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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

StructuredFuzzer: Fuzzing Structured Text-Based Control Logic Applications

Rigorous testing methods are essential for ensuring the security and reliability of industrial controller software. Fuzzing, a technique that automatically discovers software bugs, has also proven effective in finding software vulnerabilities. Unsurprisingly, fuzzing has been applied to a wide range of platforms, including programmable logic controllers (PLCs). However, current approaches, such as coverage-guided evolutionary fuzzing implemented in the popular fuzzer American Fuzzy Lop Plus Plus (AFL++), are often inadequate for finding logical errors and bugs in PLC control logic applications. They primarily target generic programming languages like C/C++, Java, and Python, and do not consider the unique characteristics and behaviors of PLCs, which are often programmed using specialized programming languages like Structured Text (ST). Furthermore, these fuzzers are ill suited to deal with complex input structures encapsulated in ST, as they are not specifically designed to generate appropriate input sequences. This renders the application of traditional fuzzing techniques less efficient on these platforms. To address this issue, this paper presents a fuzzing framework designed explicitly for PLC software to discover logic bugs in applications written in ST specified by the IEC 61131-3 standard. The proposed framework incorporates a custom-tailored PLC runtime and a fuzzer designed for the purpose. We demonstrate its effectiveness by fuzzing a collection of ST programs that were crafted for evaluation purposes. We compare the performance against a popular fuzzer, namely, AFL++. The proposed fuzzing framework demonstrated its capabilities in our experiments, successfully detecting logic bugs in the tested PLC control logic applications written in ST. On average, it was at least 83 times faster than AFL++, and in certain cases, for example, it was more than 23,000 times faster.

47 OTHER INSTRUMENTATION↗

Effect of H 2 O on the ethylene glycol/alkali dismantling of bagasse for high-value conversion

Using a high-boiling alcohol system to dismantle main components of biomass is a feasible technology. Reducing dismantle operating costs and improving dismantle efficiency are essential for promoting the green, economical, and sustainable development of biomass refining. Therefore, based on the low cost and chemical properties of H 2 O at high temperature, the effects of different H 2 O dosages in NaOH-catalyzed ethylene glycol (HBAA) system on the dismantling efficiency of bagasse, surface lignin coverage, recovered-lignin activity and enzymatic hydrolysis efficiency were investigated. Compared with the HBAA dismantling system without H 2 O, the HBAA system with 60% w/v H 2 O can obviously increase the removal rates of lignin and hemicellulose, while recovering up to 99% of cellulose and significantly declining surface lignin coverage, thus enhancing the enzymatic hydrolysis efficiency. Additionally, the results of density functional theory calculations and 2D HSQC NMR analysis prove that the synergy between H 2 O and ethylene glycol can promote the esterification reaction occurrence at the α-C carbon cation in β-O-4 structure of lignin, thereby protecting the β-O-4 aromatic ether bond. Simultaneously, when the H 2 O dosage increase from 0% to 60%, the enzymatic yield increases from 84.51% to 93.74% with an enzyme load of 10 FPU/g. Based on experimental results, this study conducted a techno-economic analysis of bagasse dismantling for ethanol and co-production of lignin, achieving a minimum ethanol selling price of $\$$1.07 per kg. Here, in this study, a green and economical solution for dismantling the main components of bagasse is developed, which is important for the high-value conversion of bagasse.

Ethylene glycol↗

Empirical global model of upper thermosphere winds based on atmosphere and dynamics explorer satellite data

Thermospheric wind data obtained from the Atmosphere Explorer E and Dynamics Explorer 2 satellites have been used to generate an empirical wind model for the upper thermosphere, analogous to the MSIS model for temperature and density, using a limited set of vector spherical harmonics. The model is limited to above approximately 220 km where the data coverage is best and wind variations with height are reduced by viscosity. The data base is not adequate to detect solar cycle (F10.7) effects at this time but does include magnetic activity effects. Mid- and low-latitude data are reproduced quite well by the model and compare favorably with published ground-based results. The polar vortices are present, but not to full detail.

