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At least 415 records · Page 23

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DOE OSTI2023

Accelerated Materials Design for Molten Salt Technologies Using Innovative High-Throughput Methods

The focus of the project is on building an innovative accelerated materials design platform for molten salt technologies using novel high-throughput methods coupled to data analytics. The main objectives is to predict a FeCrMnNi alloy compositional space with better corrosion resistance than stainless steel 316 and identify new molten salt corrosion mechanisms. The project demonstrates the feasibility to use high-throughput methods coupled to data analytics to accelerate alloy design for extreme environments applications. Using a trained and tested machine learning (ML) model, 2000 FeCrMnNi alloy corrosion rate in molten chloride salts were predicted and a compositional field with corrosion rate lower than 316 stainless steel was identified. The ML model interpretability unveiled multiple features of importance in the model prediction. Some features were expected to be of relative significance, such as work function, surface energy and alloy electronegativity, and the ML model interpretability analysis confirmed those. On the other hand, the most important feature is the diffusion coefficient of Ni in the bulk alloy which indicates that a surface diffusion mechanism plays an important role in the overall corrosion mechanism in molten salts.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Manufacturing of Fabric Electrodes using a High-Throughput Screening Platform for Redox Flow Batteries

The objective of this project is to establish a new manufacturing methodology with machine learning- based high-throughput screening for the design and development of hierarchical structured, high-performance fabric electrodes for redox flow batteries (RFBs). The end goal of the project is to design and manufacture fabric electrodes for RFB applications that can provide 250 mA/cm2 current density operation for 100-cycles with 80% average energy efficiency. This was accomplished by first examining the structure-performance-property linkages of the electrodes provided by our partner, AvCarb. The electrodes’ microstructure was characterized by determining their pore size distribution, tortuosity, specific surface area, and porosity. The ohmic, charge transfer and mass transfer resistances were then calculated using electrochemical impedance spectroscopy. Carbon cloth electrodes showed the greatest resistance, which was dominated by charge transfer resistance, which we believe is related to the surface functionalization. Full cell cycling was used in order to determine the area specific resistance and energy efficiency of the cells. All of this experimental data and the results of the mathematical model (to increase the amount of inputs with parametric sweeping) were used to develop a machine learning-based model for the design of high-performance fabric electrodes. Using the results from the machine learning tool, optimized electrodes were fabricated by AvCarb. The ohmic, charge transfer and mass transfer resistances for these new electrodes were measured, and both performed better than any of the initial samples which had been provided by AvCarb.

25 ENERGY STORAGE↗

DOE OSTI2025

Self-Organization of Plasma-Material Interfaces

The primary goals of the project are a) improve the understanding of transport processes, chemical reactions and plasma-driven self-organization such as stratification and filamentation, formation of anode spots, liquid droplets ejection from cathodes, and plasma electrolysis, b) utilize and share among the project participants computational tools developed by the participants to understand plasma-based surface functionalization and plasma-enabled pattern nucleation in a wide range of scales from nano- to millimeters, and c) use experimental methods and facilities available at the University of Alabama in Huntsville (UAH) and Sandia National Laboratories (SNL) to understand and control plasma processes, reaction pathways and the electric nature of self-organization of the plasma-exposed interface structures.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2025

Toward Thermally Stimuli-Responsive Polymeric Vesicles Fabricated by Block Copolymer Blends for Nanocarriers

