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Aromatic/aliphatic diamine derivatives for advanced compositions and polymers

Novel compositions of matter comprise certain derivatives of 9,9-dialkyl fluorene diamine (AFDA). The resultant compositions, whether compositions of matter or monomers that are subsequently incorporated into a polymer, are unique and useful in a variety of applications. Useful applications of AFDA-based material include heavy ion radiation shielding components and components of optical and electronic devices.

Delozier, Donovan M.↗

Space Weathering of Lunar Rocks and Regolith Grains

The exposed surfaces of lunar soil grains and lunar rocks become modified and coated over time with a thin rind of material (patina) through complex interactions with the space environment. These interactions encompass many processes including micrometeorite impacts, vapor and melt deposition, and solar wind implantation/sputtering effects that collectively are referred to as "space weathering". Studies of space weathering effects in lunar soils and rocks provide important clues to understanding the origin and evolution of the lunar regolith as well as aiding in the interpretation of global chemical and mineralogical datasets obtained by remote-sensing missions. The interpretation of reflectance spectra obtained by these missions is complicated because the patina coatings obscure the underlying rock mineralogy and compositions. Much of our understanding of these processes and products comes from decades of work on remote-sensing observations of the Moon, the analysis of lunar samples, and laboratory experiments. Space weathering effects collectively result in a reddened continuum slope, lowered albedo, and attenuated absorption features in reflectance spectra of lunar soils as compared to finely comminuted rocks from the same Apollo sites. Space weathering effects are largely surface-correlated, concentrated in the fine size fractions, and occur as amorphous rims on individual soil grains. Rims on lunar soil grains are highly complex and span the range between erosional surfaces modified by solar wind irradiation to depositional surfaces modified by the condensation of sputtered ions and impact-generated vapors. The optical effects of space weathering effects are directly linked to the production of nanophase Fe metal in lunar materials]. The size of distribution of nanophase inclusions in the rims directly affect optical properties given that large Fe(sup o) grains (approx 10 nm and larger) darken the sample (lower albedo) while the tiny Fe(sup o) grains (<5nm) are the primary agent in spectral "reddening". More recent work has focused on the nature and abundance of OH/H2O in the lunar regolith using orbital data and samples analyses. Advances in sample preparation techniques have made possible detailed analyses of patina-coated rock surfaces. Major advances are occurring in quantifying the rates and efficiency of space weathering processes through laboratory experimentation.

Keller, L. P.↗

Toward Large-Area Sub-Arcsecond X-Ray Telescopes

The future of x-ray astronomy depends upon development of x-ray telescopes with larger aperture areas (>1 sq m) and finer angular resolution(<1).Combined with the special requirements of nested grazing incidence optics, the mass and envelope constraints of spaceborne telescopes render such advances technologically challenging. Achieving this goal will require precision fabrication, alignment, mounting, and assembly of large areas (>100 sq m) of lightweight (1 kg/sq m areal density) high quality mirrors-possibly entailing active (in-space adjustable) alignment and figure correction. This paper discusses relevant programmatic and technological issues and summarizes progress toward large area sub-arcsecond x-ray telescopes. Key words: X-ray telescopes, x-ray optics, active optics, electroactive devices, silicon mirrors, differential deposition, ion implantation.

