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At least 415 records · Page 23

Air classification of forest residue for tissue and ash separation efficiency

The goal of this Case Study was to evaluate the performance of air classification of logging residues toward meeting conversion CMAs for carbon and ash contents, as compared to the static status quo Base Case system in which the residues are first dried and then ground in a hammer mill with a 6 mm screen and fines < 1.18 mm are removed. Also considered were moisture and ash impacts on throughput and Overall Operating Effectiveness (OOE), as well as delivered feedstock cost and minimum fuel selling price (MFSP). Laboratory data on the impacts of fan speed and moisture content on the separation efficiency of soil ash, needles and bark from white wood were received from FCIC Subtask 5.2. Average throughput and energy consumption data were obtained from the Bioenergy Feedstock National User Facility (BFNUF) for the same air classifier. These data were utilized to develop the necessary response surface equations to perform throughput analysis using discrete event simulation. Because the Base Case status quo system utilizes drying prior to grinding, we modeled the Case Study with drying prior to air classification and subsequent grinding of the separated white wood to isolate the individual quality and cost impacts of air classification relative to the Base Case system. Key takeaways from this Case Study are that air classification improves the quality of the final material, but increases the production cost, especially when lights are disposed; this becomes a tradeoff between increased conversion yield and the extra cost. Removing material should be done as early in the process as possible. Each operation that occurs prior to removing the material increases the cost of the disposed material and leads to wasted energy expenditures. As processes are included or modified, the impact on monetary and energy cost should be included in the decision process. Identifying alternative uses and the associated value for material that is separated from the feedstock stream will have a significant impact on the delivered cost of the material. Although there was an increase in production cost by adding air classification, there was a resulting benefit to the MFSP when meeting or exceeding all of the conversion CMAs; this was an important finding that should be explored further with FCIC Subtask 8.3 and potentially FCIC Task 6.

09 BIOMASS FUELS↗

Tethered Balloon System Merged Data (TBSMERGED) Value-Added Product Report

The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Tethered Balloon System Merged Data (TBSMERGED) Value-Added Product (VAP) integrates data from instruments flown on ARM’s tethered balloon system missions that collect in situ measurements of temperature, humidity, wind speed, wind direction, and aerosol properties with estimates of cloud base and boundary-layer height from a surface-based ceilometer to improve the ease of use of tethered balloon system (TBS) data sets. The TBSMERGEDINCLOUD VAP, a variation of TBSMERGED, includes supercooled liquid water content (tbsslwc) measurements collected within the cloud.

54 ENVIRONMENTAL SCIENCES↗

TRACER-MAP Field Campaign Report

During July-August 2022, the U.S. Department of Energy (DOE) Atmospheric System Research (ASR)-funded Tracking Aerosol Convection Interactions Experiment (TRACER)-MAP campaign completed an Atmospheric Radiation Measurement (ARM) user facility field study to measure and map aerosol, volatile organic compounds (VOC), trace gas, and select meteorological observations across Houston, Texas. That ASR project and ARM field campaign, TRACER-MAP, was designed to complement measurements made at the first ARM Mobile Facility (AMF1) by the Aerosol Observing System (AOS) during the TRACER campaign. In this manner, TRACER-MAP effectively extended aerosol measurements from the TRACER AMF deployment, increasing the spatial coverage across the Houston metropolitan area, characterizing a greater diversity of source mixtures (e.g., industrial, traffic, residential, and biogenic) and capturing air masses with differential aging of urban source emissions (e.g., downtown versus downwind). That rich data set now offers many possibilities for in-depth analysis that align with the ASR mission to “research aerosol processes that affect Earth’s radiative balance and hydrological cycle.”

54 ENVIRONMENTAL SCIENCES↗

2023 UAS Flights over the Blackwell-Tonkawa Area

This spring and summer, a series of uncrewed aerial system (UAS) flights will be made from the Blackwell Tonkawa Municipal Airport to the Southern Great Plains (SGP) atmospheric observatory. The SGP is operated by the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) user facility.