Polymeric vesicles, characterized by enhanced colloidal stability, excellent mechanical properties, controllable surface functionality, and adjustable membrane thickness, are extremely useful in nano- and bio-technology for potential applications as nanosized carriers for drugs and enzymes. However, a few preparative steps are necessary to achieve a unilamellar vesicle with a narrow size distribution. Herein, we report the spontaneous formation of unilamellar polymeric vesicles with nanometer sizes (<50 nm), fabricated by simply mixing diblock copolymers (P(EO-AGE)(2K-2K) and P(EO-AGE)(0.75K-2K)) with differing hydrophilic mass fractions in aqueous solutions. Depending on the mixing ratio of block copolymers and the temperature, the block copolymer mixtures self-assemble into various nanostructures, such as spherical and cylindrical micelles, or vesicles. The self-assembled structures of the block copolymer mixtures were characterized by small-angle neutron scattering, resulting in a phase diagram drawn as a function of temperature and the mixing condition. Notably, the critical temperature for the micelle-to-vesicle phase transition can be easily controlled by altering the mixing conditions; it decreases with an increase in the concentration of one of the block copolymers.

block copolymers↗

DOE OSTI2023

One-Pot Synthesis of Melamine Formaldehyde Resin-Derived N-Doped Porous Carbon for CO 2 Capture Application

The design and synthesis of porous carbons for CO 2 adsorption have attracted tremendous interest owing to the ever-soaring concerns regarding climate change and global warming. Herein, for the first time, nitrogen-rich porous carbon was prepared with chemical activation (KOH) of commercial melamine formaldehyde resin (MF) in a single step. It has been shown that the porosity parameters of the as-prepared carbons were successfully tuned by controlling the activating temperature and adjusting the amount of KOH. Thus, as-prepared N-rich porous carbon shows a large surface area of 1658 m 2 /g and a high N content of 16.07 wt%. Benefiting from the unique physical and textural features, the optimal sample depicted a CO 2 uptake of up to 4.95 and 3.30 mmol/g at 0 and 25 °C under 1 bar of pressure. More importantly, as-prepared adsorbents show great CO 2 selectivity over N 2 and outstanding recyclability, which was prominently important for CO 2 capture from the flue gases in practical application. An in-depth analysis illustrated that the synergetic effect of textural properties and surface nitrogen decoration mainly determined the CO 2 capture performance. However, the textural properties of carbons play a more important role than surface functionalities in deciding CO 2 uptake. In view of cost-effective synthesis, outstanding textural activity, and the high adsorption capacity together with good selectivity, this advanced approach becomes valid and convenient in fabricating a unique highly efficient N-rich carbon adsorbent for CO 2 uptake and separation from flue gases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1969

Hermetically sealed pump

Mechanically simple, hermetically-sealed pump utilizes pumped fluid for lubrication. The rotor, having helical grooves on the outer surface, functions as both a bearing and pump.

Ludwig, L. P.↗

NASA NTRS1974

Determination of space vehicle contamination

The contamination and degradation of externally exposed sensitive experimental and functional surfaces of the Skylab by the self-induced atmosphere surrounding the vehicle are studied. It is shown that the major contamination sources of long-term deposits on Skylab are primarily outgassing from nonmetallic coatings and rocket engine exhaust products. Analysis showed that the characteristic decay time of the outgassing source rate may be as long as 4100 hr, and that essentially 20% of RCS deposits that stick at temperatures of 0 C will remain after sublimating at a rate whose characteristic decay time is 72 hr.

Rantanen, R. O.↗

NASA NTRS1982

Acoustic propagation in rigid ducts with blockage

Acoustic levitation has been suggested for moving nonmagnetic material in furnaces for heat processing in space experiments. Basically, acoustic standing waves under resonant conditions are excited in the cavity of the furnace while the material blockage is located at a pressure node and thus at a maximum gradient. The position of the blockage is controlled by displacing the node as a result of frequency change. The present investigation is concerned with the effect of blockage on the longitudinal and transverse resonances of a cylindrical cavity, taking into account the results of a one-dimensional and three-dimensional (3-D) analysis. Based on a Green's function surface element method, 3-D analysis is tested experimentally and proved to be accurate over a wide range of geometric parameters and boundary shapes. The shift in resonance depends on the change in pressure gradient and duct shortening caused by the blockage.

