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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Dynamic Nanoscale Spatial Heterogeneity in a Perovskite-to-Brownmillerite Topotactic Phase Transformation

Phase transitions are omnipresent in modern condensed matter physics and its applications. In solids, first-order phase transformations typically occur by nucleation and growth under nonequilibrium conditions. Under constant external conditions, e.g., constant annealing temperature and pressure, the nucleation and growth dynamics are often thought of as spatially and temporally independent. Here, in situ Bragg X-ray photon correlation spectroscopy (XPCS) reveals nanoscale spatial and dynamical heterogeneity in the perovskite-to-brownmillerite topotactic phase transformation in La 0.7 Sr 0.3 CoO 3 thin films annealed under constant reducing conditions over a time span of multiple hours. Specifically, a time scale associated with domain growth remains stable, with a corresponding domain wall speed of v d = 6 ± 0.5 × 10 –4 nm/s (2 ± 0.2 nm/h), while a slower time scale, associated with temperature-driven depinning of domains, leads to accelerating dynamics with time scales following an aging power law with exponent −2.2 ± 0.5. This experiment demonstrates that Bragg XPCS is a powerful tool to study nanoscale dynamics in structural phase transformations, with the ability to extract quantitative average values related to nanodomain motion in situ. Furthermore, the results are relevant for phase engineering of phase-change devices, as they show that nanoscale dynamics, linked to domain and domain-wall motion, can continuously evolve and speed up with time, even hours after the initiation of the phase transformation, with potential repercussions on electrical performance.

X-ray photon correlation spectroscopy↗
DOE OSTI2025

Revealing and Engineering Assembly Pathways of 3D DNA Origami Crystals

Recent developments in nanomaterial self-assembly demonstrate the capability to create tailored nanostructures by engineering both the binding coordination and specificity of interactions between material subunits. DNA origami frames allow for the design and fabrication of a broad variety of ordered 3D nanoscale architectures through self-assembly, facilitated by frame-to-frame bonds with designable strength and specificity. While the bond design is critical to lattice formation, the assembly process itself is often dependent on a thermal pathway. Highly ordered nanoscale frameworks, assembled from DNA frames, are predominantly crystallized through thermal annealing pathways that typically follow a “slow” cooling approach, with experiments on the time scale of days yielding DNA origami crystals in the range of 1−10 μm. This extended assembly time scale hinders the study of crystal formation pathways, necessitating a deeper understanding of factors governing successful annealing. Lack of insight into time scale also presents a practical limitation for material fabrication. Here, we investigate key factors affecting lattice assembly pathways and demonstrate that precise engineering of assembly conditions greatly reduces assembly times by up to nearly 2 orders of magnitude. We evaluate the nucleation and growth of crystals via optical and electron microscopy, and small-angle X-ray scattering techniques, mapping the time−temperature-transformation of superlattices from the melt through single-crystal optical tracking. The results show that origami frame assembly can be described by classical nucleation and growth theory, which can, in turn, be used to prescribe the growth of the crystals. Lastly, these findings are applied to demonstrate thermal pathway-dependent assembly, forming distinct assemblies based on different thermal annealing profiles.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Nutrient Dynamics in a Coupled Terrestrial Biosphere and Land Model (ELM-FATES-CNP)

We present a representation of nitrogen and phosphorus cycling in the Functionally Assembled Terrestrial Ecosystem Simulator, a demographic vegetation model within the Energy Exascale Earth System land model. This representation is modular, and designed to allow testing of multiple hypothetical approaches for carbon-nutrient coupling in plants. Novel model hypotheses introduced in this work include, (a) the controls on plant acquisition of aqueous mineralized nutrients in the soil and (b) fairly straight forward methods of allocating nutrients to specific plant organs and their losses through live plant turnover as well as litter fluxes generated through plant mortality. This combines the new with pre-existing hypotheses (such as nitrogen fixation and soil decomposition) into a system that can accommodate plant-soil dynamics for a large number of size- and functional-type-resolved plant cohorts within a time-since-disturbance-resolved ecosystem. Root uptake of nutrients is governed by fine root biomass, and plants vary in their fine root biomass allocation in order to balance carbon and nutrient limitations to growth. We test the sensitivity of the model to a wide range of parameter variations and structural representations, and in the context of observations at Barro Colorado Island, Panama. A key model prediction is that plants in the high-light-availability canopy positions allocate more carbon to fine roots than plants in low-light understory environments, given the widely different carbon versus nutrient constraints of these two niches within a given ecosystem. This model provides a basis for exploring carbon-nutrient coupling with vegetation demography within Earth system models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Complex carbonate phases drive geologic CO2 mineralization

