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Complex igneous processes and the formation of the primitive lunar crustal rocks

Crystallization of a magma ocean with initial chondritic Ca/Al and REE ratios such as proposed by Taylor and Bence (TB, 1975), is capable of producing the suite of primitive crustal rocks if the magma ocean underwent locally extensive assimilation and mixing in its upper layers as preliminary steps in formation of an anorthositic crust. Lunar anorthosites were the earliest permanent crustal rocks to form the result of multiple cycles of suspension and assimilation of plagioclase in liquids fractionating olivine and pyroxene. There may be two series of Mg-rich cumulate rocks: one which developed as a result of the equilibration of anorthositic crust with the magma ocean; the other which formed in the later stages of the magma ocean during an epoch of magma mixing and ilmenite crystallization. This second series may be related to KREEP genesis. It is noted that crystallization of the magma ocean had two components: a low pressure component which produced a highly fractionated and heterogeneous crust growing downward and a high pressure component which filled in the ocean from the bottom up, mostly with olivine and low-Ca pyroxene.

Longhi, J.↗

Arcsec source location measurements in gamma-ray astronomy from a lunar observatory

The physical processes typically used in the detection of high energy gamma-rays do not permit good angular resolution, which makes difficult the unambiguous association of discrete gamma-ray sources with objects emitting at other wavelengths. This problem can be overcome by placing gamma-ray detectors on the moon and using the horizon as an occulting edge to achieve arcsec resolution. For the purpose of discussion, this concept is examined for gamma rays above about 20 MeV for which pair production dominates the detection process and locally-generated nuclear gamma rays do not contribute to the background.

Koch, David G.↗

Lunar and Planetary Science XXXV: Mars Polar Processes: Land and Sky

The titles in this section include: 1) Morphological Evidence for the Large-scale Evolution of Martian North Polar Troughs? 2) New Views of the Martian Polar Regions: The Latest Results from the Mars Odyssey THEMIS Investigation; 3) Observations at the Chasma Australe Re-Entrant, South Polar Region, Mars; 4) Stratigraphic Details of Uppermost Units within South Polar Layered Deposits on Mars; 5) Detailed Geologic Analysis of Part of the South Polar Layered Deposits, Planum Australe, Mars: Part II; 6) SHARAD: Radar Volume Scattering and the Polar Layered Terrains on Mars; 7) Arabia and Memnonia Equatorial Regions with High Content of Water: Data from HEND/Odyssey; 8) Alaskan Permafrost Analogs of Martian Small Valley Networks, Thermokarst, Terrain Softening, Terraces, and Volcanic Craters; 9) Periglacial Processes in the Southern Hemisphere of Mars; 10) Thermal Modeling of Possible Surface Water Ice Deposits in Juventae Chasma; 11) Modeling Depth to Ground Ice on Mars; 12) Ground Ice at the Phoenix Landing Site: A Preflight Assessment; 13) Possible Temperature-related Differences in Slope Angle between the North and South Walls of Coprates Chasma, Mars; 14) Seasonal Variations within Korolev Crater, Mars; 15) South Polar Ar Enhancement as a Tracer for Southern Winter Horizontal Meridional Mixing; 16) An Investigation of the Correlation of Water-Ice and Dust Retrievals via the MGS TES Data Set; 17) Observations of Plasma Waves near Mars and Their Implications for Atmospheric Loss.

Source record↗

Design of a lunar oxygen production plant

To achieve permanent human presence and activity on the moon, oxygen is required for both life support and propulsion. Lunar oxygen production using resources existing on the moon will reduce or eliminate the need to transport liquid oxygen from earth. In addition, the co-products of oxygen production will provide metals, structural ceramics, and other volatile compounds. This will enable development of even greater self-sufficiency as the lunar outpost evolves. Ilmenite is the most abundant metal-oxide mineral in the lunar regolith. A process involving the reaction of ilmenite with hydrogen at 1000 C to produce water, followed by the electrolysis of this water to provide oxygen and recycle the hydrogen has been explored. The objective of this 1990 Summer Faculty Project was to design a lunar oxygen-production plant to provide 5 metric tons of liquid oxygen per year from lunar soil. The results of this study describe the size and mass of the equipment, the power needs, feedstock quantity and the engineering details of the plant.