El-Raheb, M.↗

NASA NTRS1983

Acoustic loading in planar networks

The acoustic loading in a complex planar network of ducts is determined by a method in which Green function surface elements are used. The network consists of straight ducts, elbows and branched ducts. A transfer matrix technique is developed in which each duct is treated separately and the matrix of the influence coefficients is transformed to tri-diagonal form allowing efficient inversion.

El-Raheb, M.↗

NASA NTRS1993

Shuttle primary reaction control system engine exhaust plume contamination effects

Space Shuttle proximity operations constitute an important part of the SSF induced external environment. The impingement of primary reaction control system (PRCS) engine plumes on SSF functional surfaces during docking or berthing and separation leads to concerns about molecular contamination and high speed particle impact. The Shuttle Plume Impingement flight Experiment (SPIE) was designed to provide a direct measure of both the molecular contamination and particle impact rates produced by Shuttle PRCS engines in the LEO environment. The measured permanent deposition produced by PRCS engine firings was less than that assumed in current SSF programatic assessments. Only two to three possible high velocity particle impact pits were observed on the RMS end effector hardware.

Koontz, Steve↗

NASA NTRS1952

Axisymmetric supersonic flow in rotating impellers

General equations are developed for isentropic, frictionless, axisymmetric flow in rotating impellers with blade thickness taken into account and with blade forces eliminated in favor of the blade-surface function. It is shown that the total energy of the gas relative to the rotating coordinate system is dependent on the stream function only, and that if the flow upstream of the impeller is vortex-free, a velocity potential exists which is a function of only the radial and axial distances in the impeller. The characteristic equations for supersonic flow are developed and used to investigate flows in several configurations in order to ascertain the effect of variations of the boundary conditions on the internal flow and the work input. Conditions varied are prerotation of the gas, blade turning rate, gas velocity at the blade tips, blade thickness, and sweep of the leading edge.

Goldstein, Arthur W↗

NASA NTRS2012

Implications of Adhesion Studies for Dust Mitigation on Thermal Control Surfaces

Experiments measuring the adhesion forces under ultrahigh vacuum conditions (10 (exp -10) torr) between a synthetic volcanic glass and commonly used space exploration materials have recently been described. The glass has a chemistry and surface structure typical of the lunar regolith. It was found that Van der Waals forces between the glass and common spacecraft materials was negligible. Charge transfer between the materials was induced by mechanically striking the spacecraft material pin against the glass plate. No measurable adhesion occurred when striking the highly conducting materials, however, on striking insulating dielectric materials the adhesion increased dramatically. This indicates that electrostatic forces dominate over Van der Waals forces under these conditions. The presence of small amounts of surface contaminants was found to lower adhesive forces by at least two orders of magnitude, and perhaps more. Both particle and space exploration material surfaces will be cleaned by the interaction with the solar wind and other energetic processes and stay clean because of the extremely high vacuum (10 (exp -12) torr) so the atomically clean adhesion values are probably the relevant ones for the lunar surface environment. These results are used to interpret the results of dust mitigation technology experiments utilizing textured surfaces, work function matching surfaces and brushing. They have also been used to reinterpret the results of the Apollo 14 Thermal Degradation Samples experiment.

Gaier, James R.↗

NASA NTRS2010

Barium Depletion in the NSTAR Discharge Cathode After 30,000 Hours of Operation

Dispenser hollow cathodes rely on a consumable supply of barium released by impregnant materials in the pores of a tungsten matrix to maintain a low work function surface. Examinations of cathode inserts from long duration ion engine tests show deposits of tungsten at the downstream end that appear to block the flow of barium from the interior. In addition, a numerical model of barium transport in the insert plasma indicates that the barium partial pressure in the insert may exceed the equilibrium vapor pressure of the dominant barium-producing reaction, and it was postulated previously that this would suppress barium loss in the upstream part of the insert. New measurements of the depth of barium depletion from a cathode insert operated for 30,352 hours reveal that barium loss is confined to a narrow region near the downstream end, confirming this hypothesis.

plasma transport↗

NASA NTRS2016

DNA Photolithography with Cinnamate Crosslinkers

The present invention relates generally to cinnamate crosslinkers. Specifically, the present invention relates to gels, biochips, and functionalized surfaces useful as probes, in assays, in gels, and for drug delivery, and methods of making the same using a newly-discovered crosslinking configuration.

