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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Magnetosphere-Ionosphere Coupling of Precipitated Electrons in Diffuse Aurora Driven by Time Domain Structures

Recent theoretical studies and the spacecraft conjugate observations between the Time History of Events and Macroscale Interactions during Substorms (THEMIS) mission and the low-altitude Enhanced Polar Outflow Probe (e-POP) spacecraft demonstrated the connections between broadband electrostatic fluctuations, the so called time domain structures (TDSs), and electron precipitation in the region of diffuse aurora. In this letter, we used the SuperThermal Electron Transport (STET) code to implement these theoretical and experimental results and analyze magnetosphere-ionosphere energy interplay of the precipitated electrons that are driven by TDSs. To put TDSs electron scattering processes in the context with other wave scattering activities, ECH and whistler chorus waves are taken into account. Integrated electron energy fluxes in the diffuse aurora driven by TDSs are comparable to those driven by whistler waves. We find that including Magnetosphere-Ionosphere coupling processes increases the integrated electron energy fluxes by more than two times than only driven by TDSs.

diffuse aurora↗
NASA NTRS1988

Beam-plasma interactions in space experiments - A simulation study

The plasma environment in the vicinity of a spacecraft during the injection of dense electron beams is studied using a two-dimensional, isolated-system electrostatic simulation model. The dependence of the beam stagnation time on the beam width and energy is examined. It is found that the relative size of the beam stagnation time and the ambient-plasma response time determines the environment of the spacecraft. The case of cross-field injection with beam stagnation time greater than plasma response time is discussed in detail. Also, the nature of the beam properties, plasma response, and wave spectra are considered.

Pritchett, P. L.↗
DOE OSTI2025

Alkali Metal Control of Triplet-Mediated C–H Activation in Iron-Mediated Coupling of Dinitrogen and Benzene

Direct coupling of N 2 with abundant feedstocks like benzene to form N-containing organic compounds is a promising strategy for N 2 fixation pathways. The challenge of coupling N 2 activation and C–H bond oxidative addition was recently solved by introducing a reversible benzene C–H bond activation process mediated by a low-valent Fe(0) complex, which gave an organometallic product that could couple with partially reduced N 2 . Interestingly, the energetics of the C–H oxidative addition/reductive elimination step depends on the choice of alkali metal. However, the reason why the alkali metal influences the C–H bond activation remained elusive. In this work, we present a comprehensive study on this Fe(0)-mediated reversible C–H activation. Through density functional theory combined with high-level coupled cluster calculations, we discovered that the intermediate-spin triplet (S = 1) controls the energy of the transition state for C–H cleavage, while the high-spin quintet (S = 2) controls the position of the equilibrium. Na + drives the equilibrium toward oxidative addition due to an electrostatic effect, while K + and Rb + are dominated by a steric effect that favors the iron(0) species. The key role played by nonbonding interactions in the Fe-mediated C–H activation provides a conceptual model for alkali control over organometallic transformations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1971

Shift and broadening of resonance in turbulent plasmas.

The resonant wave-particle interaction is described, taking into account the effect of the turbulent field on the particle motion in lowest order. It is shown that an electrostatic turbulence produces a shift and a broadening of the Landau resonance. It is found that the resonance shift depends on the mean square spread in wave numbers of the turbulent spectrum, while the resonance width is proportional to the root square of the wave amplitude.

Birmingham, T.↗
NASA NTRS1996

The NASA Electric Propulsion Program

Nearly all space missions require on-board propulsion systems and these systems typically have a major impact on spacecraft mass and cost. Electric propulsion systems offer major performance advantages over conventional chemical systems for many mission functions and the NASA Office of Space Access and Technology (OSAT) supports an extensive effort to develop the technology for high-performance, on-board electric propulsion system options to enhance and enable near- and far-term US space missions. This program includes research and development efforts on electrothermal, electrostatic, and electromagnetic propulsion system technologies to cover a wide range of potential applications. To maximize expectations of technology transfer, the program emphasizes strong interaction with the user community through a variety of cooperative and contracted approaches. This paper provides an overview of the OSAT electric propulsion program with an emphasis on recent progress and future directions.

