Search NASA⌕ Search

SEARCH · Search NASA

Results for “RAMAN SCATTERING”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 415 records · Page 23

Non-intrusive Space Shuttle Main Engine nozzle exit diagnostics

The results of a conceptual design study on the feasibility of nonintrusive optical diagnostics have shown that UV laser-excited Raman scattering can furnish reliable and accurate temperature and multiple-species data for the Space Shuttle Main Engine's exhaust flow. Enhanced OH flow tagging by UV photodissociation of H2O was used in velocity measurements; a time-delayed pulsed dye laser beam at 308 nm excites fluorescence from OH, and the location of the convected enhanced OH zone is measured with an optical multichannel detector.

Shirley, John A.↗

A continued program of planetary study

This program conducts solar system research in support of NASA missions and of general astronomical interest. Investigations of the composition, physical characteristics, and changes in solar system bodies are conducted primarily utilizing facilities of McDonald Observatory, but also utilizing various space vehicles where appropriate. The first detection of 2 micrometer II2 emission from Jupiter's southern auroral zone was made. Previous detection of northern auroral emission from Jupiter's H2 S(1) quadrupole line at 2.12 micrometer was confirmed. Unlike the previously known 8 micrometer aurorae, this phenomenon can not be thermal in origin. Analysis of Raman scattering in the blue and ultraviolet spectrum of Uranus (200 to 500 Angstroms) show that there must be absorbing aerosol particles in the upper 10 mbar region of the atmosphere. Spectra of Pluto-Charon in and out of eclipse in the red and near IR were obtained. These data confirm that CH4 is confined to Pluto and absent on Charon.

Smith, Harlan↗

The far ultraviolet reflection spectrum of Uranus - Results from the Voyager encounter

The present analysis of the 1250-1700 A region Uranus spectrum obtained by Voyager's US spectrometer characterizes these observation results as due primarily to solar light reflected from an H2 Rayleigh and Raman scattering atmosphere with small but measurable hydrocarbon absorption. The hydrocarbon abundances obtained are substantially lower than those at comparable levels of the Saturn or Jupiter atmospheres; it is suggested, in one-dimensional terms, that this is due to diffusive separation, in conjunction with photochemical depletion caused by a very low eddy-diffusion coefficient. Strong latitudinal variations in the hydrocarbon abundances are suggested in the subsolar, polar stratosphere.

Yelle, Roger V.↗

Approximate formulation of redistribution in the Ly-alpha, Ly-beta, H-alpha system

Simple approximate formulas are given for the coupled redistribution of Ly-alpha, Ly-beta, and H-alpha, by using well-defined approximations to an essentially exact formulation. These formulas incorporate all the essential physics including Raman scattering, lower state radiative decay, and correlated terms representing emission during a collision which must be retained in order that the emission coefficients are properly behaved in the line wings. Approximate expressions for the appropriate line broadening parameters are collected. Finally, practical expressions for the source functions are given. These are formulated through newly introduced nonimpact redistribution functions, which are shown to be reasonably approximated by existing (ordinary and generalized) redistribution functions.

Cooper, J.↗

A method for measuring temperatures and densities in hypersonic wind tunnel air flows using laser-induced O2 fluorescence

Laser-induced fluorescence in oxygen, in combination with Raman scattering, is shown to be an accurate means by which temperature, density, and their fluctuations due to turbulence can be measured in air flows associated with high-speed wind tunnels. For temperatures above 60 K and densities above 0.01 amagat, the uncertainty in the temperature and density measurements can be less than 2 and 3 percent, respectively, if the signal uncertainties are dominated by photon-statistical noise. The measurements are unaffected by collisional quenching and can be achieved with laser fluences for which nonlinear effects are insignificant. Temperature measurements using laser-induced fluorescence alone have been demonstrated at known densities in the range of low temperatures and densities which are expected in a hypersonic wind tunnel.

Laufer, Gabriel↗

Three-dimensional quantitative flow diagnostics

The principles, capabilities, and practical implementation of advanced measurement techniques for the quantitative characterization of three-dimensional flows are reviewed. Consideration is given to particle, Rayleigh, and Raman scattering; fluorescence; flow marking by H2 bubbles, photochromism, photodissociation, and vibrationally excited molecules; light-sheet volume imaging; and stereo imaging. Also discussed are stereo schlieren methods, holographic particle imaging, optical tomography, acoustic and magnetic-resonance imaging, and the display of space-filling data. Extensive diagrams, graphs, photographs, sample images, and tables of numerical data are provided.

Miles, Richard B.↗

Optimization of a Raman shifted dye laser system for DIAL applications

An efficient Raman shifted dye laser system that generates tunable radiation at 765 and 940 nm with a bandwidth of 0.03/cm is described. Operating a Raman cell at hydrogen pressure below 14 atm, optimum first Stokes energy conversions of 45 percent and of 37 percent at 765 and 940 nm, respectively, were recorded. Optical depth measurements made at the centers of twenty-five absorption lines in the P branch of the oxygen A band imply a high spectral purity for both the laser and the Raman shifted radiation, and thus indicate the feasibility of using the stimulated Raman scattered radiation for differential absorption lidar (DIAL) measurements.

