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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

Lead-Free Propellant for Propellant Actuated Devices

Naval Surface Warfare Center, Indian Head Division's CAD/PAD Department has been working to remove toxic compounds from our products for about a decade. In 1992, we embarked on an effort to develop a lead-free double base propellant to replace that of a foreign sole source. At the time there were availability concerns. In 1995, the department developed a strategic proposal to include a wider range of products. Efforts included such efforts as removing lead sheathing from linear explosives and replacing lead azide and lead styphnate compounds. This paper will discuss efforts specifically related to developing non-leaded double base propellant for use in various Propellant Actuated Devices (PADs) for aircrew escape systems. The propellants can replace their leaded counterparts, mitigating lead handling, processing, or toxic exposure to the environment and personnel. This work eliminates the use of leaded compounds, replacing them with a more environmentally benign metal-organic salt. Historically double-base propellants have held an advantage over other families of energetic materials through their relative insensitivity of the burning rate to changes in temperature and pressure. This desirable ballistic effect has been obtained with the use of a lead-organic salt alone or in a physical mixture with a copper-organic salt, or more recently with a lead-copper complex. These ballistic modifiers are typically added to the double-base 'paste' prior to gelatinization on heated calendars or one type or another. The effect of constant burning rate over a pressure range is called a 'plateau' while an even more beneficial effect of decreasing burning rate with increasing pressure is termed a 'mesa.' The latter effect results in very low temperature sensitivity of the propellant burning rate. Propellants with such effects are ideal tactical rocket motor propellants. The use of lead compounds poses a concern for the environment and personnel safety due to the metal's toxic nature when introduced into the atmosphere by propellant manufacturing, rocket firings, and disposal. Two separate programs are underway at Indian Head to replace the leaded ballistic modifiers in NOSIH-AA-2 and KU propellants. Although the system requirements were very different, the programs gained valuable information from one another throughout their course.

Goodwin, John L.↗

Mars Propellant Liquefaction Modeling in Thermal Desktop

NASAs current Mars architectures are assuming the production and storage of 23 tons of liquid oxygen on the surface of Mars over a duration of 500+ days. In order to do this in a mass efficient manner, an energy efficient refrigeration system will be required. Based on previous analysis NASA has decided to do all liquefaction in the propulsion vehicle storage tanks. In order to allow for transient Martian environmental effects, a propellant liquefaction and storage system for a Mars Ascent Vehicle (MAV) was modeled using Thermal Desktop. The model consisted of a propellant tank containing a broad area cooling loop heat exchanger integrated with a reverse turbo Brayton cryocooler. Cryocooler sizing and performance modeling was conducted using MAV diurnal heat loads and radiator rejection temperatures predicted from a previous thermal model of the MAV. A system was also sized and modeled using an alternative heat rejection system that relies on a forced convection heat exchanger. Cryocooler mass, input power, and heat rejection for both systems were estimated and compared against sizing based on non-transient sizing estimates.

Cryogenics↗

Axisymmetric two-phase perfect gas performance program

Computer program calculates the inviscid axisymmetric nozzle expansion of propellant systems having both gaseous and condensed exhaust products. The program uses velocity and thermal lags and will perform calculations for contoured and conical nozzles.

Kliegel, J. R.↗

Concepts for the design of an antimatter annihilation rocket

Matter-antimatter annihilation is considered for spacecraft propulsion. Annihilation produces considerably more energy per unit mass of propellant than any other known means of energy production. An antimatter annihilation rocket requires several systems and components that are unique to its nature. Among these are an antimatter storage system, a means to extract the antimatter from storage, a system to transport the antimatter to the rocket engine, and the engine wherein annihilation occurs and thrust is produced. Design concepts of these systems and components are presented and discussed.

