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The chemical composition of the dust-free Martian atmosphere - Preliminary results of a two-dimensional model

This paper describes a two-dimensional model of the Martian atmosphere, in which chemical, radiative and dynamical processes are treated interactively. The model is developed for a carbon dioxide-hydrogen-oxygen-nitrogen atmosphere and provides estimates of concentrations for 19 chemical species. The dynamical equations are expressed in the transformed Eulerian coordinates. The wave driving and eddy mixing coefficients resulting from gravity and Rossby wave absorption are computed consistently with the evolving distribution of the mean zonal wind. The net diabatic heating/cooling rate is derived from a detailed radiative scheme including the contributions of CO2, O3, H2O and O2, and is computed consistently with the calculated distribution of temperature and trace species quantities. The computed temperature field as well as the meridional and seasonal variations of ozone column abundance are in good agreement with the distributions observed by Mariner 9 and Viking spacecrafts and the results obtained by previous studies. The present version of the model does not include the effects of dust, clouds and polar hood and only the chemistry in a dust-free atmosphere is considered.

Moreau, D.↗

A Study of Direct and Cloud-Mediated Radiative Forcing of Climate Due to Aerosols

The Intergovernmental Panel on Climate Change (IPCC) has reported that in the southeastern US and eastern China, the general greenhouse warming due to anthropogenic gaseous emissions is dominated by the cooling effect of anthropogenic aerosols. To verify this model prediction in eastern China and southeastern US, we analyzed regional patterns of climate changes at 72 stations in eastern China during 1951- 94 (44 years), and at 52 stations in the southeastern US during 1949-94 (46 years) to detect the fingerprint of aerosol radiative forcing. It was found that the mean rates of change of annual mean daily, maximum, minimum temperatures and diurnal temperature range (DTR) in eastern China were 0.8, -0.2, 1.8, and -2.0 C/100 years respectively, while the mean rates of change of annual mean daily, maximum, minimum temperatures and DTR in the southeastern US were -0.2, -0.6, 0.2, and -0.8 C/100 years, respectively. This indicates that the high rate of increase in annual mean minimum temperature in eastern China results in a slightly warming trend of daily temperature, while the high rate of decrease in annual mean maximum temperature and low rate of increase in annual mean minimum temperature lead to the cooling trend of daily temperature in the southeastern US. We found that the warming from the longwave forcing due to both greenhouse gases and aerosols was completely counteracted by the shortwave aerosol forcing in the southeastern US in the past 46 years. A slightly overall warming trend in eastern China is evident; winters have become milder. This finding is explained by hypothesizing that increasing energy usage during the past 44 years has resulted in more coal and biomass burning, thus increasing the emission of absorbing soot and organic aerosols in eastern China. Such emissions, in addition to well-known Asia dust and greenhouse gases, may be responsible for the winter warming trend in eastern China that we have reported here. The sensitivity of aerosol radiative properties to aerosol composition, size distribution, relative humidity (RH) is examined for the following aerosol systems: inorganic and organic ions (Cl-, Br-, NO3 -, SO4 2-, Na+, NH4 +, K+, Ca2+, Mg2+, HCOO-, CH3COO-, CH3CH2COO-, CH3COCOO-, OOCCOO2-, MSA-1); water-insoluble inorganic and organic compounds (elemental carbon, n-alkanes, SiO2, Al2O3, Fe2O3 and other organic compounds). The partial molar refraction method was used to calculate the real part of the refractive index. It was found that the asymmetry factor increased by approximately 48% with the real part varying from 1.40 to 1.65, and the single scattering albedo decreased by 24% with the imaginary part varying from -0.005 to -0.1. The asymmetry factor increased