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Exotic Molecules in Space: A Coordinated Astronomical Laboratory and Theoretical Study

This report details the work of NASA grant NAG5-9379 which is concerned with the discovery and characterization of new astrophysical molecules. Numerous papers have been or will be published on the laboratory detection of 21 molecules of astrophysical interest, nearly all not previously observed, and nearly all of astrophysical interest as plausible candidates for the interstellar gas and circumstellar shells. Also of interest include the laboratory detection of of optical molecular band exactly coinciding in frequency with the strongest and most widely studied optical diffuse interstellar band which remains an enigma in astrophysical spectroscopy. A new laser spectrometer has been developed and is now undergoing testing.

Thaddeus, Patrick↗

Exotic Molecules in Space: A Coordinated Astronomical Laboratory and Theoretical Study

The present report covers the third year of a grant which represents a direct continuation of NASA NAG5-4050, with the same title as before. It is dedicated as before to the discovery and characterization of new astrophysical molecules. This year, like the two before, has been extremely productive, yielding many new discoveries of astronomical interest at both radio and optical wavelengths, and the publication or submission of the 15 papers listed below. Nearly all of these articles have or will soon appear in the leading refereed journals of astrophysics, chemical physics, physics, or molecular spectroscopy. One is a major invited review for Molecular Physics. One of our other invited reviews published in Spectrochimica Acta in 2001 was recently awarded the Sir Harold Thompson Memorial Award, annually given to the best paper in that journal. During the past year significant advances have been made by our group in the laboratory study of exotic silicon and carbon molecules of astronomical interest. The most exciting discoveries include the pure silicon cluster Si3, several novel silicon hydrides, and the detection of phenyl radical, CsH5, a fundamental reactive organic ring. In addition, the rotational spectra of many carbon chains terminated with Si, N, O, and other heteroatoms have also been detected for the first time. The laboratory astrophysics of the whole set is complete in the sense that the entire radio spectrum of each species has now been measured or can be calculated to very high accuracy. Nearly all of these newly found molecules are plausible candidates for the detection by radio astronomers in the interstellar gas or in circumstellar sources because they are similar in structure and composition to known astronomical species, and because most are calculated to possess large permanent dipole moments.

Stringfellow, Guy↗

Exotic Molecules in Space: A Coordinated Astronomical Laboratory and Theoretical Study

The present report covers the first year of a grant which represents a direct continuation of NASA NAG5-4050, with the same title as before. It is dedicated as before to the discovery and characterization of new astrophysical molecules. This year, has been extremely productive, yielding many new discoveries of astronomical interest at both radio and optical wavelengths, and the publication or submission of the 15 papers listed below. Nearly all of these articles have or will soon appear in the leading refereed journals of astrophysics, chemical physics, physics, or molecular spectroscopy. One is a major invited review for Molecular Physics. One of our other invited reviews published in Spectrochimica Acta in 2001 was recently awarded the Sir Harold Thompson Memorial Award, annually given to the best paper in that journal. During the past year significant advances have been made by our group in the laboratory study of exotic silicon and carbon molecules of astronomical interest. The most exciting discoveries include the pure silicon cluster Si3, several novel silicon hydrides, and the detection of phenyl radical, C6H5, a fundamental reactive organic ring. In addition, the rotational spectra of many carbon chains terminated with Si, N, O, and other heteroatoms have also been detected for the first time. The laboratory astrophysics of the whole set is complete in the sense that the entire radio spectrum of each species has now been measured or can be calculated to very high accuracy. Nearly all of these newly found molecules are plausible candidates for the detection by radio astronomers in the interstellar gas or in circumstellar sources because they are similar in structure and composition to known astronomical species, and because most are calculated to possess large permanent dipole moments.