O'Dell, Stephen L.↗

Integrity Monitoring of Mercury Discharge Lamps

Mercury discharge lamps are critical in many trapped ion frequency standard applications. An integrity monitoring system can be implemented using end-of-life signatures observed in operational mercury discharge lamps, making it possible to forecast imminent failure and to take action to mitigate the consequences (such as switching to a redundant system). Mercury lamps are used as a source of 194-nm ultraviolet radiation for optical pumping and state selection of mercury trapped ion frequency standards. Lamps are typically fabricated using 202Hg distilled into high-purity quartz, or other 194-nm transmitting material (e.g., sapphire). A buffer gas is also placed into the bulb, typically a noble gas such as argon, neon, or krypton. The bulbs are driven by strong RF fields oscillating at .200 MHz. The lamp output may age over time by two internal mechanisms: (1) the darkening of the bulb that attenuates light transmission and (2) the loss of mercury due to migration or chemical interactions with the bulb surface. During fabrication, excess mercury is placed into a bulb, so that the loss rate is compensated with new mercury emanating from a cool tip or adjacent reservoir. The light output is nearly constant or varies slightly at a constant rate for many months/years until the mercury source is depleted. At this point, the vapor pressure abruptly falls and the total light output and atomic clock SNR (signal-to-noise ratio) decrease. After several days to weeks, the light levels decrease to a point where the atomic clock SNR is no longer sufficient to stay in lock, or the lamp self-extinguishes. This signature has been observed in four separate end-of-life lamp failures while operating in the Deep Space Network (DSN). A simple integrator circuit can observe and document steady-state lamp behavior. When the light levels drop over a predetermined time interval by a specified amount (e.g., 20 percent), an alarm is set. For critical operational applications, such as the DSN or in space flight, this warning provides notice that a failure may be imminent, and for operators or control algorithm to take action.

Tjoelker, Robert L.↗

Optical observations on the CRIT-II Critical Ionization Velocity Experiment

A rocket borne Critical Ionization Velocity (CIV0 experiment was carried out from Wallops Island at dusk on May 4, 1989. Two barium shaped charges were released below the solar terminator (to prevent photoionization) at altitudes near 400 km. The ambient ionospheric electron density was 50,000/cu cm. The neutral barium jet was directed upward and at an angle of nominally 45 degrees to B which gives approximately 3 x 10 to the 23rd neutrals with super critical velocity. Ions created by a CIV process in the region of the neutral jet would travel up along B into sunlight where they can be detected optically. Well defined ion clouds (max. brightness 750 R) were observed in both releases. An ionization rate of 0.8 percent/sec (125 sec ionization time constant) can account for the observed ion cloud near the release field line, but the ionization rate falls off with increasing distance from the release. It is concluded that a CIV process was present in the neutral jet out to about 50 km from the release, which is significantly further than allowed by current theories.

Stenbaek-Nielsen, H. C.↗

Operation of a microchannel plate counting system in a mass spectrometer

A multiplier detector system has been developed as part of a mass spectrometer in an ion counting mode. During its operation ions striking a microchannel plate release pulses of electrons which are accelerated to a phosphor layer. The resulting flash of light is carried by a fiber-optic bundle to a photodiode array. The detector simultaneously counts ions throughout a mass spectrum covering more than 30 amu. It extends the mass spectrometer's operation toward low count rates for trace gas analysis. Each mass peak can be independently measured at count rates between 0.1 and 1000 counts/s. Higher rates on a few peaks do not blind the entire detector. The detector's capabilities have been demonstrated by measuring Kr and Xe isotopes in air at natural abundances. The mass spectrometer, detector, and readout electronics are sufficiently compact to permit use in a balloon-borne experiment.