by 5.4 times with the geometric standard deviation varying from 1.2 to 3.0. The radiation transmission is very sensitive to the change in size distribution; other factors are not as significant. To determine the aerosol direct radiative forcing (ADRF), the aerosol optical depth (AOD) values at the three operational wavelengths (415, 500 and 673 nm) were determined at a regionally representative site, namely, Mt. Gibbs (35.78 deg N, 82.29 deg W, elevation 2006 m) in Mt. Mitchell State Park, NC, and a site located in an adjacent valley (Black Mountain, 35.66 deg N, 82.38 deg W, elevation 951 m) in the southeastern US. The two sites are separated horizontally by 10 km and vertically by 1 km. It was found that the representative total AOD values at 500 nm at the valley site for highly polluted (HP), marine (M) and continental (C) air masses were 0.68 +/- 0.33, 0.29 +/- 0.19 and 0.10 +/- 0.04, respectively. A search-graph method was used to retrieve the columnar size distribution (number concentration N, effective radius reff and geometric standard deviation=?g) from the optical depth observations at three operational wavelengths. The ground albedo, single scattering albedo and imaginary part of the refractive index were calculated using a mathematically unique procedure involving a Mie code and a radiative transfer code in conjunction with the retrieved aerosol size distribution, AOD, and diffuse-direct irradiance ratio. It was found that N, r(eff) and sigma(g) were in the ranges of 10 to 1.7 x 10(exp 4)/cubic cm, 0.09 to 0.68 micrometers and 1.12 to 2.95, respectively. The asymmetry factor and single scattering albedo were in the ranges of 0.63 to 0.75 and 0.74 to 0.97 respectively. The ground albedo for the forested terrain and imaginary part of refractive index were found to be in the ranges of 0.06 to 0.29 and 0.005 to 0.051 respectively. On the basis of these aerosol radiative properties obtained at the research sites and computations using the Column Radiation Model (CRM) of National Center of Atmospheric Research (NCAR) Community Climate Model (CCM3), it was found that the average cloud-free 24-hour ADRF values were -13 +/- 8, -8 +/- 3, -33 +/- 16 W/square m for marine, continental, and polluted air masses, respectively. On the assumption that the fractional coverage of clouds is 0.61, it was estimated that the annual mean ADRF was 7 +/- 2 W/square m in the southeastern US. The review with respect to the current knowledge of organic acids shows that aerosol formate and acetate concentrations range from 0.02 to 5.3 nmol/cubic m and from 0.03 to 12.4 nmol/cubic m respectively, and that between 34% to 77% of formate and between 21% to 66% of acetate are present in the fine fraction of aerosols. It was found that although most (98-99%) of these volatile organic acids were present in the gas phase, their concentrations in the aerosol particles were sufficient to make them a good candidate for cloud condensation nuclei (CCN). It is hypothesized that organic acids are at least one of the primary sources of CCN in the atmosphere due to their ubiquitous presence in the troposphere, especially over the continental forested areas. The results of our measurements at Palmer Station, Antarctica show that the daily average CCN concentrations at 0.3% and 1% supersaturations ranged from 0.3 to 160/cubic cm and from 4 to 168/cubic cm, respectively, during the period from 17 January to 26 February, 1994. New evidence for substantial and definitive CCN enhancement near and within cloud has been observed at Mt. Mitchell, North Carolina. The results show that the average monthly CCN concentrations were 460 +/- 217, 386 +/- 286, 429 +/- 228 and 238 +/- 134/cubic cm for in-cloud, overcast, clear and rainy conditions, respectively. The typical CCN spectra show that there were a lot of small CCN produced and the ion concentrations (especially H+ and SO4 2-) were very high during the CCN enhancement period. The significantly positive correlation between black carbon (BC) and CCN at 1% supersaturation indicates that a percentage of the BC measured at the site may be in the form of an internal mixture and participated in the formation of CCN.