54 ENVIRONMENTAL SCIENCES↗

Vertical Aerosol Profiling during SAIL (VAPS) Field Campaign Report

To more fully address the science goals of the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility’s Surface Atmosphere Integrated Field Laboratory (SAIL) campaign, particularly the key science question of “How strongly do aerosols affect the surface energy and water balance by altering clouds, precipitation, and surface albedo, and how do these impacts vary seasonally?”, our campaign added instrumentation to planned tethered balloon system (TBS) flights in May and July of 2022. A key aspect of aerosol-cloud interactions is understanding cloud condensation nuclei (CCN) and ice nucleating particle (INP) populations, and how they vary seasonally and spatially. Because the interactions between aerosols and clouds is the target of this work, vertical distributions are particularly important to evaluate. Measurements of aerosol at ground level, below-cloud, and in-cloud will allow a better understanding of the airmasses that are feeding cloud-active particles into low- and mid-level clouds. Measurements of INP and aerosol populations often differ between the ground and aloft, with relationships that likely depend on regional and seasonal. Because of this, collocated measurements of aerosol, CCN, and INP, across different seasons, are crucial to reducing uncertainties in relationships between ground-level and cloud-base aerosol populations. Our campaign added online measurements of CCN using a compact CCN counter and offline filter collections for measurement of INP populations to the SAIL campaign TBS flights in May and July of 2022. The CCN instrument, the CloudPuck, flew and successfully collected data for a total of eight flights across both campaign periods. The IcePuck flew for most flights during the same period. Both instruments have continued to be used for other campaign requests in the SAIL domain. Analysis of this data was proposed through a concurrent DOE Atmospheric System Research (ASR) project submission, which was not funded in 2022. A similar proposal, which would involve analysis of the samples and data collected from this campaign, has been resubmitted in 2023 but a funding decision has not yet been made. If the proposal is again declined, we will seek other resources to ensure that this data can be analyzed.

54 ENVIRONMENTAL SCIENCES↗

Real-Time, Simultaneous Soil Water Content and Meteorological Data Measurement to Support TRACER over Harris County, Texas (Field Campaign Report: Part I)

The main purpose of this project was to provide ground-truth and satellite-based soil water content data in the Houston, Texas, area to support the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s 2022 field campaign, the Tracking Aerosol Convection Interactions ExpeRiment (TRACER). This involved installing four soil monitoring stations at different locations in the Houston area, two of which were part of the ARM facility and two were ancillary. The two stations associated directly with ARM were installed alongside other facilities managed and maintained by the TRACER research team during the intensive operational period (IOP), one located at the La Porte, Texas airport and the other near Guy, Texas. Data from these stations were assimilated with similar data collected by the Harris County Flood Control District (HCFCD) to improve the spatial coverage of the real-time monitoring network. The ground-truth data were compared to the satellite-based (National Aeronautics and Space Administration [NASA]’s Soil Moisture Active Passive [SMAP] mission) data in the TRACER area of interest, and analyzed further to nowcast gridded data over the Houston area. The nowcasted, gridded data product was made available to TRACER researchers for use in climate and land-atmosphere interaction modeling that can help understand formation and persistence of convective storms in dense urban areas, and predict possible environmental events such as floods.

54 ENVIRONMENTAL SCIENCES↗

TRACER Lightning Mapping Array Field Campaign Report

Our observational contribution to the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Tracking Aerosol Convection Interactions Experiment (TRACER) was the deployment of additional Lightning Mapping Array sensors to provide enhanced capability to the Houston Lightning Mapping Array (HLMA) during the TRACER intensive operational period. To that end, the Texas Tech University personnel (Professor Bruning and Dr. Brunner, and graduate students Jessica Souza, David Singewald, Stephanie Weiss, and Matthew Miller) deployed two portable LMA antennae at locations G and B shown in the map below. The map also shows the predicted lightning flash detection efficiency in black contours, as well as color-shaded very-high-frequency (VHF) source detection efficiency, which roughly corresponds to the sensitivity to lightning channel detail. Feeds from these sensors were integrated in the HLMA processing in real-time and in post-processing, partially leveraging National Science Foundation support through the TRACER campaign that supported the core HLMA, operated by Timothy Logan.

