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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Salts as Additives: A Route to Improve Performance and Stability of n-Type Organic Electrochemical Transistors

Organic electrochemical transistors (OECTs) are becoming increasingly ubiquitous in various applications at the interface with biological systems. However, their widespread use is hampered by the scarcity of electron-conducting (n-type) backbones and the poor performance and stability of the existing n-OECTs. Here, we introduce organic salts as a solution additive to improve the transduction capability, shelf life, and operational stability of n-OECTs. We demonstrate that the salt-cast devices present a 10-fold increase in transconductance and achieve at least one year-long stability, while the pristine devices degrade within four months of storage. The salt-added films show improved backbone planarity and greater charge delocalization, leading to higher electronic charge carrier mobility. These films show a distinctly porous morphology where the interconnectivity is affected by the salt type, responsible for OECT speed. The salt-based films display limited changes in morphology and show lower water uptake upon electrochemical doping, a possible reason for the improved device cycling stability. Our work provides a new and easy route to improve n-type OECT performance and stability, which can be adapted for other electrochemical devices with n-type films operating at the aqueous electrolyte interface.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Ultrarapid crystallization of low-dimensional perovskite with excellent stability for future high-throughput fabrication

We report perovskite solar cells (PSCs) as an emerging photovoltaic technique have achieved exceptional power conversion efficiency (PCE) up to 25.7% after fast development over the past decade. But currently some critical issues are still not well addressed in terms of realizing large-scale fabrication, for example, fast fabrication of high-quality perovskite film with good stability. Here, we demonstrate the use of stable and fast-crystallizing low-dimensional (LD) perovskite thin films as the light absorber with only a 10 s annealing time at 250 °C, delivering a PCE of 18.16%. The crystallization and photoelectric properties of LD perovskite are well illustrated. The reduction in the annealing time will dramatically increase the productivity of PSCs. The PSCs based on rapidly annealed LD perovskite thin films exhibit excellent stability, with only 12% loss of PCE after 1000 h storage at 85 °C and 40-70% relative humidity.

14 SOLAR ENERGY↗
DOE OSTI2025

Influence of Electrolyte Additives on Interfacial Stability of Manganese-Rich Lithium-Ion Battery Cathodes

Affordable, long-lasting energy storage has become critical to support increased electricity demand in recent years. Cobalt-free, lithium- and manganese-rich lithium nickel manganese oxide (LMR-NM) cathodes stand to reduce cost and supply-chain concerns associated with traditional cobalt-containing cathodes for lithium-ion batteries by leveraging more earth-abundant materials; however, they have shown issues with long-term cycling stability. Here, we investigate lithium difluoro(oxalate)borate (LiDFOB), tris(trimethylsilyl) phosphite (TMSPi), and vinylene carbonate (VC) electrolyte additives for their ability to improve cycling performance of LMR-NM (0.3 Li 2 MnO 3 + 0.7 LiMn 0.5 Ni 0.5 0 2 ) cells. Cryogenic scanning transmission electron microscopy (cryo-STEM) with electron energy loss spectroscopy enables the construction of a structure–function relationship between cathode electrolyte interphase (CEI) characteristics and the electrochemical performance of cells aged with these additives. We find the combination of 2 wt % TMSPi + 1 wt % LiDFOB performs better than any single additive, achieving a 28% improvement in specific capacity over the baseline electrolyte after long-term cycling. We attribute this to LiDFOB mitigating Mn ion dissolution, with cryo-STEM showing Mn stabilized up to the CEI surface, coupled with improved CEI structure and chemistry enabled by TMSPi, evidenced by a moderately thick (∼7–15 nm) CEI that appears to protect against further electrolyte reactions with the particle. These results, achieved through site-specific nanoscale characterization, directly reveal mechanisms through which electrolyte engineering can improve the performance of earth-abundant cathodes, enabling informed development of more affordable and reliable batteries to meet future energy storage needs.

