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At least 415 records · Page 23

Empirical orthogonal functions and multiple flow regimes in the Southern Hemisphere winter

A new empirical orthogonal function (EOF) analysis of winter 500 mb geopotential height anomalies in the Southern Hemisphere is presented. An earlier EOF analysis prefiltered the anomalies to exclude wavenumbers 5 and higher; the present analysis does not. The different preprocessing of data affects the results. All three distinct planetary flow regimes identified in the winter circulation of the Southern Hemisphere by a pattern correlation method are captured by the new set of EOFs; only two of those regimes were captured by the earlier set. The new results, therefore, lend further support to the idea that EOFs point to distinct planetary flow regimes.

Farrara, John D.↗

Loop current eddy shedding estimated using Geosat altimeter data

A method for extracting periodic signals from altimeter data is applied in the Gulf of Mexico using data from the first two years of the Geosat Exact Repeat Mission. The least squares fitting of selected frequencies of sine and cosine functions to the time series of sea surface height at each point of the Geosat ground track is used to estimate the dominant frequency in the gulf for this time period. Optimal interpolation of the sine and cosine coefficients at the dominant frequency to a uniformly spaced grid allows reconstruction of the time series in the gulf and shows eddies shedding from the Loop Current with a period of approximately 10.5 months, consistent with shedding periods determined from numerical models and analysis of satellite infrared data. This technique is a novel method for investigation of periodic signals in Geosat altimetry and is not severely affected by the data outages present in the time series.

Jacobs, Gregg A.↗

Scanning Backscatter Lidar Observations for Characterizing 4-D Cloud and Aerosol Fields to Improve Radiative Transfer Parameterizations

Clouds have a powerful influence on atmospheric radiative transfer and hence are crucial to understanding and interpreting the exchange of radiation between the Earth's surface, the atmosphere, and space. Because clouds are highly variable in space, time and physical makeup, it is important to be able to observe them in three dimensions (3-D) with sufficient resolution that the data can be used to generate and validate parameterizations of cloud fields at the resolution scale of global climate models (GCMs). Simulation of photon transport in three dimensionally inhomogeneous cloud fields show that spatial inhomogeneities tend to decrease cloud reflection and absorption and increase direct and diffuse transmission, Therefore it is an important task to characterize cloud spatial structures in three dimensions on the scale of GCM grid elements. In order to validate cloud parameterizations that represent the ensemble, or mean and variance of cloud properties within a GCM grid element, measurements of the parameters must be obtained on a much finer scale so that the statistics on those measurements are truly representative. High spatial sampling resolution is required, on the order of 1 km or less. Since the radiation fields respond almost instantaneously to changes in the cloud field, and clouds changes occur on scales of seconds and less when viewed on scales of approximately 100m, the temporal resolution of cloud properties should be measured and characterized on second time scales. GCM time steps are typically on the order of an hour, but in order to obtain sufficient statistical representations of cloud properties in the parameterizations that are used as model inputs, averaged values of cloud properties should be calculated on time scales on the order of 10-100 s. The Holographic Airborne Rotating Lidar Instrument Experiment (HARLIE) provides exceptional temporal (100 ms) and spatial (30 m) resolution measurements of aerosol and cloud backscatter in three dimensions. HARLIE was used in a ground-based configuration in several recent field campaigns. Principal data products include aerosol backscatter profiles, boundary layer heights, entrainment zone thickness, cloud fraction as a function of altitude and horizontal wind vector profiles based on correlating the motions of clouds and aerosol structures across portions of the scan. Comparisons will be made between various cloud detecting instruments to develop a baseline performance metric.