54 ENVIRONMENTAL SCIENCES↗

Advanced Mixed-Mode Pixel Array Detector for X-rays Above 20 keV (Final Report)

The objective of the work reported upon was to perform research and development and test advanced prototype imaging x-ray detectors needed to meet pressing scientific research needs at U.S. x-ray synchrotron user facilities. The high x-ray brightness of the Nation’s x-ray synchrotron sources in the DOE National Laboratories holds promise to advance science and technology in a broad range of fundamental and applied disciplines, including physics, chemistry, biomedical areas and engineering. At present, progress in many areas is being limited not by the x-ray source but by the lack of imaging x-ray detectors capable of meeting experimental needs. Specifically, there is pressing need for imaging detectors with high dynamic range, low noise, high frame rates and the ability to capture x-ray images with x-rays of energy > 20 keV. This Final Technical Report summarizes progress made at Cornell University on novel integrating x-ray detectors that address these characteristics.

36 MATERIALS SCIENCE↗

TRACER-Coastal Urban Boundary-Layer Interactions with Convection (TRACER-CUBIC) Field Campaign Report

To better understand the complicated web of processes governing convective cloud life cycle and aerosol-convection interactions, the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) user facility supported deployment of a variety of advanced atmospheric measurement systems to the greater Houston, Texas, area from 1 October 2021 to 30 September 2022 as part of the Tracking Aerosol Convection Interactions Experiment (TRACER). Houston was selected as a study area because isolated convection and a variety of aerosol conditions are common in this region. This one-year ARM Mobile Facility (AMF) deployment featured a four-month intensive operational period (IOP) during summer 2022 (1 June–30 September). The ARM instrumentation was deployed at three sites along an east-west transect from La Porte, Texas to an ancillary site in a less-polluted rural region southwest of downtown Houston (Figure 1). At the La Porte Site, which is located near the Houston ship channel in an area that experiences significant pollution, the first ARM Mobile Facility (AMF1) was deployed. During the IOP, the ARM tethered balloon system (TBS) operated at the ancillary site. The second-generation C-Band Scanning ARM Precipitation Radar (CSAPR) operated near Pearland, Texas, roughly halfway between the Laporte and ancillary sites. As part of the TRACER- Coastal Urban Boundary-Layer Interactions with Convection (CUBIC) project, three boundary-layer profiling systems) were deployed along a north-south transect spanning from the University of Houston Coastal Center to the Aldine site north of downtown Houston (also blue dot in Figure 1) during the TRACER IOP. These systems included the National Oceanic and Atmospheric Administration (NOAA) National Severe Storms Laboratory CLAMPS2 (C2), which was deployed at the UHCC, the University of Wisconsin SPARC, which was deployed at the ARM CSAPR site near Pearland (orange diamond in middle of map in Figure 1), and the University of Oklahoma CLAMPS1 (C1), which was deployed at Aldine. These three systems have been successfully operated in various field campaigns, providing data sets that collectively offer new insights into atmospheric-boundary-layer (ABL) processes, sea-breeze (SB) circulations, and convection initiation (CI). For the TRACER IOP window, these systems ran continuously between 1 June and 26 September, 2022. Due to commitments to NOAA projects, the Doppler lidar at the UHCC site was not available until 24 June 2022. The CLAMPS and SPARC profiling systems are self-contained platforms that have benefited from several years of development and deployment. Instruments and data processing were maintained remotely, which made the 4-month deployment for the TRACER-CUBIC IOP period possible. The same basic instrument configuration comprises each system: a scanning Doppler wind lidar for flow characterization and passive profiler(s) for characterizing planetary-boundary-layer (PBL) thermodynamic properties. Each platform includes a Halo Streamline Doppler wind lidar, an Atmospheric Emitted Radiance Interferometer (AERI), and a surface meteorology station. CLAMPS1 and CLAMPS2 each also include a microwave radiometer (MWR, Figure 1d). The TRACER-CUBIC hypotheses included (i) Interactions of SB and urban circulations and how they affect the PBL structure in the Houston environment, causing spatially (horizontally and vertically) and temporally highly variable flow patterns, (ii) heat, moisture, and aerosol transport and mixing depend on these flow dynamics, and (iii) an improved understanding of the flow patterns and PBL structure are critical for investigating the processes leading to CI. To test these hypotheses, the project aimed at (i) characterizing SB circulations and their impacts on the diurnal evolution of the structure of the ABL, (ii) studying the evolution of Houston’s complex urban boundary layer, and (iii) identifying effects of urban-induced circulations on pre-convective environments. TRACER-CUBIC observations generally provide good coverage during the summer IOP. Initial screening of the data indicates a good number of cases with bay-breeze (BB) and/or SB signatures, local CI, and interesting boundary-layer features such as strong nocturnal low-level jets (LLJs, Table 1). The numbers listed in rows 3-5 in this table will be further updated as part of ongoing in-depth analyses and systematic identification of local circulations and CI events. More detailed information about the data availability and quality for each instrument is provided in the “readme” files that were submitted to the ARM Data Center along with each archived data sets. These “readme” files also provide instrument descriptions, information about the data collection and processing procedures, data formats, and any additional information relevant for further data analysis.