25 ENERGY STORAGE↗
DOE OSTI2026

Thermo-hydro-mechanical analysis of subsurface ice-based thermal energy storage

Ice-based thermal energy storage systems are widely utilized for cooling and managing peak electrical demand globally, offering daily or weekly storage capabilities for both individual homes and larger office buildings. However, scaling these systems for district-level cooling or integrating them with renewable energy sources presents challenges, especially in accommodating larger volumes and addressing seasonal storage requirements in densely populated urban areas. This paper proposes a novel solution by evaluating subsurface ice-based thermal energy storage, in which the underground is subjected to seasonal freeze/thaw cycles. However, these cycles may influence ground behavior, affecting pore pressure and inducing ground movement. To systematically investigate these challenges, we enhance the TOUGH-FLAC simulator by integrating water/ice phase change capabilities and updating the effective stress–strain constitutive relation. Both modifications are validated against analytical solutions or experimental data. Through numerical simulations spanning a decade with ten seasonal freeze/thaw cycles, we evaluate the performance and long-term stability of a generic subsurface ice-based thermal energy storage system, considering factors such as ground permeability, freezing pipe spacing, freeze/thaw damage, and glycol solution temperature. The simulations indicate that ice formation induces pore pressure variations that drive seasonal surface heave and settlement, controlled by ground permeability, pipe spacing, and glycol solution temperature, along with tensile and localized shear deformation around freeze pipes. This highlights the need for accurate ground property characterization and geomechanical analysis for subsurface ice-based thermal energy storage.

Ground freezing↗
DOE OSTI2022

Impact of Quaternary-Pumped Storage Hydropower on Frequency Response of U.S. Western Interconnection with High Renewable Penetrations: Preprint

As renewable penetration increases in the United States, maintaining stability and reliability of low-inertia power grid by providing sufficient frequency control capability becomes a challenge. Advanced pumped storage hydro technologies (APSH) will be expected to play an important role for future grid as not only an energy supplier, but also as an ancillary services provider. This paper studies the impact of using quaternary pumped storage hydropower (Q-PSH), as one of the newly proposed APSH technology, to provide primary frequency response. To quantify the impact of Q-PSH on frequency response of the U.S. Western Interconnection, a user-defined dynamic model of Q-PSH is developed on the GE Positive Sequence Load Flow (PSLF) platform and is implemented in a set of detailed U.S. Western Electricity Coordination Council (WECC) planning cases in which renewable penetration levels are 20%, 40%, 60% and 80%. Simulation results show that Q-PSH can help improve frequency nadir and settling frequency comparing to the conventional PSH.

frequency response↗
DOE OSTI2025

In situ Mössbauer spectroscopy confirms that fluoroethylene carbonate stabilizes Fe 4+ in charged NaFeO 2

The development of Fe-based materials for energy storage is hindered by difficulties in understanding Fe-ion redox. Here we demonstrate in situ Mössbauer spectroscopy to monitor the dynamics of Fe 4+ in charged NaFeO 2 without disassembling the cell. Furthermore, this allows direct confirmation that a fluoroethylene carbonate (FEC) additive stabilizes the otherwise rapidly degrading Fe 4+ .

Abdul Razak, Iddrisu Bachokun [University of Tenne↗
DOE OSTI2025

Typical Use Cases for Energy Storage in Rural Areas

Public power utilities and cooperatives play a crucial role in delivering reliable and affordable electricity to remote and sparsely populated regions. Unlike their urban counterparts, these utilities often face a unique set of challenges that can complicate their operations and service delivery. One of the primary challenges is the vast geographical area they must cover, which often results in higher transmission and distribution costs per customer. Additionally, public power utilities in rural areas often cannot afford the investments required to maintain and upgrade aging grid infrastructure to provide reliable and resilient power or withstand the impacts of recurring, severe weather events, which can cause extended outages and disrupt service delivery. Energy storage has emerged as a promising tool to help public power utilities meet these challenges. By enabling the storage of excess energy during low demand periods and providing a source of backup electricity during outages, energy storage systems can help utilities balance supply and demand more effectively. Additionally, they can help integrate a portfolio of various energy sources, reduce the need for expensive peak power purchases and provide ancillary services that stabilize the grid. This white paper describes potential use cases for energy storage in rural areas as well as documents a set of relevant example projects by project types.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Evolution of thermo-mechanical properties of concrete with calcium aluminate cement and special aggregates for energy storage