Radhakrishnan, Ramalingam↗

Connecting Returned Apollo Soils and Remote Sensing: Application to the Diviner Lunar Radiometer

The Diviner Lunar Radiometer, onboard NASA's Lunar Reconnaissance Orbiter, has produced the first global, high resolution, thermal infrared observations of an airless body. The Moon, which is the most accessible member of this most abundant class of solar system objects, is also the only body for which we have extraterrestrial samples with known spatial context, returned Apollo samples. Here we present the results of a comprehensive study to reproduce an accurate simulated lunar environment, evaluate the most appropriate sample and measurement conditions, collect thermal infrared spectra of a representative suite of Apollo soils, and correlate them with Diviner observations of the lunar surface. It has been established previously that thermal infrared spectra measured in simulated lunar environment (SLE) are significantly altered from spectra measured under terrestrial or martian conditions. The data presented here were collected at the University of Oxford Simulated Lunar Environment Chamber (SLEC). In SLEC, we simulate the lunar environment by: (1) pumping the chamber to vacuum pressures (less than 10‐4 mbar) sufficient to simulate lunar heat transport processes within the sample, (2) cooling the chamber with liquid nitrogen to simulate radiation to the cold space environment, and (3) heating the samples with heaters and lamp to set‐up thermal gradients similar to those experienced in the upper hundreds of microns of the lunar surface. We then conducted a comprehensive suite of experiments using different sample preparation and heating conditions on Apollo soils 15071 (maria) and 67701 (highland) and compared the results to Diviner noontime data to select the optimal experimental conditions. This study includes thermal infrared SLE measurements of 10084 (A11 - LM), 12001 (A12 - LM), 14259 (A14 - LM), 15071 (A15 - S1), 15601 (A15 - S9a), 61141 (A16 - S1), 66031 (A16 - S6), 67701 (A16 - S11), and 70181 (A17 - LM). The Diviner dataset includes all six Apollo sites at approximately 200 m spatial resolution We find that analyses of Diviner observations of individual sampling stations and SLE measurements returned Apollo soils show good agreement, while comparisons to thermal infrared reflectance under ambient conditions do not agree well, which underscores the need for SLE measurements and validates the Diviner compositional measurement technique.

Greenhagen, B. T.↗

Modeling Solar-Wind Heavy-Ions' Potential Sputtering of Lunar KREEP Surface

Recent laboratory data suggest that potential sputtering may be an important weathering mechanism that can affect the composition of both the lunar surface and its tenuous exosphere; its role and implications, however, remain unclear. Using a relatively simple kinetic model, we will demonstrate that solar-wind heavy ions induced sputtering of KREEP surfaces is critical in establishing the timescale of the overall solar-wind sputtering process of the lunar surface. We will also also show that potential sputtering leads to a more pronounced and significant differentiation between depleted and enriched surface elements. We briefly discuss the impacts of enhanced sputtering on the composition of the regolith and the exosphere, as well as of solar-wind sputtering as a source of hydrogen and water on the moon.

Barghouty, A. F.↗

A Synthesis of Experimental Data Describing the Partitioning of Moderately Volatile Elements in Major Rock Forming Minerals: Implications for the Moon

