants defective in these genes will then be assessed for phenotype by the mapping and quantification of leaf vascular patterning by NASA's VESsel GENeration (VESGEN) software to model specific vascular differences of plants grown in spaceflight.

Weitzeal, A. J.↗

Unlocking the potential: machine learning applications in electrocatalyst design for electrochemical hydrogen energy transformation

Machine learning (ML) is rapidly emerging as a pivotal tool in the hydrogen energy industry for the creation and optimization of electrocatalysts, which enhance key electrochemical reactions like the hydrogen evolution reaction (HER), the oxygen evolution reaction (OER), the hydrogen oxidation reaction (HOR), and the oxygen reduction reaction (ORR). This comprehensive review demonstrates how cutting-edge ML techniques are being leveraged in electrocatalyst design to overcome the time-consuming limitations of traditional approaches. ML methods, using experimental data from high-throughput experiments and computational data from simulations such as density functional theory (DFT), readily identify complex correlations between electrocatalyst performance and key material descriptors. Leveraging its unparalleled speed and accuracy, ML has facilitated the discovery of novel candidates and the improvement of known products through its pattern recognition capabilities. This review aims to provide a tailored breakdown of ML applications in a format that is readily accessible to materials scientists. Hence, we comprehensively organize ML-driven research by commonly studied material types for different electrochemical reactions to illustrate how ML adeptly navigates the complex landscape of descriptors for these scenarios. We further highlight ML's critical role in the future discovery and development of electrocatalysts for hydrogen energy transformation. Potential challenges and gaps to fill within this focused domain are also discussed. As a practical guide, we hope this work will bridge the gap between communities and encourage novel paradigms in electrocatalysis research, aiming for more effective and sustainable energy solutions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Relationships between solar activity and climate change

Recurrent droughts are related to the double sunspot cycle. It is suggested that high solar activity generally increases meridional circulations and blocking patterns at high and intermediate latitudes, especially in winter. This effect is related to the sudden formation of cirrus clouds during strong geomagnetic activity that originates in the solar corpuscular emission.

Roberts, W. O.↗

The compressible vortex pair

A numerical solution for the flow field associated with a compressible pair of counter-rotating vortices is developed. The compressible, two-dimensional potential equation is solved utilizing the numerical method of Osher et al. (1985) for flow regions in which a non-zero density exists. Close to the vortex centers, vacuum 'cores' develop owing to the existence of a maximum achievable flow speed in a compressible flow field. A special treatment is required to represent these vacuum cores. Typical streamline patterns and core boundaries are obtained for upstream Mach numbers as high as 0.3, and the formation of weak shocks, predicted by Moore and Pullin (1987), is observed.

Heister, S. D.↗

Fundamental and practical limitations of FUV/EUV photon-counting image detectors

In EUV and FUV space-astronomy applications, the best contemporary detector designs are based on the use of microchannel plates due to their ability to deliver photon-counting performance with high efficiency. The major unresolved issue is the choice of position-readout system for the individual photoevents. Electrical event-readout systems are divided into two classes: the discrete wire anodes that perform coordinate digitization by wire-group selection, and the continuous centroid-position encoders for which coordinates are digitized in the associated electronics. The centroid-position encoder techniques are discussed in terms of how they overcome the four chief limitations of the discrete-wire readouts - their limited format size, their flat focal surface, their fundamental hex-channel vs squared-pixel moire pattern, and their image undersampling. With these limitations overcome, microchannel based image systems can deliver the performance demanded by the forthcoming generation of applications in space astronomy.

Lampton, M.↗

SeaWiFS technical report series. Volume 21: The heritage of SeaWiFS. A retrospective on the CZCS NIMBUS Experiment Team (NET) program

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) mission is based on the scientific heritage of the Coastal Zone Color Scanner (CZCS), a proof-of-concept instrument carried on the National Aeronautics and Space Administration (NASA) NIMBUS-7 environmental satellite for the purpose of measuring upwelling radiance from the ocean surface. The CZCS mission provided the first observations of ocean color from space, and over the mission lifetime of 1978-1986, allowed oceanographers an initial opportunity to observe the variable patterns of global biological productivity. One of the key elements of the CZCS mission was the formation of the CZCS NIMBUS Experiment Team (NET), a group of optical physicists and biological oceanographers. The CZCS NET was designated to validate the accuracy of the CZCS radiometric measurements and to connect the instrument's measurements to standard measures of oceanic biological productivity and optical seawater clarity. In the period following the cessation of CZCS observations, some of the insight and experience gained by the CZCS NET activity has dissipated as several proposed follow-on sensors failed to achieve active status. The Sea WiFS mission will be the first dedicated orbital successor to CZCS it in turn precedes observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) of the Earth Observing System (EOS). Since the CZCS NET experience is an important model for Sea WiFS and MODIS surface truth efforts, this document is intended to provide a comprehensive review of the validation of oceanographic data for the first orbital ocean color sensor mission. This document also summarizes the history of the CZCS NET activities. The references listed in the Bibliography are a listing of published scientific research which relied upon the CZCS BET algorithms, or research which was conducted on the basis of CZCS mission elements.

