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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23

Nearly degenerate two-color impulsive coherent Raman hyperspectral imaging

Impulsive stimulated Raman scattering (ISRS) is a robust technique for studying low frequency (<300 cm –1 ) Raman vibrational modes, but ISRS has faced difficulty in translation to an imaging modality. A primary challenge is the separation of the pump and probe pulses. Here we introduce and demonstrate a simple strategy for ISRS spectroscopy and hyperspectral imaging that uses complementary steep edge spectral filters to separate the probe beam detection from the pump and enables simple ISRS microscopy with a single-color ultrafast laser source. ISRS spectra are obtained that span from the fingerprint region down to <50 cm –1 vibrational modes. Furthermore, hyperspectral imaging and polarization-dependent Raman spectra are also demonstrated.

47 OTHER INSTRUMENTATION↗

Modeling the Vertical Response of an Aeroseismometer Balloon System

Aeroseismometery is a novel, cutting edge capability that involves balloon based systems for detecting and geolocating sources of infrasound. The incident infrasound from a range of sources such as volcanos, earthquakes, explosions, supersonic aircraft impinges upon the balloon system causing it to respond dynamically. The dynamic response is post-processed to locate the infrasound source. This report documents the derivation of an analytical model that predicts the balloon dynamics. Governing equations for the system are derived as well as a transfer function relating the infrasound signal to the net force on the balloon components. Experimental measurements of the infrasound signals are convolved with the transfer function and the governing equations numerically time integrated to obtain predictions of the displacement, velocity and acceleration of the balloon system. The predictions are compared to the experimental measurements with good agreement observed. The derivation focuses only on the vertical dynamics of the balloon system. Future work will develop governing equations for the swinging response of the balloon to the incident infrasound.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A network approach for multiscale catchment classification using traits

Abstract. The classification of river catchments into groups with similar biophysical characteristics is useful to understand and predict their hydrological behavior. The increasing availability of remote sensing and other large-scale geospatial datasets has enabled the use of advanced data-driven approaches to classify catchments using traits such as topography, geology, climate, land cover, land use, and human influence. Unsupervised clustering algorithms based on the Euclidean distance are commonly used for trait-based classification but are not suitable for highly dimensional data. In this study we present a new network-based method for multi-scale catchment classification, which can be applied to large datasets and used to determine the traits associated with different catchment groups. In this framework, two networks are analyzed in parallel: the first being where the nodes are traits and the second being where the nodes are catchments. In both cases, edges represent pairwise similarity, and a network cluster detection algorithm is used for the classification. The trait network is used to investigate redundancy in the trait data and to condense this information into a small number of interpretable categories. The catchments network is used to classify the catchments into clusters and to identify representative catchments for the different groups using the degree centrality metric. We apply this method to classify 9067 river catchments across the contiguous United States at both regional and continental scales using 274 non-categorical traits. At the continental scale, we identify 25 interpretable trait categories and 34 catchment clusters of sizes greater than 50. We find that catchments with similar trait categories are typically located in the same region, with different spatial patterns emerging among clusters dominated by natural and anthropogenic traits. We also find that the catchment clusters exhibit distinct hydrological behavior based on an analysis of streamflow indices. This network approach provides several advantages over traditional means of classification, including better separation of clusters, the use of alternate similarity metrics that are more suitable for highly dimensional data, and reducing redundancy in the trait information. The paired catchment–trait networks enable analysis of hydrological behavior using the dominant trait categories for each catchment cluster. The approach can be used at multiple spatial scales since the network topologies adjust automatically to reflect the trait patterns at the scale of investigation. Finally, the representative catchments identified as hub nodes in the network can be used to guide transferable observational and modeling strategies. The method is broadly applicable beyond hydrology for classification of other complex systems that utilize different types of trait datasets.