Highly volatile elements [condensation temperatures below about 700 K] and water are highly informative about lunar bulk composition (hence origin), differentiation and magmatic evolution, and the role of impacts in delivering volatiles to the Moon. Fractionation of volatile elements compared to moderately volatile and refractory elements are informative about high-temperature conditions that operated in the proto-lunar disk. Existing data show clearly that the Moon is depleted in volatile elements compared to the bulk silicate Earth. For example, K/Th is ~400-700 in the Moon compared to 2800-3000 in Earth. A complicating factor is that the abundances of the highly volatile elements in major lunar lithologies vary by approximately two orders of magnitude. Perhaps most interesting, H2O is not correlated with the concentration of volatile elements, indicating a decoupling of highly volatile elements from the even more volatile H2O. We contend that this decoupling could be a significant tracer of processes operating during lunar formation, differentiation, and bombardment, and the combination of analyzing both volatile elements and water is likely to provide significant insight into lunar geochemical history. This variation and lack of correlation raises the question: what were the relative contributions of crystallization in the magma ocean, subsequent mantle overturn, production of secondary magmas, and addition of volatiles by large impacts in producing this apparently large range in volatile abundances? This current study will produce new partitioning data relevant to the role and distribution of the volatile and non-volatile, yet geochemically significant elements (Co, Ni, Zn, Se, Rb, Sr, Mo, Ag, Cd, In, Sb, Ce, Yb, Tl, Pb, Bi) during the thermal and magmatic evolution of the Moon.

Vander Kaaden, Kathleen E.↗

Vacuum Sintering of Highland Simulant CSM-LHT-1G

Sintering of lunar regolith is a process of interest to consolidate the ubiquitous granular material in durable structures on the lunar surface such as platforms, landing/launch pads, roads, and foundations for long-term robotic and human activities. Many publications do not report quantitative assessment of the effects of processing conditions on the strength properties of the sintered products. The work presented is an investigation into such effects on a carefully selected simulant, CSM-LHT-1G prepared for high temperature processing to eliminate undesired components that would not be present from lunar materials. Careful experiments under vacuum were conducted to identify the relevant factors that dominate the properties and the quality of the sintered product. CSM-LHT-1G simulant is a variant of the CSM-LHT-1 lunar highland simulant produced by Colorado School of Mines. The original mineralogical composition of CSM-LHT-1 (70 wt.% Greenspar, 30 wt.% Merriam Crater basalt) was modified to obtain a 30 wt.% glass content with the addition of NU-LHT-5M glass balanced with pyroxene (augite) to yield CSM-LHT-1G.

Vacuum Sintering↗

Vapor Deposits in the Lunar Regolith

Since the Apollo missions, we have emphasized the following points, which are based on theoretical calculations and on laboratory studies of the properties of evaporated silicate deposits and of lunar samples. The mass of vapor generated by impacts on the lunar surface is comparable in magnitude to the mass of impact melt glasses; the physics of impact into a porous regolith requires that much of this vapor be retained in the soil rather than lost to space (as is widely believed); experimental coatings made from vaporized or sputtered lunar basalt contain abundant inclusions of submicroscopic, super paramagnetic metallic Fe; and this Fe may explain the magnetic signature, low albedo, reddened spectrum, and subdued absorption bands of lunar regolith. Our conclusions have been generally rejected by the lunar geochemical community for two reasons: there seemed to be no direct evidence for vapor deposits in Apollo samples, and it seemed that the lunar optical properties could be explained by the presence of impact melt glasses alone. However, advances in our understanding of the optical properties of glasses and of light scattering by planetary regoliths, and now the direct detection of vapor deposits, show that these objections are not valid. Vapor phase transport is a major process on the lunar surface, and unless its effects are taken into account, the chemical, magnetic, and optical properties of the regolith cannot be understood.

Hapke, Bruce↗

Revised Thickness of the Lunar Crust from GRAIL Data: Implications for Lunar Bulk Composition

High-resolution gravity data from GRAIL have yielded new estimates of the bulk density and thickness of the lunar crust. The bulk density of the highlands crust is 2550 kg m-3. From a comparison with crustal composition measured remotely, this density implies a mean porosity of 12%. With this bulk density and constraints from the Apollo seismic experiment, the average global crustal thickness is found to lie between 34 and 43 km, a value 10 to 20 km less than several previous estimates. Crustal thickness is a central parameter in estimating bulk lunar composition. Estimates of the concentrations of refractory elements in the Moon from heat flow, remote sensing and sample data, and geophysical data fall into two categories: those with refractory element abundances enriched by 50% or more relative to Earth, and those with abundances the same as Earth. Settling this issue has implications for processes operating during lunar formation. The crustal thickness resulting from analysis of GRAIL data is less than several previous estimates. We show here that a refractory-enriched Moon is not required

