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At least 415 records · Page 23

Corrosion testing of candidates for the alkaline fuel cell cathode

Current/voltage data have been obtained for specially made corrosion electrodes of some oxides and of gold materials for the purpose of developing a screening test of catalysts and supports for use at the cathode of the alkaline fuel cell. The data consist of measurements of current at fixed potentials and cyclic voltammograms. These data will have to be correlated with longtime performance data in order to evaluate fully this approach to corrosion screening.

Singer, Joseph↗

Oxygen electrodes for rechargeable alkaline fuel cells, 3

The investigation and development of electrocatalysts and supports for the positive electrode of moderate-temperature single unit rechargeable alkaline fuel cells is described with focus on chemical and electrochemical stability and O2 reduction/evolution activity.

L Swette↗

Bifunctional alkaline oxygen electrodes

The authors describe the identification and testing of electrocatalysts and supports for the positive electrode of moderate-temperature, single-unit, rechargeable alkaline fuel cells. Recent work on Na(x)Pt3O4, a potential bifunctional catalyst, is described, as well as the application of novel approaches to the development of more efficient bifunctional electrode structures. The three dual-character electrodes considered here showed similar superior performance; the Pt/RhO2 and Rh/RhO2 electrodes showed slightly better performance than the Pt/IrO2 electrode. It is concluded that Na(x)Pt3O4 continues to be a promising bifunctional oxygen electrode catalyst but requires further investigation and development.

Swette, L.↗

The Martian ocean: First acid, then alkaline

In Mars' distant past, carbon dioxide and water may have been plentiful. Values of total outgassed CO2 from several to about 10 bar are consistent with present knowledge, and this amount of CO2 implies an amount of water outgassed equal to an equivalent depth of 500 to 1000 m. It is quite reasonable, therefore, to envision an early Mars in which there was a body or bodies of liquid water, perhaps in the northern plains, and a dense carbon dioxide atmosphere. Under such conditions, the pH of the water will be low, due to the dissolution of carbon dioxide in the water to form carbonic acid. This acidic water is capable of weathering the available rock quite intensely, particularly because this rock is likely to be heavily fractured (from meteorite bombardment) or even consist of fine particles (such as pyroclastic deposits). As time goes on, however, the carbon dioxide atmosphere will rapidly pass through the ocean to form carbonate deposits. As the density of the atmosphere decreases, so will the flux of carbonic acid into the ocean. Without this input of carbonic acid, the effect of the dissolved weathering products will be to increase the pH of the water. The ocean will then become alkaline. To study this process, I have developed a geochemical cycle model for the atmosphere-hydrosphere-regolith system of Mars. The treatment of geochemical cycles as complex kinetic chemical reactions has been undertaken for terrestrial systems in recent years with much success. This method is capable of elegantly handling the interactions between the simultaneous chemical reactions needed to understand such a system.

Schaefer, M. W.↗

X-ray Diffraction Studies of the Structure and Thermochemistry of Alkaline-Earth Oxide-Coated Thermionic Cathodes

NASA LeRC has a broad, active cathode technology development program in which both experimental and theoretical studies are being employed to further development of thermionic cathodes for use as electron sources in vacuum devices for communications and other space applications. One important type of thermionic cathode under development is the alkaline-earth oxide-coated (BaO, SrO, CaO) cathode. Significant improvements in the emission characteristics of this cathode have been obtained through modification of the chemical composition and morphology of the oxide coating, with the best result thus far coming from the addition of In2O3 and Sc2O3. Whereas the In2O3 produces a finer, more uniform particle structure, the exact chemical state and role of the Sc2O3 in the emission enhancement is unknown. The purpose of this cooperative agreement is to combine the studies of the surface chemistry and electron emission at NASA LeRC of chemically modified oxide coatings with a study of the thermochemistry and crystal structure using X-ray diffraction equipment and expertise at Clark Atlanta University (CAU). The study at CAU is intended to provide the description and understanding of the structure and thermochemistry needed for further improvement and optimization of the modified coatings. A description of the experimental procedure, preliminary X-ray diffraction test results, together with the design of an ultrahigh vacuum chamber necessary for high temperature thermochemistry studies will be presented.

