A study of the mechanism of chemical reactivity of nitrogen tetroxide with titanium alloys Quarterly report, 1 Jan. - 31 Mar. 1968
Chemical reaction mechanism of stress corrosion cracking of titanium alloys exposed to liquid nitrogen tetroxide
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Chemical reaction mechanism of stress corrosion cracking of titanium alloys exposed to liquid nitrogen tetroxide
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Role of moisture and hydrogen in hot salt stress corrosion cracking of titanium alloys
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Stress corrosion cracking of Ti alloys in nitrogen tetroxide and methyl alcohol environments in Apollo spacecraft pressure vessels
Reactions between liquid dinitrogen tetraoxide and titanium alloy that result in stress corrosion cracking
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Methanol stress corrosion cracking of Ti-Al-V foil inhibited by pretreatment in aqueous solutions of electrolytes, discussing colloidal character of microcrystallites
Materials development topics include: development of analysis techniques to adjust heterogeneous data; determination of thermal conductivity for AISI 347 stainless steel and elastic moduli and Poisson's ratio for Inconel 718 and Ti 5Al-2.5Sn; embrittlement effects of 1400 psi gaseous hydrogen for alloy 718 and Ti 5Al-2.5Sn; cryogenic radiation damage of Ti 5Al-2.5Sn; and evaluation of prepreg, impregnation, and fabric materials for optimum fibrous graphite properties. Component support topics include: tensile design allowable development of Ti 5Al-2.5Sn for turbopump applications; evaluation of fatigue, fracture toughness, and stress corrosion properties of AA 7039-T63 for pressure vessel applications; development of AISI 347 sheet tensile and creep properties for nozzle applications; evaluation of orbital weld techniques for aluminum line fabrication; material selection of shield materials; development of high load friction and wear properties of hard chrome/gold plate combinations; and evaluation of weld processes for NASS duct coolant channel fabrication.
The susceptibility of Ti-6Al-4V foil to stress corrosion cracking (SCC) by methanol can be decreased by treatment of the foil with 2,4-pentanedione prior to its immersion in the corroding media. It is assumed that such treatments remove from the protective film formed on the foil by exposure to the atmosphere, certain metal ions whose oxides are more readily penetrated by the ions, Na + and Cl- or Fe(3+) and Cl-, present in the corroding media.