54 ENVIRONMENTAL SCIENCES↗

Cloud and Precipitation Experiment at Kennaook (Cape-K) Science Plan

The Cloud and Precipitation Experiment at Kennaook (CAPE-K) will augment ongoing measurements at the Kennaook/Cape Grim Baseline Air Pollution Station (KCG) with components of the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s second Mobile Facility (AMF2) in a deployment that is scheduled to extend from April 2024 through September 2025. Located at Kennaook/Cape Grim on the northwestern tip of Tasmania (40.68° S, 144.69° E), KCG has produced the longest and most consequential record of Southern Hemisphere aerosol and gas-phase chemistry; however, extensive cloud and precipitation measurements have not been collected at this site. CAPE-K is motivated by the fact that model uncertainty in the surface radiation budget due to clouds and precipitation remain significant in this region, where strong latitudinal gradients in cloud feedbacks are found and there are strong and well-documented seasonal variations in marine aerosol properties. Satellite data suggest that cloud properties co-vary with the seasonal cycle in aerosol in the Southern Ocean (SO), yet detailed vertically resolved measurements of cloud and precipitation in the marine boundary layer are sparse. CAPE-K will provide the first such seasonal cycle of measurements in this important latitude band. CAPE-K will provide detailed cloud and precipitation observations over two winter seasons and align with complementary high-value-add activities planned by Australian colleagues, including a voyage of the Research Vessel Investigator (RVI) in May 2025 that will conduct measurements just offshore of KCG.

54 ENVIRONMENTAL SCIENCES↗

TRACER-Vertical Profile of Aerosol in Convective System (TRACER-VPACS) Field Campaign Report

We investigated physicochemical properties of aerosol at different altitudes during the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) user facility Tracking Aerosol Convection Interactions Experiment (TRACER). We used ARM’s tethered balloon system (TBS) and multi-modal offline analysis techniques available at DOE’s Environmental Molecular Sciences Laboratory (EMSL) at Pacific Northwest National Laboratory (PNNL) and at the Advanced Light Source (ALS) at the Lawrence Berkley National Laboratory (LBNL). The main scientific aim of this project was to understand the influence of the vertical profile of aerosol composition on the properties of deep convective clouds. The effect of aerosol properties on convective activity is still poorly understood and debated. For example, previous studies suggested that higher concentration of hygroscopic aerosol may lead to lower collection efficiency and eventually delay in onset of precipitation and total amount of precipitation. However, some observations suggested that increased aerosol concentration may result in vigorous convection and a higher amount of precipitation. In addition, the radiative forcing of the ambient aerosol is strongly influenced by the vertical distribution of aerosols and their chemical composition, and not well constrained in climate models. The estimation of the indirect effect of aerosol also has a significant uncertainty due to the spatial variation of the aerosol, especially at the cloud base. Detailed size-resolved chemical composition studies of aerosol and their microphysical properties, along with in situ measurements from ARM’s mobile facilities, help to improve our understanding of the role of aerosol in deep convective cloud formation over a broad range of environmental thermodynamic and aerosol conditions.