Yu, Shao-Cai↗

An LES Survey of Cold-Air Outbreaks Spanning ACTIVATE and COMBLE

Two recent field campaigns offer unique new opportunities to survey coupled aerosol and cloud processes operating within cold-air outbreaks (CAOs). NASA's 2019-2023 Aerosol Cloud meTeorology Interactions oVer the western Atlantic Experiment (ACTIVATE) project provided airborne in situ and remote sensing observations in multiple CAOs off the central US Eastern Seaboard. Contemporaneously, DOE's 2019-2020 Cold-air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) provided continuous ground-based in situ and remote sensing measurements during hundreds of hours of CAO conditions at two sites flanking the Norwegian Sea. Here we highlight lessons learned from contrasting sets of aerosol-aware Lagrangian large-eddy simulation case studies derived from each campaign, as well as outstanding uncertainties. Cases simulated include all of the most extensively sampled CAO flights during ACTIVATE, and a wide range of CAO strengths and mesoscale structures during COMBLE. Each case study is also suitable for simulation with large-scale models in single-column model mode or with a limited-domain approach using periodic boundary conditions. We seek to address the central question: what microphysical process pathways control the Lagrangian evolution of surface and top-of-atmosphere radiative fluxes under ACTIVATE and COMBLE conditions? Many science team members, co-investigators, and collaborators will be gratefully acknowledged in association with their contributions to making this work possible.

cold-air outbreaks↗

An Integrated 0-1 Hour First-Flash Lightning Nowcasting, Lightning Amount and Lightning Jump Warning Capability

Lightning one of the most dangerous weather-related phenomena, especially as many jobs and activities occur outdoors, presenting risk from a lightning strike. Cloud-to-ground (CG) lightning represents a considerable safety threat to people at airfields, marinas, and outdoor facilities-from airfield personnel, to people attending outdoor stadium events, on beaches and golf courses, to mariners, as well as emergency personnel. Holle et al. (2005) show that 90% of lightning deaths occurred outdoors, while 10% occurred indoors despite the perception of safety when inside buildings. Curran et al. (2000) found that nearly half of fatalities due to weather were related to convective weather in the 1992-1994 timeframe, with lightning causing a large component of the fatalities, in addition to tornadoes and flash flooding. Related to the aviation industry, CG lightning represents a considerable hazard to baggage-handlers, aircraft refuelers, food caterers, and emergency personnel, who all become exposed to the risk of being struck within short time periods while convective storm clouds develop. Airport safety protocols require that ramp operations be modified or discontinued when lightning is in the vicinity (typically 16 km), which becomes very costly and disruptive to flight operations. Therefore, much focus has been paid to nowcasting the first-time initiation and extent of lightning, both of CG and of any lightning (e.g, in-cloud, cloud-to-cloud). For this project three lightning nowcasting methodologies will be combined: (1) a GOESbased 0-1 hour lightning initiation (LI) product (Harris et al. 2010; Iskenderian et al. 2012), (2) a High Resolution Rapid Refresh (HRRR) lightning probability and forecasted lightning flash density product, such that a quantitative amount of lightning (QL) can be assigned to a location of expected LI, and (3) an algorithm that relates Pseudo-GLM data (Stano et al. 2012, 2014) to the so-called "lightning jump" (LJ) methodology (Shultz et al. 2011) to monitor lightning trends and to anticipate/forecast severe weather (hail > or =2.5 cm, winds > or =25 m/s, tornadoes). The result will be a time-continuous algorithm that uses GOES satellite, radar fields, and HRRR model fields to nowcast first-flash LI and QL, and subsequently monitors lightning trends on a perstorm basis within the LJ algorithm for possible severe weather occurrence out to > or =3 hours. The LI-QL-LJ product will also help prepare the operational forecast community for Geostationary Lightning Mapper (GLM) data expected in late 2015, as these data are monitored for ongoing convective storms. The LI-QL-LJ product will first predict where new lightning is highly probable using GOES imagery of developing cumulus clouds, followed by n analysis of NWS (dual-polarization) radar indicators (reflectivity at the -10 C altitude) of lightning occurrence, to increase confidence that LI is immanent. Once lightning is observed, time-continuous lightning mapping array and Pseudo-GLM observations will be analyzed to assess trends and the severe weather threat as identified by trends in lightning (i.e. LJs). Additionally, 5- and 15-min GOES imagery will then be evaluated on a per-storm basis for overshooting and other cloud-top features known to be associated with severe storms. For the processing framework, the GOES-R 0-1 hour convective initiation algorithm's output will be developed within the Warning Decision Support System - Integrated Information (WDSS-II) tracking tool, and merged with radar and lightning (LMA/Psuedo-GLM) datasets for active storms. The initial focus of system development will be over North Alabama for select lightning-active days in summer 2014, yet will be formed in an expandable manner. The lightning alert tool will also be developed in concert with National Weather Service (NWS) forecasters to meet their needs for real-time, accurate first-flash LI and timing, as well as anticipated lightning trends, amounts, continuation and cessation, so to provide key situational awareness and decision support information. The NASA Short-term Prediction Research and Transition (SPoRT) Center will provide important logistical and collaborative support and training, involving interactions with the NWS and broader user community.

