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At least 415 records · Page 23

Processes Controlling Water Vapor in the Winter Arctic Tropopause Region

This work describes transport and thermodynamic processes that control water vapor near the tropopause during the SAGE III-Ozone Loss and Validation Experiment (SOLVE), held during the Arctic 1999/2000 winter season. Aircraft-based water vapor, carbon monoxide, and ozone measurements were analyzed so as to establish how deeply tropospheric air mixes into the Arctic lowermost stratosphere and what the implications are for cloud formation and water vapor removal in this region of the atmosphere. There are three major findings. First, troposphere-to-stratosphere exchange extends into the Arctic stratosphere to about 13 km. Penetration is to similar levels throughout the winter, however, because ozone increases with altitude most rapidly in the early spring, tropospheric air mixes with the highest values of ozone in that season. The effect of this upward mixing is to elevate water vapor mixing ratios significantly above their prevailing stratospheric values of above 5ppmv. Second, the potential for cloud formation in the stratosphere is highest during early spring, with about 20% of the parcels which have ozone values of 300-350 ppbv experiencing ice saturation in a given 10 day period. Third, during early spring, temperatures at the troposphere are cold enough so that 5-10% of parcels experience relative humidities above 100%, even if the water content is as low as 5 ppmv. The implication is that during this period, dynamical processes near the Arctic tropopause can dehydrate air and keep the Arctic tropopause region very dry during early spring.

Pfister, Leonhard↗

Gasoline Vapor Recovery

Gasoline is volatile and some of it evaporates during storage, giving off hydrocarbon vapor. Formerly, the vapor was vented into the atmosphere but anti-pollution regulations have precluded that practice in many localities, so oil companies and storage terminals are installing systems to recover hydrocarbon vapor. Recovery provides an energy conservation bonus in that most of the vapor can be reconverted to gasoline. Two such recovery systems are shown in the accompanying photographs (mid-photo at right and in the foreground below). They are actually two models of the same system, although.configured differently because they are customized to users' needs. They were developed and are being manufactured by Edwards Engineering Corporation, Pompton Plains, New Jersey. NASA technological information proved useful in development of the equipment.

Source record↗

Cassini/CIRS Observations of Water Vapor in Saturn's Stratosphere

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2004. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory (Feuchtgruber et al 1997) and subsequently confirmed by the Submillimeter Wave Astronomy Satellite (Rergin et al 2000). CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus. large spectral averages as well as improvements in calibration are necessary to detect water vapor. Zonally averaged nadir spectra were produced every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304 cm(exp -1). The origin of water vapor is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney (1986) proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al (2006) interpreted a minimum in the abundance of acetylene from ultraviolet spectra near 41S on Saturn as possibly due to an enhanced influx of water. Existing CIRS far-IR spectra are at relatively low spatial resolution, but observations at closer range planned for the extended mission will be able to test the "ring rain" mechanism by searching for localized water vapor enhancement at midlatitudes.

Bjoraker, G. L.↗

Advances in Raman Lidar Measurements of Water Vapor, Cirrus Clouds and Carbon Dioxide

Narrow-band interference filters with improved transmission in the ultraviolet have been developed under NASA-funded research and used in the Raman Airborne Spectroscopic Lidar (RASL) in ground- based, upward-looking tests. RASL is an airborne Raman Lidar system designed to measure water vapor mixing ratio, and aerosol backscatter/extinction/depolarization. It also possesses the capability to make experimental measurements of cloud liquid water and carbon dioxide. It is being prepared for first flight tests during the summer of 2006. With the newly developed filters installed in RASL, measurements were made of atmospheric water vapor, cirrus cloud optical properties and carbon dioxide that improve upon any previously demonstrated using Raman lidar. Daytime boundary layer profiling of water vapor mixing ratio is performed with less than 5% random error using temporal and spatial resolution of 2-minutes and 60 - 210, respectively. Daytime cirrus cloud optical depth and extinction- to-backscatter ratio measurements are made using 1-minute average. Sufficient signal strength is demonstrated to permit the simultaneous profiling of carbon dioxide and water vapor mixing ratio into the free troposphere during the nighttime. Downward-looking from an airborne RASL should possess the same measurement statistics with approximately a factor of 5 - 10 decrease in averaging time. A description of the technology improvements are provided followed by examples of the improved Raman lidar measurements.