Springfellow, Guy↗

Exotic Molecules in Space: A Coordinated Astronomical Laboratory and Theoretical Study

The final report covers the two year of a grant which represents a direct continuation of NASA NAG5-4050, with the same title as before. It is dedicated as before to the discovery and characterization of new astrophysical molecules. The four years (two of the original grant plus two years extension) have been extremely productive, yielding many new discoveries of astronomical interest at both radio and optical wavelengths, and the publication or submission of the 49 papers listed below. These articles have appeared or will soon appear in the leading refereed journals of astrophysics, chemical physics, physics, or molecular spectroscopy. One is a major invited review (#27) for Moleculur Physics. One of our other invited reviews published in Spectrochimica Acta in 2001 was recently awarded the Sir Harold Thompson Memorial Award, annually given to the best paper in that journal. Michael McCarthy has recently been awarded the Broida Prize.

Stringfellow, Guy↗

Determination of Ground-Laboratory to In-Space Effective Atomic Oxygen Fluence for DC 93?500 Silicone

The objective of this research was to calibrate the ground-to-space effective atomic oxygen fluence for DC 93-500 silicone in a thermal energy electron cyclotron resonance (ECR) oxygen plasma facility. Silicones, commonly used spacecraft materials, do not chemically erode with atomic oxygen attack like other organic materials but form an oxidized hardened silicate surface layer. Therefore, the effective atomic oxygen fluence in a ground test facility should not be determined based on mass loss measurements, as they are with organic polymers. A technique has been developed at the Glenn Research Center to determine the equivalent amount of atomic oxygen exposure in an ECR ground test facility to produce the same degree of atomic oxygen damage as in space. The approach used was to compare changes in the surface hardness of ground test (ECR) exposed DC 93-500 silicone with DC 93-500 exposed to low Earth orbit (LEO) atomic oxygen as part of a shuttle flight experiment. The ground to in-space effective atomic oxygen fluence correlation was determined based on the fluence in the ECR source that produced the same hardness for the fluence in-space. Nanomechanical hardness versus contact depth measurements were obtained for five ECR exposed DC 93-500 samples (ECR exposed for 18 to 40 hrs, corresponding to Kapton effective fluences of 4.2 x 10(exp 20) to 9.4 x 10(exp 20) atoms/sq cm, respectively) and for space exposed DC 93-500 from the Evaluation of Oxygen Interactions with Materials III (EOIM III) shuttle flight experiment, exposed to LEO atomic oxygen for 2.3 x 10(exp 20) atoms/sq cm. Pristine controls were also evaluated. A ground-to-space correlation value was determined based on correlation values for four contact depths (150, 200, 250, and 300 nm), which represent the near surface depth data. The results indicate that the Kapton effective atomic oxygen fluence in the ECR facility needs to be 2.64 times higher than in LEO to replicate equivalent exposure damage in the ground test silicone as occurred in the space exposed silicone.

deGroh, Kim K.↗

The NASA Space Radiation Research Program

We present a comprehensive overview of the NASA Space Radiation Research Program. This program combines basic research on the mechanisms of radiobiological action relevant for improving knowledge of the risks of cancer, central nervous system and other possible degenerative tissue effects, and acute radiation syndromes from space radiation. The keystones of the NASA Program are five NASA Specialized Center's of Research (NSCOR) investigating space radiation risks. Other research is carried out through peer-reviewed individual investigations and in collaboration with the US Department of Energies Low-Dose Research Program. The Space Radiation Research Program has established the Risk Assessment Project to integrate data from the NSCOR s and other peer-reviewed research into quantitative projection models with the goals of steering research into data and scientific breakthroughs that will reduce the uncertainties in current risk projections and developing the scientific knowledge needed for future individual risk assessment approaches and biological countermeasure assessments or design. The NASA Space Radiation Laboratory (NSRL) at Brookhaven National Laboratory was created by the Program to simulate space radiation on the ground in support of the above research programs. New results from NSRL will be described.