Schwemmer, Geary K.↗

Determining True Sensor Spatial Resolution of Very High Resolution Optical Imagery

Some satellite data is delivered in images with gridded pixels. This gridded pixel size is often assumed to be the spatial resolution of the satellite sensor; however, this is not always the case. An image can be grided to any arbitrary pixel size, but the sensor resolution will remain constant. For example, an image with a pixel grid size much smaller than the sensor resolution will appear blurry along what should be sharp transitions. This discrepancy between an image’s pixel size and true sensor spatial resolution can be the source of much confusion and even misinformation among data users, which may lead them to waste time and resources on using images that do not suit their spatial resolution needs. This presentation will highlight our evaluation of the true spatial resolution of various government and commercial images in the pixel size range of 0.3 m to 60 m. Images evaluated include ESA’s Sentinel-2 (60 m, 20 m, 10 m pixels), USGS’s Landsat 8/9 (30 m & 15 m pixels), Planet’s SuperDoves (3 m pixels), BlackSky’s Globals (~1 m pixels), and the optical bands of Maxar’s WorldView-2 (2.4 m – 0.41 m pixels) and WorldView-3 (1.38 m – 0.31 m pixels). Our evaluation of true sensor spatial resolution, or ‘footprint size’ is based on the sensor’s line spread function (LSF). We calculate the width at half the height of the LSF to find the full width at half maximum (FWHM). The FWHM is how we report sensor spatial resolution. Different objects are examined for constructing the LSF depending on the sensor spatial resolution. Coarser resolution sensors in this evaluation such as Sentinel-2 and Landsat 8/9 are examined at bridges over a dark water background. The bright bridge acts as a line impulse, giving a sensor’s line spread function (LSF) in one direction. Additionally, we simulate the impacts of bridge width on the apparent LSF to obtain a true LSF without the effects of bridge width for these sensors. Finer resolution sensors will image the irregularities in bridges such as trusses, sidewalks, and in some cases painted lines, interfering with the LSF construction. Instead, these sensors are evaluated at large (60 m – 140 m) black and white checkerboards known as Cal/Val sites. At these locations, the image’s transition from black to white is extracted as an edge spread function (ESF). We calculate the derivative of this ESF to obtain the sensor’s LSF. From there, we find the FWHM as we do for the coarser resolution images. With the FWHM and pixel size, we determine how over- or under-sampled the images are. When the ratio of a sensor’s spatial resolution and the gridded image’s pixel size is less than 1, the image is considered under-sampled. In this case, each pixel’s information is unique but only a portion of that pixel’s ground area has been measured. On the other side, if the ratio is greater than 1, the image is considered over-sampled. That is, each pixel’s information is sourced from within the ground extent of the pixel and some extent outside additionally. We will show the true spatial resolution and the extent of over-/under-sampling in the imagery from ESA’s Sentinel-2 (60 m, 20 m, 10 m pixels), USGS’s Landsat 8/9 (30 m & 15 m pixels), Planet’s SuperDoves (3 m pixels), BlackSky’s Globals (~1 m pixels), and the optical bands of Maxar’s WorldView-2 (2.4 m – 0.41 m pixels) and WorldView-3 (1.38 m – 0.31 m pixels).

Alana Semple↗

Programmable Site-Specific Functionalization of DNA Origami with Polynucleotide Brushes

Combining surface-initiated, TdT (terminal deoxynucleotidyl transferase) catalyzed enzymatic polymerization (SI-TcEP) with precisely engineered DNA origami nanostructures (DONs) presents an innovative pathway for the generation of stable, polynucleotide brush-functionalized DNA nanostructures. Here we demonstrate that SI-TcEP can site-specifically pattern DONs with brushes containing both natural and non-natural nucleotides. The brush functionalization can be precisely controlled in terms of the location of initiation sites on the origami core and the brush height and composition. Coarse-grained simulations predict the conformation of the brush-functionalized DONs that agree well with the experimentally observed morphologies. We find that polynucleotide brush-functionalization increases the nuclease resistance of DONs significantly, and that this stability can be spatially programmed through the site-specific growth of polynucleotide brushes. The ability to site-specifically decorate DONs with brushes of natural and non-natural nucleotides provides access to a large range of functionalized DON architectures that would allow for further supramolecular assembly, and for potential applications in smart nanoscale delivery systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Landscape-scale characterization of Arctic tundra vegetation composition, structure, and function with a multi-sensor unoccupied aerial system