Hedin, A. E.↗

A co-ordinated and synergistic analysis strategy for future ground-based and space helioseismology

The variety of helioseismology observational programs planned for the mid-1990s represents an unprecedented opportunity to improve understanding of the solar interior. This review discusses the coordination of the GONG, IRIS, Birmingham and other ground-based observational programs with the space experiments on the SOHO mission: GOLF, VIRGO, and MDI. The integration and coordination of the different data streams in terms of the spatial and temporal coverage as well as the implications of the different spectral resolution and stability characteristics of each experiment are discussed. The study of the effect of active regions on various helioseismology signals is presented as an example of how ground-based and space experiments can be coordinated.

Ulrich, Roger K.↗

Gravitational microlensing - The effect of a single lens and the impact of sparse sampling

Topics in gravitational microlensing are examined. One issue is that even in cases in which the surface mass density is quite low, microlensing events cannot be considered as caused by individual stars. Whenever a high-magnification event occurs, the quasar has crossed a caustic. These caustics, however, are complex structures even for low surface-mass densities. This is illustrated by removing a single low-mass star from an ensemble of microlenses. The magnification patterns and light curves are compared with and without this star. The differences are striking and much more complex than expected. The effect of sparse sampling on the perception of microlensed light curves is examined, and attention is given to the influence of poor time coverage on simulated light curves. A regular monitoring program for microlensing candidates (especially 2237 + 0305) with a dedicated telescope is needed to make observations in different wavebands each night.

Wambsganss, Joachim↗

Understanding the Atmosphere of 51 Eri b: Do Photochemical Hazes Cloud the Planets Spectrum?

The first young giant planet to be discovered by the Gemini Planet Imager was the (is) approximately 2MJ planet 51 Eri b. This approximately 20 Myr old young Jupiter is the first directly imaged planet to show unmistakable methane in H band. To constrain the planet's mass, atmospheric temperature, and composition, the GPI J and H band spectra as well as some limited photometric points were compared to the predictions of substellar atmosphere models. The best fitting models reported in the discovery paper (Macintosh et al. 2015) relied upon a combination of clear and cloudy atmospheric columns to reproduce the data. However for an object as cool as 700 K, the origin of the cloud coverage is somewhat puzzling, as the global silicate and iron clouds would be expected to have sunk well below the photosphere by this effective temperature. While strong vertical mixing in these low gravity atmospheres remains a plausible explanation, we have explored whether atmospheric photochemistry, driven by the UV flux from the primary star, may yield hazes that also influence the observed spectrum of the planet. To explore this possibility we have modeled the atmospheric photochemistry of 51 Eri b using two state-of-the-art photochemical models, both capable of predicting yields of complex hydrocarbons under various atmospheric conditions. In our presentation we will summarize the modeling approach employed to characterize 51 Eri b, explaining constraints on the planet's effective temperature, gravity, and atmospheric composition and also present results of our studies of atmospheric photochemistry. We will discuss whether photochemical hazes could indeed be responsible for the particulate opacity that apparently sculpts the spectrum of the planet.

GPI - Gemini Planet Imager↗

Developing Fast and Accurate Radiative Transfer Models to Meet the Needs of Modern Satellite Remote Sensing Applications

Modern hyperspectral satellite remote sensors provide highly accurate measurements the Earth’s Top-of-Atmosphere (TOA) radiance, reflectance, or polarized spectra with hundreds to thousands of spectral channels and with millions of observations per day. The large data volume and high spectral dimensionality of the data pose challenges for retrieval algorithms. To process the satellite Level-1 data (e.g. calibrated TOA spectra) into Level-2 products (e.g. atmospheric and surface properties) using physical-based retrieval algorithms, accurate and fast Radiative Transfer Models (RTMs) are needed. RTMs are usually the limiting factor in determining the speed of a level-2 algorithm. For example, more than one million Line-by-Line (LBL) radiative transfer (RT) calculations are needed in order to properly capture the spectral contributions of important atmospheric molecules for an IR hyperspectral sensor with a spectral coverage from 3.5 m to 15 m or a solar hyperspectral sensor with spectral coverage from 0.25 m to 2.5 m. In this presentation, we will discuss advantages and disadvantages of different ways (e.g. correlated k and effective transmittance) to accelerate the speed of a fast RTM. We finally describe a Principal Component-based Radiative Transfer Model (PCRTM), which can calculate TOA radiance or reflectance spectra from 50 cm-1 to 40,000 cm-1 (200 m to 0.25 m). It has demonstrated very good accuracy relative to reference LBL RTMs and saves orders of magnitude in computational time. The PCRTM has been used in many satellite remote sensing applications. Examples include forward modeling in Level-2 and Level-3 retrieval algorithms, high fidelity satellite instrument simulators and instrument performance trade studies, spectral and radiometric accuracy characterizations of satellite Level-1 data, tools for inter-satellite calibrations, tools for satellite RTM lookup table generations, and tools for generating physically based training datasets for Artificial Intelligence (AI) algorithms.

