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At least 415 records · Page 23

Radiation Shielding Materials Containing Hydrogen, Boron, and Nitrogen: Systematic Computational and Experimental Study

The key objectives of this study are to investigate, both computationally and experimentally, which forms, compositions, and layerings of hydrogen, boron, and nitrogen containing materials will offer the greatest shielding in the most structurally robust combination against galactic cosmic radiation (GCR), secondary neutrons, and solar energetic particles (SEP). The objectives and expected significance of this research are to develop a space radiation shielding materials system that has high efficacy for shielding radiation and that also has high strength for load bearing primary structures. Such a materials system does not yet exist. The boron nitride nanotube (BNNT) can theoretically be processed into structural BNNT and used for load bearing structures. Furthermore, the BNNT can be incorporated into high hydrogen polymers and the combination used as matrix reinforcement for structural composites. BNNT's molecular structure is attractive for hydrogen storage and hydrogenation. There are two methods or techniques for introducing hydrogen into BNNT: (1) hydrogen storage in BNNT, and (2) hydrogenation of BNNT (hydrogenated BNNT). In the hydrogen storage method, nanotubes are favored to store hydrogen over particles and sheets because they have much larger surface areas and higher hydrogen binding energy. The carbon nanotube (CNT) and BNNT have been studied as potentially outstanding hydrogen storage materials since 1997. Our study of hydrogen storage in BNNT - as a function of temperature, pressure, and hydrogen gas concentration - will be performed with a hydrogen storage chamber equipped with a hydrogen generator. The second method of introducing hydrogen into BNNT is hydrogenation of BNNT, where hydrogen is covalently bonded onto boron, nitrogen, or both. Hydrogenation of BN and BNNT has been studied theoretically. Hyper-hydrogenated BNNT has been theoretically predicted with hydrogen coverage up to 100% of the individual atoms. This is a higher hydrogen content than possible with hydrogen storage; however, a systematic experimental hydrogenation study has not been reported. A combination of the two approaches may be explored to provide yet higher hydrogen content. The hydrogen containing BNNT produced in our study will be characterized for hydrogen content and thermal stability in simulated space service environments. These new materials systems will be tested for their radiation shielding effectiveness against high energy protons and high energy heavy ions at the HIMAC facility in Japan, or a comparable facility. These high energy particles simulate exposure to SEP and GCR environments. They will also be tested in the LaRC Neutron Exposure Laboratory for their neutron shielding effectiveness, an attribute that determines their capability to shield against the secondary neutrons found inside structures and on lunar and planetary surfaces. The potential significance is to produce a radiation protection enabling technology for future exploration missions. Crew on deep space human exploration missions greater than approximately 90 days cannot remain below current crew Permissible Exposure Limits without shielding and/or biological countermeasures. The intent of this research is to bring the Agency closer to extending space missions beyond the 90-day limit, with 1 year as a long-term goal. We are advocating a systems solution with a structural materials component. Our intent is to develop the best materials system for that materials component. In this Phase I study, we have shown, computationally, that hydrogen containing BNNT is effective for shielding against GCR, SEP, and neutrons over a wide range of energies. This is why we are focusing on hydrogen containing BNNT as an innovative advanced concept. In our future work, we plan to demonstrate, experimentally, that hydrogen, boron, and nitrogen based materials can provide mechanically strong, thermally stable, structural materials with effective radiation shielding against GCR, SEP, and neutrons.

Radiation↗

Earth's magnetospheric processes; Proceedings of the Symposium, Cortina, Italy, August 30-September 10, 1971.

New data obtained by satellites, rockets, aircraft, and ground-based observations are interpreted in papers dealing with the magnetospheric structure and processes, particle distributions, magnetic and electric fields, plasma convection, particle acceleration and diffusion mechanisms, and substorm phenomena. Attention is given to particle populations in different magnetospheric regions, auroral particle precipitation patterns, effects of electric fields on plasma convection, VLF phenomena, a high-energy proton model for the inner radiation belt, substorm behavior of plasma sheet particles, and interpretations of magnetic field variations during substorms. Individual items are announced in this issue.