Callahan, Lisa Wood↗
NASA NTRS1998

Locations of Halide Ions in Tetragonal Lysozyme Crystals

Anions play an important role in the crystallization of lysozyme, and are known to bind to the crystalline protein. Previous studies employing X-ray crystallography had found one chloride ion binding site in the tetragonal crystal form of the protein and four nitrate ion binding sites in the monoclinic form. Studies using other approaches have reported more chloride ion binding sites, but their locations were not known. Knowing the precise location of these anions is also useful in determining the correct electrostatic fields surrounding the protein. In the first part of this study the anion positions in the tetragonal form were determined from the difference Fourier map obtained from the lysozyme crystals grown in bromide and chloride solutions under identical conditions. The anion locations were then obtained from standard crystallographic methods and five possible anion binding sites were found in this manner. The sole chloride ion binding site found in previous studies was confirmed. The remaining four sites were new ones for tetragonal lysozyme crystals. However, three of these new sites and the previously found one corresponded to the four unique binding sites found for nitrate ions in monoclinic crystals. This suggests that most of the anion binding sites in lysozyme remain unchanged, even when different anions and different crystal forms of lysozyme are employed. It is unlikely that there are many more anions in the tetragonal lysozyme crystal structure. Assuming osmotic equilibrium it can be shown that there are at most three more anions in the crystal channels. Some of the new anion binding sites found in this study were, as expected, in pockets containing basic residues. However, some of them were near neutral, but polar, residues. Thus, the study also showed the importance of uncharged, but polar groups, on the protein surface in determining its electrostatic field. This was important for the second part of this study where the electrostatic field surrounding the protein was accurately determined. This was achieved by solving the linearized version of the Poisson-Boltzmann equation for the protein in solution. The solution was computed employing the commercial code Delphi which uses a finite difference technique. This has recently become available as a module in the general protein visualization code Insight II. Partial charges were assigned to the polar groups of lysozyme for the calculations done here. The calculations showed the complexity of the electrostatic field surrounding the protein. Although most of the region near the protein surface had a positive field strength, the active site cleft was negatively charged and this was projected a considerable distance. This might explain the occurrence of "head-to-side" interactions in the formation of lysozyme aggregates in solution. Pockets of high positive field strength were also found in the vicinity of the anion locations obtained from the crystallographic part of this study, confirming the validity of these calculations. This study clearly shows not only the importance of determining the counterion locations in protein crystals and the electrostatic fields surrounding the protein, but also the advantage of performing them together.

Lim, Kap↗
NASA NTRS2020

Implementation Concept of Operation for a Multi-Purpose Cassegrain Solar Concentrator, Micro-Spectrometers, and Electrostatic Neutralizers to Enable In Situ Construction Activities plus Lunar, Planetary, and Deep Space Science Exploration on the Moon

The ability to utilize regolith would support human missions to the Moon and Mars by both stabilizing the surface as well as the use of indigenous resources. Precision landing requirements include surface stabilization to prevent damage or contamination due to regolith projectiles as a result of plume interaction with regolith. The use of indigenous resources rather than hauling materials from Earth appears to be economically a palatable option by converting indigenous resources to usable products. However, such activities have new technical challenges to overcome the issues related to lunar environmental conditions, a wide range of temperature fluctuation, extremely high vacuum, and electrostatically charged fine regolith dusts. For both the regolith sintering and extraction of resources onsite, a Cassegrain solar concentrator was studied for not only sintering lunar regolith into a hardened stabilized surface, but also other multiple applications. This report illustrates a Cassegrain solar concentrator that has multi-functional capabilities for space missions. Proper design and implementation of high-performance lightweight composite materials for the primary mirror of the Cassegrain concentrator can offer multiple capabilities to be performed on the Moon. The multiple applications studied with Cassegrain concentrators are (1) Solar sintering for landing pad and habitats, (2) Harvest of volatiles: H2O, O2, H2, and He-3, (3) Space antenna for telemetry and telecommunication, and (4) Space telescope with 20-meter aperture that exceeds the space telescopes to date in terms of the State-of-Art (SOA) in resolution and aperture diameter. In this study, a key emphasis was placed on the NASA Langley-developed boron nitride nanotube (BNNT) nanocomposite technology which is ideal for the segmented primary mirror structure of the Cassegrain system because it promises a very low coefficient of thermal expansion (CTE) and negligible Poisson ratio. Also, BNNT nanocomposites offer several noticeable benefits, such as light weight, radiation shielding capability, and mechanical strength for structural applications. Additionally, the NASA Langley-developed bullet-like micro-spectrometer and electrostatic power generator were reviewed for mineral mapping applications and electrostatic power generation and dust mitigation from electrostatically charged regolith.

landing pad↗
NASA NTRS1977

The effect of environmental plasma interactions on the performance of the solar sail system

Interaction between the solar sail and the natural plasma environment were examined for deleterious impacts upon the operation of the sail and its associated payload. Electrostatic charging of the sail in the solar wind and in near earth environment were examined. Deployment problems were studied. An analysis of electromechanical oscillations coupling the sail to the natural plasma was performed. As a result of these studies, it was concluded that none of these effects will have a significant negative impact upon the sail operation. The natural environment will be significantly perturbed and this will preclude measurements of electric and magnetic fields from an attached payload.