climate data record↗

Additive Transforms Paint into Insulation

Tech Traders Inc. sought assistance developing low-cost, highly effective coatings and paints that created useful thermal reflectance and were safe and non-toxic. In cooperation with a group of engineers at Kennedy Space Center., Tech Traders created Insuladd, a powder additive made up of microscopic, inert gas-filled, ceramic microspheres that can be mixed into ordinary interior or exterior paint, allowing the paint to act like a layer of insulation. When the paint dries, this forms a radiant heat barrier, turning the ordinary house paint into heat-reflecting thermal paint. According to Tech Traders, the product works with all types of paints and coatings and will not change the coverage rate, application, or adhesion of the paint. Other useful applications include feed storage silos to help prevent feed spoilage, poultry hatcheries to reduce the summer heat and winter cold effects, and on military vehicles and ships. Tech Traders has continued its connection to the aerospace community by recently providing Lockheed Martin Corporation with one of its thermal products for use on the F-22 Raptor.

Source record↗

Mechanistic and kinetic relevance of hydrogen and water in CO 2 hydrogenation on Cu-based catalysts

Here, we ally steady-state kinetics, kinetic isotope effects, and density functional theory (DFT) calculations to illustrate that Cu-based catalysts remain saturated by H-adatoms (H*) and molecular formic acid (HCOOH**) during CO 2 hydrogenation. High H* coverage under methanol synthesis conditions is evidenced by reverse water-gas shift (RWGS) rates that exhibit positive H 2 reaction orders only at P H2 ≲ 0.5 bar, above which methanol synthesis and RWGS rates exhibit first and zeroth order dependence on P H2 , respectively. HCOOH** also accumulates on the surface with increasing P CO2 as informed by the Langmuir-type dependence on P CO2 (0.25-23 bar) for both methanol synthesis and RWGS. As both HCOOH** and H* have one H-atom per site occupied, the two species share the same P H2 dependence and give rise to CO 2 reaction orders that are independent of P H2 . Surface coverages determined based on kinetic analyses are further corroborated with DFT-derived adsorption energies that show favorable HCOOH** adsorbate-adsorbate interactions as well as repulsive interactions for bidentate formate (HCOO**) on H*-saturated surfaces. Methanol selectivity remains invariant with P CO2 and P CO despite CO inhibiting reaction rates, thereby demonstrating methanol synthesis and RWGS occur on the same active site. In contrast, water preferentially inhibits methanol synthesis rates, increases methanol synthesis H 2 reaction order from 1.0 to 1.5, and alters the methanol synthesis H 2 /D 2 kinetic isotope effect; the inhibitory effect of H 2 O thus cannot be attributed to competitive adsorption alone and instead reflects a change in the rate-determining step for methanol synthesis. The disparate kinetics of methanol synthesis and RWGS evince a branching pathway where methanol is formed from formates and CO is formed from carboxylates. The presented work thus identifies the relevant surface species, underscores the distinct catalytic role of water in branching methanol synthesis and RWGS pathways, and, in doing so, details a mechanistic picture that yields predictable rates and reaction orders for both methanol synthesis and RWGS on Cu-based CO 2 hydrogenation catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Catalight─An Open-Source Automated Photocatalytic Reactor Package Illustrated through Plasmonic Acetylene Hydrogenation