Whiteman, David N.↗

Observational Evidence of Changes in Water Vapor, Clouds, and Radiation at the ARM SGP Site

Characterizing water vapor and cloud effects on the surface radiation budget is critical for understanding the current climate because water vapor is the most important greenhouse gas in the atmosphere and clouds are one of the largest sources of uncertainty in predicting potential future climate change. Several studies have shown that insolation over land declined until 1990 then increased until the present. Using 8 years of data collected at the ARM Southern Great Plains (SGP) surface site, we found that the insolation increased from 1997 to 2000, but significantly decreased from 2001 to 2004, changes that exactly mirror the variation in the second-order fit of cloud fraction. Under clear-sky conditions, the rates of water vapor, insolation and downwelling longwave (LW) flux are -0.166 cm/yr, 0.48 Wm(exp -2)/yr, and -1.16 Wm(exp -2)/yr, respectively, indicating that water vapor changes are more important for LW flux than for insolation.

Dong, Xiquan↗

Water-Vapor Raman Lidar System Reaches Higher Altitude

A Raman lidar system for measuring the vertical distribution of water vapor in the atmosphere is located at the Table Mountain Facility (TMF) in California. Raman lidar systems for obtaining vertical water-vapor profiles in the troposphere have been in use for some time. The TMF system incorporates a number of improvements over prior such systems that enable extension of the altitude range of measurements through the tropopause into the lower stratosphere. One major obstacle to extension of the altitude range is the fact that the mixing ratio of water vapor in the tropopause and the lower stratosphere is so low that Raman lidar measurements in this region are limited by noise. Therefore, the design of the TMF system incorporates several features intended to maximize the signal-to-noise ratio. These features include (1) the use of 355-nm-wavelength laser pulses having an energy (0.9 J per pulse) that is high relative to the laser-pulse energy levels of prior such systems, (2) a telescope having a large aperture (91 cm in diameter) and a narrow field of view (angular width .0.6 mrad), and (3) narrow-bandpass (wavelength bandwidth 0.6 nm) filters for the water-vapor Raman spectral channels. In addition to the large-aperture telescope, three telescopes having apertures 7.5 cm in diameter are used to collect returns from low altitudes.

Leblanc, Thierry↗

VAPoR - Volatile Analysis by Pyrolysis of Regolith - an Instrument for In Situ Detection of Water, Noble Gases, and Organics on the Moon

We present the Volatile Analysis by Pyrolysis of Regolith (VAPoR) instrument design and demonstrate the validity of an in situ pyrolysis mass spectrometer for evolved gas analyses of lunar and planetary regolith samples. In situ evolved gas analyses of the lunar regolith have not yet been carried out and no atmospheric or evolved gas measurements have been made at the lunar poles. VAPoR is designed to do both kinds of measurements, is currently under development at NASA's Goddard Space Flight Center, and will be able to heat powdered regolith samples or rock drill fines up to 1400 C in vacuo. To validate the instrument concept, evolved gas species released from different planetary analogs were determined as a function of temperature using a laboratory breadboard. Evolved gas measurements of an Apollo 16 regolith sample and a fragment of the carbonaceous meteorite Murchison were made by VAPoR and our results compared with existing data. The results imply that in situ evolved gas measurements of the lunar regolith at the polar regions by VAPoR will be a very powerful tool for identifying water and other volatile signatures of lunar or exogenous origin as potential resources for future human exploration.

ten Kate, I. L.↗

AIRS Water Vapor and Cloud Products Validate and Explain Recent Negative Global and Tropical OLR Trends Observed by CERES