Mecikalski, John↗

Aircraft/island/ship/satellite intercomparison: Preliminary results from July 16, 1987

The First ISCCP Regional Experiment (FIRE) objective of validating and improving satellite algorithms for inferring cloud properties from satellite radiances was one of the central motivating factors in the design of the specific field experimental strategies used in the July, 1987 marine stratocumulus intensive field observations (IFO). The in situ measuring platforms were deployed to take maximum advantage of redundant measurements (for intercomparison of the in situ sensors) and to provide optimal coverage within satellite images. One of the most ambitious of these strategies was the attempt to coordinate measurements from San Nicolas Island (SNI), the R/V Pt. Sur, the meteorological aircraft, and the satellites. For the most part, this attempt was frustrated by flight restrictions in the vicinity of SNI. The exception was the mission of July 16, 1987, which achieved remarkable success in the coordination of the platforms. This presentation concerns operations conducted by the National Center for Atmospheric Research (NCAR) Electra and how data from the Electra can be integrated with and compared to data from the Pt. Sur, SNI, and the satellites. The focus is on the large-scale, integrated picture of the conditions on July 16 from the perspective of the Electra's flight operations.

Hanson, Howard P.↗

Analysis of Physical Properties of Dust Suspended in the Mars Atmosphere

Methods for iteratively determining the infrared optical constants for dust suspended in the Mars atmosphere are described. High quality spectra for wavenumbers from 200 to 2000 1/cm were obtained over a wide range of view angles by the Mariner 9 spacecraft, when it observed a global Martian dust storm in 1971-2. In this research, theoretical spectra of the emergent intensity from Martian dust clouds are generated using a 2-stream source-function radiative transfer code. The code computes the radiation field in a plane-parallel, vertically homogeneous, multiply scattering atmosphere. Calculated intensity spectra are compared with the actual spacecraft data to iteratively retrieve the optical properties and opacity of the dust, as well as the surface temperature of Mars at the time and location of each measurement. Many different particle size distributions a-re investigated to determine the best fit to the data. The particles are assumed spherical and the temperature profile was obtained from the CO2 band shape. Given a reasonable initial guess for the indices of refraction, the searches converge in a well-behaved fashion, producing a fit with error of less than 1.2 K (rms) to the observed brightness spectra. The particle size distribution corresponding to the best fit was a lognormal distribution with a mean particle radius, r(sub m) 0.66 pm, and variance, omega(sup 2) = 0.412 (r(sub eff) = 1.85 microns, v(sub eff) =.51), in close agreement with the size distribution found to be the best fit in the visible wavelengths in recent studies. The optical properties and the associated single scattering properties are shown to be a significant improvement over those used in existing models by demonstrating the effects of the new properties both on heating rates of the Mars atmosphere and in example spectral retrieval of surface characteristics from emission spectra.

Snook, Kelly↗

Mariner 6 and 7 picture analysis

Analysis of Mariner 6 and 7 far-encounter (FE) pictures is discussed. The purpose of the studies was to devise ways to combine digital data from the full set of FE pictures so as to improve surface resolution, distinguish clouds and haze patches from permanent surface topographic markings, deduce improved values for radius, oblateness, and spin-axis orientation, and produce a composite photographic map of Mars. Attempts to measure and correct camera distortions, locate each image in the frame, and convert image coordinates to martian surface coordinates were highly successful; residual uncertainties in location were considerably less than one pixel. However, analysis of the data to improve the radius, figure, and axial tilt and to produce a composite map was curtailed because of the superior data provided by Mariner 9. The data, programs, and intermediate results are still available (1976), and the project could be resumed with little difficulty.