The Arctic is experiencing some of the most rapid climate change on Earth, with strong impacts on tundra ecosystems that are characterized by high land-surface and vegetation heterogeneity. Previous studies have explored this complexity using satellite remote sensing, however these typically coarse spatial resolution data have generally missed sub-pixel heterogeneity, leaving critical gaps in our understanding of tundra vegetation dynamics from the community to landscape scales. To address these gaps, we collected very high-resolution (1-5 cm) optical, structural, and thermal data at three low-Arctic tundra sites on the Seward Peninsula, Alaska, using a multi-sensor unoccupied aerial system (UAS). We examined the application of these data to studying tundra vegetation dynamics, by quantifying (1) canopy height and thermoregulation (leaf-air temperature) of representative plant functional types (PFTs), (2) fine-scale patterns of vegetation composition across landscapes, and (3) impacts of fine-scale vegetation composition on landscape-scale variation of canopy height and thermoregulation. Our results show that deciduous tall shrubs (those that can potentially grow >2 m) had a strong cooling effect, with canopy temperatures significantly lower than local air temperatures and other PFTs. Increased cover of tall shrubs also had the potential to reduce the cover of low-stature PFTs across the landscape, potentially associated with their closed canopy (i.e., increased light competition) and strong thermoregulation. To understand the connections between fine-scale vegetation composition and large-scale ecosystem processes, we produced a random forest model which showed that fine-scale PFT composition accounted for 86.8% and 74.2% of the landscape-scale variation in canopy height and thermoregulation, respectively. These findings highlight the importance of spatially detailed characterization of tundra PFTs to improve our ecological understanding and model representation of tundra vegetation, also transcend our study to show the need for continued collection of similar datasets to better understand the impacts of surface heterogeneity on the mapping and modeling of tundra ecosystem dynamics, as well as assist with conservation management and biodiversity monitoring strategies.

54 ENVIRONMENTAL SCIENCES↗

Investigation of K + K – interactions via femtoscopy in Pb-Pb collisions at s N N = 2.76 TeV at the CERN Large Hadron Collider

Femtoscopic correlations of nonidentical charged kaons (K + K – ) are studied in Pb-Pb collisions at a center-of-mass energy per nucleon-nucleon collision $\sqrt{s_{NN}}$=2.76 TeV by ALICE at the CERN Large Hadron Collider. One-dimensional K + K – correlation functions are analyzed in three centrality classes and eight intervals of particle-pair transverse momentum. The Lednický and Luboshitz interaction model used in the K + K – analysis includes the final-state Coulomb interactions between kaons and the final-state interaction through a 0 (980) and f 0 (980) resonances. The mass of f 0 (980) and coupling were extracted from the fit to K + K – correlation functions using the femtoscopic technique. The measured mass and width of the f 0 (980) resonance are consistent with other published measurements. The height of the $\phi$(1020) meson peak present in the K + K – correlation function rapidly decreases with increasing source radius, qualitatively in agreement with an inverse volume dependence. A phenomenological fit to this trend suggests that the $\phi$(1020) meson yield is dominated by particles produced directly from the hadronization of the system. The small fraction subsequently produced by final-state interactions could not be precisely quantified with data presented in this paper and will be assessed in future work.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Reflectance Modeling

The main thrust of the work conducted is in the modeling of spectral responses of discontinuous conifer forest canopies, considered as collections of conical forms that are illuminated at an angle and cast shadows on contracting background. The three first-year objectives are: (1) modification of the variance-driven model to incorporate overlapping of shadows and crowns; (2) collection and analysis of photographic data to calibrate tree-spacing functions; and (3) collection of field data to determine height, spacing, and shape of conifers in open and closed stands in the Goosenest (California) test area. Modification of the invertible model uses a linear approximation to correct for the reduction in shadow and canopy area that occurs when shadows fall on crowns or tree crowns intersect. Comparison of the results of the approximation with a series of Monte Carlo simulations shows that the mean area covered by crowns or shadows is approximated quite accurately, but the variance calculated departs significantly from simulated values. The analysis of tree spacing patterns using air photos showed that spacing tended to be somewhat regular at a scale approximately equal to the average distance between trees, but at larger distance scales counts of trees in cells could be approximated acceptably by a Poisson (random) function.