Singh, Upendra N.↗

Laser Spectroscopic Measurement Of Temperature And Density

Report discusses research on use of laser-induced fluorescence in oxygen and Raman scattering in air for simultaneous measurement of temperature and density of air. Major application of laser spectroscopic techniques, measurement of fluctuations of temperature and density in hypersonic flows in wind tunnels.

Mckenzie, Robert L.↗

Study of diamond film growth and properties

The objective was to study diamond film growth and its properties in order to enhance the laser damage threshold of substrate materials. Calculations were performed to evaluate laser induced thermal stress parameter, R(sub T) of diamond. It is found that diamond has several orders of magnitude higher in value for R(sub T) compared to other materials. Thus, the laser induced damage threshold (LIDT) of diamond is much higher. Diamond films were grown using a microwave plasma enhanced chemical vapor deposition (MPECVD) system at various conditions of gas composition, pressure, temperature, and substrate materials. A 0.5 percent CH4 in H2 at 20 torr were ideal conditions for growing of high quality diamond films on substrates maintained at 900 C. The diamond films were polycrystalline which were characterized by scanning electron microscopy (SEM) and Raman scattering spectroscopy. The top surface of the growing film is always rough due to the facets of polycrystalline film while the back surface of the film replicates the substrate surface. An analytical model based on two dimensional periodic heat flow was developed to calculate the effective in-plane (face parallel) diffusivity of a two layer system. The effective diffusivity of diamond/silicon samples was measured using a laser pulse technique. The thermal conductivity of the films was measured to be 13.5 W/cm K, which is better than that of a type Ia natural diamond. Laser induced damage experiments were performed on bare Si substrates, diamond film coated Si, and diamond film windows. Significant improvements in the LIDT were obtained for diamond film coated Si compared to the bare Si.

Albin, Sacharial↗

Characterization of devices, circuits, and high-temperature superconductor transmission lines by electro-optic testing

The development of a capability for testing transmission lines, devices, and circuits using the optically-based technique of electro-optics sampling was the goal of this project. Electro-optic network analysis of a high-speed device was demonstrated. The project involved research on all of the facets necessary in order to realize this result, including the discovery of the optimum electronic pulse source, development of an adequate test fixture, improvement of the electro-optic probe tip, and identification of a device which responded at high frequency but did not oscillate in the test fixture. In addition, during the process of investigating patterned high-critical-temperature superconductors, several non-contacting techniques for the determination of the transport properties of high T(sub c) films were developed and implemented. These are a transient, optical pump-probe, time-resolved reflectivity experiment, an impulsive-stimulated Raman scattering experiment, and a terahertz-beam coherent-spectroscopy experiment. The latter technique has enabled us to measure both the complex refractive index of an MgO substrate used for high-T(sub c) films and the complex conductivity of a YBa2Cu3O(7-x) sample. This information was acquired across an extremely wide frequency range: from the microwave to the submillimeter-wave regime. The experiments on the YBCO were conducted without patterning of, or contact to, the thin film. Thus, the need for the more difficult transmission-line experiments was eliminated. Progress in all of these areas was made and is documented in a number of papers. These papers may be found in the section listing the abstracts of the publications that were issued during the course of the research.

Whitaker, John F.↗

The internal caustic structure of illuminated liquid droplets

The internal electric field of an illuminated liquid droplet is studied in detail using both wave theory and ray theory. The internal field obtains its maximum values on the caustics within the droplet. Ray theory is used to determine the equations of these caustics and the density of rays on them. The Debye series expansion of the interior field Mie amplitudes is used to calculate the wave theory version of these caustics. The physical interpretation of the sources of stimulated Raman scattering and fluorescence emission within a liquid droplet is then given.

Lock, James A.↗

Stimulated Raman shifting of the Nd:YAG fourth harmonic (266 nm) in H2, HD, and D2

The dependence of the first Stokes stimulated Raman conversion efficiency of fourth-harmonic radiation from a Nd:YAG laser at 266 nm has been studied for the isotopic species H2, HD, and D2 as a function of gas pressure and laser energy using a low numerical aperture (about 0.0045) pumping geometry. While the laser energy threshold for first Stokes conversion varies significantly among the species, photon conversion efficiencies of at least 50 percent can be achieved for all of them for laser pump energies at 266 nm of 50 mJ/pulse or less. This study provides a new measurement of the differential cross section for stimulated Raman scattering in HD of 8.1 + or - 2.4 x 10 to the -29th sq cm/sr at 266 nm and at high pressures, and agreement is found with previous measurements of the cross sections for H2 and D2. The results have been used to optimize the laser transmitter system for a differential-absorption lidar to measure tropospheric ozone concentration profiles.