Abstract Geologic carbon sequestration in mafic and ultramafic reservoirs is a scalable strategy for carbon dioxide removal, offering permanent storage via mineralization as stable carbonates. However, there is limited information on the structure and composition of key mineralization endpoints during sequestration. Here, we unravel the atomic structure, composition, and nanoscale morphology of carbonates recovered from a field-scale demonstration of CO 2 mineralization in basalt. Using transmission electron microscopy, we mapped mineralogical variations from the initial to later stages of subsurface carbonate growth and identified a previously unknown cation-ordered ankerite phase that exerts a primary control over carbonation processes. This study has provided a new understanding of subsurface carbonation pathways which will impact the parameterization of predictive geochemical models for future sequestration efforts in basalt formations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Fast imaging of laser ablation of cerium: Dependence of plasma plume dynamics and structure on native oxide growth

We have imaged the evolution of plasma following nanosecond pulsed laser ablation of cerium in air with sub-10 ns resolution. We find the ablated plasma plume expansion and shape to be strongly dependent on the time after mechanical polishing of the sample surface. After an initial shock front common to both new and aged samples (velocities up to 16 km s ₋1 ), we observe a second front that is relatively localized to the surface vicinity of newly polished samples, but in the case of older samples it moves outward at velocities of up to 4 km s ₋1 . We attribute this behavior to the formation and growth of a native oxide layer on the order of hours after polishing. These results demonstrate that plasma imaging can be used to diagnose the presence of, and evaluate the extent of, thin surface oxides or other compounds that form soon after exposure to some atmosphere. These findings also highlight the need to explicitly consider the presence of such overlayers when modeling laser/metal interaction, when making measurements of vapor phase chemistry, and when analyzing the composition, phase, and morphology of solid particulates formed after the ablation of reactive metals.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Charge-ordered state satisfying the Anderson condition in LiRh 2 O 4 arising from local dimer order

Here we report on the charge-ordered structure of LiRh 2 O 4 arising below the metal-insulator transition at 170 K. Structural studies using synchrotron x rays have revealed that the charge-ordered states of Rh 3+ and Rh 4+ with dimerization are realized in the low-temperature phase below 170 K. Although the low-temperature ground state resembles that of CuIr 2 S 4 , a charge-ordering pattern satisfying the Anderson condition is realized in LiRh 2 O 4 . Based on structural information such as the short-range order of dimers appearing above the transition temperature and the weakening of the correlation between rhodium one-dimensional chains appearing in the crystal structure, we argue that the Coulomb interaction plays an important role in determining the charge-ordering patterns.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Nonlinear dynamics and quantum chaos of a family of kicked p -spin models

Herein we introduce kicked p-spin models describing a family of transverse Ising-like models for an ensemble of spin-1/2 particles with all-to-all p-body interaction terms occurring periodically in time as delta-kicks. This is the natural generalization of the well-studied quantum kicked top (p = 2) [Haake, Kus', and Scharf, Z. Phys. B 65, 381 (1987)]. We fully characterize the classical nonlinear dynamics of these models, including the transition to global Hamiltonian chaos. The classical analysis allows us to build a classification for this family of models, distinguishing between p = 2 and p > 2, and between models with odd and even p's. Quantum chaos in these models is characterized in both kinematic and dynamic signatures. For the latter, we show numerically that the growth rate of the out-of-time-order correlator is dictated by the classical Lyapunov exponent. Finally, we argue that the classification of these models constructed in the classical system applies to the quantum system as well.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