Strahler, A. H.↗

Application of the Convolution Formalism to the Ocean Tide Potential: Results from the Gravity and Recovery and Climate Experiment (GRACE)

A computationally efficient approach to reducing omission errors in ocean tide potential models is derived and evaluated using data from the Gravity Recovery and Climate Experiment (GRACE) mission. Ocean tide height models are usually explicitly available at a few frequencies, and a smooth unit response is assumed to infer the response across the tidal spectrum. The convolution formalism of Munk and Cartwright (1966) models this response function with a Fourier series. This allows the total ocean tide height, and therefore the total ocean tide potential, to be modeled as a weighted sum of past, present, and future values of the tide-generating potential. Previous applications of the convolution formalism have usually been limited to tide height models, but we extend it to ocean tide potential models. We use luni-solar ephemerides to derive the required tide-generating potential so that the complete spectrum of the ocean tide potential is efficiently represented. In contrast, the traditionally adopted harmonic model of the ocean tide potential requires the explicit sum of the contributions from individual tidal frequencies. It is therefore subject to omission errors from neglected frequencies and is computationally more intensive. Intersatellite range rate data from the GRACE mission are used to compare convolution and harmonic models of the ocean tide potential. The monthly range rate residual variance is smaller by 4-5%, and the daily residual variance is smaller by as much as 15% when using the convolution model than when using a harmonic model that is defined by twice the number of parameters.

models↗

Interface formation and Schottky barrier height for Y, Nb, Au, and Pt on Ge as determined by hard x-ray photoelectron spectroscopy

Development of a robust, thin, hole-blocking (n+) contact on high purity germanium (HPGe) has been the main challenge in the development of Ge-based radiation sensors. Yttrium has been reported to be a viable hole-blocking contact on HPGe, and detectors with low leakage have been fabricated. Niobium has also been considered as a potential hole-blocking contact due to its low work function. Here, we investigate interface chemistry and the Schottky barrier height of Y and Nb, as well as electron-blocking contacts Au and Pt, on Ge(100) surfaces using hard x-ray photoelectron spectroscopy. We find a barrier height of 1.05 ± 0.10 eV for Y/HPGe, confirming the formation of a hole-blocking barrier. For Nb/HPGe, the barrier height of 0.13 ± 0.10 eV demonstrates that the interface is not hole-blocking. The Schottky barrier of Au and Pt was found to be 0.45 ± 0.10 and 0.51 ± 0.10 eV, respectively.

36 MATERIALS SCIENCE↗

The effect of latent heat release on synoptic-to-planetary scale wave interactions: Observational study

A blocking pattern which formed over eastern North America following the landfall of Hurricane Juan during November 1985 was investigated. It is hypothesize that latent heat released in the Hurricane's rainfall was either directly or indirectly responsible for the large observed 500 mb height rises over eastern Canada during the formation of this block. This idea is evaluated with a diagnostic model for the height tendency field which includes latent heat release as a forcing function. The total column heating is calculated using satellite-derived precipitation estimates. These estimates are qualitatively congruent with observations, but overestimate light rainfall and underestimate heavy rainfall. The calculations reveal that the direct contribution of the heating to the 500 mb height tendency field is small relative to the quasigeostrophic forcing. However, maxima in heating coincide with regions where anticyclonic potential vorticity is generated. Once such region is just upstream of the location of large 500 mb height rises in the incipient block. An indirect role is proposed for the heating in this case. Specifically, anticyclonic potential vorticity is generated near the heating maxima; this vorticity is then advected downstream, forcing the 500 mb heights to rise and the block to develop.