An open-source and modular Python package, Catalight, is developed and demonstrated to automate (photo)catalysis measurements. (Photo)catalysis experiments require studying several parameters to evaluate performance, including the temperature, gas flow rate and composition, illumination power, and spectral profile. Catalight orchestrates measurements over this complicated parameter space and systematically stores, analyzes, and visualizes the results. To showcase the capabilities of Catalight, we perform an automated apparent activation barrier measurement of acetylene hydrogenation over a plasmonic AuPd catalyst on an Al 2 O 3 support, simultaneously varying laser power, wavelength, and temperature in a multiday experiment controlled by a simple Python script. Our chemical results unexpectedly show an increased activation barrier upon light excitation, contrary to previous findings for other plasmonic reactions and catalysts. We show that the reaction rate order with respect to both acetylene and hydrogen remains unchanged upon illumination, suggesting that molecular surface coverage is not changed by light. By analyzing the inhomogeneity of the laser-induced heating, we attribute these results to a partial photothermal effect combined with a photochemical/hot electron-driven mechanism. In conclusion, our findings highlight the capabilities of a new experiment automation tool; explore the photocatalytic mechanism for an industrially relevant reaction; and identify systematic sources of error in canonical photocatalysis experimental procedures.

Catalysts↗

Upgrade of the Lyman-alpha diagnostic system on DIII-D for main chamber edge neutral studies

The LLAMA (Lyman Alpha Measurement Apparatus) pinhole camera diagnostic had previously been deployed on DIII-D to measure radial profiles of the Lyman-α (Ly-α) deuterium neutral line brightness across the plasma boundary in the lower chamber to infer neutral deuterium density and ionization rate profiles. This system has recently been upgraded with a new diagnostic head, named ALPACA, that also encloses two pinhole cameras and duplicates the LLAMA views in the upper chamber. Similar to LLAMA, ALPACA provides two times 20 lines of sight, viewing the plasma edge on the inboard and outboard sides with a radial resolution of ~2.5 cm (FWHM) and an effective time resolution of ~1 ms that allows for the investigation of inter-ELM dynamics. The extended Ly-α system provides better coverage to study neutrals in experiments with various plasma shapes utilizing both the upper and lower divertors. Furthermore, post-campaign calibration of the LLAMA diagnostic has successfully been demonstrated for the first time. This was facilitated by various upgrades to the calibration set-up and detailed measurements of the emissivity distribution of the Ly-α calibration source using a pinhole collimator. It was found that the sensitivity of the inboard LLAMA pinhole camera was reduced by a factor of 2.0 ± 0.2 over the course of six months of plasma operation in 2021. In conclusion, the upgraded Ly-α system, equipped with improved absolute calibration, will provide key input for neutral fueling and pedestal particle transport studies and for 2D edge transport code validation on the DIII-D tokamak.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Automated techniques for spacecraft monitoring

The feasibility of implementing automated spacecraft monitoring depends on four factors: sufficient computer resources, suitable monitoring function definitions, adequate spacecraft data, and effective and economical test systems. The advantages of automated monitoring lie in the decision-making speed of the computer and the continuous monitoring coverage provided by an automated monitoring program. Use of these advantages introduces a new concept of spacecraft monitoring in which system specialists, ground based or onboard, freed from routine and tedious monitoring, could devote their expertise to unprogrammed or contingency situations.

Segnar, H. R.↗

Cepheid variables as extra-galactic distance indicators

The role of Cepheid variables in establishing the inner distance scale to nearby galaxies is discussed. Emphasis is placed on the necessity for broad wavelength coverage in attempting to account for metallicity differences and reddening internal to the parent galaxies. In addition linear detectors are essential in minimizing the effects of any unresolved background contribution to the photometry. Recent infrared observations of Cepheids in Local Group galaxies are surveyed and all published data on extra galactic Cepheids are presented for convenient access.