Acker, James G.↗

Experiment K-7-21: Effect of Microgravity on 1: Metabolic Enzymes of Type 1 and Type 2 Muscle Fibers, and on 2: Metabolic Enzymes, Neurotransmitter Amino Acids, and Neurotransmitter Associated Enzymes in Selected Regions of the Central Nervous System: The Distribution of Selected Enzymes and Amino Acids in the Hippocampal Formation - Part 2

Six key metabolic enzymes plus glutaminase and glutamate decarboxylase, as well as glutamate, aspartate and GABA, were measured in 11 regions of the hippocampal formation of synchronous, flight and tail suspension rats. Major differences were observed in the normal distribution patterns of each enzyme and amino acid, but no substantive effects of either microgravity or tail suspension on these patterns were clearly demonstrated.

Lowry, O. H.↗

The Role of Mesoscale Variability on Plankton Dynamics in the North Atlantic

The intensive field observational phase of JGOFS in the North Atlantic Ocean has shown the importance of oceanic mesoscale variability on biogeochemical cycles and on the strength of the ocean biological pump. Mesoscale physical dynamics govern the major time/space scales of bulk biological variability (biomass, production, and export). Mesoscale eddies seem to have a strong impact on the ecosystem structure and functioning, but observational evidence is rather limited. For the signature of the mesoscale features to exist in the ecosystem, the comparison of temporal scales of formation and evolution of mesoscale features and reaction of the ecosystem is a key factor. Biological patterns are driven by active changes in biological source and sink terms rather than simply by passive turbulent mixing. A first modelling assessment of the regional balances between horizontal and vertical eddy-induced nutrient supplies in the euphotic zone shows that the horizontal transport predominates over the vertical route in the subtropical gyre, whereas the reverse holds true for the other biogeochemical provinces of the North Atlantic. Presently, despite some difference in numbers, the net impact of modelled eddies yields an enhancement of the biological productivity in most provinces of the North Atlantic Ocean. Key issues remaining include variation on the mesoscale of subsurface particle and dissolved organic matter remineralization, improved knowledge of the ecological response to patterns of variability, synopticity in mesoscale surveys along with refining measures of biogeochemical time/space variability. Eventual success of assimilation of in situ and satellite data, still in its infancy in coupled physical/biogeochemical models, will be crucial to achieve JGOFS synthesis in answering which data are most informative, standing stocks or rates, and which ones are relevant. Depending on which end of the spectrum quantification of the effect of mesoscale features on production and community structure is required, complementary strategies are offered. Either one may choose to increase resolution of models up to the very fine mesoscale features scale (a few kms) for the high end, or to include a parametric representation of eddies for the low end.

Garcon, Veronique C.↗

The Role of Mesoscale Variability on Plankton Dynamics in the North Atlantic

The intensive field observational phase of JGOFS in the North Atlantic Ocean has shown the importance of oceanic mesoscale variability on biogeochemical cycles and on the strength of the ocean biological pump. Mesoscale physical dynamics govern the major time/space scales of bulk biological variability (biomass, production and export). Mesoscale eddies seem to have a strong impact on the ecosystem structure and functioning, but observational evidence is rather limited. For the signature of the mesoscale features to exist in the ecosystem, the comparison of temporal scales of formation and evolution of mesoscale features and reaction of the ecosystem is a key factor. Biological patterns are driven by active changes in biological source and sink terms rather than simply by passive turbulent mixing. A first modelling assessment of the regional balances between horizontal and vertical eddy-induced nutrient supplies in the euphotic zone shows that the horizontal transport predominates over the vertical route in the subtropical gyre, whereas the reverse holds true for the other biogeochemical provinces of the North Atlantic. Presently. despite some difference in numbers, the net impact of modelled eddies yields an enhancement of the biological productivity in most provinces of the North Atlantic Ocean. Key issues remaining include variation on the mesoscale of subsurface particle and dissolved organic matter remineralization, improved knowledge of the ecological response to patterns of variability, synopticity in mesoscale surveys along with refining measures of biogeochemical time/space variability. Eventual success of assimilation of in situ and satellite data, still in its infancy in coupled physical/biogeochemical models, will be crucial to achieve JGOFS synthesis in answering which data are most informative, standing stocks or rates, and which ones are relevant. Depending on which end of the spectrum quantification of the effect of mesoscale features on production and community structure is required, complementary strategies are offered. Either one may choose to increase resolution of models up to the very fine mesoscale features scale (a few kms) for the high end, or to include a parametric representation of eddies for the low end.