Colucci, Stephen↗

Ion temperature troughs induced by a meridional neutral air wind in the night-time equatorial topside ionosphere

A mathematical model was constructed to calculate O(+) and H(+) concentrations, field-aligned velocities, and electron temperatures in the night-time equatorial topside ionosphere. The model is used to establish the ability of F-region neutral air winds to produce observed ion temperature distributions, and to study the properties of ion temperature troughs as functions of altitude, latitude, and ionospheric composition. The O(+) - H (+) transition height represents an altitude limit above which the ion cooling from adiabatic expansion of the plasma is very small; the northern and southern edges of the ion temperature troughs are restricted to the limiting dip altitudes determined by magnetic field line geometry and by the functional form of the F-region neutral wind velocity.

Bailey, G. J.↗

Building heights and urban canopy parameters for urban modeling

GLObal Building heights for Urban Studies (UT-GLOBUS) is a random forest model based framework that provides a level-of-detail-1 (LoD-1) building height dataset. The primary objective of UT-GLOBUS is not to precisely predict the height and footprint of individual buildings, but rather to offer a functional framework for generating building level information using open-source datasets for modeling applications. Specifically, UT-GLOBUS is tailored to meet the requirements of deriving urban canopy parameters (UCPs) for the multi-layer model within the Weather Research and Forecasting (WRF) model and building heights for the SOLWEIG and SUEWS model. Building-level data is accessible in vector file format (GeoPackage: .gpkg), which can be converted into raster file format (geoTIFF). The vector files employ the Universal Transverse Mercator (UTM) projection. The vector files are compatible with GIS platforms like QGIS and ArcGIS, and can be imported for analysis using programming languages such as Python. We are also providing UCPs required by the multi-layer urban model in the urban WRF in binary file format. Additionally, we provide the urban fractions calculated using ESA world cover dataset (https://esa-worldcover.org/en) for WRF model in binary file format. These binary files can be directly incorporated into the WRF pre-processing system (WPS).

54 ENVIRONMENTAL SCIENCES↗

Infrared spectra of molecules and materials of astrophysical interest

The Raman spectra of gaseous, liquid and solid, and infrared spectra of gaseous and solid isopropylamine-d sub 0 and -d sub 2 was investigated between 4000 and 50 cm superscript -1. Differences between the spectrum of the solid phase and that of the fluid phases were interpreted in terms of an equilibrium between low energy s-trans and high energy gauche conformers, and a complete vibrational assignment was proposed for the s-trans conformer. The far infrared spectra of the gaseous compounds contained bands due to the asymmetric amino and coupled methyl torsions; the assignment of these bands was aided by observation of a number of two quantum transitions for each vibrational mode. The asymmetric potential functions were calculated, which resulted in values for the enthalpy differences between conformers in the gaseous phase of 446 and 523 callmole for the sub 0 -d and -d sub 2 compounds, respectively. The methyl torsional potential function of isopropylamine-d sub 0 was calculated which led to a value for the barrier height to internal rotation of the methyl rotors of 4.23 + or - 0.06 kcal/mole. Values for the ideal gas thermodynamic functions were calculated over a range of temperatures.

Durig, J. R.↗

A three-dimensional model of terrain-induced updrafts for movement ecology studies