Murphy, D. M.↗

NASA Tech Briefs, July 2008

Topics covered include: Torque Sensor Based on Tunnel-Diode Oscillator; Shaft-Angle Sensor Based on Tunnel-Diode Oscillator; Ground Facility for Vicarious Calibration of Skyborne Sensors; Optical Pressure-Temperature Sensor for a Combustion Chamber; Impact-Locator Sensor Panels; Low-Loss Waveguides for Terahertz Frequencies; MEMS/ECD Method for Making Bi(2-x)Sb(x)Te3 Thermoelectric Devices; Low-Temperature Supercapacitors; Making a Back-Illuminated Imager with Back-Side Contact and Alignment Markers; Compact, Single-Stage MMIC InP HEMT Amplifier; Nb(x)Ti(1-x)N Superconducting-Nanowire Single-Photon Detectors; Improved Sand-Compaction Method for Lost-Foam Metal Casting; Improved Probe for Evaluating Compaction of Mold Sand; Polymer-Based Composite Catholytes for Li Thin-Film Cells; Using ALD To Bond CNTs to Substrates and Matrices; Alternating-Composition Layered Ceramic Barrier Coatings; Variable-Structure Control of a Model Glider Airplane; Axial Halbach Magnetic Bearings; Compact, Non-Pneumatic Rock-Powder Samplers; Biochips Containing Arrays of Carbon-Nanotube Electrodes; Nb(x)Ti(1-x)N Superconducting-Nanowire Single-Photon Detectors; Neon as a Buffer Gas for a Mercury-Ion Clock; Miniature Incandescent Lamps as Fiber-Optic Light Sources; Bidirectional Pressure-Regulator System; and Prism Window for Optical Alignment. Single-Grid-Pair Fourier Telescope for Imaging in Hard-X Rays and gamma Rays Range-Gated Metrology with Compact Optical Head Lossless, Multi-Spectral Data Compressor for Improved Compression for Pushbroom-Typetruments.

Source record↗

Optical study of charge exchange collisions between He+ and CO2.

Helium ions were produced in an electron bombardment ion source and directed into a gas cell containing carbon dioxide. A Wien filter placed between the ion source and the gas cell insured that only singly charged helium ions reached the cell. The spectrum obtained for the bombardment of carbon dioxide with the helium ions at 1200 eV is shown in a graph. Prominent features of the lower spectrum are two atomic lines at 3889 and 4471 A.

Coplan, M. A.↗

A 7700 hour endurance test of a 30-cm Kaufman thruster

This paper describes an ongoing endurance test of the ion thruster which is expected to form the basis of future prime propulsion systems. The purpose of the test is to demonstrate the lifetime capability of such critical components as cathodes, vaporizers, isolators, and optics. The endurance test was preceded by development of an ion engine life test system and several intermediate duration tests. The elements of the test system are briefly described and the thruster modifications which resulted from the intermediate tests are evaluated in terms of the endurance test results. Thruster performance during the endurance test is described as well as the conclusions that can be drawn from the 8600 hours that have been completed as of March 6, 1975.

Collett, C. R.↗

SR90, strontium shaped-charge critical ionization velocity experiment

In May 1986 an experiment was performed to test Alfven's critical ionization velocity (CIV) effect in free space, using the first high explosive shaped charge with a conical liner of strontium metal. The release, made at 540 km altitude at dawn twilight, was aimed at 48 deg to B. The background electron density was 1.5 x 10(exp 4) cu cm. A faint field-aligned Sr(+) ion streak with tip velocity of 2.6 km/s was observed from two optical sites. Using two calibration methods, it was calculated that between 4.5 x 10(exp 20) and 2 x 10(exp 21) ions were visible. An ionization time constant of 1920 s was calculated for Sr from the solar UV spectrum and ionization cross section which combined with a computer simulation of the injection predicts 1.7 x 10(exp 21) solar UV ions in the low-velocity part of the ion streak. Thus all the observed ions are from solar UV ionization of the slow (less than critical) velocity portion of the neutral jet. The observed neutral Sr velocity distribution and computer simulations indicate that 2 x 10(exp 21) solar UV ions would have been created from the fast (greater than critical) part of the jet. They would have been more diffuse, and were not observed. Using this fact it was estimated that any CIV ions created were less than 10(exp 21). It was concluded that future Sr CIV free space experiments should be conducted below the UV shadow height and in much larger background plasma density.

Wescott, Eugene M.↗

Hubble Space Telescope Faint Object Spectrograph and ground-based observations of the broad absorption line quasar 0226-1024

Faint Object Spectrograph data from the Hubble Space Telescope of the broad absorption line quasar 0226-1024 have revealed the presence of 8-10 absorbing ions between 680 and 1000 A (restframe): C III, N III, N IV, O III, O IV, O VI, S V, S VI, possibly Ne VIII, and possibly O V* arising from a metastable excited state. We also present ground-based optical observations of the broad line troughs for the following ions: H I, C IV, N V, Si IV, and possibly Fe III, S IV, P V, and C III* (also arising from a metastable excited state). The results of this fit are used to estimate the absorbing ionic column densities. There is evidence that the broad absorption line clouds are optically thick and either do not completely cover the continuum source or narrow unresolved lines are present.