Taylor, G. Jeffrey↗

Mission Life Thermal Analysis and Environment Correlation for the Lunar Reconnaissance Orbiter

Standard thermal analysis practices include stacking worst-case conditions including environmental heat loads, thermo-optical properties and orbital beta angles. This results in the design being driven by a few bounding thermal cases, although those cases may only represent a very small portion of the actual mission life. The NASA Goddard Space Flight Center Thermal Branch developed a procedure to predict the flight temperatures over the entire mission life, assuming a known beta angle progression, variation in the thermal environment, and a degradation rate in the coatings. This was applied to the Global Precipitation Measurement core spacecraft. In order to assess the validity of this process, this work applies the similar process to the Lunar Reconnaissance Orbiter. A flight-correlated thermal model was exercised to give predictions of the thermal performance over the mission life. These results were then compared against flight data from the first two years of the spacecraft s use. This is used to validate the process and to suggest possible improvements for future analyses.

Garrison, Matthew B.↗

Comparison of Martian and lunar multi-ringed circular basins

Many similarities between Martian and lunar multi-ringed basins are outlined. There is a similar relation between basin size and number of rings; the second ring seems to appear in the crater-basin continuum in roughly the same diameter range. The similarities are tentatively considered great enough to indicate that Martian and lunar basins were formed by the same process. Morphological and statistical studies of lunar basins have strongly indicated this process to be impact.

Wilhelms, D. E.↗

Solar wind nitrogen - Mechanisms for isotopic evolution

Isotope systematics of nitrogen implanted in the lunar regolith indicate that the N-15/N-14 ratio at the source of the nitrogen has increased substantially with time. This source is most plausibly identified as the solar wind reservoir. However, rigorous testing of possible mechanisms for isotopic evolution of the solar convective zone shows that they all fail, by large factors, to explain the observed effect. Evolutionary processes on the lunar surface may be similarly eliminated, leaving the lunar nitrogen isotope anomaly currently unexplained.

Kerridge, J. F.↗

Space Weathering in the Fine Size Fractions of Lunar Soils: Soil Maturity Effects