Morgan, D. L., Jr.↗

Plume Diagnostics of the RSRM Static Firings for the Pressure Perturbation Studies

During the STS-54 launch (RSRM-29), the right hand solid rocket motor experienced a 13.9 psi chamber pressure perturbation at 67 seconds into the motor operation. This pressure augmentation equated to a thrust change of 51 klb. Concerns were raised regarding the adverse effects of this thrust imbalance on the shuttle system and the overall thrust into the external tank structural elements. Pressure perturbations have been observed in solid rocket motors due to expulsion of igniter or insulation materials; the motor thrust during such events drop abruptly before rising. However, the RSRM motors do not exhibit such behavior during the large chamber pressure perturbation events. Several scenarios were investigated to explain these pressure perturbations in the RSRM motors based on a fault tree developed after STS-54. Of these, the expulsion of the slag accumulated in the submerged nozzle region appeared to be the most plausible scenario to explain the observations. Slag is a natural combustion product of aluminized solid rocket motors. The RSRM propellant contains 16% by weight of aluminum. Any ejection of this slag mass during nozzle vectoring or other side loads on the motor will result in the chamber pressure perturbation. Two RSRM static firings were instrumented extensively to further understand the slag expulsion phenomenon in the RSRM and the associated pressure perturbations.

Mathias, Edward C.↗

Developments of Bosch Process Architectures for ISRU Terrestrial Applications

To effectively realize NASA’s goals of a sustainable presence on the Moon and be-yond, In-Situ Resource Utilization (ISRU) must be leveraged. To reduce launch mass for space missions, commodities such as oxygen and carbon can be produced in-situ. Oxygen can be used for life support and as a propellant, and carbon can be used for battery production, filtration, additive manufacturing, and steel casting. Carbon is a required reactant in the carbothermal reduction process, a leading candidate for oxygen production on the lunar surface. To pro-duce these consumables, the Carbon Utilization Technology for Lunar and Atmospheric Systems (CUTLAS) project is developing architectures that leverage the Bosch process. The Bosch process re-acts CO 2 and H 2 to produce carbon powder and water, which can then be electrolyzed, leaving O 2 and recycled H 2 . This process is also applicable to carbon dioxide emissions on Earth.

Carbon capture↗

Hydrogen production in microbial electrolysis cells with biocathodes

Electroautotrophic microbes at biocathodes in microbial electrolysis cells (MECs) can catalyze the hydrogen evolution reaction with low energy demand, facilitating long-term stable performance through specific and renewable biocatalysts. However, MECs have not yet reached commercialization due to a lack of understanding of the optimal microbial strains and reactor configurations for achieving high performance. Here, we critically analyze the criteria for the inocula selection, with a focus on the effect of hydrogenase activity and microbe–electrode interactions. We also evaluate the impact of the reactor design and key parameters, such as membrane type, composition, and electrode surface area on internal resistance, mass transport, and pH imbalances within MECs. Furthermore, this analysis paves the way for advancements that could propel biocathode-assisted MECs toward scalable hydrogen gas production.

Biotechnology & Applied Microbiology↗

Common In-Situ Consumable Production Plant for Robotic Mars Exploration

Utilization of extraterrestrial resources, or In-Situ Resource Utilization (ISRU), is viewed by the Human Exploration and Development of Space (HEDS) Enterprise as an enabling technology for the exploration and commercial development of space. A key subset of ISRU which has significant cost, mass, and risk reduction benefits for robotic and human exploration, and which requires a minimum of infrastructure, is In-Situ Consumable Production (ISCP). ISCP involves acquiring, manufacturing, and storing mission consumables from in situ resources, such as propellants, fuel cell reagents, and gases for crew and life support, inflation, science and pneumatic equipment. One of the four long-term goals for the Space Science Enterprise (SSE) is to 'pursue space science programs that enable and are enabled by future human exploration beyond low-Earth orbit - a goal exploiting the synergy with the human exploration of space'. Adequate power and propulsion capabilities are critical for both robotic and human exploration missions. Minimizing the mass and volume of these systems can reduce mission cost or enhance the mission by enabling the incorporation of new science or mission-relevant equipment. Studies have shown that in-situ production of oxygen and methane propellants can enhance sample return missions by enabling larger samples to be returned to Earth or by performing Direct Earth Return (DER) sample return missions instead of requiring a Mars Orbit Rendezvous (MOR). Recent NASA and Department of Energy (DOE) work on oxygen and hydrocarbon-based fuel cell power systems shows the potential of using fuel cell power systems instead of solar arrays and batteries for future rovers and science equipment. The development and use of a common oxygen/methane ISCP plant for propulsion and power generation can extend and enhance the scientific exploration of Mars while supporting the development and demonstration of critical technologies and systems for the human exploration of Mars.