Mccormac, B. M.↗

Current review of the Jupiter, Saturn, and Uranus ionospheres

The ionospheres of the major planets Jupiter, Saturn, and Uranus are reviewed in light of Pioneer and Voyager observations. Some refinements to pre-Voyager theoretical models are required to explain the results, most notably the addition of significant particle ionization from 'electroglow' and auroral processes and the need for additional chemical loss of protons via charge exchange reactions with water. Water from the Saturn rings has been identified as a major modifier of the Saturn ionosphere and water influx from satellites and/or meteorites may also be important at Jupiter and Uranus as well, as evidenced by the observed ionospheric structure and the identification of cold stratospheric carbon monoxide at Jupiter.

Waite, J. H., Jr.↗

Monte Carlo track structure for radiation biology and space applications

Over the past two decades event by event Monte Carlo track structure codes have increasingly been used for biophysical modelling and radiotherapy. Advent of these codes has helped to shed light on many aspects of microdosimetry and mechanism of damage by ionising radiation in the cell. These codes have continuously been modified to include new improved cross sections and computational techniques. This paper provides a summary of input data for ionizations, excitations and elastic scattering cross sections for event by event Monte Carlo track structure simulations for electrons and ions in the form of parametric equations, which makes it easy to reproduce the data. Stopping power and radial distribution of dose are presented for ions and compared with experimental data. A model is described for simulation of full slowing down of proton tracks in water in the range 1 keV to 1 MeV. Modelling and calculations are presented for the response of a TEPC proportional counter irradiated with 5 MeV alpha-particles. Distributions are presented for the wall and wall-less counters. Data shows contribution of indirect effects to the lineal energy distribution for the wall counters responses even at such a low ion energy.

NASA Center JSC↗

Energy conversion at liquid/liquid interfaces: artificial photosynthetic systems

This chapter focuses on multielectron reactions in organized assemblies of molecules at the liquid/liquid interface. We describe the thermodynamic and kinetic parameters of such reactions, including the structure of the reaction centers, charge movement along the electron transfer pathways, and the role of electric double layers in artificial photosynthesis. Some examples of artificial photosynthesis at the oil/water interface are considered, including water photooxidation to the molecular oxygen, oxygen photoreduction, photosynthesis of amphiphilic compounds and proton evolution by photochemical processes.

Non-NASA Center↗

Global Simulation of Electromagnetic Ion Cyclotron Waves

It is well known that the effects of electromagnetic ion cyclotron (EMIC) waves on ring current (RC) ion and radiation belt (RB) electron dynamics strongly depend on such particle/wave characteristics as the phase-space distribution function, frequency, wave-normal angle, wave energy, and the form of wave spectral energy density. The consequence is that accurate modeling of EMIC waves and RC particles requires robust inclusion of the interdependent dynamics of wave growth/damping, wave propagation, and particles. Such a self-consistent model is being progressively developed by Khazanov et al. [2002 - 2007]. This model is based on a system of coupled kinetic equations for the RC and EMIC wave power spectral density along with the ray tracing equations. We will discuss the recent progress in understanding EMIC waves formation mechanisms in the inner magnetosphere. This problem remains unsettled in spite of many years of experimental and theoretical studies. Modern satellite observations by CRRES, Polar and Cluster still do not reveal the whole picture experimentally since they do not stay long enough in the generation region to give a full account of all the spatio-temporal structure of EMIC waves. The complete self-consistent theory taking into account all factors significant for EMIC waves generation remains to be developed. Several mechanisms are discussed with respect to formation of EMIC waves, among them are nonlinear modification of the ionospheric reflection by precipitating energetic protons, modulation of ion-cyclotron instability by long-period (Pc3/4) pulsations, reflection of waves from layers of heavy-ion gyroresonances, and nonlinearities of wave generation process. We show that each of these mechanisms have their attractive features and explains certain part experimental data but any of them, if taken alone, meets some difficulties when compared to observations. We conclude that development of a refined nonlinear theory and further correlated analysis of modern satellite and ground-based data is needed to solve this very intriguing problem.