54 ENVIRONMENTAL SCIENCES↗

TRACER Carbonaceous Aerosols Thrust – University of California, Davis Field Campaign Report

The broader U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s TRacking Aerosol Convection interactions ExpeRiment (TRACER) campaign aims to increase our understanding of convective cloud life cycles and aerosol-convection interactions. Our TRACER Carbonaceous Aerosols Thrust-University of California, Davis (TRACER-CAT-UCDavis) study complemented these broader aims by characterizing and quantifying the optical properties and composition of carbonaceous aerosols during part of the TRACER intensive sampling period (July 1- July 31, 2022) at the first ARM Mobile Facility (AMF1) main site (M1) in La Porte, Texas. Our measurements complemented the suite of instrumentation already provided by the AMF1, expanding the capabilities through deployment of unique, state-of-the-science instrumentation. The instrumentation included: (i) two cavity-attenuated phase shift spectroscopy single-scatter albedo (CAPS-SSA) instruments operating at 530 nm and 630 nm, and that were modified to characterize particle light absorption, extinction, and scattering at elevated humidities; (ii) the UC Davis dual-wavelength cavity ringdown-photoacoustic spectrometer (CRD-PAS), which characterizes dry particle extinction and absorption at 405 nm and 532 nm; (iii) a soot particle aerosol mass spectrometer (SP-AMS) that operated in “laser only” mode that characterized the size-dependent compositions of black carbon (BC)-containing particles; (v) a thermal denuder, to remove coatings on particles; and (vi) a scanning electrical mobility sizer (SEMS), to characterize particle mobility diameters from 10-1300 nm. Our measurements occurred alongside complementary observations made by Los Alamos National Laboratory (LANL) during the TRACER-CAT-LANL study, including a humidified CAPS-SSA instrument operating at 450 nm. Our primary scientific interest is in understanding the relationship between particle composition and light absorption, with a particular focus on the influence of water uptake. While it is known that coatings on BC can enhance absorption, the extent to which this occurs in the atmosphere and the specific role that water plays as a coating remain unclear. The TRACER-CAT-UCDavis measurements were made with near-complete coverage for the CRD-PAS, SP-AMS, and SEMS throughout the intensive period. The UC Davis humidified CAPS-SSA instruments had significant challenges with operation owing to the demanding conditions (large temperature fluctuations, high humidity), exacerbated by supply chain issues that delayed resolution of these challenges. However, the humidified CAPS-SSA instrument operated by LANL operated throughout the intensive period with near-complete coverage. The dry light extinction measurements from the CRD-PAS measurements and the LANL CAPS-SSA exhibited a good correlation, although the CAPS-SSA systematically measured greater extinction values than expected. While all instruments, with the exception of an aerodynamic particle sizer (APS), measured behind a common particulate matter (PM)2.5 μm cyclone, the greater extinction measured by the LANL CAPS-SSA compared to the CRD-PAS may have resulted from different losses of larger particles in the sampling lines from the cyclone to the instruments; the tubing length was shorter from the cyclone to the LANL CAPS-SSA, consistent with this idea. A summary of the TRACER-CAT-UCDavis measurements, along with some of the TRACER-CAT-LANL measurements, are shown in the figure below. Notably, there were periods when the contributions of presumed dust were substantial and even dominated the observed light extinction and absorption. Also, there was a clear shift in the behavior of submicron particles from before July 16, 2022 to after, with the prior period exhibiting regular episodes of new particle formation and the latter period exhibiting rapid variations in the concentrations of small particles.

54 ENVIRONMENTAL SCIENCES↗

Direct Measurement of Small Particle Growth and Aging at the Atmospheric Radiation Measurement Southern Great Plains Observatory Field Campaign Report