Cucinotta, Francis A.↗

A Stochastic Model of Space Radiation Transport as a Tool in the Development of Time-Dependent Risk Assessment

A new computer model, the GCR Event-based Risk Model code (GERMcode), was developed to describe biophysical events from high-energy protons and heavy ions that have been studied at the NASA Space Radiation Laboratory (NSRL) [1] for the purpose of simulating space radiation biological effects. In the GERMcode, the biophysical description of the passage of heavy ions in tissue and shielding materials is made with a stochastic approach that includes both ion track structure and nuclear interactions. The GERMcode accounts for the major nuclear interaction processes of importance for describing heavy ion beams, including nuclear fragmentation, elastic scattering, and knockout-cascade processes by using the quantum multiple scattering fragmentation (QMSFRG) model [2]. The QMSFRG model has been shown to be in excellent agreement with available experimental data for nuclear fragmentation cross sections

Kim, Myung-Hee Y.↗

Verification of Dosimetry Measurements with Timepix Pixel Detectors for Space Applications

The current capabilities of modern pixel-detector technology has provided the possibility to design a new generation of radiation monitors. Timepix detectors are semiconductor pixel detectors based on a hybrid configuration. As such, the read-out chip can be used with different types and thicknesses of sensors. For space radiation dosimetry applications, Timepix devices with 300 and 500 microns thick silicon sensors have been used by a collaboration between NASA and University of Houston to explore their performance. For that purpose, an extensive evaluation of the response of Timepix for such applications has been performed. Timepix-based devices were tested in many different environments both at ground-based accelerator facilities such as HIMAC (Heavy Ion Medical Accelerator in Chiba, Japan), and at NSRL (NASA Space Radiation Laboratory at Brookhaven National Laboratory in Upton, NY), as well as in space on board of the International Space Station (ISS). These tests have included a wide range of the particle types and energies, from protons through iron nuclei. The results have been compared both with other devices and theoretical values. This effort has demonstrated that Timepix-based detectors are exceptionally capable at providing accurate dosimetry measurements in this application as verified by the confirming correspondence with the other accepted techniques.

Kroupa, M.↗

Effects Of Five-Ion Galactic Cosmic Radiation Simulation On Immune Function, Brain, And Behavior In Male And Female Mice

Exposure to galactic cosmic radiation is a principal consideration of spaceflight missions, and with upcoming missions to the Moon and Mars, it is increasingly imperative to elucidate the effects of space travel beyond the lower Earth orbit. Additionally, with the first female astronaut to soon travel to the Moon there is a strong need to understand the biological sex differences to adaptation to the deep space environment. While the effects of spaceflight on the nervous system are not fully known, studies in animal models have shown that exposure to ionizing radiation can cause neuronal damage and lead to downstream cognitive and behavioral deficits. To simulate the type of radiation exposure occurring during spaceflight, model organisms can be exposed to relevant doses via Five-Ion Galactic Cosmic Radiation Simulation at the NASA National Space Radiation Laboratory at Brookhaven National Laboratory. We have investigated the neurobehavioral responses to space environment-like radiation exposure. Male and female 23–24-week-old mice (age-matched to average astronaut age) were exposed to 5, 15 and 50 cGy. Following exposure, immune, brain and behavioral (sensorimotor, risk-taking and cognitive) measures were acquired at ‘Acute’ (IR+24hrs, IR+72hrs), ‘Intermediate’ (IR+14 days) and ‘Delayed’ (IR+28 to IR+124 days) to inform biological responses anticipated during a transit to Moon and Mars. There were pronounced sex differences observed in all outcome measurements, while very few radiation induced effects were observed. Those dose effects that were observed were primarily in cytokine expression and less so in behavioral measurements. Further studies will investigate if radiation, microgravity and social isolation combine synergistically to trigger an oxidative stress response that alters immune homeostasis, brain structure/function, and neurobehavioral/cognitive performance, ultimately to characterize risks and identify appropriate countermeasures in both women and men in anticipation of future deep space missions.