Abstract Background Spatially explicit simulation models of animal movements through the atmosphere necessarily require a representation of the spatial and temporal variation of atmospheric conditions. In particular, for movements of soaring birds that rely extensively on vertical updrafts to avoid flapping flight, accurate and reliable estimation of the vertical component of wind is critical. The interaction between wind and complex terrain shapes both the horizontal and vertical wind fields, highlighting the need to model the coupling between local terrain features and atmospheric conditions at scales relevant to animal movement. Methods In this work, we propose a new empirical model for estimating the orographic updraft field. The model is developed using computational fluid dynamics simulations of canonical atmospheric conditions over moderately complex terrain. To isolate buoyancy and thermal effects, and focus on terrain-induced effects, we use only simulations of a neutrally stratified atmosphere to develop the model. The model, which we name Engineering Vertical Velocity Estimator (EVVE), is simple to implement and is a function of the underlying terrain elevation map, the desired height above ground level (AGL), and wind conditions at a reference height (80 m). We validate the model with data from the Alaiz mountain (Spain) field campaign. Results Compared to observations, the proposed improved model estimates the updrafts at 120 m AGL with a mean error of 0.11 m/s ( $$\sigma =0.28$$ σ = 0.28 m/s), compared to 0.85 m/s ( $$\sigma =0.58$$ σ = 0.58 m/s) for its baseline. For typical land-based wind turbine hub heights of 80 m AGL, the proposed model has a mean error of 0.04 m/s ( $$\sigma =0.25$$ σ = 0.25 m/s), compared to baseline 0.54 m/s ( $$\sigma =0.45$$ σ = 0.45 m/s) estimations. We illustrate an application of the model in movement ecology by comparing simulated tracks and presence maps of golden eagles ( Aquila chrysaetos ) moving across two distinct landscapes. The tracks and presence maps are obtained using a simple heuristic-based movement model, with the updraft field given by the proposed model and a wind vector-based estimation approach that is currently in wide use in movement ecology studies of raptors and other soaring birds. Conclusions We highlight that movement model results can be sensitive to the underlying orographic updraft model, especially in studies of fine-scale movements in regions of complex topography. We suggest adopting the proposed model rather than the wind vector estimation method for studies of soaring bird movements.

17 WIND ENERGY↗

Systems for measuring response statistics of gigahertz bandwidth photomultipliers

New systems have been developed for measuring the average impulse response, the pulse-height spectrum, the transit-time statistics as a function of signal level, and the dark-count spectrum of gigahertz bandwidth photomultipliers. Measurements showed that the 0.53 microns pulse used as an optical test source had a 30 picoseconds and less than 70 ps pulse width. Calibration data showed the system resolution to be less than 20 ps for root mean square transit-time measurements. Test data for a static crossed-field photomultiplier showed 2-photoelectron resolution and less than 30-ps time jitter over the 1- to 100-photoelectron range.

Abshire, J. B.↗

Observations and models of inertial waves in the deep ocean

A study of the structure of the inertial peak in deep ocean kinetic energy is presented, based on records taken from Polymode arrays deployed in the western North Atlantic Ocean. Results are interpreted in terms of both local sources and turning point effects on internal waves generated at lower latitudes, and it is found that three classes of environment and their corresponding spectra emerge from peak height variations: (1) the 1500-m level near the Mid-Atlantic Ridge, with the greatest peak height of 18 dB; (2) the upper and deep ocean over rough topography and the deep ocean underneath the Gulf Stream, with the intermediate peak height of 11.5 dB; and (3) the deep ocean over smooth topography, with the lowest peak height of 7.5 dB. Using the globally valid wave functions obtained by Munk and Phillips (1968), frequency spectra near f are calculated numerically. The model is latitudinally dependent, with the frequency shift and bandwidth of the inertial peak decreasing with latitude.

Fu, L.-L.↗

Capillary rise, wetting layers, and critical phenomena in confined geometry

Interferometric procedures have been used to measure the thickness of the wetting layers of liquid SF6 which intrude between SF6 vapor and the walls of an interferometer. Close to the critical temperature the measurements show that the layers become thicker as the height at which they are observed approaches the height of the bulk liquid-vapor meniscus. The functional form of the thickness increase agrees with the dependence expected from models in which the layers' thicknesses are governed by a competition between gravitational and van der Waals forces. The layers are a factor of three thicker than a simple estimate based on such models. No evidence is found of a transition from three-dimensional critical behavior towards two-dimensional critical behavior in the available temperature and size ranges. This contrasts with the interpretation of experiments in binary liquid mixtures carried out with comparable size and temperature resolution.

Moldover, M. R.↗