Highlights: • CAC Concrete with stable aggregates is suitable for high temperatures with cycles. • Concrete suffered performance changes after the first thermal cycle (dehydration). • Subsequent thermal cycles showed stabilization and slight performance decreases. With the ever-expanding presence of solar energy, the design of cost-efficient heat energy storage systems is becoming increasingly relevant. Concrete is a potential solid material for these systems but raises questions of its response at high temperatures in operating conditions. This work studies concrete designed with calcium aluminate cement and three types of aggregates that are stable at high temperatures. The designed concrete mixes were exposed to thermal cycles (290–550 °C), and their thermal fatigue response was evaluated with mechanical, cracking, thermal, and microstructural analyses at room temperature after heat cycles. The obtained results show that the main changes are mostly produced after the first thermal cycle and are stabilized during successive thermal cycles, with only a slight decrease in the thermo-mechanical properties. The results showed stabilization of cracking, crack widths between 10 and 80 μm, reduction of compressive strength, around 50–65%, and reduction of the thermal conductivity by 30%.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Combined Precursor Engineering and Grain Anchoring Leading to MA‐Free, Phase‐Pure, and Stable α‐Formamidinium Lead Iodide Perovskites for Efficient Solar Cells

Abstract α‐Formamidinium lead iodide (α‐FAPbI 3 ) is one of the most promising candidate materials for high‐efficiency and thermally stable perovskite solar cells (PSCs) owing to its outstanding optoelectrical properties and high thermal stability. However, achieving a stable form of α‐FAPbI 3 where both the composition and the phase are pure is very challenging. Herein, we report on a combined strategy of precursor engineering and grain anchoring to successfully prepare methylammonium (MA)‐free and phase‐pure stable α‐FAPbI 3 films. The incorporation of volatile FA‐based additives in the precursor solutions completely suppresses the formation of non‐perovskite δ‐FAPbI 3 during film crystallization. Grains of the desired α‐phase are anchored together and stabilized when 4‐ tert ‐butylbenzylammonium iodide is permeated into the α‐FAPbI 3 film interior via grain boundaries. This cooperative scheme leads to a significantly increased efficiency close to 21 % for FAPbI 3 perovskite solar cells. Moreover, the stabilized PSCs exhibit improved thermal stability and maintained ≈90 % of their initial efficiency after storage at 50 °C for over 1600 hours.

Ling, Xufeng↗
DOE OSTI2025

Electronic Structural Optimization of the Air Electrodes for Reversible Protonic Ceramic Electrochemical Cells via IIIA Cation Doping

Reversible protonic ceramic electrochemical cells (R-PCECs) have emerged as a novel technology for clean and efficient energy generation and storage. Improving the oxygen and proton conduction characteristics and stability of air electrodes at intermediate temperatures is crucial for achieving a high performance. Herein, we optimize the electronic structure of a state-of-the-art PrBa 0.8 Ca 0.2 Co 2 O 5+δ (PBCC) air electrode via doping IIIA cations (Al 3+ , Ga 3+ , and In 3+ ). Also, it is shown that PrBa 0.8 Ca 0.2 Co 1.9 Ga 0.10 O 5+δ (PBCCGa 0.10 ) exhibits improved oxygen reaction activity and hydration capability. Density functional theory calculations confirm that Ga doping provides the most favorable electronic structure. An R-PCEC with PBCCGa 0.10 achieves a peak power density of 2.21 W cm -2 and a current density of −4.64 A cm -2 at 1.3 V at 650 °C. Additionally, the PBCCGa 0.10 electrode performs good operational stability in FC mode (for about 100 h), EC mode (for about 100 h), and reversible cyclic testing (over 200 h) at 600 °C.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2022

Photoelectrochemical CO 2 Reduction toward Multicarbon Products with Silicon Nanowire Photocathodes Interfaced with Copper Nanoparticles

The development of photoelectrochemical systems for converting CO 2 into chemical feedstocks offers an attractive strategy for clean energy storage by directly utilizing solar energy, but selectivity and stability for these systems have thus been limited. Here, we interface silicon nanowire (SiNW) photocathodes with a copper nanoparticle (CuNP) ensemble to drive efficient photoelectrochemical CO 2 conversion to multicarbon products. This integrated system enables CO 2 -to-C 2 H 4 conversion with faradaic efficiency approaching 25% and partial current densities above 2.5 mA/cm 2 at -0.50 V vs RHE, while the nanowire photocathodes deliver 350 mV of photovoltage under 1 sun illumination. Under 50 h of continual bias and illumination, CuNP/SiNW can sustain stable photoelectrochemical CO 2 reduction. In conclusion, these results demonstrate the nanowire/catalyst system as a powerful modular platform to achieve stable photoelectrochemical CO 2 reduction and the feasibility to facilitate complex reactions toward multicarbons using generated photocarriers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Population ecology and biogeochemical implications of ssDNA and dsDNA viruses along a permafrost thaw gradient