Feng, Lang↗

NASA NTRS2019

Innovative Compact Coronagraph Approach for Balloon-Borne Investigation of Temperature and Speed of Electrons in the Corona (BITSE)

We are developing an innovative compact coronagraph for studying the physical conditions in the solar wind acceleration region. This paper presents the new development of the compact coronagraph for the investigation of temperature and speed of electrons in the solar corona. The proposed compact coronagraph is a one stage externally occulted coronagraph without internal occulter or Lyot stop mask. The key of the new idea is to set the inner field cutoff at the External Occulter (EO) much smaller than the specified inner field cutoff. A second occulter on the surface of the detector array removes the remaining diffraction. The occulter on the detector surface functions similar to an internal occulter with the Inner Field of View Cutoff (IFoVC) exactly the same as specified. For BITSE, the desired inner field cutoff is 3 R, but the cutoff at EO is only 1.5 R☉. The diffraction analysis shows that in the sensor plane, the diffraction intensity at the 3 R☉ is not sensitive to the EO cutoff, either at 1.5 R☉ or close to 3 R☉. The advantage of having a smaller EO cutoff is that the vignetting decreased for the Field of View (FoV) near 3 R☉, therefore, the signal increases. Meanwhile, the diffraction of Point Spread Function is much less in the radial direction, which not only increases the image quality around 3 R☉, but also increases the encircled energy and signal to noise ratio. In other words, the data is useful right at 3 R☉! The BITSE optical design and diffraction analysis will be presented in detail. The simulation shows the signal to noise ratio obtained from the diffraction and vignetting data enables corona temperature and speed measurement.

Gong, Qian↗

NASA NTRS2019

Innovative Compact Coronagraph Approach for Balloon-Borne Investigation of Temperature and Speed of Electrons in the Corona (BITSE)

Gong, Qian↗

DOE OSTI2016

Durable polymer-aerogel based superhydrophobic coatings: a composite material

Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140.degree. and a contact angle hysteresis of less than about 1.degree.. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores.

36 MATERIALS SCIENCE↗

DOE OSTI2018

Nanocomposite Coatings with Tunable Properties Prepared by Atomic Layer Deposition

We report that nanocomposite coatings, comprised of a precisely blended mixture of components, have diverse applications in microelectronics, optics, sensors, and solid-state detectors. By varying the composition of the mixture, the electrical, optical, and physical properties of the coatings can be “tuned” over almost the full range of the individual components, and can sometimes yield properties distinct from those of any of the constituents. There are many techniques for producing nanocomposite coatings, but atomic layer deposition (ALD) is particularly well suited for controlling the properties of the fabricated coatings. ALD uses alternating cycles of gaseous precursors to a solid surface to deposit materials in an atomic layer-by-layer fashion. Because a chemical reaction on the surface naturally terminates when the surface functional groups are all reacted, the amount of material deposited in one ALD cycle is easily controlled. This self-limiting property, coupled with facile diffusion of the precursor vapors into narrow pores and voids, allows complex, 3-dimensional substrates to be coated with excellent uniformity and conformality. ALD can be used to deposit a wide variety of materials including metal oxides, nitrides, sulfides, and even pure elements. By alternating between two materials (e.g., a metal and a metal oxide), we can synthesize complex nanocomposite coatings. Lastly, the thickness of the coating is controlled by the total number of ALD cycles performed, and the composition is controlled by the ratio of the ALD cycles executed for each of the two components.

36 MATERIALS SCIENCE↗