Two identical Captive Aerosol Growth and Evolution (CAGE) chambers were operated at the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Southern Great Plains (SGP) observatory in the late summer and fall of 2021. The field study was scheduled to begin in spring, 2020, but was delayed because of the pandemic. CAGE chambers are designed to expose particles to an environment that mirrors that of the surroundings with or without a controlled perturbation designed to assess a sensitivity. The analysis here focuses on roughly the last two months of the overall study period during which measurements were almost continuous and when several perturbation experiments were conducted. Though the utility of a dual-chamber system is the ability to measure the influence of a single change on top of ambient conditions, both chambers were initially operated in the same way, with ambient air pulled through the gas exchange channel in both and ammonium sulfate particles injected into both. The similar time-dependent particle growth observed in the chambers for those periods provides confidence in differences observed during the subsequent perturbation experiments. The growth rate of particles in the reference chamber into which only ammonium sulfate particles were injected and for which only ambient air was pulled through were used to describe time-of-day averages. The average growth rate was highest in the evening and in the morning after sunrise and lowest in the late afternoon. The sensitivity of particle growth to secondary aerosol precursor gases was studied by adding them at a controlled rate to the ambient air flow pulled through one of the two chambers. Addition of 5 ppb of α-pinene resulted in an average particle growth rate of 4.4 nm hr -1 , compared with that of just 0.8 nm hr -1 in the reference chamber. The added α-pinene also triggered one new particle formation (NPF) event in the early evening just before sunset and another in the morning just after sunrise. Similarly, addition of 5 ppb of SO 2 to one chamber led to a pair of NPF events and to increased particle growth rate, though unlike the impact of added α-pinene, growth was enhanced only during the daytime when OH concentration is highest. The influence of aerosol liquid water on secondary aerosol formation and particle growth was investigated by injecting ammonium sulfate seed particles into one chamber and potassium sulfate particles into the other. Particles were injected into the two chambers four times over a 1.5-day period. The chamber relative humidity (RH) history during and following each injection was used to determine whether each particle type was crystalline or aqueous. For the case when both particle types remained crystalline throughout the period, they were tracked and for the case when they remained aqueous, the magnitude and time-dependence of the growth of both were almost exactly the same. For the other two cases the ammonium sulfate particles deliquesced upon injection and remained aqueous, while the potassium sulfate particles remained crystalline. For those two cases, the aqueous particles grew substantially faster than did the crystalline particles, providing evidence of the role of aerosol liquid water on secondary aerosol formation and particle growth.

54 ENVIRONMENTAL SCIENCES↗

UCO TRISO Minifuel FY23 NSUF-Kairos Power Post-Irradiation Examination Status Report

Irradiation of miniature tristructural isotropic (TRISO)–coated particle fuel compacts at high-power particle was performed in the Oak Ridge National Laboratory’s (ORNL’s) High Flux Isotope Reactor (HFIR) using the MiniFuel irradiation capability. Each compact comprised 20 TRISO particles with a low-enriched uranium carbide uranium oxide (UCO), natural UCO, or low-enriched UO 2 kernel within a graphitic matrix. After irradiation, the MiniFuel targets and subcapsules were disassembled to recover the irradiated fuel specimens and pursue post-irradiation examination (PIE) to inform Kairos Power on the fuel specimen performance. This report describes the PIE results collected to date, including dilatometry on the passive thermometry to confirm the irradiation temperature, fission gas release measurements, and gamma counting. This work was funded by the Nuclear Science User Facilities program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

GeoCarb Calibration Campaign Field Campaign Report

The GeoCarb Calibration Campaign, referred to as the Total Carbon Column Observing Network (TCCON) calibration campaign within this report for clarity, involved a series of single- and multiple-day Bruker EM27/SUN Fourier transform infrared (FTIR) spectrometer deployments at the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Southern Great Plains (SGP) observatory in Oklahoma. The EM27/SUN instruments directly measure infrared solar radiation in a wavelength range from 4000 to 11000 cm -1 at a spectral resolution of 0.5 cm -1 and varied temporal resolution of approximately 15 seconds. The solar radiation observed by these spectrometers contains information about the concentrations of atmospheric constituents present between the instruments and the top of the atmosphere, as every gas and particle in the atmosphere absorbs solar radiation at different wavelengths depending on their physical and chemical makeup. Through retrieval algorithm processing, the solar radiation data collected by EM27/SUN instruments can be used to infer total column dry-air mole fractions, or total column concentrations, of different trace gases present in the atmosphere. These total column concentrations, denoted as Xgas , represent the concentration, in ppb or ppm, of a trace gas in the column of atmosphere between an instrument and the top of the atmosphere. EM27/SUN instruments are primarily used to infer total column concentrations of carbon dioxide (CO 2 ), carbon monoxide (CO), methane (CH 4 ), and water vapor.