54 ENVIRONMENTAL SCIENCES↗

Satellite monitoring of vegetation and geology in semi-arid environments

The possibility of mapping various characteristics of the natural environment of Tanzania by various LANDSAT techniques was assessed. Interpretation and mapping were carried out using black and white as well as color infrared images on the scale of 1:250,000. The advantages of several computer techniques were also assessed, including contrast-stretched rationing, differential edge enhancement; supervised classification; multitemporal classification; and change detection. Results Show the most useful image for interpretation comes from band 5, with additional information being obtained from either band 6 or band 7. The advantages of using color infrared images for interpreting vegetation and geology are so great that black and white should be used only to supplement the colored images.

Kihlblom, U.↗

Wave-particle interaction at the plasmasphere-ring current interface

During the plasmasphere filling process following geomagnetic storms, an outward density decrease of the cold plasma at L = 3-4 is typically observed. When this structure overlaps with the sharp inner edge of the ring current, wave activity is detected at linearly stable phase velocities. The excitation of these waves around the lower hybrid frequency and their effects on the heating of thermal ions is analyzed. It is found that lower hybrid drift waves are most effective at heating lower mass ions, e.g. plasmaspheric H(+), versus He(+), which may be heated more effectively by electromagnetic ion cyclotron waves driven unstable by the ring current loss cone.

Roth, Ilan↗

Tropospheric Wind Profiles Obtained with the GLOW Molecular Doppler Lidar during the 2002 International H2O Project

The Goddard Lidar Observatory for Winds (GLOW) is a mobile direct detection Doppler lidar system which uses the double edge technique to measure the Doppler shift of the molecular backscattered laser signal at a wavelength of 355 nm. In the spring of 2002 GLOW was deployed to the western Oklahoma profiling site (36 deg 33.500 min N, 100 deg 36.371 min W) to participate in the International H2O Project (IHOP). During the IHOP campaign over 240 hours of wind profiles were obtained with the GLOW lidar in support of a variety of scientific investigations.

Gentry, Bruce M.↗

Tropospheric Wind Profiles Obtained with the GLOW Molecular Doppler Lidar during the 2002 International H2O Project

The Goddard Lidar Observatory for Winds (GLOW) is a mobile direct detection Doppler lidar system hich uses the double edge technique to measure the Doppler shift of the molecular backscattered laser signal at a wavelength of 355 nm. In the spring of 2002 GLOW was deployed to the western Oklahoma profiling site (36 deg 33.500 min N, 100 deg 36.371 min W) to participate in the International H2O Project (MOP). During the MOP campaign over 240 hours of wind profiles were obtained with the GLOW lidar in support of a variety of scientific investigations.

Gentry, Bruce M.↗

Wind Profiles Obtained with a Molecular Direct Detection Doppler Lidar During IHOP-2002

The Goddard Lidar Observatory for Winds (GLOW) is a mobile direct detection Doppler lidar system which uses the double edge technique to measure the Doppler shift of the molecular backscattered laser signal at a wavelength of 355 nm. In the spring of 2002 GLOW was deployed to the western Oklahoma profiling site (36 deg 33.500 min. N, 100 deg. 36.371 min. W) to participate in the International H2O Project (IHOP). During the IHOP campaign over 240 hours of wind profiles were obtained with the GLOW lidar in support of a variety of scientific investigations.

Gentry, Bruce M.↗

Thermographic Characterization of Impact Damage in SiC/SiC Composite Materials

SiC/SiC composite materials targeted as turbine components for next-generation aero-engines are being investigated at NASA Glenn Research Center. In order to examine damage mechanisms in these materials, SiC/SiC coupons were impacted with 1.59 mm diameter steel spheres at increasing velocities from 115 m/s to 400 m/s. Pulsed thermography, a nondestructive evaluation technique that monitors the thermal response of a sample over time, was utilized to characterize the impact damage. A thermal standard of similar material was fabricated to aid in the interpretation of the thermographic data and to provide information regarding thermography system detection capabilities in 2.4 mm thick SiC/SiC composite materials. Flat bottom holes at various depths with aspect ratios greater than 2.5 were detectable in the thermal images. In addition, the edges of holes at depths of 1.93 mm into the sample were not as resolvable as flat bottom holes closer to the surface. Finally, cooling behavior was characterized in SiC/SiC materials and used to determine impact damage depth within an 8.5% error of a known depth.