Garcon, Veronique, C.↗

Impacts of Urbanization in the Coastal Tropical City of San Juan, Puerto Rico

Urban sprawl in tropical locations is rapidly accelerating and it is more evident in islands where a large percentage of the population resides along the coasts. This paper focuses on the analysis of the impacts of land use and land cover for urbanization in the tropical coastal city of San Juan, in the Caribbean island of Puerto Rico. A mesoscale numerical model, the Regional Atmospheric Modeling System (RAMS), is used to study the impacts of land use for urbanization in the environment including specific characteristics of the urban heat island in the San Juan Metropolitan Area (SJMA), one of the most noticeable urban cores of the Caribbean. The research also makes use of the observations obtained during the airborne San Juan Atlas Mission. Surface and rawinsonde data from the mission are used to validate the atmospheric model yielding satisfactory results. Airborne high resolution remote sensing data are used to update the model's surface characteristics in order to obtain a more accurate and detailed configuration of the SJMA and perform a climate impact analysis based on land cover/land use (LCLU) changes. The impact analysis showed that the presence of the urban landscape of San Juan has an impact reflected in higher air temperatures over the area occupied by the city, with positive values of up to 2.5 C, for the simulations that have specified urban LCLU indexes in the model's bottom boundary. One interesting result of the impact analysis was the finding of a precipitation disturbance shown as a difference in total accumulated rainfall between the present urban landscape and with a potential natural vegetation, apparently induced by the presence of the urban area. Results indicate that the urban enhanced cloud formation and precipitation development occur mainly downwind of the city, including the accumulated precipitation. This spatial pattern can be explained by the presence of a larger urbanized area in the southwest sector of the city, and of the approaching northeasterly trade winds. No significant impacts were found in the sea breeze patterns of the city.

Comarazamy, Daniel E.↗

Impacts of Urbanization in the Coastal Tropical City of San Juan, Puerto Rico

Urban sprawl in tropical locations is rapidly accelerating and it is more evident in islands where a large percentage of the population resides along the coasts. This paper focuses on the analysis of the impacts of land use and land cover for urbanization in the tropical coastal city of San Juan, in the Caribbean island of Puerto Rico. A mesoscale numerical model, the Regional Atmospheric Modeling System (RAMS), is used to study the impacts of land use for urbanization in the environment including specific characteristics of the urban heat island in the San Juan Metropolitan Area (SJMA), one of the most noticeable urban cores of the Caribbean. The research also makes use of the observations obtained during the airborne San Juan Atlas Mission. Surface and raw insonde data from the mission are used to validate the atmospheric model yielding satisfactory results. Airborne high resolution remote sensing data are used to update the model's surface characteristics in order to obtain a more accurate and detailed configuration of the SJMA and perform a climate impact analysis based on land cover/land use (LCLU) changes. The impact analysis showed that the presence of the urban landscape of San Juan has an impact reflected in higher air temperatures over the area occupied by the city, with positive values of up to 2.5 degrees C, for the simulations that have specified urban LCLU indexes in the model's bottom boundary. One interesting result of the impact analysis was the finding of a precipitation disturbance shown as a difference in total accumulated rainfall between the present urban landscape and with a potential natural vegetation, apparently induced by the presence of the urban area. Results indicate that the urban-enhanced cloud formation and precipitation development occur mainly downwind of the city, including the accumulated precipitation. This spatial pattern can be explained by the presence of a larger urbanized area in the southwest sector of the city, and of the approaching northeasterly trade winds.