Leighton, R. B.↗

Mariner 9 observations of the Mars north polar hood

Mariner 9 photographs showing variations in the behavior of the Mars atmosphere over 21 consecutive days during northern winter are displayed. The photographs show the north polar cloud hood to be highly variable from day to day, with variations suggestive of development, motion, and decay of baroclinic waves. Lee wave clouds apparently composed primarily of water ice, convective cloud lines inferred to consist of CO2 ice, and dust clouds all occur frequently in the active region between latitudes 40 and 60 N. The wave clouds show that persistent surface westerlies and strong westerly shear occur in this region.

Briggs, G. A.↗

Martian atmospheric lee waves

Areas of extensive mountain lee wave phenomenon in the northern midlatitudes during late winter are observed in Mariner 9 television pictures of Mars. The lee wave pattern is due to the discrete spectrum of waves generated by a crater ridge in an airstream. The cloud patterns resulting from the waves generated by the flow across a mountain or crater are dependent on the velocity profile of the airstream and the vertical stability of the atmosphere. A two-layer velocity model of the airstream is used in calculations based on the theory of mountain lee waves. Regardless of the simple model used for the airstream, the calculations appear to be capable of reproducing the observed wave patterns. The many observations of lee waves suggest that the near surface wind speeds as implied by the lower stream velocities do not greatly exceed, and most of the time are less than, 40 m/sec in the northern midlatitudes during late winter except possibly on a very localized scale. Results are in agreement with circulation models, especially the Leovy and Mintz (1969) two-layer numerical model.

Pirraglia, J. A.↗

On the reality of the Venus winds

The article presents a rebuttal of Young's (1975) view that the 140 m/sec horizontal wind at 45 km reported by Venera 8 is anomalous or spurious. Some errors are discussed and the largest contribution is attributed to descent probe measurements designed to find the true probe descent rate. Young's suggestion of error in in situ measurement of winds due to selection of a reference speed and to unrecognized oscillator drift is scrutinized. Evidence is seen for a wide band of variable high-grade retrograde horizontal winds girdling Venus at the equator. Mariner 10 evidence (UV photographs) is taken into account. The band of winds at 45 km is seen to extend well beyond the top of the visible cloud, and an upper turbulent region is attributed to vertical convection currents carried along by high-speed horizontal winds.

Ainsworth, J. E.↗

Use of microwave satellite data to study variations in rainfall over the Indian Ocean

The University of Wisconsin Space Science and Engineering Center mapped rainfall over the Indian Ocean using a newly developed Scanning Multichannel Microwave Radiometer (SMMR) rain-retrieval algorithm. The short-range objective was to characterize the distribution and variability of Indian Ocean rainfall on seasonal and annual scales. In the long-range, the objective is to clarify differences between land and marine regimes of monsoon rain. Researchers developed a semi-empirical algorithm for retrieving Indian Ocean rainfall. Tools for this development have come from radiative transfer and cloud liquid water models. Where possible, ground truth information from available radars was used in development and testing. SMMR rainfalls were also compared with Indian Ocean gauge rainfalls. Final Indian Ocean maps were produced for months, seasons, and years and interpreted in terms of historical analysis over the sub-continent.

Hinton, Barry B.↗

Analysis of diurnal variation of SCu layer using 2 days of CLASS soundings on San Nicolas Island

Sixty-nine soundings were taken at San Nicolas Island during the FIRE marine stratocumulus experiment. The archived thermodynamic data at 5mb vertical resolution were reduced to 25mb vertical resolution by averaging. Ceilometer data showed the time variation of cloud-base. A subset of 20 soundings taken during a 2 day period of light winds were analyzed. The soundings are grouped into 6 hr. averages (with 5 soundings in each category) to examine the diurnal variation of the thermodynamic structure. Consistent with the solar heating during the daytime, cloud-base rises during the daytime hours and the cloud layer thins. The subcloud layer also becomes more stable, suggesting some uncoupling of the cloud layer from the surface.