Karikari, E. K.↗

Alkaline Hypersaline Lakes as Analogs for Ancient Microbial Habitats on Mars

As the climate of ancient Mars became colder and drier with time, open bodies of water would have entered a regime in which evaporation exceeded input from precipitation or runoff. This would have resulted in increases in salinity and perhaps pH. The last open water on Mars was most likely found in alkaline hypersaline lakes, and these lakes would have been the last surface aquatic habitats for life on Mars. It follows, then, that the biomarkers most likely to be found in ancient sedimentary basins on Mars are those left by organisms adapted to high salt and high pH environments. We have begun to investigate the nature of biological diversity and adaptation to these environments, and the potential for biomarker preservation in them, using Mono Lake as a terrestrial analog environment. Additional information is contained in the original extended abstract.

McDonald, G. D.↗

Light Weight Design Nickel-Alkaline Cells Using Fiber Electrodes

Using fiber electrode technology, currently produced by Bekaert Corporation (Bekaert), Electro Energy, Inc., (EEI) Mobile Energy Products Group (formerly, Eagle-Picher Technologies, LLC., Power Systems Department) in Colorado Springs, CO has demonstrated that it is feasible to manufacture flight weight nickel-hydrogen cells having about twice the specific energy (80 vs. 40 watt-hr/kg) as state-of-the-art nickel-hydrogen cells that are flown on geosynchronous communications satellites. Although lithium-ion battery technology has made large in-roads to replace the nickel-alkaline technology (nickel-cadmium, nickel-metal hydride), the technology offered here competes with lithium-ion weight and offers alternatives not present in the lithium-ion chemistry such as ability to undergo continuous overcharge, reversal on discharge and sustain rate capability sufficient to start automotive and aircraft engines at subzero temperatures. In development to date seven 50 ampere-hour nickel-hydrogen have been constructed, acceptance tested and briefly tested in a low earth orbit (LEO) cycle regime. The effort was jointly funded by Electro Energy, Inc. and NASA Glenn Research Center, Cleveland, OH. Five of the seven cells have been shipped to NASA GRC for further cycle testing. Two of the cells experienced failure due to internal short circuits during initial cycle testing at EEL Destructive Physical Analysis (DPA) of one of the cells has shown the failure mode to be due to inadequate hydrogen catalyst electrodes that were not capacity balanced with the higher energy density nickel oxide electrodes. In the investigators opinion, rebuild of the cells using proper electrode balance would result in cells that could sustain over 30,000 cycles at moderate depths-of-discharge in a LEO regime or endure over 20 years of geosynchronous orbit (GEO) cycling while realizing a two-fold increase in specific energy for the battery or a 1.1 kg weight savings per 50 ampere-hour cell. Additional information is included in the original extended abstract.

Pickett, David F.↗

Alkaline battery, separator therefore

An improved battery separator for alkaline battery cells has low resistance to electrolyte ion transfer and high resistance to electrode ion transfer. The separator is formed by applying an improved coating to an electrolyte absorber. The absorber, preferably, is a flexible, fibrous, and porous substrate that is resistant to strong alkali and oxidation. The coating composition includes an admixture of a polymeric binder, a hydrolyzable polymeric ester and inert fillers. The coating composition is substantially free of reactive fillers and plasticizers commonly employed as porosity promoting agents in separator coatings. When the separator is immersed in electrolyte, the polymeric ester of the film coating reacts with the electrolyte forming a salt and an alcohol. The alcohol goes into solution with the electrolyte while the salt imbibes electrolyte into the coating composition. When the salt is formed, it expands the polymeric chains of the binder to provide a film coating substantially permeable to electrolyte ion transfer but relatively impermeable to electrode ion transfer during use.

Schmidt, George F.↗

Prebiotic Peptide (Amide) Bond Synthesis Accelerated by Glycerol and Bicarbonate Under Neutral to Alkaline Dry-Down Conditions

Past studies of prebiotic peptide bond synthesis have generally been carried out in the acidic to neutral pH range [1, 2]. Here we report a new process for peptide bond (amide) synthesis in the neutral to alkaline pH range that involves simple dry-down heating of amino acids in the presence of glycerol and bicarbonate. Glycerol was included in the reaction mixture as a solvent and to provide hydroxyl groups for possible formation of ester intermediates previously implicated in peptide bond synthesis under acidic to neutral conditions [1]. Bicarbonate was added to raise the reaction pH to 8-9.

Forsythe, J. G.↗

ISRU Advanced Alkaline Electrolyzer (AAE) BAA

This is the one-page status update for the Game Changing Development (GCD) Advanced Alkaline Electrolyzer (AAE) Broad Agency Announcement (BAA) contract with Teledyne Energy Systems, Inc (TESI) to be presented at the fiscal year 2020 (FY20) GCD Annual Review. This activity to develop and demonstrate a contamination-tolerant liquid water electrolyzer for use in in-situ resource utilization (ISRU) applications to generate gaseous hydrogen and oxygen.