Korista, Kirk T.↗

Heavy-ion total and absorption cross sections above 25 MeV/nucleon

Within the context of a double-folding optical potential approximation to the exact nucleus-nucleus multiple-scattering series, eikonal scattering theory is used to generate tables of heavy ion total and absorption cross sections at incident kinetic energies above 25 MeV/nucleon for use in cosmic ray high-energy heavy ion transport and shielding studies. Comparisons of predictions with nucleus-nucleus experimental data show excellent agreement except at the lowest energies, where the eikonal approximation may not be completely valid. Even at the lowest energies, however, agreement is typically within 20 percent.

Townsend, L. W.↗

Ellipsometric and optical study of amorphous hydrogenated carbon films

A low-frequency plasma deposition system was used to prepare amorphous hydrogenated carbon (a-C:H) films. The growth energy was varied by changing the power and/or pressure of the plasma. Ellipsometry and optical absorption were used to obtain the optical energy gap, the density of states, and the refractive index. Ion sputtering was used in conjunction with ellipsometry and Auger electron spectroscopy to get absolute sputtering rates. The plasma deposited a-C:H is amorphous with an optical energy gap of approximately 2.0-2.4 eV. These a-C:H films have higher density and/or hardness, higher refractive index, and lower optical energy gaps with increasing energy of the particles in the plasma, while the density of states remains unchanged. These results are in agreement with, and give a fine-tuned positive confirmation to, an existing conjecture on the nature of the a-C:H films (Kaplan et al., 1985).

Alterovitz, S. A.↗

Preparation and analysis of standardized waste samples for Controlled Ecological Life Support Systems (CELSS)

The preparation and analysis of standardized waste samples for controlled ecological life support systems (CELSS) are considered. Analysis of samples from wet oxidation experiments, the development of ion chromatographic techniques utilizing conventional high pressure liquid chromatography (HPLC) equipment, and an investigation of techniques for interfacing an ion chromatograph (IC) with an inductively coupled plasma optical emission spectrometer (ICPOES) are discussed.

Carden, J. L.↗

Analysis and design of ion thrusters for large space systems

This study undertakes the analysis and conceptual design of a 0.5 Newton electrostatic ion thruster suitable for use on large space system missions in the next decade. Either argon or xenon gas shall be used as propellant. A 50 cm diameter discharge chamber was selected to meet stipulated performance goals. The discharge plasma is contained at the boundary by a periodic structure of alternating permanent magnets generating a series of line cusps. Anode strips between the magnets collect Maxwellian electrons generated by a central cathode. Ion extraction utilizes either two or three grid optics at the user's choice. An extensive analysis was undertaken to investigate optics behavior in the high power environment of this large thruster. A plasma bridge neutralizer operating on inert gas provides charge neutralizing electrons to complete the design. The resulting conceptual thruster and the necessary power management and control requirements are described.

James, E. L.↗

Ion propulsion system design and throttling strategies for planetary missions

This paper describes recent advances in ion propulsion system design which promise to increase the propulsion system reliability by reducing the overall system complexity. The greatest simplification in the overall propulsion system operation is accomplished through a change in the ion engine throttling strategy. By using three grid optics it is possible to effect engine throttling at a constant beam curent over at least a 3.8 to 1 variation in input power. Throttling at a constant beam current results in a single discharge chamber operating point and eliminates the need for active propellant flow controllers and complex engine throttling software. Detailed mission analysis calculations for a CNSR mission performed using this constant beam current throttling strategy indicate only a small reduction in delivered payload and increase in required propellant relative to a conventional throttling profile based on varying the beam curent.

Garner, Charles E.↗