Betts, Alan K.↗

Mercury's Atmosphere and Magnetosphere: MESSENGER Third Flyby Observations

MESSENGER's third flyby of Mercury en route to orbit insertion about the innermost planet took place on 29 September 2009. The earlier 14 January and 6 October 2008 encounters revealed that Mercury's magnetic field is highly dipolar and stable over the 35 years since its discovery by Mariner 10; that a structured, temporally variable exosphere extends to great altitudes on the dayside and forms a long tail in the anti-sunward direction; a cloud of planetary ions encompasses the magnetosphere from the dayside bow shock to the downstream magnetosheath and magnetotail; and that the magnetosphere undergoes extremely intense magnetic reconnect ion in response to variations in the interplanetary magnetic field. Here we report on new results derived from observations from MESSENGER's Mercury Atmospheric and Surface Composition Spectrometer (MASCS), Magnetometer (MAG), and Energetic Particle and Plasma Spectrometer (EPPS) taken during the third flyby.

Slavin, James A.↗

Where Is the Upper Altitude Boundary of Earth's Biosphere? An Upcoming Stratosphere Exploration Mission

Earths atmosphere provides a relatively thin barrier to the severe conditions of space. Terrestrial microorganisms from our planets surface gets swept up into the atmosphere at rates which are influenced by meteorology, season, and variety of other regionally-dependent conditions. Residence time of microbes in the atmosphere, dispersal patterns, and metabolic activity in clouds are topics of special interest in tropospheric aerobiology. But what about even higher altitudes? A century of ocean exploration has allowed the scientific community to characterize marine life at every depth. Such knowledge was enabled by routine access, specifically, submersible vehicles with sample return systems. The outer reaches of Earth's atmosphere probably contain trace signatures of microbial life swept up from the surface, but high-altitude exploration (from 18-50 km above sea level) has been severely constrained by a shortage of reliable affordable sample acquisition systems. Thus, attempts to establish the upper altitude limits of Earths biosphere boundary remain unresolved. Previous conclusions based on observations of microbial growth and DNA signatures from samples collected in the upper atmosphere have resulted in extraordinary claims for the tenacity of life in the stratosphere. This altitude range can be regarded as a natural laboratory for examining the edge of habitability, a topic of central important to the field of astrobiology; in fact, stratosphere conditions (high UV light and low extremes of temperature, pressure, and relative humidity) closely resemble stressors associated with the surface of Mars. Moreover, low biomass detection instruments developed exploring Earths upper atmosphere can contribute to future strategies for life detection with spacecraft exploring other worlds. While pioneering, many past stratospheric microbiology studies have been qualitative in nature and lacking rigorous contamination control measurements to verify system sterility. We have designed, constructed, and recently flown a novel system for collecting upper atmosphere bioaerosols using the NASA C20A aircraft. We will report preliminary mission results from the lower stratosphere (characterizing abundance, diversity and survivability or airborne microorganisms), describe our methods for reducing false positives, and outline the open scientific engineering challenges in an ongoing effort to better establish Earths high-altitude biosphere boundary.

Smith, David J.↗

An Overview of the Aerosol and Clouds-Convection-Precipitation Study (A-CCP) and its Relationship to the Geostationary AC-VC

The 2017 Decadal Survey (DS) highlighted Earth System Science themes, science and application questions, and several high priority objectives that have led to the inclusion of Aerosols (A) and Clouds-Convection-Precipitation (CCP) as Designated Observables (DOs) The aerosol-related science questions outlined by the DS focus on two major themes: 1) Climate Variability and Change and 2) Weather and Air Quality. The Aerosol mission observables targeted to address these major objectives may potentially contribute to three additional themes: 3) Marine and Terrestrial Ecosystems, 4) Global Hydrological Cycle, and 5) Earth Surface and Interior; this study will examine these linkages.In response to NASA's Designated Observables Guidance for Multi-Center Study Plans released on June 1, 2018, GSFC, LaRC, JPL, MSFC, GRC and ARC submitted Study Plan to the NASA Earth Science Division for the Aerosol (A) and Cloud, Convection, and Precipitation (CCP) Pre-formulation Study (A-CCP). The DS recognized the science merit in combining the A and CCP DOs for both enhancing the ability to address a number of Most Important (MI) objectives defined by the disciplinary panels and also to provide an expanded capability to address additional objectives beyond those addressed by individual DOs. The DS also identified Integrating Themes that can also be addressed through combinations of observables including potential combinations of DOs and the PoR. The combined A+CCP portion of this study will demonstrate how the combination of A and CCP observables will enhance the objectives of A and CCP individually, while providing the ability to expand the DS objectives addressed, and will closely connect to the A and CCP studies being performed in parallel. A critical element of the A-CCP observing strategy is to make extensive use of the so-called Program-of-Record (PoR). In this regard, the Geostationary Atmospheric Composition Virtual Constellation consisting of the GEMS, TEMPO and SENTINEL-4 and other relevant geostationary assets will provide a critical foundation for A-CCP. In this talk we will discuss how the A-CCP measurements contributes to air-quality and the geostationary constellation, and conversely, how the geostationary constellation helps answering fundamental A-CCP science objectives.

