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NASA NTRS1983

Venus

The present conference concerning the study of Venus discusses stellar magnitude and albedo data for the planet, radio astronomical studies, results of the Venera 13 and 14 missions, Venus optical properties, topography, surface properties and tectonic evolution, the tectonic implications of the interior of Venus, the thermal structure, photochemistry, composition, general circulation, and electrical activity of the Venus atmosphere, and the thermal balance of the lower, middle and upper atmoshere of Venus. Also discussed are the observation and interpretation of the Venus ionosphere, its model calculation, the interaction of the solar wind with the ionosphere of Venus in light of flow field models, the origin and evolution of the Venus atmosphere, and the problem posed by rare gases in the atmosphere of Venus.

Hunten, D. M.↗

NASA NTRS1983

Albedo asymmetry of Iapetus

Observational data for Iapetus and other Saturn moons are used to show that the dark areas on Iapetus feature organic chromophores caused by UV irradiation of CH4-rich ice. The Iapetus albedo pattern, brighter at the poles and in the trailing hemisphere, is suggested to originate from ballistic impact redistribution of surface material in terms of an impact flux gradient. The orange/violet color ratios from Voyager imagery were measured as 1.46 for the leading hemisphere and 1.24 for the trailing hemisphere. The evolution of the Iapetus regolith during processes of ice evaporation, impact ablation, material transport, and chemical alteration is discussed for factors causing the albedo asymmetry. Comparisons of surface features of Titan, Oberon,, and Hyperion with those of Iapetus indicate a balance may exist between UV photochemistry and ablation on Iapetus, with the impact gradient having been determined by the tidally locked revolution of the moon. Voyager 2 data on the uranian moons are expected to offer confirmation or denial of the model.

Squyres, S. W.↗

NASA NTRS1983

Examination of wintertime latitudinal gradients in stratospheric NO2 using theory and LIMS observations

Nimbus 7 LIMS data and a photochemical model are used to show that the observed sharp latitudinal gradients in stratospheric wintertime NO2 are consistent with the conversion of NO2 to N2O5 at high latitudes. This conversion, and the sharp gradients, are brought about by the interaction between transport and photochemistry. Calculated variations show good agreement with observations.

Callis, L. B.↗

NASA NTRS1984

Aeronomy

The central theme of Aeronomy in the 1990 period will be the formulation of a coupled global view of the upper atmosphere as an integral extension of the lower regions. Photochemistry, atmospheric dynamics, the atmospheric energy, and observational requirements for the 1990's are discussed.

Hays, P.↗

NASA NTRS1983

A modeling study of SO(x)-NO(x)-hydrocarbon plumes and their transport to the background troposphere

The behavior of a complex urban plume and its transport to the background troposphere are analyzed in terms of a model including sulfur oxide, nitrogen oxide and hydrocarbon (HC) photochemistry. A reaction mechanism consisting of 73 NO(x), SO(x) and HC reactions is employed in a model taking account of plume dilution, entrainment, deposition and the development of a diurnal mixing layer from a ground-based nocturnal inversion. When simulation results are compared with field measurements of the urban plumes leaving St. Louis and Milwaukee, and a power plant within the Milwaukee plume, the predicted concentration profiles of NO(x), SO2 and O3 are found to be in close agreement with the measurement, although agreement with the rate of transformation of SO2 to SO4(2-) is less good. Simulations made for a hypothetical urban location under a range of background concentrations and initial HC concentrations show particulate sulfate concentrations to depend strongly on the HC/NO(x) ratio, indicating that the homogeneous gas-phase transformation may occur at night.

Balko, J. A.↗

NASA NTRS1983

A two-dimensional model simulation of the EL Chichon volcanic eruption cloud

Using a two-dimensional model of sulfate photochemistry, transport, and aerosol microphysics, a 2-year period following the eruptions of El Chichon have been simulated. Present calculations suggest that the residence time of the cloud in the stratosphere exceeds 2 years. The model reproduces the observed optical depth, lidar backscatter, and infrared extinction coefficients, if about 10 megatonnes of SO2 are injected. The major deficiency of the model is a somewhat too rapid transport.

Capone, L. A.↗

NASA NTRS1984

The effect of clouds on photolysis rates and ozone formation in the unpolluted troposphere

The photochemistry of the lower atmosphere is sensitive to short- and long-term meteorological effects; accurate modeling therefore requires photolysis rates for trace gases which reflect this variability. As an example, the influence of clouds on the production of tropospheric ozone has been investigated, using a modification of Luther's two-stream radiation scheme to calculate cloud-perturbed photolysis rates in a one-dimensional photochemical transport model. In the unpolluted troposphere, where stratospheric inputs of odd nitrogen appear to represent the photochemical source of O3, strong cloud reflectance increases the concentration of NO in the upper troposphere, leading to greatly enhanced rates of ozone formation. Although the rate of these processes is too slow to verify by observation, the calculation is useful in distinguishing some features of the chemistry of regions of differing mean cloudiness.