Douglas, M.↗
NASA NTRS1985

The physics of comets

This volume of the 'Fundamentals of Cosmic Physics' is concerned with the physics of comets. Aspects regarding the nucleus are discussed, taking into account observations, radius and albedo, mass, rotation, splitting and disruption, the temperature and sublimation of the cometary nucleus, the chemical composition, the electrostatic charging of the cometary nucleus, and the structure and evolution of the cometary nucleus. Other topics explored are related to the atmosphere and its interaction with the solar wind, the plasma tail, and the dust tail. Attention is given to excitation mechanisms, atmospheric abundances and production rates, chemical models of the inner coma, collisional processes and the multifluid approach, radiative transfer, the ionization processes, models of the inner layer, the outer coma, acceleration mechanisms in the plasma tail, the structure of the plasma tail, the cometary magnetosphere, dust grain orbits, gas-dust interaction in the inner coma, and the nature of the cometary dust.

Mendis, D. A.↗
NASA NTRS1985

A possible mechanism for the observed streaming of O(+) and H(+) ions at nearly equal speeds in the distant magnetotail

In recent years, O(+) and H(+) ions streaming away from the earth along geomagnetic field lines have been observed in the distant magnetotail region. In the present paper, it is suggested that the transverse acceleration of the ions occurs on auroral field lines at altitudes above the field-aligned potential drops, where ion beams and electrostatic hydrogen cyclotron (EHC) waves have been simultaneously observed. It is pointed out that the preferential acceleration of O(+) relative to H(+) occurs through the interaction of O(+) ions with weak EHC waves, as suggested by Singh et al. (1983). A quantitative explanation is provided for the observed relationship between the energies of O(+) and H(+) ions.

Singh, N.↗
NASA NTRS2019

Source of the Bursty Bulk Flow Diffuse Aurora: Electrostatic Cyclotron Harmonic and Whistler Waves in the Coupling of Bursty Bulk Flows to Auroral Precipitation

Electron cyclotron harmonic (ECH) and whistler chorus waves are recognized as the two mechanisms responsible for the resonant wave‐particle interactions necessary to precipitate plasma sheet electrons into the ionosphere, producing the diffuse Aurora. Previous work has demonstrated ECH waves dominate electron scattering at L shells >8, while whistler chorus dominates scattering at L shells L < 8. However, we find from Time History of Events and Macroscale (THEMIS) Interactions during Substorms observations of fast flows at L = 12 that oblique whistler chorus emissions play the dominant role in scattering electrons. Previous works have identified whistler‐mode waves within fast flows that are produced by an electron temperature anisotropy Te,⊥/Te,||> 1, consistent with electron betatron acceleration. Here, however, we find whistler chorus emissions throughout an interval of fast flows where Te,⊥/Te,||< 1. Parallel electron beams account for the enhanced parallel electron temperature and serve as the instability mechanism for the whistler chorus. The parallel electron beams and associated cigar‐shaped distributions are consistent with Fermi acceleration at dipolarizations in fast flows. We demonstrate that the scattering efficiency of the whistler chorus exceeds that of ECH waves, which THEMIS also detects during the fast flows. The obliquity of the whistler waves permits efficient scattering of lower‐energy electrons into the diffuse aurora. We conclude that Fermi acceleration of electrons provides one important free‐energy source for the wave‐particle interactions responsible for coupling plasma sheet electrons into the diffuse aurora during substorm conditions.

Wendel, D. E.↗
NASA NTRS1972

Nonlinear interaction of plasma waves in a cold magnetized plasma.

Coupling equations are derived for the general case of nonlinear coupling of any wave modes in a cold magnetized plasma with particle drift motions. Specifically, the transformation of electrostatic waves is studied in connection with solar type-III radiation. A relevant numerical analysis is also presented.

Chin, Y.-C.↗
DOE OSTI2025

Alkali-induced catalytic tuning at metal and metal oxide interfaces

Alkali metals have been recognized as effective promoters in heterogeneous catalysis, capable of enhancing catalytic activity and tuning product distributions. Over the past few decades, significant efforts have been made aiming to reveal the mechanisms underlying the promoting effect of alkalis. However, the roles that alkali metals play in the catalytic process remain elusive due to challenges in capturing their catalytic behaviours upon exposure to reactive environments. This review summarizes recent surface science and theoretical studies of alkali (potassium, cesium)-decorated metal and metal oxide model catalysts, revealing the crucial tuning by alkalis of activity and selectivity for CO 2 hydrogenation. The analysis of electronic structures identifies the selective binding mechanism of the positively charged alkali ions on the surface, being able to reduce the surface work function and lead to strong electron polarization on the surfaces. Depending on the alkali–support interaction, the deposition of alkalis can selectively modify the bindings of reaction intermediates involved in CO 2 hydrogenation via the interplay among the ionic, covalent and electrostatic tunings. As a result, CO 2 can be effectively activated and converted into diverse products at the alkali–support interface, ranging from formic acid to methanol and ethanol. The identified selective bond-tuning advances the application of alkalis in promoting catalytic activity and controlling catalytic selectivity at alkali–support interfaces.