Fox, Dennis S.↗

Orbiter LH2 Feedline Flowliner Cracking Problem

In May of 2002, three cracks were found in the downstream flowliner at the gimbal joint in the LH2 feedline at the interface with the Low Pressure Fuel Turbopump (LPFP) of Space Shuttle Main Engine (SSME) #1 of Orbiter OV-104. Subsequent inspections of the feedline flowliners in the other orbiters revealed the existence of 8 additional cracks. No cracks were found in the LO2 feedline flowliners. A solution to the cracking problem was developed and implemented on all orbiters. The solution included weld repair of all detectable cracks and the polishing of all slot edges to remove manufacturing discrepancies that could initiate new cracks. Using the results of a fracture mechanics analysis with a scatter factor of 4 on the predicted fatigue life, the orbiters were cleared for return to flight with a one-flight rationale requiring inspections after each flight. OV-104 flew mission STS-112 and OV-105 flew mission STS-113. The post-flight inspections did not find any cracks in the repaired flowliners. At the request of the Orbiter Program, the NESC conducted an assessment of the Orbiter LH2 Feedline Flowliner cracking problem with a team of subject matter experts from throughout NASA.

Harris, Charles E.↗

The circumstellar environments of intermediate mass main sequence stars

Analysis of archival Infrared Astronomy Satellite (IRAS) and International Ultraviolet Explorer (IUE) data resulted in identification of accreting gas toward a 2.8 Myr post-Herbig Be star in the R CrA star formation region, and identification of accreting gas toward HD 93563, previously identified as a classical Be star. Accreting gas was also detected toward two B(e) stars of previously controversial evolutionary state, resulting in identification of these systems as pre-Main Sequence Herbig Be stars viewed edge-on to their circumstellar disks. In parallel with this effort, accreting gas was detected toward the Herbig Ae star HR 5999, resulting in development of identification criteria for edge-on PMS proto-planetary disk systems. The work on individual stars is described.

Grady, Carol A.↗

Nondestructive Evaluation for the Space Shuttle's Wing Leading Edge

The loss of the Space Shuttle Columbia highlighted concerns about the integrity of the Shuttle's thermal protection system, which includes Reinforced Carbon-Carbon (RCC) on the leading edge. This led NASA to investigate nondestructive evaluation (NDE) methods for certifying the integrity of the Shuttle's wing leading edge. That investigation was performed simultaneously with a large study conducted to understand the impact damage caused by errant debris. Among the many advanced NDE methods investigated for applicability to the RCC material, advanced digital radiography, high resolution computed tomography, thermography, ultrasound, acoustic emission and eddy current systems have demonstrated the maturity and success for application to the Shuttle RCC panels. For the purposes of evaluating the RCC panels while they are installed on the orbiters, thermographic detection incorporating principal component analysis (PCA) and eddy current array scanning systems demonstrated the ability to measure the RCC panels from one side only and to detect several flaw types of concern. These systems were field tested at Kennedy Space Center (KSC) and at several locations where impact testing was being conducted. Another advanced method that NASA has been investigating is an automated acoustic based detection system. Such a system would be based in part on methods developed over the years for acoustic emission testing. Impact sensing has been demonstrated through numerous impact tests on both reinforced carbon-carbon (RCC) leading edge materials as well as Shuttle tile materials on representative aluminum wing structures. A variety of impact materials and conditions have been evaluated including foam, ice, and ablator materials at ascent velocities as well as simulated hypervelocity micrometeoroid and orbital debris impacts. These tests have successfully demonstrated the capability to detect and localize impact events on Shuttle's wing structures. A first generation impact sensing system has been designed for the next Shuttle flight and is undergoing final evaluation for deployment on the Shuttle's first return to flight. This system will employ wireless accelerometer sensors that were qualified for other applications on previous Shuttle flights. These sensors will be deployed on the wing's leading edge to detect impacts on the RCC leading edge panels. The application of these methods will help to insure the continued integrity of the Shuttle wing's leading edge system as the Shuttle flights resume and until their retirement.