Thompson, A. M.↗

NASA NTRS1984

A one-dimensional photochemical model of the troposphere with planetary boundary-layer parameterization

A time-dependent, one-dimensional photochemical model of the troposphere is used to describe the vertical distribution of atmospheric trace constituents for summer-time conditions at midlatitudes in the Northern Hemisphere. The model incorporates a planetary boundary layer (PBL) parametrization and a detailed chemical mechanism that includes the photochemistry of important nonmethane hydrocarbon species formed during the oxidation process. One result of the parametrized PBL is that the concentrations of some trace species in the free troposphere are 20-30 percent higher than when mixing processes are described by a vertical eddy diffusion coefficient which is held constant with respect to height and time. The lifetime of the oxides of nitrogen against photochemical conversion to nitric acid during summertime conditions is on the order of six hours. This lifetime is short enough to deplete most of the NO(x) in the PBL so that other reactive nitrogen species are more abundant than NO(x) throughout the free troposphere.

Fishman, J.↗

NASA NTRS1985

The solar spectral irradiance between 150 and 200 nm

The absorption of solar photons controls the composition of the middle atmosphere. Concern about the effects of man's industrial activities on his environment has led to a number of long-term programs related to stratospheric photochemistry. An important part of these programs represents studies of the variability of the sun's solar spectral irradiance. A program to measure the solar ultraviolet flux, both within and outside the earth's atmosphere, has been in progress for a number of years. This program has the objective to develop techniques which would provide an absolute accuracy of at least 5 percent. The amount of satellite instrument degradation is determined on the basis of a comparison of data provided by these instruments with data obtained in connection with rocket flights. It was found that a significant decrease in the solar irradiance below 190 nm occurred between 1980 and 1981.

Mentall, J. E.↗

NASA NTRS1984

The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O3) over the 10-km to 65-km range and water vapor, nitrogen dioxide, and nitric acid over the 10-km to 50-km range. Latitude coverage extended from 64 deg S to 84 deg N. Several general features of the atmosphere have emerged from data analyzes thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO3 data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O3, NO2, and HNO3 are strongly affected during a stratospheric warming.

Russell, J. M., III↗

NASA NTRS1985

A new reeling technique for very long extension scanning in the stratosphere

A balloon-borne winching system has been developed for extending a very long tether with payload down into the stratosphere and recovering it, this has been flight proven by being carrried to an altitude of 40 km, lowering a 62-kg stratospheric photochemistry experiment 12 km at a descent velocity of about 6-8 m/sec and recovering it at comparable velocities. During the first flight, the data gave no evidence of dynamic instabilities due to the system or the stratospheric interactions. The future utility of this payload is discussed with attention to the design factors that bound the range of performance of this type of system.

Hazen, N. L.↗

NASA NTRS1985

Tentative identification of the 780/cm nu-4 band Q branch of chlorine nitrate in high-resolution solar absorption spectra of the stratosphere

According to models of the photochemistry of the stratosphere, chlorine nitrate (ClONO2) is an important temporary reservoir of stratospheric chlorine. At night, ClO is believed to combine in a three-body reaction with NO2 to form chlorine nitrate. During daylight, chlorine nitrate is destroyed by photolysis to form free chlorine and NO3. Infrared spectroscopy has the potential to provide a technique for conducting important quantitative measurements of stratospheric chlorine nitrate. The present paper reports a detailed study of spectra in the 780/cm region. This study has led to the tentative identification of the nu-4 band Q branch of ClONO2 as a significant contributor to the observed stratospheric absorption near 780.21 per cm.

Rinsland, C. P.↗

NASA NTRS1985

The response of ozone to solar proton events during solar cycle 21 - A theoretical interpretation

The effects associated with the solar proton events (SPE) during solar cycle 21 are examined. The only SPE documented to cause an ozone depletion below 45 km (approximately 2 mbar) was the event which occurred on Aug. 4, 1972. The ozone decreases associated with this event follow approximately the theoretically predicted behavior discussed by Heath et al. (1977) and Reagan et al. (1981). Ozone decreases during the July 13, 1982 and the Dec. 8, 1982, SPEs also follow approximately their theoretically predicted behavior between 60 and 85 km. Attention is given to the energy deposition by solar protons and electrons, photochemistry, model descriptions, model results, the solar zenith angle effect, three solar proton events during solar cycle 20, sensitivity studies, and temperature effects.