Sanders, G. B.↗

Celebrating a Century of Flight

Since 1915, the National Advisory Committee for Aeronautics (NACA), transformed into NASA in 1958, has performed cutting-edge research to solve the problems of flight. Using a Grumman F4F-3 Wildcat during World War II, NACA engineers at the Langley Aeronautical Laboratory (now Langley Research Center) in Hampton, Virginia, used this aircraft to investigate the cuffs on the propeller blades to determine their efficiency. While not built to the full production standard of other Grumman Wildcats, research on this aircraft, the second F4F-3, proved most successful in advancing knowledge of the aerodynamics of this engine and propeller system. A close-up of the propeller blades with Curtiss Electric Propellers' logo is shown.

OKeefe, Sean O.↗

Conceptual design of a lunar oxygen pilot plant Lunar Base Systems Study (LBSS) task 4.2

The primary objective was to develop conceptual designs of two pilot plants to produce oxygen from lunar materials. A lunar pilot plant will be used to generate engineering data necessary to support an optimum design of a larger scale production plant. Lunar oxygen would be of primary value as spacecraft propellant oxidizer. In addition, lunar oxygen would be useful for servicing nonregenerative fuel cell power systems, providing requirements for life support, and to make up oxygen losses from leakage and airlock cycling. Thirteen different lunar oxygen production methods are described. Hydrogen reduction of ilmenite and extraction of solar-wind hydrogen from bulk lunar soil were selected for conceptual design studies. Trades and sensitivity analyses were performed with these models.

Source record↗

Elastomeric Thermal Insulation Design Considerations in Long, Aluminized Solid Rocket Motors

An all-new sounding rocket was designed at NASA's Marshall Space Flight Center that featured an aft finocyl, aluminized solid propellant grain and silica-filled ethylene-propylene-diene monomer (SFEPDM) internal insulation. Upon the initial static firing of the first of this new design, the solid rocket motor (SRM) case failed thermally just upstream of the aft closure early in the burn time. Subsequent fluid modeling indicated that the high-velocity combustion-product jets emanating from the fin-slots in the propellant grain were likely inducing a strongly swirling flow, thus substantially increasing the severity of the convective environment on the exposed portion of the SFEPDM insulation in this region. The aft portion of the fin-slots in another of the motors were filled with propellant to eliminate the possibility of both direct jet impingement on the exposed SFEPDM and the appearance of strongly swirling flow in the aft region of the motor. When static-fired, this motor's case still failed in the same axial location, and, though somewhat later than for the first static firing, still in less than 1/3rd of the desired burn duration. These results indicate that the extreme material decomposition rates of the SFEPDM in this application are not due to gas-phase convection or shear but rather to interactions with burning aluminum or alumina slag. Further comparisons with between SFEPDM performance in this design and that in other hot-fire tests provide insight into the mechanisms of SFEPDM decomposition in SRM aft domes that can guide the upcoming redesign effort, as well as other future SRM designs. These data also highlight the current limitations of modeling elastomeric insulators solely with diffusion-controlled, gas-phase thermochemistry in SRM regions with significant viscous shear and/or condense-phase impingement or flow.

Martin, Heath T.↗

Low-temperature elastomer production and curing

Thermally and chemically stable polymers are needed for materials applications, particularly highly-stable elastomers for solid propellant binders where initial high temperature required for dissolving anhydride in polymer is deerimental. Solvent reactant system allows polymerization without condensation of products under low heat. Solvents utilized were dimethylacetamide, dimethyflormamide, etc.