Khazanov, G. V.↗

Global Simulation of Electromagnetic Ion Cyclotron Waves

It is very well known that the effects of electromagnetic ion cyclotron (EMIC) waves on ring current (RC) ion and radiation belt (RB) electron dynamics strongly depend on such particle/wave characteristics as the phase-space distribution function, frequency, wave-normal angle, wave energy, and the form of wave spectral energy density. The consequence is that accurate modeling of EMIC waves and RC particles requires robust inclusion of the interdependent dynamics of wave growth/damping, wave propagation, and particles. Such a self-consistent model is being progressively developed by Khazanov et al. This model is based on a system of coupled kinetic equations for the RC and EMIC wave power spectral density along with the ray tracing equations. We will discuss the recent progress in understanding EMIC waves formation mechanisms in the inner magnetosphere. This problem remains unsettled in spite of many years of experimental and theoretical studies. Modern satellite observations by CRRES, Polar and Cluster still do not reveal the whole picture experimentally since they do not stay long enough in the generation region to give a full account of all the spatio-temporal structure of EMIC waves. The complete self-consistent theory taking into account all factors significant for EMIC waves generation remains to be developed. Several mechanisms are discussed with respect to formation of EMIC waves, among them are nonlinear modification of the ionospheric reflection by precipitating energetic protons, modulation of ion-cyclotron instability by long-period (Pc3/4) pulsations, reflection of waves from layers of heavy-ion gyroresonances, and nonlinearities of wave generation process. We show that each of these mechanisms have their attractive features and explains certain part experimental data but any of them, if taken alone, meets some difficulties when compared to observations. We conclude that development of a refined nonlinear theory and further correlated analysis of modern satellite and ground-based data is needed to solve this very intriguing problem.

Khazanov, George V.↗

Design of Two RadWorks Storm Shelters for Solar Particle Event Shielding

In order to enable long-duration human exploration beyond low-Earth orbit, the risks associated with exposure of astronaut crews to space radiation must be mitigated with practical and affordable solutions. The space radiation environment beyond the magnetosphere is primarily a combination of two types of radiation: galactic cosmic rays (GCR) and solar particle events (SPE). While mitigating GCR exposure remains an open issue, reducing astronaut exposure to SPEs is achievable through material shielding because they are made up primarily of medium-energy protons. In order to ensure astronaut safety for long durations beyond low-Earth orbit, SPE radiation exposure must be mitigated. However, the increasingly demanding spacecraft propulsive performance for these ambitious missions requires minimal mass and volume radiation shielding solutions which leverage available multi-functional habitat structures and logistics as much as possible. This paper describes the efforts of NASA's RadWorks Advanced Exploration Systems (AES) Project to design two minimal mass SPE radiation shelter concepts leveraging available resources: one based upon reconfiguring habitat interiors to create a centralized protection area and one based upon augmenting individual crew quarters with waterwalls and logistics. Discussion items include the design features of the concepts, a radiation analysis of their implementations, an assessment of the parasitic mass of each concept, and the result of a human in the loop evaluation performed to drive out design and operational issues.

Simon, Matthew↗

RadWorks Storm Shelter Design for Solar Particle Event Shielding

In order to enable long-duration human exploration beyond low-Earth orbit, the risks associated with exposure of astronaut crews to space radiation must be mitigated with practical and affordable solutions. The space radiation environment beyond the magnetosphere is primarily a combination of two types of radiation: galactic cosmic rays (GCR) and solar particle events (SPE). While mitigating GCR exposure remains an open issue, reducing astronaut exposure to SPEs is achievable through material shielding because they are made up primarily of medium-energy protons. In order to ensure astronaut safety for long durations beyond low-Earth orbit, SPE radiation exposure must be mitigated. However, the increasingly demanding spacecraft propulsive performance for these ambitious missions requires minimal mass and volume radiation shielding solutions which leverage available multi-functional habitat structures and logistics as much as possible. This paper describes the efforts of NASA's RadWorks Advanced Exploration Systems (AES) Project to design minimal mass SPE radiation shelter concepts leveraging available resources. Discussion items include a description of the shelter trade space, the prioritization process used to identify the four primary shelter concepts chosen for maturation, a summary of each concept's design features, a description of the radiation analysis process, and an assessment of the parasitic mass of each concept.