Jackman, C. H.↗

NASA NTRS1986

The D to H ratio on Titan and the planets: Implications for origin and evolution of planetary atmospheres

Measurements of deuterated methane show that Titan's atmosphere is enriched by at least several times in deuterium compared to the major planets. Potential causative factors for this enrichment are condensation to form tropospheric methane clouds, fractionation occuring over a hypothetical CH4-C2H2 ocean and between the ocean and the clathrate crust beneath, fractionation which occurred during the formation of Titan and fractionation occuring as a result of the evolution of Titan's atmosphere. The greater part of the observed fractionation is probably derived from the formation of Titan and the subsequent evolution of Titan atmosphere driven by photochemistry. The latter process is developed here for the first time. The D/H ratio in a planetary atmosphere is one readily available measure of the origin and evolution of the hydrogen bearing volatiles on the planet. Comparison between D/H ratio in the inner solar system and the outer solar system may pose important constraints on current theories.

Pinto, J. P.↗

NASA NTRS1986

Preliminary experiment requirements document for Solar and Terrestrial Atmospheres Spectrometer (STAS)

The principal scientific objective of the Solar and Terrestrial Atmospheres Spectrometer (STAS) project is the measurement of the absolute ultraviolet solar spectral irradiance with: (1) resolution of better than 15 mA, and (2) absolute irradiance uncertainty at the state of the art (less than or equal to 3%). High measurement accuracy coupled with high spectral resolution are necessary to identify the nature of the radiation, its variability, and to identify solar processes which may cause the changes. Solar radiation between 1200 and 3600 A dominates the photochemistry of the mesosphere and stratosphere. Some important minor species, such as NO, show very complex and fundamentally narrow structure in their photodestruction cross sections, especially in the region of the Schumann-Runge bands of O2. Understanding the photochemical processes in the terrestrial atmosphere requires knowledge of both the cross sections and of the solar spectrum with the highest possible resolution and accuracy.

Source record↗

NASA NTRS1985

Transport of trace species deduced from LIMS observations

One of the critical problems in the middle atmosphere at this time is understanding the interaction between atmospheric motions and photochemistry, and the way in which these two processes maintain the distributions of photochemically active species such as ozone. Recent work has shown that a great deal can be learned by considering the zonally averaged distributions and transports, i.e., working in the latitude-altitude plane. This 2-dimensional approach has been used in the past in Eulerian formation. Recent work (DUNKERTON, 1978) has shown that formulating the transport problems in terms of the residual mean circulation, which has similarity to the Lagrangian mean motion, results in a more physical picture of the way in which the transport takes place. Here, data from the Limb Infrared Monitor of the Stratosphere (LIMB) experiment are used to investigate how well the residual mean formulation works with real data, in the sense of asking how well the predicted ozone changes match those in regions of the lower stratosphere in which chemical changes may be neglected. This allows a test of the approximations that are made, and of the strengths and weaknesses of this approach to transport calculation.

Gille, J. C.↗

NASA NTRS1985

Far-infrared spectroscopy of the earth's stratosphere

This paper discusses the spectrum of the earth's stratosphere in the far-infrared, from 5 to 250/cm. Many of the trace gases that are important in stratospheric photochemistry have been measured, or are potentially measurable in the far-infrared. The spectral features of these gases are discussed with application to spacecraft measurements. In particular, the suitability of the spectrum for measurements of the HO(x) and ClO(x) families and of O3 are compared for different classes of instruments: Fourier transform spectrometers, filter radiometers, and scanning high-resolution Fabry-Perot instruments. It is found that these types of instruments have complementary capabilities that would best be used in combination in a comprehensive multispecies measurement scheme.

Chance, K. V.↗

NASA NTRS1985

The upper atmosphere research satellite

The Upper Atmosphere Research Satellite (UARS) will provide, for the first time, data on a global basis for the study of the physical processes acting witin and upon the stratosphere, mesosphere, and lower thermosphere. Specifically, the areas of scientifc study to be addressed are energy input and loss, photochemistry, dynamics, and the coupling among processes and between atmospheric regions. The UARS is a single observatory consisting of a multimission modular spacecraft (MMS) and an instrument module containing 10 scientific instruments. The satellite will be Shuttle launched and placed in a 57 deg inclined orbit at 600 km altitude. A Central Data Handling Facility (CDHF) will receive data from the satellite and process these data into atmospheric quantities for use by the science team. The 'processed' data will be stored at the CDHF and will be available via communication lines for analysis by the investigators at their home laboratories using remote computers. Together with other satellite programs, balloons, sounding rockets, and laboratory efforts, UARS will make available the opportunity for extensive coordination of data devoted to solar terrestrial study.

Burr, P. T.↗