Ingham, J. D.↗

Robust Exploration and Commercial Missions to the Moon Using LANTR Propulsion and In-Situ Propellants Derived From Lunar Polar Ice (LPI) Deposits

Since the 1960s, scientists have conjectured that water icecould survive in the cold, permanently shadowed craters located at the Moons poles Clementine (1994), Lunar Prospector (1998),Chandrayaan-1 (2008), and Lunar Reconnaissance Orbiter (LRO) and Lunar CRater Observation and Sensing Satellite(LCROSS) (2009) lunar probes have provided data indicating the existence of large quantities of water ice at the lunar poles The Mini-SAR onboard Chandrayaan-1discovered more than 40 permanently shadowed craters near the lunar north pole that are thought to contain 600 million metric tons of water ice. Using neutron spectrometer data, the Lunar Prospector science team estimated a water ice content (1.5 +-0.8 wt in the regolith) found in the Moons polar cold trap sand estimated the total amount of water at both poles at 2 billion metric tons Using Mini-RF and spectrometry data, the LRO LCROSS science team estimated the water ice content in the regolith in the south polar region to be 5.6 +-2.9 wt. On the basis of the above scientific data, it appears that the water ice content can vary from 1-10 wt and the total quantity of LPI at both poles can range from 600 million to 2 billion metric tons NTP offers significant benefits for lunar missions and can take advantage of the leverage provided from using LDPs when they become available by transitioning to LANTR propulsion. LANTR provides a variablethrust and Isp capability, shortens burn times and extends engine life, and allows bipropellant operation The combination of LANTR and LDP has performance capability equivalent to that of a hypothetical gaseousfuel core NTR (effective Isp 1575 s) and can lead to a robust LTS with unique mission capabilities that include short transit time crewed cargo transports and routine commuter flights to the Moon The biggest challenge to making this vision a reality will be the production of increasing amounts of LDP andthe development of propellant depots in LEO, LLO and LPO. An industry-operated, privately financed venture, with NASA as its initial customer, might provide a possible blueprint for future development and operation With industry interested in developing cislunar space and commerce, and competitive forces at work, the timeline for developing this capability could well be accelerated, quicker than any of us can imagine, and just the beginning of things to come.

Nuclear Thermal Propulsion↗

Xenon Acquisition Strategies for High-Power Electric Propulsion NASA Missions

The benefits of high-power solar electric propulsion (SEP) for both NASA's human and science exploration missions combined with the technology investment from the Space Technology Mission Directorate have enabled the development of a 50kW-class SEP mission. NASA mission concepts developed, including the Asteroid Redirect Robotic Mission, and those proposed by contracted efforts for the 30kW-class demonstration have a range of xenon propellant loads from 100's of kg up to 10,000 kg. A xenon propellant load of 10 metric tons represents greater than 10% of the global annual production rate of xenon. A single procurement of this size with short-term delivery can disrupt the xenon market, driving up pricing, making the propellant costs for the mission prohibitive. This paper examines the status of the xenon industry worldwide, including historical xenon supply and pricing. The paper discusses approaches for acquiring on the order of 10 MT of xenon propellant considering realistic programmatic constraints to support potential near-term NASA missions. Finally, the paper will discuss acquisitions strategies for mission campaigns utilizing multiple high-power solar electric propulsion vehicles requiring 100's of metric tons of xenon over an extended period of time where a longer term acquisition approach could be implemented.

Electric Propulsion↗

Study of solid rocket motors for a space shuttle booster. Volume 1: Executive summary

The design, development, production, and launch support analysis for determining the solid propellant rocket engine to be used with the space shuttle are discussed. Specific program objectives considered were: (1) definition of engine designs to satisfy the performance and configuration requirements of the various vehicle/booster concepts, (2) definition of requirements to produce booster stages at rates of 60, 40, 20, and 10 launches per year in a man-rated system, and (3) estimation of costs for the defined SRM booster stages.

Source record↗