Anthropogenic-driven climate change is accelerating permafrost thaw, threatening to release vast carbon stores through increased microbial activity. While microbial roles are increasingly studied, the contributions of viruses remain largely unexplored, in part due to soil-associated technical challenges that have hindered their detection and characterization. Here, we applied an optimized virion enrichment workflow along a permafrost thaw gradient, identifying 9,963 viral populations (vOTUs), including single- and double-stranded DNA viruses, with 99.9% novelty compared to other soils. Hosts were predicted for 38% of vOTUs, spanning nine archaeal, and 36 bacterial phyla, 22% of which were linked to metagenome-assembled genomes, including key carbon-cycling taxa. Genomic analyses revealed 811 putative auxiliary metabolic genes (AMGs) from 658 vOTUs, nearly half involved in carbon processing. These included 59 glycoside hydrolases (GH) across nine GH families, 45 for monosaccharide degradation, and seven involved in short-chain fatty acid and C1 metabolism, linking viruses to both early and late stages of carbon turnover. Additionally, six vOTUs carried racD, which may stabilize microbial necromass and promote long-term carbon storage. Viral and AMG functional diversity increased with thaw stage, indicating that viruses might participate in a broadening range of microbial metabolic processes as permafrost thaws. These findings expand our understanding of virus contributions in microbial carbon processing and suggest their important role in deciphering soil carbon fate under changing climate conditions.

Biological and medical sciences↗
DOE OSTI2021

Electrodeposition of ligand-free copper nanoparticles from aqueous nanodroplets

Copper nanoparticles have emerged as promising electrocatalysts for energy storage and conversion. Generally, homogenous nanoparticle synthesis requires a stabilizing ligand, which may influence the electrocatalysis. Ligands can be avoided by direct nanoparticle electrodeposition. Here, we extend nanodroplet-mediated electrodeposition to the electrodeposition of copper nanoparticles from aqueous nanodroplets suspended in 0.1 M tetrabutylammonium hexafluorophosphate ([TBA][PF 6 ]) and 1,2-dichloroethane. Stochastic electrochemistry on microelectrodes was used to elucidate nanoparticle growth kinetics for various solution conditions and substrate materials. A study on the effect of surfactants on nanoparticle morphology and growth kinetics demonstrated the surfactant's role as an avenue for morphological control. Nanoparticle morphology was studied by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). Energy-dispersive X-ray Spectroscopy (EDX) confirmed the presence of copper nanoparticles. TEM and Selected Area Electron Diffraction (SAED) confirmed nanoparticle size, morphology, and polycrystallinity. We demonstrate tunable nanoparticle size using cyclic voltammetry on single aqueous nanodroplets by altering the voltammetric sweeping potentials of copper electroreduction. Finite element simulations validate the voltammetric response and ability to control the nanoparticle size with nanometer resolution during a voltammetric sweep. These results inform the electrodeposition of copper nanoparticles from aqueous nanodroplets for important applications, such as the conversion of CO 2 to hydrocarbon fuels.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Insights on seasonal solifluction processes in warm permafrost Arctic landscape using a dense monitoring approach across adjacent hillslopes