Stephanie Puukila↗

The International Space Station: A National Science Laboratory

After more than a decade of assembly missions and on the heels of the final voyage of Space Shuttle Discovery, the International Space Station (ISS) has reached assembly completion. With visiting spacecraft now docking with the ISS on a regular basis, the Station now serves as a National Laboratory to scientists back on Earth. ISS strengthens relationships among NASA, other Federal entities, higher educational institutions, and the private sector in the pursuit of national priorities for the advancement of science, technology, engineering, and mathematics. In this lecture we will explore the various areas of research onboard ISS to promote this advancement: (1) Human Research, (2) Biology & Biotechnology, (3) Physical & Material Sciences, (4) Technology, and (5) Earth & Space Science. The ISS National Laboratory will also open new paths for the exploration and economic development of space.

Giblin, Timothy W.↗

NASA Facility for the Study of Space Radiation Effects

Space particulate radiation from the Van Allen belts, solar flares, galactic cosmic, and manmade sources have energies and fluxes which are capable of producing damage in space mission payloads. NASA - Langley Research Center, Hampton, Virginia, has initiated the construction of a ground-based Space Radiation Effects Laboratory which simulates most of the space particulate energy spectrum and which can be used in a radiation research program for minimizing or eliminating deleterious radiation effects. A 600-megaelectronvolt synchrocyclotron of variable energy and electron accelerators from 1 to 10 megaelectronvolts will be included in the laboratory for accelerated testing. The plan of the proposed test areas reflects the latest advances in the state of the art as it pertains to the engineering and basic experimental requirements in flexibility, radiation background levels, shielding, and isolation. The laboratory operational plan permits three Virginia institutions of higher learning to cooperate with the Langley Research Center in carrying out radiation programs.

RADIATION EFFECT↗

Experiment definition phase shuttle laboratory: LDRL-10.6 experiment

Progress is reported in the development of the space shuttle laboratory laser data relay link. The system transmittance of various surfaces was considered in order to examine the coating tradeoffs for the beryllium mirrors. The results of six coating combinations considered are summarized. It is recommended that silver coatings be used throughout the system. Design of the pre-expander and a preliminary alignment procedure implemented to align all optical elements to the reference mechanical axis (the rotational axis of the outer gimbal bearing located between the two Gregorian telescopes) are included. The local oscillator subsystem, consisting of the laser, Stark cell, Stark cell electronics, power supply, starting circuit, and conditioning optics were completed and installed in the optimechanical subsystem and operation against a 10.6 micrometer source was attempted. Preliminary measurements of the HgCdTe mixer showed that this critical element was inoperative and in subsequent tests the receiver front end electronics had also failed. Possible reasons for these failures and corrective action and steps to prevent future recurrence are discussed.

Source record↗

Optical characterization of solar concentrator mirrors using the solar beam of the JPL 25-foot space simulator

The Jet Propulsion Laboratory 25-foot space simulator with its 5.8-m (19-ft) diameter simulated solar beam provides an excellent facility for measuring the optical characteristics of parabolic solar concentrator panels and gores. The virtual source position and size were determined by using a single lamp of the 37 xenon 30-kW source array with only the center lens in the 19-channel optical mixer. This data was used to define the optical test geometry, and it allowed accurate measurement of focal length and surface deviations of the mirror under test. A flux distribution of a typical solar concentrator placed directly on the solar beam gives measurements of performance at the focal point of the parabolic surface.

Argoud, M. J.↗

Applied human factors research at the NASA Johnson Space Center Human-Computer Interaction Laboratory

The applied human factors research program performed at the NASA Johnson Space Center's Human-Computer Interaction Laboratory is discussed. Research is conducted to advance knowledge in human interaction with computer systems during space crew tasks. In addition, the Laboratory is directly involved in the specification of the human-computer interface (HCI) for space systems in development (e.g., Space Station Freedom) and is providing guidelines and support for HCI design to current and future space missions.