The effects of space weathering on the optical properties of lunar materials have been well documented. These effects include a reddened continuum slope, lowered albedo, and attenuated absorption features in reflectance spectra of lunar soils as compared to finely comminuted rocks from the same Apollo sites. However, the regolith processes that cause these effects are not well known, nor is the petrographic setting of the products of these processes fully understood. A Lunar Soil Characterization Consortium has been formed with the purpose of systematically integrating chemical and mineralogical data with the optical properties of lunar soils. Understanding space-weathering effects is critical in order to fully integrate the lunar sample collection with remotely-sensed data from recent robotic missions (e.g., Lunar Prospector, Clementine, and Galileo) We have shown that depositional processes (condensation of impact-derived vapors, sputter deposits, accreted impact material, e.g., splash glass, spherules, etc.) are a major factor in the modification of the optical surfaces of lunar regolith materials. In mature soils, it is the size and distribution of the nanophase metal in the soil grains that has the major effect on optical properties. In this report, we compare and contrast the space-weathering effects in an immature and a mature soil with similar elemental compositions. For this study, we analyzed <10 micron sieve fractions of two Apollo 17 soils, 79221 (mature, Is/FeO = 81) and 71061 (immature, Is/FeO = 14). Details of the sieving procedures and allocation scheme are given else where. The results of other detailed chemical, mineralogical, and spectroscopic analyses of these soil samples are reported elsewhere. A representative sample of each soil was embedded in low-viscosity epoxy, and thin sections (about 70nm thick) were obtained through ultra microtomy. The thin sections used for these analyses typically contained cross sections of up to 500 individual grains. The thin sections were studied using a JEOL 2010 transmission electron microscope (TEM) equipped with a thin window energy-dispersive X-ray (EDX) spectrometer. An individual thin section was selected from each soil, and for each grain in the section we determined (1) the elemental composition by EDX; (2) whether the grain was crystalline or glassy using electron diffraction and darkfield imaging; (3) the presence or absence of rims and accreted material; and (4) the distribution of nanophase Fe where present. Most of the categories are self-evident; however, we divide the agglutinate derived material into agglutinitic glass (glass with approximately the same composition as the bulk soil that contains nanophase Fe with or without vesicles) and agglutinate fragments, which are composed of crystalline grains and agglutinitic glass. Lithic fragments are defined as polymineralic grains with no glass. Pyroxene grains have been divided into high- and low-Ca groups. As expected, there are a number of differences in the petrography of the <10-microns fractions of 79221 and 71061 given the great difference in their respective maturities, but we focus here on two major distinctions: agglutinate content and the number of grains with micropatina. Slightly over 50% of the particles in 79221 consist of agglutinitic glass and agglutinate fragments, while the remainder are predominantly crystalline mineral grains. The agglutinic glass particles contain abundant nanophase Fe and vesicles. Angular particles are rare, with most showing smooth, rounded exteriors, Of the mineral grains analyzed thus far, over 90% of the grains have amorphous rims that contain nanophase Fe (these rims are believed to have formed by vapor deposition and irradiation effects). The nanophase Fe in these rims probably accounts for a significant fraction of the increase in Is/FeO measured in these size fractions. In addition to the rims, the majority of particles also show abundant accreted material in the form of glass splashes and spherules that also contain nanophase Fe. In stark contrast, the surfaces of the mineral grains in the 71061 sample are relatively prisitine, as only about 14% of the mineral grains in the sample exhibited amorphous rims. Furthermore, the mineral particles are more angular and show greater surface roughness than in the mature sample. Accreted material on particle surfaces is rare. Agglutinitic material is a major component of the 71061 sample; however, nanophase Fe and vesicles are not as well developed as in the 79221 sample. It is now recognized that nanophase Fe is probably the main agent in modifying the optical properties of lunar soil grains. The most important result of this study is the observation that in the fine size fractions of mature soils, nearly every grain has nanophase Fe within 100 run of the particle surface. (Additional Information contained in original)

Keller, L. P.↗

The Global Albedo of the Moon at 1064 nm from LOLA

The Lunar Orbiter Laser Altimeter (LOLA) measures the backscattered energy of the returning altimetric laser pulse at its wavelength of 1064 nm, and these data are used to map the reflectivity of the Moon at zero-phase angle with a photometrically uniform data set. Global maps have been produced at 4 pixels per degree (about 8 kilometers at the equator) and 2 kilometers resolution within 20 deg latitude of each pole. The zero-phase geometry is insensitive to lunar topography, so these data enable characterization of subtle variations in lunar albedo, even at high latitudes where such measurements are not possible with the Sun as the illumination source. The geometric albedo of the Moon at 1064 nm was estimated from these data with absolute calibration derived from the Kaguya Multiband Imager and extrapolated to visual wavelengths. The LOLA estimates are within 2 sigma of historical measurements of geometric albedo. No consistent latitude-dependent variations in reflectance are observed, suggesting that solar wind does not dominate space weathering processes that modify lunar reflectance. The average normal albedo of the Moon is found to be much higher than that of Mercury consistent with prior measurements, but the normal albedo of the lunar maria is similar to that of Mercury suggesting a similar abundance of space weathering products. Regions within permanent shadow in the polar regions are found to be more reflective than polar surfaces that are sometimes illuminated. Limiting analysis to data with slopes less than 10 deg eliminates variations in reflectance due to mass wasting and shows a similar increased reflectivity within permanent polar shadow. Steep slopes within permanent shadow are also more reflective than similar slopes that experience at least some illumination. Water frost and a reduction in effectiveness of space weathering are offered as possible explanations for the increased reflectivity of permanent shadow; porosity is largely ruled out as the sole explanation. The south polar crater Shackleton is found to be among the most reflective craters in its size range globally but is not the most reflective, so mass wasting cannot be ruled out as a cause for the crater's anomalous reflectance. Models of the abundance of ice needed to account for the reflectance anomaly range from 3 to 14% by weight or area depending on assumptions regarding the effects of porosity on reflectance and whether ice is present as patches or is well mixed in the regolith. If differences in nanophase iron abundances are responsible for the anomaly, the permanently shadowed regions have between 50 and 80% the abundance of nanophase iron in mature lunar soil.