Solifluction processes in the Arctic are highly complex, introducing uncertainties in estimating current and future soil carbon storage and fluxes, and assessment of hillslope and infrastructure stability. This study aims to enhance our understanding of triggers and drivers of soil movement of permafrost-affected hillslopes in the Arctic. To achieve this, we established an extensive soil deformation and temperature sensor network, covering 48 locations across multiple hillslopes within a 1 km² watershed on the Seward Peninsula, AK. We report depth-resolved measurements down to 1.8 m depth for May to September 2022, a period conducive to soil movement due to deepening thaw layers and frequent rain events. Over this period, surface movements of up to 334 mm were recorded. In general, these movements occur close to the thawing front, and are initiated as thawing reaches depths of 0.4 to 0.75 m. The largest movements were observed at the top of the south-east facing slope, where soil temperatures are cold (mean annual soil temperatures averaging -1.13°C) and slopes are steeper than 15°. Our analysis highlights three primary factors influencing movements: slope angle, soil thermal conditions, and thaw depth. The latter two significantly impact the generation of pore water pressures at the thaw–freeze interface. Specifically, soil thermal conditions govern the liquid water content, while thaw depth influences both the height of the water column and, consequently, the pressure at the thawing front. These factors affect soil properties, such as cohesion and internal friction angle, which are crucial determinants of slope stability. This underscores the significance of a precise understanding of subsurface thermal conditions, including spatial and temporal variability in soil temperature and thaw depth, when assessing and predicting slope instabilities. Based on our observations, we developed a Factor of Safety proxy that consistently falls below the triggering threshold for all probes exhibiting displacements exceeding 50 mm. This study offers novel insights into patterns and triggers of hillslope movements in the Arctic and provides a venue to evaluate their impact on soil redistribution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Optimization of Preparation Method, Nucleating Agent, and Stabilizers for Synthesizing Calcium Chloride Hexahydrate (CaCl2.6H2O) Phase Change Material

This study investigates improvements in low-cost latent heat storage material calcium chloride hexahydrate (CaCl2.6H2O). Its melting point is between 25 and 28 °C, with relatively high enthalpy (170–190 J/g); however, this phase change material (PCM) shows supercooling and phase separation. In CaCl2.6H2O incongruent melting causes lower hydrates of CaCl2 to form, which affects the overall energy storage capacity and long-term durability. In this work, PCM performance enhancement was achieved by adding SrCl2.6H2O as a nucleating agent and NaCl/KCl as a stabilizer to prevent supercooling and phase separation, respectively. We investigated the PCM preparation method and optimized the proportions of SrCl2.6H2O and NaCl/KCl. Thermal testing for 25 cycles combined with DSC and T-history testing was performed to observe changes in enthalpy, phase transitions and supercooling over the extended period of usage. X-ray diffraction was used to verify crystalline structure in the compounds. It was found that the addition of 2 wt.% of SrCl2.6H2O reduced supercooling from 12 °C to 0 °C compared to unmodified CaCl2.6H2O. The addition of 5 wt.% NaCl or KCl proved to effectively suppress separation and the melting enthalpy achieved was 169 J/g–178 J/g with congruent melting over 25 cycles, with no supercooling and almost no reduction in the latent heat.

42 ENGINEERING↗
DOE OSTI2022

Origin for electrochemically driven phase transformation in the oxygen electrode for a solid oxide cell

The next generation of fuel cells, electrolyzers, and batteries requires higher power, faster kinetics, and larger energy density, which necessitate the use of compositionally complex oxides to achieve multifunctionalities and activity. These compositionally complex oxides may change their phases and structures during an electrochemical process—a so-called “electrochemically driven phase transformation.” The origin for such a phase change has remained obscure. The aim of this paper is to present an experimental study and a theoretical analysis of phase evolution in praseodymium nickelates. Nickelate-based electrodes show up to 60 times greater phase transformation during operation when compared with thermally annealed ones. Theoretical analysis suggests that the presence of a reduced oxygen partial pressure at the interface between the oxygen electrode and the electrolyte is the origin for the phase change in an oxygen electrode. Guided by the theory, the addition of the electronic conduction in the interface layer leads to the significant suppression of phase change while improving cell performance and performance stability.

25 ENERGY STORAGE↗
DOE OSTI2022

Accelerator Physics at NSLS-II: Research Accomplishments in 2022

NSLS-II accelerator physicists are working on scientific support of the NSLS-II operations and start-up of the accelerator systems including Storage Ring, Injector, beam diagnostics, and top-off injection; improvement of beam stability and orbit feedbacks; commissioning of a superconducting wiggler for the HEX beamline; development of a new operation mode for time-resolved experiments. The routine lattice characterization is continued to keep tracking the machine, the storage ring lattice model including strong coupling is developed, and seasonal variations of the ring circumference are studied. The collaboration with the EIC project is ongoing. In the frameworks of three LDRD projects, the physicists are working on the lattice development, studies of collective effects, and specifications of alignment and stability for the NSLS-II accelerator upgrade; novel methods of lattice design and optimization; studies of free-electron laser options; ultrafast electron diffraction and microscopy. Research accomplishments achieved in 2022, are summarized in this report.

43 PARTICLE ACCELERATORS↗