Rudisill, Marianne↗

Modeling of PCG fluid dynamics: Salient results

Materials processing in space-based laboratories has already yielded higher quality crystals during previous space flights, and opportunities for several fluids experiments are anticipated during the extended duration missions planned for the future. Crystal growth in space benefits not only from its reduced gravity environment but also from the absence of the hydrostatic pressure which assists certain crystal growth and refinement methods. Gravity-driven phenomena are thus reduced in strength, and a purely diffusive fluid's behavior can be attained. In addition, past materials science experiments have shown that microgravity can also help produce larger crystals. While gravity-related effects are definitely curtailed in space, they are nevertheless present to some degree due to the acceleration environment onboard the spacecraft. This residual acceleration level is comprised of quasi-steady, oscillatory, and transient components, and is caused by a variety of mechanisms. For example, gravity gradient forces produce low frequency disturbances, and the operation of machinery, control thrusters, solar panels, human activity, etc. contribute to higher frequency accelerations. These disturbances are collectively referred to as g-jitter, and they can be deleterious to certain experiments where the minimization of the acceleration level is important. Advanced vibration isolation techniques can be utilized to actively filter out some of the detrimental frequencies and help in obtaining optimum results. However, the successful application of this technology requires the detailed analysis of candidate fluids experiments to gauge their response to g-jitter and to determine their acceleration sensitivities. Several crystal growth experiments in the Protein Crystal Growth (PCG) area, besides others, are expected to be carried out on future shuttle flights and on Space Station Freedom. The need for vibration isolation systems or components for microgravity science experiments can be expected to grow as experiments and available hardware becomes more complex. This technology will also find increased application as the science community develops an awareness of their specific needs relative to the environment available in manned space missions. Vibration isolation research strives to develop a microgravity environment requirement that defines tolerance limits on the allowable g-level, and provides the required technology to achieve it. This effort will assist in establishing the tolerable acceleration levels for specific fluids experiments. The primary effort is directed towards modeling PCG and the approach undertaken for this investigation is outlined. The objectives of this research are: (1) to computationally determine vibration sensitivity of protein crystal growth experiments; (2) determine if these experiments can benefit from vibration isolation techniques; and (3) provide realistic requirements for vibration isolation technology.

Ramachandran, N.↗

United States/Russia Space Cooperation Documentary

This video documents the initiative to develop a multinational, permanent space research laboratory. Historical background on the U.S. and Soviet manned space flight program as well as joint efforts such as the Apollo-Soyuz link up is shown. The current initiative will begin with collaborative missions involving NASA's space shuttle and Russia's Mir space station, and culminate in a permanently manned space station involving the U.S., Russia, Japan, Canada, and ESA. Shown are computer simulations of the proposed space station. Commentary is provided by the NASA administrator, former astronauts, cosmonauts, and Russian and American space experts.

Source record↗

On the Development of a Magnetically Vectored Variable ISP Plasma Rocket

The development of a Magnetically Vectored Variable I(sub sp) Plasma Rocket at the Advanced Space Propulsion Laboratory (ASPL) is in progress at NASA's Johnson Space Center. The facility is using a small, 3.2 m tandem mirror device to study the application of RF heated magnetically contained plasmas for space propulsion. The central cell radius is 0.1 m and fields of 0.2 T and 2 T are possible in the central and end-cell mirror sections, respectively. A magnetoplasmadynamic (MPD) injector has just been acquired and will be used along with other methods of plasma refueling. A 1 MW magnet power supply upgrade is being developed with full implementation by the Spring of 1997. Two microwave systems for discharge initiation and plasma heating at 2.45 GHz and 14.0 GHz, respectively, are in operation. Additionally, RF systems with 200 kW and 1 MW of power are being modified and conditioned for operation. The concept provides electrode-less operation and variable thrush'specific impulse at constant power (200 -30 N /5000-30,000 seconds at 10 MW with a 60% efficiency). Optimization for speed or payload are possible with the same engine, giving the rocket great flexibility. Missions to Mars in 90 days are described, and missions to Pluto are under study.

Feliciano, Enectali Figueroa↗