PSR↗

Lunar surface dynamics - Some general conclusions and new results from Apollo 16 and 17

The exposure ages of Apollo 17 rocks as measured by tracks and rare gases are discussed and a description is given of an investigation of a unique rock. The investigation will be an aid for the establishment of the long-term energy spectrum of solar flare heavy particles. The track record of several Apollo 17 soils is examined. It is shown that the Apollo 17 deep drill stem might make it possible to extend the energy range over which the fossil record of galactic cosmic rays can be studied. A review is provided regarding the experimental data obtained for the rates of several dynamical processes on the lunar surface.

Crozaz, G.↗

Simulating the Diffusion of Hydrogen in Amorphous Silicates: A ‘Jumping’ Migration Process and its Implications for Solar Wind Implanted Lunar Volatiles

We use molecular dynamics (MD) simulations to better explain the movement of atomic hydrogen in amorphous silica and quantify the planetary science implications of these findings. Previous MD simulations had a large range of predicted values and did not agree well with experiment. Our simulations sample atomic motion for a longer duration and consider a wider range of temperatures than previous simulations. In contrast to constant atomic motion, the hydrogen atoms were shown to undergo random intermittent jumps from one oxygen atom to another, the number of which increase with temperature. Predicted diffusion coefficients had a better agreement to experimental values than previous MD simulations, suggesting the importance of longer simulation durations for better statistics. The low activation energy and jumps observed at lunar temperatures do not support the theory of diurnal variations in OH content for an undamaged amorphous silica surface. Instead, we conclude that energetic solar wind impacts can induce two competing atomic hydrogen motion processes in the exposed surface: A prompt effect that induces jumps in the temperature spike volume, but also a long term effect of damage in the structure that traps atomic hydrogen. We then use SDTrimSP to quantify the damage created during exposure and MD to demonstrate the H retention and trapping near these defects. Damage was shown to be dependent on impact energy, with defects easily retaining implanted hydrogen. MD results like those presented herein on unweathered surfaces are therefore most relevant to magnetic anomalies. As a result, we demonstrate the importance of lunar volatile models to account for the damage state of the substrate when modelling hydrogen diffusion, retention, and subsequent OH/water production.

Liam S. Morrissey↗

Excavation on the Moon: Regolith Collection for Oxygen Production and Outpost Site Preparation

The development of a robust regolith moving system for lunar and planetary processing and construction is critical to the NASA mission to the Moon and Mars. Oxygen production may require up to 200 metric tons of regolith collection per year; outpost site development may require several times this amount. This paper describes progress in the small vehicle implement development and small excavation system development. Cratos was developed as a platform for the ISRU project to evaluate the performance characteristics of a low center of gravity, small (0.75m x 0.75m x 0.3m), low-power, tracked vehicle performing excavation, load, haul, and dump operations required for lunar ISRU. It was tested on loose sand in a facility capable of producing level and inclined surfaces, and demonstrated the capability to pick up, carry, and dump sand, allowing it to accomplish the delivery of material to a site. Cratos has demonstrated the capability to pick up and deliver simulant to a bury an inflatable habitat, to supply an oxygen production plant, and to build a ramp.

Caruso, John J.↗