This paper compares spatial and temporal anomalies and trends of OLR as observed by CERES and computed based on AIRS retrieved surface and atmospheric geophysical parameters over the time period September 2002 February 2010. This time period is marked by a substantial decreasing OLR trend on the order of -0.1 W/m2/yr averaged over the globe. There are very large spatial variations of these trends however, with local values ranging from -2.6 W/m2/yr to +3.0 W/m2/yr in the tropics. The spatial patterns of the AIRS and CERES trends are in essentially perfect agreement with each other, as are the anomaly time series averaged over different spatial regions. This essentially perfect agreement of OLR anomalies and trends derived from observations by two different instruments, in totally independent and different manners, implies that both sets of results must be highly accurate. The agreement of anomalies and trends of OLR as observed by CERES and computed from AIRS derived products also indirectly validates the anomalies and trends of the AIRS derived products as well. We used the anomalies and trends of AIRS derived water vapor and cloud products to explain why global OLR has had a large negative trend over the time period September 2002 through February 2010. Tropical OLR began to decrease significantly at the onset of a strong La Nina in mid-2007. AIRS products show that cloudiness and mid-tropospheric water vapor began to increase in the region 5degN - 20degS latitude extending eastward from 150degW - 30 E longitude at that time, with a corresponding very large drop in OLR in this region. Late 2009 is characterized by a strong El-Nino, with a corresponding change in sign of observed anomalies of mid-tropospheric water vapor, cloud cover, and OLR in this region, as we] l as that of OLR anomalies in the tropics and globally. Monthly mean anomalies of OLR, water vapor and cloud cover over this region are all shown to be highly correlated in time with those of an El Nino anomaly index four months previously. The El Nino index is defined as the SST anomaly averaged over the area 15S to 15N and 160W eastward to 30E. If one excludes the area 5degN - 20degS, 150degW - 30degE from the statistics, the negative area mean tropical OLR trends, as well as OLR trends over the rest of the globe, are substantially

Susskind, Joel↗

Cassini/CIRS Observations of Water Vapor in Saturn's Stratosphere

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2001. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory [1] and subsequently confirmed by the Submillimeter Wave Astronomy Satellite [2], CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. long integrations at the full 0.5/cm spectral resolution were performed at targeted latitudes on Saturn. High emission angles were chosen to enhance stratospheric emission. Over the course of the prime and extended mission a set of observations has been built up spaced roughly every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v'4 band centered at 1501/cm. The origin of water vapor is believed to be from the ablation of micrometeorites containing eater ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney [3] proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al [4] interpreted a minimum in the abundance of acetylene from ultraviolet spectra gear 41S on Saturn as possibly due to an enhanced influx of water. We will be able to test the "ring rain" mechanism by searching, for localized water vapor enhancement at mid-latitudes. Our results may be used to constrain photochemical models of Saturn's stratosphere [5].

Bjoraker, Gordon↗

Plasma Spray-Physical Vapor Deposition (PS-PVD) of Ceramics for Protective Coatings

In order to generate advanced multilayer thermal and environmental protection systems, a new deposition process is needed to bridge the gap between conventional plasma spray, which produces relatively thick coatings on the order of 125-250 microns, and conventional vapor phase processes such as electron beam physical vapor deposition (EB-PVD) which are limited by relatively slow deposition rates, high investment costs, and coating material vapor pressure requirements. The use of Plasma Spray - Physical Vapor Deposition (PS-PVD) processing fills this gap and allows thin (< 10 microns) single layers to be deposited and multilayer coatings of less than 100 microns to be generated with the flexibility to tailor microstructures by changing processing conditions. Coatings of yttria-stabilized zirconia (YSZ) were applied to NiCrAlY bond coated superalloy substrates using the PS-PVD coater at NASA Glenn Research Center. A design-of-experiments was used to examine the effects of process variables (Ar/He plasma gas ratio, the total plasma gas flow, and the torch current) on chamber pressure and torch power. Coating thickness, phase and microstructure were evaluated for each set of deposition conditions. Low chamber pressures and high power were shown to increase coating thickness and create columnar-like structures. Likewise, high chamber pressures and low power had lower growth rates, but resulted in flatter, more homogeneous layers