Eric I Madaras↗

High-Pressure Investigation of 2,4,6-Trinitro-3-bromoanisole (TNBA): Structural Determination and Piezochromism

Understanding phase transitions in energetic materials is crucial for developing predictive models of detonation. 2,4,6-Trinitro-3-bromoanisole (TNBA), an energetic material, was studied in its single-crystal form up to pressures of 45 GPa in a diamond anvil cell. The material was characterized by using X-ray, Raman, and optical transmission measurements. From single-crystal X-ray diffraction, the ambient structure of TNBA was determined which crystallizes in the P2 1 /c space group having four molecular units per unit cell. The X-ray data up to 9.2 GPa were fitted to a third-order Birch–Murnaghan equation of state by using the parameters K o = 13.2(2.4) GPa and K p = 5.1(1.4). Between 6.8 and 7.3 GPa, a phase transition was inferred in TNBA from concurrent fading of X-ray diffraction, disappearance of Raman peaks, increase in sample fluorescence, and discontinuous color change. The new phase was consistent with an amorphous state of at least partially intact molecules judging from the presence of higher-order Raman modes and irreversibility of the Raman spectra upon release. Piezochromism was observed with the translucent yellow TNBA gradually darkening and becoming opaque black at ~25 GPa. This correlated to the absorption edge gradually shifting to the red in the visible spectrum. Signs of two possible additional structural transitions were detected in the 32.4–41.0 GPa range as suggested by a jump in the absorption edge, the irreversible changes in the absorption spectrum upon release to ambient pressure, and by the lack of Raman modes in recovered samples. Here, the crystal and electronic structures of TNBA were also investigated up to 10 GPa by using DFT calculations and crystal structure prediction (CSP) simulations. In agreement with the experimentally observed transition at 7 GPa, the simulations at 10 GPa found a bevy of polymorphs lower in enthalpy and higher in density than P2 1 /c. The lowest calculated enthalpy structure was determined to be P2 1 2 1 2 1 , being in a different space group than the ambient experimental result.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Integrating 5G Technology for Improved Process Monitoring and Network Slicing in ICS

Industrial Control Systems (ICS) are crucial for monitoring physical processes that support essential cyber-enabled services like power generation. The use of proprietary communication and lack of effective intrusion detection mechanisms pose constraints for efficient operation. Therefore, there is a need to modernize these systems with decentralized technologies like Edge Computing and 5G. However, integrating 5G and Edge Computing into large-scale ICS networks presents implementation and performance challenges. To address these challenges, this paper proposes an integrated ICS architecture that combines 5G and Edge Computing technologies with traditional ICS protocols. The objective is to minimize implementation and operational difficulties while improving the monitoring of physical processes and enabling robust intrusion detection. The proposed architecture outlines the necessary components, services, and communication protocols required for the integration of 5G and Edge Computing.

Aguayo, Jared M.↗

Smart Methane Emission Detection System Development (Final Report)