Electrolyzer↗

Rechargeable alkaline battery using organic materials as negative electrodes

An energy storage device may provide a positive electrode, an electrolyte, and a negative electrode. The energy storage device may utilize an aqueous alkaline electrolyte, which may be nonflammable. The energy storage device may utilize organic material(s) as the negative electrode, such as, but not limited to, poly(anthraquinonyl sulfide) (PAQS), organic carbonyl compounds, organosulfur compounds, redox polymers, or radical polymers.

25 ENERGY STORAGE↗

Highly sustained electrodes and electrolytes for salty alkaline and neutral water splitting

A corrosion resistant anode is provided for oxygen evolution reaction in water including chloride ions. The anode includes: (1) a substrate; (2) a passivation layer coating the substrate; and (3) an electrocatalyst layer coating the passivation layer. Polyanion adjusted alkaline seawater electrolyte for hydrogen generation by electrolysis is also provided.

Kenney, Michael J.↗

Alkaline cation enrichment and water electrolysis to provide CO 2 mineralization and global-scale carbon management

Provided herein are methods of removing carbon dioxide from an aqueous stream or gaseous stream by: contacting the gaseous stream comprising carbon dioxide, when present, with an aqueous solution comprising ions capable of forming an insoluble carbonate salt; contacting the aqueous solution comprising carbon dioxide with an electroactive mesh that induces its alkalinization thereby forcing the precipitation of a carbonate solid from the solution and thereby the removal of dissolved inorganic carbon by electrolysis; and removing the precipitated carbonate solids from the solution, or the surface of the mesh where they may deposit. Also provided herein are flow-through electrolytic reactors comprising an intake device in fluid connection with a rotating cylinder comprising an electroactive mesh, and a scraping device and/or liquid-spray based device for separating a solid from the mesh surface.

Sant, Gaurav↗

Extraction of Ln(III) and An(III) from Alkaline Solutions by Sulfonamide Ligands and Analogs - 20216

As part of our effort to develop advanced separations involving combined extraction of cesium, strontium, and actinides from High-Level Waste (HLW) at the Savannah River Site, we are now reporting highly efficient extraction of Sm(III) from aqueous media of various alkalinity by dichloromethane solutions of several ligands, including tri-sulfonamides, o-mono-sulfonamido-phenols and o-phenylenediamine- derived disulfonamides. Distribution experiments and DFT calculations provide insights on the complexation of Samarium vs Americium by these ligands. Further optimization of these ligands for extraction into highly lipophilic solvents and application to HLW simulants are underway. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Thin, Highly Selective Polymer Membrane Separators for Advanced Liquid Alkaline Water Electrolysis

Our team will develop novel, dense, polymer electrolyte separators based on polybenzimidazole (PBI) derivatives that will enable tuning of water/KOH uptake in mechanically robust films for advanced liquid alkaline water electrolysis (LAWE). These material advances will enable thinner separators with increased selectivity (hydroxide conductivity/hydrogen permeability), thereby enabling higher operating currents, increased dynamic operating high-temperature stability, and catalyst-coated membranes (zero-gap design advantages) in direct alignment with stated lab call goals.

HYDROGEN↗

Cactus-like NiCo 2 S 4 @NiFe LDH hollow spheres as an effective oxygen bifunctional electrocatalyst in alkaline solution

The high-performance non-precious electrocatalysts for both oxygen redn. reaction (ORR) and oxygen evolution reaction (OER) are crucial to the practical application of fuel cells and metal-air batteries. Herein, a novel cactus-like NiCo 2 S 4 @NiFe LDH hollow sphere assembled by one-dimensional (1D) NiFe LDH nanowires and two-dimensional (2D) NiFe LDH nanosheets on the NiCo 2 S 4 hollow spheres is prepd. by a facile hydrothermal method. The outer NiFe LDH nanowires and NiFe LDH nanosheets can effectively suppress the collapse and corrosion of inner NiCo 2 S 4 hollow structure during long-term stability tests. The integration of the effective OER electrocatalyst NiFe LDH into NiCo 2 S 4 to form heterostructures, as well as the strong electronic interaction between NiCo 2 S 4 and NiFe LDH, can greatly boost both ORR and OER activities. Due to the above merits, the NiCo 2 S 4 @NiFe LDH achieves remarkably a small potential gap (ΔE = E j =10-E 1/2 ) of only 0.667 V. In this paper, we offer a facile strategy to design efficient catalysts with heterostructures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