Harder, Bryan J.↗

Passive Vaporizing Heat Sink

A passive vaporizing heat sink has been developed as a relatively lightweight, compact alternative to related prior heat sinks based, variously, on evaporation of sprayed liquids or on sublimation of solids. This heat sink is designed for short-term dissipation of a large amount of heat and was originally intended for use in regulating the temperature of spacecraft equipment during launch or re-entry. It could also be useful in a terrestrial setting in which there is a requirement for a lightweight, compact means of short-term cooling. This heat sink includes a hermetic package closed with a pressure-relief valve and containing an expendable and rechargeable coolant liquid (e.g., water) and a conductive carbon-fiber wick. The vapor of the liquid escapes when the temperature exceeds the boiling point corresponding to the vapor pressure determined by the setting of the pressure-relief valve. The great advantage of this heat sink over a melting-paraffin or similar phase-change heat sink of equal capacity is that by virtue of the =10x greater latent heat of vaporization, a coolant-liquid volume equal to =1/10 of the paraffin volume can suffice.

Knowles, TImothy R.↗

Fiber-Optic Gratings for Lidar Measurements of Water Vapor

Narrow-band filters in the form of phase-shifted Fabry-Perot Bragg gratings incorporated into optical fibers are being developed for differential-absorption lidar (DIAL) instruments used to measure concentrations of atmospheric water vapor. The basic idea is to measure the relative amounts of pulsed laser light scattered from the atmosphere at two nearly equal wavelengths, one of which coincides with an absorption spectral peak of water molecules and the other corresponding to no water vapor absorption. As part of the DIAL measurement process, the scattered light is made to pass through a filter on the way to a photodetector. Omitting other details of DIAL for the sake of brevity, what is required of the filter is to provide a stop band that: Surrounds the water-vapor spectral absorption peaks at a wavelength of 946 nm, Has a spectral width of at least a couple of nanometers, Contains a pass band preferably no wider than necessary to accommodate the 946.0003-nm-wavelength water vapor absorption peak [which has 8.47 pm full width at half maximum (FWHM)], and Contains another pass band at the slightly shorter wavelength of 945.9 nm, where there is scattering of light from aerosol particles but no absorption by water molecules. Whereas filters used heretofore in DIAL have had bandwidths of =300 pm, recent progress in the art of fiber-optic Bragg-grating filters has made it feasible to reduce bandwidths to less than or equal to 20 pm and thereby to reduce background noise. Another benefit of substituting fiber-optic Bragg-grating filters for those now in use would be significant reductions in the weights of DIAL instruments. Yet another advantage of fiber-optic Bragg-grating filters is that their transmission spectra can be shifted to longer wavelengths by heating or stretching: hence, it is envisioned that future DIAL instruments would contain devices for fine adjustment of transmission wavelengths through stretching or heating of fiber-optic Bragg-grating filters nominally designed and fabricated to have transmission wavelengths that, in the absence of stretching, would be slightly too short.

Vann, Leila B.↗

The Influence of Summertime Convection Over Southeast Asia on Water Vapor in the Tropical Stratosphere