54 ENVIRONMENTAL SCIENCES↗

Biological and Environmental Research Network Requirements Review (Final Report)

The Energy Sciences Network (ESnet) is the high-performance network user facility for the US Department of Energy (DOE) Office of Science (SC) and delivers highly reliable data transport capabilities optimized for the requirements of data-intensive science. In essence, ESnet is the circulatory system that enables the DOE science mission by connecting all its laboratories and facilities in the US and abroad. ESnet is funded and stewarded by the Advanced Scientific Computing Research (ASCR) program and managed and operated by the Scientific Networking Division at Lawrence Berkeley National Laboratory (LBNL). ESnet is widely regarded as a global leader in the research and education (R&E) networking community. Between August 2022 and April 2023, ESnet and the Office of Biological and Environmental Research (BER) of the DOE SC organized an ESnet requirements review of BER-supported activities. Preparation for these events included identification of key stakeholders: program and facility management, research groups, and technology providers. Each stakeholder group was asked to prepare formal case study documents about its relationship to the BER ESS program to build a complete understanding of the current, near-term, and long-term status, expectations, and processes that will support the science going forward. A series of pre-planning meetings better prepared case study authors for this task, along with guidance on how the review would proceed in a virtual fashion.

97 MATHEMATICS AND COMPUTING↗

SAIL Field Campaign X-Band Precipitation Radar Surface Quantitative Precipitation Estimation (SQUIRE) Value-Added Product Report

In 2010, the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility procured 3- and 5-cm wavelength radars for documenting the macrophysical, microphysical, and dynamical structure of precipitating systems. In order to maximize the scientific impact, ARM supported the development of an application chain to correct for various phenomena in order to retrieve the lowest retrieved value on a Cartesian grid. This report details the motivation, science, and progress to date, as well as charting a path forward.

54 ENVIRONMENTAL SCIENCES↗

2022 Annual Site Environment Report, Princeton Plasma Physics Laboratory

This report provides the U.S. Department of Energy (DOE) and the public with information on the level of radioactive and non-radioactive pollutants (if any) that are added to the environment as a result of Princeton Plasma Physics Laboratory’s (PPPL) operations. This report fulfills the annual public reporting requirements of DOE Order 231.1B. The results of PPPL’s 2022 environmental surveillance and monitoring program are presented and discussed. The report also summarizes environmental initiatives, assessments, and community involvement programs that were undertaken in 2022. PPPL’s on-site operations started to be restored in 2022, following curtailments in 2020 and 2021 for the global coronavirus (COVID-19) pandemic. PPPL has engaged in fusion energy research since 1951 and at its current locations since 1958. The Laboratory’s mission is to develop the scientific knowledge and advanced engineering to enable fusion to power the U.S. and the world, and to develop the understanding of plasmas from the nano- to the astrophysical scale. PPPL’s primary experiment, the National Spherical Torus Experiment-Upgrade (NSTX-U) is a collaboration among national laboratories, universities, and national and international research institutions and is a major element in the US Fusion Energy Sciences Program. Its design tests the physics principles of spherical torus (ST) plasmas, playing an important role in the development of smaller, more economical fusion reactors. Due to previous operational issues, NSTX-U did not operate in 2022. PPPL is engaged in a project to replace key NSTX-U components and systems to enable the operation of this international magnetic fusion user facility. In 2022, PPPL’s radiological environmental monitoring program measured tritium in the air at onsite sampling stations. Using highly sensitive air monitors, PPPL is capable of detecting small changes in the ambient levels of tritium. The operation of monitors located on D-site is used to demonstrate compliance with the National Emission Standard for Hazardous Air Pollutants (NESHAPs) regulations. Also included in PPPL’s radiological environmental monitoring program, are water monitoring – ground, surface, and waste waters. PPPL’s radiological monitoring program characterized the background levels of tritium in the environment and those data are presented in this report. Ground water monitoring continued under New Jersey Department of Environmental Protection’s (NJDEP) Site Remediation Program regulations. PPPL monitored for non-radiological contaminants, mainly volatile organic compounds (components of common degreasing solvents). In 2022, PPPL complied with permit limits for surface water and sanitary wastewater discharges. PPPL was honored with an award for EPEAT-certified electronics purchasing from the Global Electronics Council.

54 ENVIRONMENTAL SCIENCES↗