Madore, B. F.↗

VLF space transmitter

A practical operational system for communicating with submarines located at high latitudes, particularly those under the ice cap, is described. A 10-20-km dipole is deployed which utilized tether technology and which operated at 1-3 kHz. A pair of hollow-cathode-based plasma sources, establishing contact between the ends of the tether system and the ambient plasma, allows utilization of the natural dynamo effect of the tether. It is suggested that a 12-satellite constellation in quasi-polar orbit at 500-1000 km altitude could provide coverage for a 4 million sq km area at 75 percent duty cycle.

Olsen, R. C.↗

A synthetic aperture microwave radiometer to measure soil moisture and ocean salinity from space

A concept is presented for a microwave radiometer in space to measure soil moisture and ocean salinity as part of an 'Earth Probe' mission. The measurements could be made using an array of stick antennas. The L-band channel (1.4 GHz) would be the primary channel for determining soil moisture, with the S-band (2.65-GHz) and C-band (5.0-GHz) channels providing ancillary information to help correct for the effects of the vegetation canopy and possibly to estimate a moisture profile. A preliminary study indicates that an orbit at 450 km would provide coverage of better than 95 percent of the earth every 3 days. A 10-km resolution cell (at nadir) requires stick antennas about 9.5-m long at L-band. The S-band and C-band sticks would be substantially shorter (5 m and 2.7 m, respectively).

Le Vine, D. M.↗

Thermal radiation heat transfer (3rd revised and enlarged edition)

This book first reviews the overall aspects and background information related to thermal radiation heat transfer and incorporates new general information, advances in analytical and computational techniques, and new reference material. Coverage focuses on radiation from opaque surfaces, radiation interchange between various types of surfaces enclosing a vacuum or transparent medium, and radiation including the effects of partially transmitting media, such as combustion gases, soot, or windows. Boundary conditions and multiple layers are discussed with information on radiation in materials with nonunity refractive indices.

Siegel, Robert↗

Radiative Effects of Aerosols Generated from Biomass Burning, Dust Storms, and Forest Fires

Atmospheric aerosol particles, both natural and anthropogenic, are important to the earth's radiative balance. They scatter the incoming solar radiation and modify the shortwave reflective properties of clouds by acting as Cloud Condensation Nuclei (CCN). Although it has been recognized that aerosols exert a net cooling influence on climate (Twomey et al. 1984), this effect has received much less attention than the radiative forcings due to clouds and greenhouse gases. The radiative forcing due to aerosols is comparable in magnitude to current anthropogenic greenhouse gas forcing but opposite in sign (Houghton et al. 1990). Atmospheric aerosol particles generated from biomass burning, dust storms and forest fires are important regional climatic variables. A recent study by Penner et al. (1992) proposed that smoke particles from biomass burning may have a significant impact on the global radiation balance. They estimate that about 114 Tg of smoke is produced per year in the tropics through biomass burning. The direct and indirect effects of smoke aerosol due to biomass burning could add up globally to a cooling effect as large as 2 W/sq m. Ackerman and Chung (1992) used model calculations and the Earth Radiation Budget Experiment (ERBE) data to show that in comparison to clear days, the heavy dust loading over the Saudi Arabian peninsula can change the Top of the Atmosphere (TOA) clear sky shortwave and longwave radiant exitance by 40-90 W/sq m and 5-20 W/sq m, respectively. Large particle concentrations produced from these types of events often are found with optical thicknesses greater than one. These aerosol particles are transported across considerable distances from the source (Fraser et al. 1984). and they could perturb the radiative balance significantly. In this study, the regional radiative effects of aerosols produced from biomass burning, dust storms and forest fires are examined using the Advanced Very High Resolution Radiometer (AVHRR) Local Area Coverage (LAC) data and the instantaneous scanner ERBE data from the NOAA-9 and NOAA-10 satellites.

Christopher Sundar A.↗

Metal-Air Batteries: (Latest citations from the Aerospace Database)

The bibliography contains citations concerning applications of metal-air batteries. Topics include systems that possess different practical energy densities at specific powers. Coverage includes the operation of air electrodes at different densities and performance results. The systems are used in electric vehicles as a cost-effective method to achieve reliability and efficiency. Zinc-air batteries are covered more thoroughly in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.)

FUEL CELLS↗