The relative contributions of Southeast Asian convective source regions during boreal summer to water vapor in the tropical stratosphere are examined using Lagrangian trajectories. Convective sources are identified using global observations of infrared brightness temperature at high space and time resolution, and water vapor transport is simulated using advection-condensation. Trajectory simulations are driven by three different reanalysis data sets, GMAO MERRA, ERA-Interim, and NCEP/NCAR, to establish points of consistency and evaluate the sensitivity of the results to differences in the underlying meteorological fields. All ensembles indicate that Southeast Asia is a prominent boreal summer source of tropospheric air to the tropical stratosphere. Three convective source domains are identified within Southeast Asia: the Bay of Bengal and South Asian subcontinent (MON), the South China and Philippine Seas (SCS), and the Tibetan Plateau and South Slope of the Himalayas (TIB). Water vapor transport into the stratosphere from these three domains exhibits systematic differences that are related to differences in the bulk characteristics of transport. We find air emanating from SCS to be driest, from MON slightly moister, and from TIB moistest. Analysis of pathways shows that air detrained from convection over TIB is most likely to bypass the region of minimum absolute saturation mixing ratio over the equatorial western Pacific; however, the impact of this bypass mechanism on mean water vapor in the tropical stratosphere at 68 hPa is small 0.1 ppmv). This result contrasts with previously published hypotheses, and it highlights the challenge of properly quantifying fluxes of atmospheric humidity.

Wright, J. S.↗

Simultaneous Water Vapor and Dry Air Optical Path Length Measurements and Compensation with the Large Binocular Telescope Interferometer

The Large Binocular Telescope Interferometer uses a near-infrared camera to measure the optical path length variations between the two AO-corrected apertures and provide high-angular resolution observations for all its science channels (1.5-13 microns). There is however a wavelength dependent component to the atmospheric turbulence, which can introduce optical path length errors when observing at a wavelength different from that of the fringe sensing camera. Water vapor in particular is highly dispersive and its effect must be taken into account for high-precision infrared interferometric observations as described previously for VLTI/MIDI or the Keck Interferometer Nuller. In this paper, we describe the new sensing approach that has been developed at the LBT to measure and monitor the optical path length fluctuations due to dry air and water vapor separately. After reviewing the current performance of the system for dry air seeing compensation, we present simultaneous H-, K-, and N-band observations that illustrate the feasibility of our feed forward approach to stabilize the path length fluctuations seen by the LBTI nuller uses a near-infrared camera to measure the optical path length variations between the two AO-corrected apertures and provide high-angular resolution observations for all its science channels (1.5-13 microns). There is however a wavelength dependent component to the atmospheric turbulence, which can introduce optical path length errors when observing at a wavelength different from that of the fringe sensing camera. Water vapor in particular is highly dispersive and its effect must be taken into account for high-precision infrared interferometric observations as described previously for VLTI MIDI or the Keck Interferometer Nuller. In this paper, we describe the new sensing approach that has been developed at the LBT to measure and monitor the optical path length fluctuations due to dry air and water vapor separately. After reviewing the current performance of the system for dry air seeing compensation, we present simultaneous H-, K-, and N-band observations that illustrate the feasibility of our feed forward approach to stabilize the path length fluctuations seen by the LBTI nuller.

which can introduce optical path length errors whe↗

Water Vapor Corrosion in EBC Constituent Materials

Environmental Barrier Coating (EBC) materials are sought after to protect ceramic matrix composites (CMC) in high temperature turbine engines. CMCs are particularly susceptible to degradation from oxidation, Ca-Al-Mg-Silicate (CMAS), and water vapor during high temperature operation which necessitates the use of EBCs. However, the work presented here focuses on water vapor induced recession in EBC constituent materials. For example, in the presence of water vapor, silica will react to form Si(OH)4 (g) which will eventually corrode the material away. To investigate the recession rate in EBC constituent materials under high temperature water vapor conditions, thermal gravimetric analysis (TGA) is employed. The degradation process can then be modeled through a simple boundary layer expression. Ultimately, comparisons are made between various single- and poly-crystalline materials (e.g. TiO2, SiO2) against those found in literature.

coating↗

Influence of Deep Convection on Cirrus and Water Vapor Concentration in the Upper Troposphere and Lower Stratosphere