Haner, David A.↗

Method for measuring temperatures and densities in hypersonic wind tunnel air flows using laser-induced O2 fluorescence

Laser-induced fluorescence in oxygen, in combination with Raman scattering, is shown to be an accurate means by which temperature, density, and their fluctuations owing to turbulence can be measured in air flows associated with high-speed wind tunnels. For temperatures above 60 K and densities above 0.01 amagat, the uncertainties in the temperature and density measurements can be less than 2 percent, if the signal uncertainties are dominated by photon statistical noise. The measurements are unaffected by collisional quenching and can be achieved with laser fluences for which nonlinear effects are insignificant. Temperature measurements using laser-induced fluorescence alone have been demonstrated at known densities in the range of low temperatures and densities which are expected in a hypersonic wind tunnel.

Laufer, Gabriel↗

A hardened CARS system utilized for temperature measurements in a supersonic combustor

A coherent anti-Stokes Raman scattering (CARS) system has been hardened for utilization in a NASA Langley supersonic combustion test cell that can obtain temperature cross sections of the flow at three locations. This system is remotely operated and environmentally protected. Measurements were obtained in a scramjet combustor model consisting of a rearward-facing step, followed by an expansion duct. The freestream conditions were Mach 2, with static pressure that ranged from 0.8 to 1.9 atm, and a static temperature of about 800 K. Data for two different flow conditions were obtained that provided a comparison between reacting and nonreacting mixing of injected hydrogen fuel with the combustion-heated supersonic stream.

Antcliff, Richard R.↗

Simultaneous measurements of temperature and density in air flows using UV laser spectroscopy

The simultaneous measurement of temperature and density using laser-induced fluorescence of oxygen in combination with Q-branch Raman scattering of nitrogen and oxygen is demonstrated in a low-speed air flow. The lowest density and temperature measured in the experiment correspond to the freestream values at Mach 5 in the Ames 3.5-Foot Hypersonic Wind Tunnel for stagnation conditions of 100 atm and 1000 K. The experimental results demonstrate the viability of the optical technique for measurements that support the study of compressible turbulence and the validation of numerical codes in supersonic and hypersonic wind tunnel flows.

Fletcher, D. G.↗

Simultaneous temperature and multi-species measurements in opposed jet flames of nitrogen-diluted hydrogen and air

A narrowband UV Raman scattering system is used to obtain measurement profiles of major and minor species concentrations, temperature, and mixture fraction in opposed jet diffusion flames. The measurement profiles can be compared to previously obtained temperature and concentration profiles (Pellett et al., 1989), obtained using CARS, and they can also be qualitatively compared to the predicted concentration and temperature profiles in pure hydrogen/air flames (Gutheil and Williams, 1990) and in diluted hydrogen/air flames (Dixon-Lewis and Missaghi, 1988; Ho and Isaac, 1991). The applied stress-rates for the two flame conditions studied are 240/s and 340/s, with respective hydrogen concentrations in the fuel jet of 0.67 and 0.83, on a mole fraction basis (0.13 and 0.26 hydrogen mass fractions, respectively).

Wehrmeyer, J. A.↗

Finite-rate chemistry effects in a Mach 2 reacting flow

UV spontaneous vibrational Raman scattering and laser-induced predissociative fluorescence (LIPF) are combined and applied to a supersonic flame. For the first time, simultaneous measurements of temperature, major species (H2, O2, N2, H2O), and minor species (OH) concentrations are obtained with a 'single' excimer laser in a supersonic-lifted hydrogen-air diffusion flame. In the supersonic flame, a small amount of reaction occurs upstream of the lifted flame base, due to shock wave interactions and mixing with hot vitiated air. The strong turbulent mixing and high total enthalpy fluctuations lead to nonequilibrium values of temperature, and major and minor species concentrations. Combustion occurs farther downstream of the lifted region where slow three-body recombination reactions result in superequilibrium OH concentrations that depress the temperatures below their equilibrium values. Farther downstream, ambient air entrainment contaminates flame properties.

Cheng, T. S.↗

Optical transitions in diamond at ultrahigh pressures

Optical studies on diamond at ultrahigh pressures are described which show that the unique properties of diamonds are affected by such stresses. Spectroscopic measurements show that the optical absorption edge shifts from UV to red with increasing pressures, and Raman scattering measurements how evidence for new structural transitions associated with large macroscopic deformation, beginning at a pressure of about 150 GPa. The changes are reversible and are associated with intense luminescence peaks at 2.0-2.2 eV under 458-514 nm radiation. These results may be related to the onset of bandgap closure in the approach to a new high-pressure phase. These spectral features must also be taken into account when diamond is used as optical windows for ultrahigh-pressure investigations.

Mao, H. K.↗