03 NATURAL GAS↗
DOE OSTI2024

Dynamical Inference and 3D Imaging of Magnetized Dusty Plasmas

This is the final technical report for this DOE award. The motion of dust particles in a laboratory plasma has been studied for nearly 30 years and has led to the discovery of strongly-coupled crystalline structures and nonequilibrium dynamics governed by gravitational, hydrodynamic, and electrostatic forces. Many of the inter-particle forces are complex; they can be non-reciprocal, and non-additive. Deciphering the mélange of particle interactions has been a challenging task, nevertheless, magnetized dusty plasmas remains an open challenge with limited understanding. With applications ranging from magnetically-confined plasmas for fusion to near-surface planetary environments, this research field is ripe for well-controlled, laboratory experiments and new theoretical tools. In collaboration with the MDPX experiment at Auburn University, this proposal aims to tease apart both the known and unknown forces that drive dusty plasmas in magnetized environments using high-resolution, three-dimensional imaging and particle tracking coupled with modern dynamical inference and machine learning techniques.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2007

Space Plasma Testing of High-Voltage Thin-Film Solar Arrays with Protective Coatings

This paper gives an overview of the space plasma test program for thin-film photovoltaics (TFPV) technologies developed at the Air Force Research Laboratory (AFRL). The main objective of this program is to simulate the effects of space plasma characteristic of LEO and MEO environments on TFPV. Two types of TFPV, amorphous silicon (a-Si) and copper-indium-gallium-diselenide (CIGS), coated with two types of thin-film, multifunctional coatings were used for these studies. This paper reports the results of the first phase of this program, namely the results of preliminary electrostatic charging, arcing, dielectric breakdown, and collection current measurements carried out with a series of TFPV exposed to simulated space plasma at the NASA Glenn Plasma Interaction Facility. The experimental data demonstrate that multifunctional coatings developed for this program provide effective protection against the plasma environment while minimizing impact on power generation performance. This effort is part of an ongoing program led by the Space Vehicles Directorate at the AFRL devoted to the development and space qualification of TFPV and their protective coatings.

Tlomak, Pawel↗
DOE OSTI2026

Understanding cold electron impact on parallel-propagating whistler chorus waves via moment-based quasilinear theory

Earth's magnetosphere hosts a wide range of collisionless particle populations that interact through various wave-particle processes. Among these, cold electrons, with energies below 100 eV, often dominate the plasma density but remain poorly characterized due to measurement challenges such as spacecraft charging and photoelectron contamination. Understanding the contribution of these cold populations to wave–particle interaction is of significant interest. Recent kinetic simulations identified a secondary drift-driven instability, in which parallel-propagating whistler-mode chorus waves excite oblique electrostatic whistler waves near the resonance cone and Bernstein-mode turbulence. These secondary modes enable a new channel of energy transfer from the parallel-propagating whistler wave to the cold electrons. In this work, we develop a moment-based quasilinear theory of the secondary instabilities to quantify such energy exchange. Our results show that these secondary instabilities persist for a wide range of parameters and, in many cases, lead to nearly complete damping of the primary wave. Such secondary instability might limit the amplitude of parallel-propagating whistler waves in Earth's magnetosphere and might explain why high-amplitude oblique whistler or electron Bernstein waves are rarely observed simultaneously with high-amplitude field-aligned whistler waves in the inner magnetosphere.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Single-shot ionization-based monitor for pulsed electron beams

In this work, we present an experimental demonstration of a single-shot, nondestructive electron beam diagnostic based on the ionization of a low-density pulsed gas jet. In our study, 7 MeV electron bunches from a radio-frequency photoinjector, carrying up to 100 pC of charge, traversed a localized distribution of nitrogen gas (N 2 ). The interaction of the electron bunches with the N 2 gas generated a correlated signature in the ionized particle distribution, which was spatially magnified using a series of electrostatic lenses and recorded with a microchannel-plate detector. Various modalities, including point-to-point imaging and velocity mapping, are investigated. A temporal trace of the detector current enabled the identification of single- and double-ionization events. The characteristics of the ionization distribution, dependence on gas density, total bunch charge, and other parameters, are described. Approaches to scaling to higher electron bunch density and energy are suggested. Additionally, the instrument proves useful for comprehensive studies of the ionization process itself.

47 OTHER INSTRUMENTATION↗