Simon, Matthew A.↗

Strategy for Maturing Active Radiation Shielding Concepts

Active shielding strategies for protecting astronauts on exploration missions has long been a dream that proved evasive. Study after study since the early 1970’s has shown that solutions are both mass and power prohibitive. This talk will give an overview of current NASA work aimed at making advancements in the area of active shielding. The basic project premise is that we may have a better chance at success if we: (1) remove the constraint of having to reduce the exposure to zero, and instead focus on how to increase the number of ‘safe’ days in space according to the current NASA risk posture; (2) sub-divide the proton and heavy ion energy spectrum to identify a starting point in energy that may yield a non-negligible reduction in ion flux at power levels achievable with current technology, and; (3) develop methods to use scaling to build, test and mature small-scale shielding structures on the ground as a pathway to identifying technology development investment strategies. A top-level overview of these strategies will be presented during this talk.

Radiation Protection↗

Computer simulation of ion channel gating: the M(2) channel of influenza A virus in a lipid bilayer

The transmembrane fragment of the influenza virus M(2) protein forms a homotetrameric channel that transports protons. In this paper, we use molecular dynamics simulations to help elucidate the mechanism of channel gating by four histidines that occlude the channel lumen in the closed state. We test two competing hypotheses. In the "shuttle" mechanism, the delta nitrogen atom on the extracellular side of one histidine is protonated by the incoming proton, and, subsequently, the proton on the epsilon nitrogen atom is released on the opposite side. In the "water-wire" mechanism, the gate opens because of electrostatic repulsion between four simultaneously biprotonated histidines. This allows for proton transport along the water wire that penetrates the gate. For each system, composed of the channel embedded in a hydrated phospholipid bilayer, a 1.3-ns trajectory was obtained. It is found that the states involved in the shuttle mechanism, which contain either single-protonated histidines or a mixture of single-protonated histidines plus one biprotonated residue, are stable during the simulations. Furthermore, the orientations and dynamics of water molecules near the gate are conducive to proton transfer. In contrast, the fully biprotonated state is not stable. Additional simulations show that if only two histidines are biprotonated, the channel deforms but the gate remains closed. These results support the shuttle mechanism but not the gate-opening mechanism of proton gating in M(2).

NASA Center ARC↗

Interstellar Ices and Radiation-Induced Oxidations of Alcohols

Infrared spectra of ices containing alcohols that are known or potential interstellar molecules are examined before and after irradiation with 1 MeV protons at ~20 K. The low-temperature oxidation (hydrogen loss) of six alcohols is followed, and conclusions are drawn based on the results. The formation of reaction products is discussed in terms of the literature on the radiation chemistry of alcohols and a systematic variation in their structures. The results from these new laboratory measurements are then applied to a recent study of propargyl alcohol. Connections are drawn between known interstellar molecules, and several new reaction products in interstellar ices are predicted.

astrochemistry – infrared: ISM – ISM: molecule↗

Interstellar Ices and Radiation-induced Oxidations of Alcohols

Infrared spectra of ices containing alcohols that are known or potential interstellar molecules are examined before and after irradiation with 1 MeV protons at ~20 K. The low-temperature oxidation (hydrogen loss) of six alcohols is followed, and conclusions are drawn based on the results. The formation of reaction products is discussed in terms of the literature on the radiation chemistry of alcohols and a systematic variation in their structures. The results from these new laboratory measurements are then applied to a recent study of propargyl alcohol. Connections are drawn between known interstellar molecules, and several new reaction products in interstellar ices are predicted.

astrochemistry – infrared: ISM – ISM: molecule↗

Interstellar Ices and Radiation-Induced Oxidations of Alcohols

Infrared spectra of ices containing alcohols that are known or potential interstellar molecules are examined before and after irradiation with 1 MeV protons at ~20 K. The low-temperature oxidation (hydrogen loss) of six alcohols is followed, and conclusions are drawn based on the results. The formation of reaction products is discussed in terms of the literature on the radiation chemistry of alcohols and a systematic variation in their structures. The results from these new laboratory measurements are then applied to a recent study of propargyl alcohol. Connections are drawn between known interstellar molecules, and several new reaction products in interstellar ices are predicted.