It is well known that stratospheric humidity is primarily controlled by freeze drying (ice crystal growth and sedimentation) of air ascending across the cold tropical tropopause. However, the suggestion of an important source of water vapor from deep convection that extends above the tropical tropopause has persisted. There exists much anecdotal evidence of direct convective hydration of the lower stratosphere based on measurements from high altitude aircraft campaigns, but quantifying the impact of deep convection on the overall budget of stratospheric water vapor has proven challenging. The role of convection on the humidity of the upper troposphere and lower stratosphere (UTLS) is investigated in simulations of cirrus clouds along trajectories launched from given potential temperature level surfaces. The one-dimensional (vertical) cloud model tracks individual ice crystals through their life cycles, beginning with nucleation or detrainment from convection, followed by deposition growth, sedimentation and sublimation. Convective influence of the parcels is diagnosed by tracing the trajectories through time-dependent fields of convective cloud-top height adjusted to match the CloudSAT and CALIPSO statistics. Model simulations of UTLS water vapor and cloud fields are evaluated and constrained by comparison with MLS and CALIPSO measurements. The simulation results indicate that the overall impact of convection on water vapor near the tropical tropopause is 10-15%, while the impact on lower stratospheric humidity is no more than a few percent. Ice crystals detrained from deep convection have relatively small effect. The general implications for the importance of deep convection on UTLS humidity and cirrus cloud fraction will be discussed.

Ueyama, Rei↗

Simultaneous lidar profiling of water vapor, aerosol, and wind over the eastern Pacific and implications for observational challenges on clouds, circulation, and climate sensitivity

Moist convective processes and related circulations are key components of the Earth’s climate system. Improving our understanding of moisture and cloud processes over oceans is especially challenging due to observational limitations, but also important due to the large radiative effects of cloud over ocean as well as the ties to local and global-scale circulations. A unique dataset for addressing these topics was collected over 5 flights with the NASA HALO (water vapor DIAL and aerosol HSRL) and DAWN (Doppler wind) lidar systems onboard the NASA DC-8 aircraft during the spring 2019 ADM-Aeolus Cal/Val test flight campaign. High-resolution water vapor, aerosol/cloud, and wind profiles were simultaneously collected and complimented with in situ high-resolution dropsonde measurements of temperature, relative humidity, and wind profiles. Airborne lidar measurements of these key variables captured both large-scale spatial variability across different cloud and atmospheric conditions as well as finer features, providing insight into processes from large-scale circulations down to aerosol/cloud interactions. The 5 flights spanned the northeast Pacific and southwest U.S. from 6 N to 52 N and 112 W to 157 W and captured several features of interest including moist layers from the ascending region of the Hadley circulation, very dry layers above midlatitude marine stratocumulus and cloud-free planetary boundary layers, and cloud top height and spatial variability. High covariance of aerosol and water vapor in the free troposphere was also observed for the first time. Preliminary analysis of these data sets will be presented as they apply to clouds and circulations, supplemented by model reanalysis to inform how regional water vapor structure and large-scale motion may contribute to observed shallow cloud formations and other meteorological processes that underpin our current understanding of how these state variables couple to impact the Earth’s weather and climate systems. The potential of complementary measurements in future field campaigns will also be mentioned.

Brian James Carroll↗

A high capability raman lidar for upper troposhperic and lower stratospheric water vapor measurements

A new Water Vapor Raman lidar is being built at the Table Mountain Facility (TMF) of the Jet Propulsion Laboratory (JPL) in California (34.4N, 117.7W). The new system is designed to reach accuracies better than 5% anywhere up to 12 km altitude, and with the capability to measure water vapor mixing ratios as low as 1 ppm near the tropopause and in the lower stratosphere. The principal components of the proposed lidar, a high-energy Nd:YAG laser and a large telescope, are already available at TMF. The lidar receiver system, and data acquisition hardware and software are currently being implemented. The initial system in a non-optimized configuration already showed promising results, as water vapor lidar returns were clearly detected up to 20 km altitude. The initial configuration, and preliminary results are discussed in this short paper. The optimized configuration of the system, and the first calibrated water vapor profiles obtained from this optimized system will be shown at the conference.

Walsh, Daniel T.↗