Working with the Department of Energy's National Energy Technology Laboratory, Southwest Research Institute® (SwRI®) developed a system to identify methane leaks reliably, accurately, and autonomously at critical midstream sections of the natural gas distribution network in real-time for the purpose of mitigating methane emissions using Optical Gas Imaging (OGI) cameras. SwRI's Smart Leak Detection – Methane (SLED/M) adds a high degree of automation to the process of methane leak detection to minimize sources of human error, minimize response time to a leak event, and maximize midstream visibility. Furthermore, SwRI has been working towards integrating Quantitative OGI (QOGI) capabilities into this existing technology. By leveraging Deep Learning, SwRI now has the capability to estimate fugitive emission leak rates quickly and reliably, which allows operators to detect emissions, quantify leak rate, prioritize repairs, and validate the repairs in a single instrument. The next generation QOGI technology leverages the same cameras used in Leak Detection and Repair (LDAR) programs, with improvements in safety and speed for traditional quantification-based repairs, ultimately leading to less overhead cost for the operators. The goals for this research were to develop two types of models with the following goals: Run in real-time on the edge (≥ 12 Hz), Classification: Achieve less than 5% false positive detection, Classification: Achieve ≥ 95% methane plume detection rate, Regression: achieve ≤ 10 standard cubic feet per hour (scfh) prediction > 70% of the time. In order to achieve these results, multiple infrared (IR) and other sensors were investigated in tandem with the midwave IR (MWIR) OGI to provide additional information to train the underlying models. Information on atmospheric conditions including humidity, temperature, pressure, and solar radiation was provided by a weather station. Several machine learning and deep learning architectures and methods, including looking at quantized classification networks and regressions networks, were explored. As further data was collected, curated, and labeled, it allowed for more refined regressive networks to be adequately trained, leading to better insight into the true flow rates being observed. An important valuable deliverable of this research effort was the development of an advanced network which underwent multiple iterations capable of giving a continuous output. The current network has a predicted mean average percentage error (MAPE) of 12.3% just outside our target goal of 10.00%, but an accuracy of 97.78% at ±50 scfh, well within the overall goal for the Department of Energy (DOE) program. Upon closer inspection, it was observed that more than 10% of datapoints contributing to the MAPE predictions were the result of low flow rate predictions and are beyond the sensitivity of instrument measurement as a result of normal operational variation and noise.

03 NATURAL GAS↗

The Spaceguard Survey - Protecting the earth from cosmic impacts

The conclusions of the NASA International Near-Earth-Object Detection Workshop (May 1991-January 1992) are summarized. Near-earth asteroids and short-period comets constitute about 90 percent of potential earth-impacting projectiles. The greatest risk is from those with diameters greater than 1 km. The objective of a near-earth object survey is to find such objects, calculate their long-term orbital trajectories, and identify any that may impact the earth over the next several centuries. There will generally be a period of at least several decades to take corrective action if any potential earth-impactors are found. A region of space extending outward from the earth to approximately the inner edge of the main asteroid belt must be monitored. Detection can be by reflected sunlight or infrared. Though faint, the objects should be readily detectable with ground-based telescopes, and thus there is no need for a more expensive space-based system.

Morrison, David↗

Transmission interference fringe ( TIF ) technique for the dynamic visualization of evaporating droplet

Here, the transmission interference fringe (TIF) technique was developed to visualize the dynamics of evaporating droplets based on the Reflection Interference Fringe (RIF) technique for micro-sized droplets. The geometric formulation was conducted to determine the contact angle (CA) and height of macro-sized droplets without the need for the prism used in RIF. The TIF characteristics were analyzed through experiments and simulations to demonstrate a wider range of contact angles from 0 to 90°, in contrast to RIF's limited range of 0–30°. TIF was utilized to visualize the dynamic evaporation of droplets in the constant contact radius (CCR) mode, observing the droplet profile change from convex-only to convex-concave at the end of dry-out from the interference fringe formation. The TIF also observed the contact angle increase from the fringe radius increase. This observation is uniquely reported as the interference fringe (IF) technique can detect the formation of interference fringe between the reflection from the center convex profile and the reflection from the edge concave profile on the far-field screen. Unlike general microscopy techniques, TIF can detect far-field interference fringes as it focuses beyond the droplet-substrate interface. The formation of the convex-concave profile during CCR evaporation is believed to be influenced by the non-uniform evaporative flux along the droplet surface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Improved scene generator capability

Components of an integrated system having all functions for model preparation and generation, image computation and scene generation, and collision detection and reporting for the visual simulation of space shuttle maneuvers and its interaction with the manipular arm and other objects, as well as during earth landing exercises are described. High surface solution by range priority allows for correct views of dynamically moving objects from any viewpoint. Smooth shading, anti-aliasing and edge smoothing techniques provide a high quality picture. The collision detection system allows for simulation of impenetrable objects and docking maneuvers, and the modeling systems permit production of new data bases for desired simulations.

Source record↗