astrochemistry – infrared: ISM – ISM: molecules – ↗

Proton-induced radiation damage in germanium detectors

High-purity germanium (HPGe) detectors will be used in future space missions for gamma-ray measurements and will be subject to interactions with energetic particles. To simulate this process, several large-volume n-type HPGe detectors were incrementally exposed to a particle fluence of up to 10 to the 8th protons/sq cm (proton energy: 1.5 GeV) at different operating temperatures (90 to 120 K) to induce radiation damage. Basic scientific and engineering data on detector performance were collected. During the incremental irradiation, the peak shape produced by the detectors showed a significant change from a Gaussian shape to a broad complex structure. After the irradiation, all detectors were thoroughly characterized by measuring many parameters. To remove the accumulated radiation damage, the detectors were stepwise-annealed at temperatures below 110 C, while kept in their specially designed cryostats. This study shows that n-type HPGe detectors can be used in charged-particle environments as high-energy resolution devices until a certain level of radiation damage is accumulated and that the damage can be removed at moderate annealing temperatures and the detector returned to operating condition.

Brueckner, J.↗

Pair-density transitions in accretion disk coronae

The thermal and e(+)e(-)-pair equilibrium structure of two-temperature disk coronae above a cool (about 10 exp 6 K) disk around a black hole of 10 solar masses are investigated. Soft photons are assumed to be amply supplied from the cool disk. Two-pair thermal equilibrium points are found for a given proton column density: the low state with very small pair density and the high state dominated by pairs. Both states are thermally unstable, while for perturbations in pair density the high state is unstable and the low state is stable. Two possible scenarios are discussed for the fate of a two-temperature corona. When the proton optical depth is relatively small (e.g., less than 1) and the temperature of input soft photons is low (e.g., less than 10 exp 6 K), the corona will undergo a limit cycle between the high state and the low state on a time scale of milliseconds. As a consequence of Compton scattering of the soft photons, the emergent spectrum in the high state is rather flat with a big Wien bump at about 100 keV, whereas it is composed of a power-law component in the low state. Some observational consequences are briefly discussed in connection with the high-low spectral transition in Cyg X-1.

Kusunose, Masaaki↗

Overview of the Graphical User Interface for the GERMcode (GCR Event-Based Risk Model)

The descriptions of biophysical events from heavy ions are of interest in radiobiology, cancer therapy, and space exploration. The biophysical description of the passage of heavy ions in tissue and shielding materials is best described by a stochastic approach that includes both ion track structure and nuclear interactions. A new computer model called the GCR Event-based Risk Model (GERM) code was developed for the description of biophysical events from heavy ion beams at the NASA Space Radiation Laboratory (NSRL). The GERMcode calculates basic physical and biophysical quantities of high-energy protons and heavy ions that have been studied at NSRL for the purpose of simulating space radiobiological effects. For mono-energetic beams, the code evaluates the linear-energy transfer (LET), range (R), and absorption in tissue equivalent material for a given Charge (Z), Mass Number (A) and kinetic energy (E) of an ion. In addition, a set of biophysical properties are evaluated such as the Poisson distribution of ion or delta-ray hits for a specified cellular area, cell survival curves, and mutation and tumor probabilities. The GERMcode also calculates the radiation transport of the beam line for either a fixed number of user-specified depths or at multiple positions along the Bragg curve of the particle. The contributions from primary ion and nuclear secondaries are evaluated. The GERMcode accounts for the major nuclear interaction processes of importance for describing heavy ion beams, including nuclear fragmentation, elastic scattering, and knockout-cascade processes by using the quantum multiple scattering fragmentation (QMSFRG) model. The QMSFRG model has been shown to be in excellent agreement with available experimental data for nuclear fragmentation cross sections, and has been used by the GERMcode for application to thick target experiments. The GERMcode provides scientists participating in NSRL experiments with the data needed for the interpretation of their experiments, including the ability to model the beam line, the shielding of samples and sample holders, and the estimates of basic physical and biological outputs of the designed experiments. We present an overview of the GERMcode GUI, as well as providing training applications.

Kim, Myung-Hee Y.↗