Da Silva, Arlindo↗

Natural versus anthropogenic factors affecting low-level cloud albedo over the North Atlantic

Cloud albedo plays a key role in regulating earth's climate. Cloud albedo depends on column-integrated liquid water content and the density of cloud condensation nuclei, which consists primarily of submicrometer-sized aerosol sulfate particles. A comparison of two independent satellite data sets suggests that, although anthropogenic sulfate emissions may enhance cloud albedo immediately adjacent to the east coast of the United States, over the central North Atlantic Ocean the variability in albedo can be largely accounted for by natural marine and atmospheric processes that probably have remained relatively constant since the beginning of the industrial revolution.

Falkowski, Paul G.↗

Research Participation in the Mars Orbiter Laser Altimeter Experiment

This report describes the tasks that have been completed by the Principal Investigator, Gordon Pettengill, and his team during the first year of this grant. Dr. Pettengill was assisted by Dr. Peter Ford and Ms. Joan Quigley. Our main task has been to analyze the polar clouds detected by MOLA (Mars Orbiter Laser Altimeter) during the nominal mission of the Mars Global Surveyor (MGS) in 1999-2001 and to correlate the results with other data sets, in particular that from TES, the MGS thermal emission spectrometer. Starting with the Martian cloud database that we constructed prior to the start of this grant, we have examined all TES footprints that overlap MOLA clouds in time and space, correlating the thermal signature against specific categories that we assign to MOLA clouds on the basis of visual inspection. We are particularly interested in clouds in the region of "cold spots", areas of anomalously low thermal brightness temperature that have been detected in the polar winter by several instruments beginning with IRIS on Mariner 9. They are thought to indicate regions of active CO2 sublimation or snowfall, and it is hoped that MOLA measurements may tell us more about these regions.

Pettengill, Gordon H.↗

Aerosol Size Distribution Properties Associated With Cold-Air Outbreaks in the Norwegian Arctic

The aerosol particles serving as cloud condensation and ice nuclei contribute to key cloud processes associated with cold-air outbreak (CAO) events but are poorly constrained in climate models due to sparse observations. Here we retrieve aerosol number size distribution modes from measurements at Andenes, Norway, during the Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) and at Zeppelin Observatory, approximately 1000 km upwind from Andenes at Svalbard. During CAO events at Andenes, the sea-spray-mode number concentration is correlated with strong over-ocean winds with a mean of 8±4 cm−3 that is 71 % higher than during non-CAO conditions. Additionally, during CAO events at Andenes, the mean Hoppel minimum diameter is 6 nm smaller than during non-CAO conditions, though the estimated supersaturation is lower, and the mean number concentration of particles that likely activated in-cloud is 109±61 cm−3 with no statistically significant difference from the non-CAO mean of 99±66 cm−3. For CAO trajectories between Zeppelin Observatory and Andenes, the upwind-to-downwind change in number concentration is the largest for the accumulation mode with a mean decrease of 93±95 cm−3, likely attributable primarily to precipitation scavenging. These characteristic properties of aerosol number size distributions during CAO events provide guidance for evaluating CAO aerosol–cloud interaction processes in models.

accumulation mode particle scavenging↗