Comarazamy, Daniel E.↗

Interpreting Chromosome Aberration Spectra

Ionizing radiation can damage cells by breaking both strands of DNA in multiple locations, essentially cutting chromosomes into pieces. The cell has enzymatic mechanisms to repair such breaks; however, these mechanisms are imperfect and, in an exchange process, may produce a large-scale rearrangement of the genome, called a chromosome aberration. Chromosome aberrations are important in killing cells, during carcinogenesis, in characterizing repair/misrepair pathways, in retrospective radiation biodosimetry, and in a number of other ways. DNA staining techniques such as mFISH ( multicolor fluorescent in situ hybridization) provide a means for analyzing aberration spectra by examining observed final patterns. Unfortunately, an mFISH observed final pattern often does not uniquely determine the underlying exchange process. Further, resolution limitations in the painting protocol sometimes lead to apparently incomplete final patterns. We here describe an algorithm for systematically finding exchange processes consistent with any observed final pattern. This algorithm uses aberration multigraphs, a mathematical formalism that links the various aspects of aberration formation. By applying a measure to the space of consistent multigraphs, we will show how to generate model-specific distributions of aberration processes from mFISH experimental data. The approach is implemented by software freely available over the internet. As a sample application, we apply these algorithms to an aberration data set, obtaining a distribution of exchange cycle sizes, which serves to measure aberration complexity. Estimating complexity, in turn, helps indicate how damaging the aberrations are and may facilitate identification of radiation type in retrospective biodosimetry.

Levy, Dan↗

Quantifying Spatial Drought Propagation Potential in North America Using Complex Network Theory

Droughts have a dominant three-dimensional (3-D) spatiotemporal structure typically spanning hundreds of kilometers and often lasting for months to years. Here, we introduced a novel framework to explore the 3-D structure of the evolution of droughts based on network theory concepts. The proposed framework is applied to identify critical source regions responsible for large-scale drought onsets during 1901–2014 for the North American continent using the Standardized Precipitation Evaporation Index (SPEI). We built a spatial network connecting the drought onset timings for the North American continent. Using a spatially weighted network partitioning algorithm, the whole continent is then classified into regional spatial drought networks (RSN), where droughts are more likely to propagate within these regional systems. Finally, a customized network metric was applied to identify locations (source regions) where the drought onsets further propagate to other areas within the regional spatial network. Our results indicated that the West coast, Texas coastal region, and Southeastern Arkansas as major source regions through which atmospheric drought propagates to Western, South Central, and Eastern North America. The formation of drought source regions are due to presence of high pressure ridges and anomalous wind patterns. Furthermore, our results indicate that the drought propagation from these source regions may be due to inadequate moisture transport. The proposed framework can help to develop an early warning detection system for droughts and other spatially extensive extreme events such as heatwaves and floods.

Goutam Konapala↗

Tracking the Rates and Mechanisms of Canopy Damage and Recovery Following Hurricane Maria Using Multitemporal Lidar Data

Hurricane Maria, a Category 4 storm, snapped and uprooted canopy trees, removed large branches, and defoliated vegetation across Puerto Rico. The magnitude of forest damages and the rates and mechanisms of forest recovery following Maria provide important benchmarks for understanding the ecology of extreme events. We used airborne Lidar data acquired before (2017) and after Maria (2018, 2020) to quantify landscape-scale changes in forest structure along a 439-ha elevational gradient (100–800 m) in the Luquillo Experimental Forest. Damages from Maria were widespread, with 73% of the study area losing ≥ 1 m in canopy height (mean = −7.1 m). Taller forests at lower elevations suffered more damage than shorter forests above 600 m. Yet only 13.5% of the study area had canopy heights ≤ 2 m in 2018, a typical threshold for forest gaps, highlighting the importance of damaged trees and advanced regeneration on post-storm forest structure. Heterogeneous patterns of regrowth and recruitment yielded shorter and more open forests by 2020. Nearly 45% of forests experienced initial height loss > 1 m (2017–2018) followed by rapid height gain > 1 m (2018–2020), whereas 21.6% of forests with initial height losses showed little or no height gain, and 17.8% of forests exhibited no height changes larger than ± 1 m in either period. Canopy layers < 10 m tall accounted for most increases in canopy height and fractional cover between 2018 and 2020, with gains split evenly between height growth and lateral crown expansion by surviving individuals. These findings benchmark rates of gap formation, crown expansion, and canopy closure following hurricane damage and highlight the diversity of ecosystem impacts from heterogeneous spatial patterns and vertical stratification of forest regrowth following a major disturbance event.

forest structure↗