Proton Dynamics Scenarios in the Integrable Optics Test Accelerator (IOTA) at Fermilab

The Integrable Optics Test Accelerator (IOTA) at Fermilab provides a versatile platform for studying the interplay of space-charge, impedance, and non-linear optics in high-intensity hadron beams within synchrotrons and storage rings. This report examines the parameters and dynamics of 2.5~MeV proton beam operations in two configurations of the bare IOTA lattice: one for demonstrating Non-linear Integrable Optics with the Danilov-Nagaitsev magnet, and the other for use with electron cooling. We offer order-of-magnitude estimates of the transverse emittance growth rate as a function of beam intensity, highlighting contributions from residual gas scattering, intra-beam scattering, and space-charge effects. Under nominal conditions, the beam lifetime is projected to be less than 7~minutes at low intensity with the current vacuum quality, and fewer than 100,000~turns at high intensity due to strong space-charge effects. The calculations presented here will guide strategies to mitigate emittance growth and inform future IOTA experiments.

43 PARTICLE ACCELERATORS↗
NASA NTRS1975

Ordinary electromagnetic mode instability

The instability of the ordinary electromagnetic mode propagating perpendicular to an external magnetic field is analyzed for a single-species plasma with ring velocity distribution. The marginal instability boundaries for both the purely growing mode and the propagating growing modes are calculated from the instability criteria. The dispersion characteristics are derived for a cold plasma and a very strong static magnetic field. The point is determined at which the real parts of the complex frequency band are centered. The typical growth rates are found to be of the order of the cyclotron frequency and can be enhanced by increasing the ratio of parallel kinetic pressure to magnetic pressure.

Cheng, C.-Z.↗
NASA NTRS1979

Tidal interactions in the expanding universe - The formation of prolate systems

The study estimates the magnitude of the anisotropy that can be tidally induced in neighboring initially spherical protostructures, be they protogalaxies, protoclusters, or even uncollapsed density enhancements in the large-scale structure of the universe. It is shown that the linear analysis of tidal interactions developed by Peebles (1969) predicts that the anisotropy energy of a perturbation grows to first order in a small dimensionless parameter, whereas the net angular momentum acquired is of second order. A simple model is presented for the growth of anisotropy by tidal interactions during the nonlinear stage of the development of perturbations. A possible observational test is described of the alignment predicted by the model between the orientations of large-scale perturbations and the positions of neighboring density enhancements.

Binney, J.↗
NASA NTRS1982

Electromagnetic cyclotron-loss-cone instability associated with weakly relativistic electrons

The amplification of fast extraordinary mode waves at frequencies very close to the electron cyclotron frequency, due to the presence of a population of energetic electrons with a loss-cone type distribution, is studied. Low-energy background electrons are included in the analysis. Two types of loss-cone distribution functions are considered, and it is found that the maximum growth rates for both distribution functions are of the same order of magnitude. When the thermal effects of the energetic electrons are included in the dispersion equation, the real frequencies of the waves are lower than those obtained by using the cold plasma approximation. This effect tends to enhance the growth rate. An idealized case including a parallel electric field such that the distribution function of the trapped energetic electrons is modified is also considered. It is assumed that the parallel electric field can remove the low-energy background electrons away from the source region of radiation. Both these effects increase the growth rate.

Wong, H. K.↗
NASA NTRS1985

A theory of post-stall transients in multistage axial compression systems

A theory is presented for post stall transients in multistage axial compressors. The theory leads to a set of coupled first-order ordinary differential equations capable of describing the growth and possible decay of a rotating-stall cell during a compressor mass-flow transient. These changing flow features are shown to have a significant effect on the instantaneous compressor pumping characteristic during unsteady operation, and henace on the overall system behavior. It is also found from the theory that the ultimate mode of system response, stable rotating stall or surge, depends not only on the B parameter but also on other parameters, such as the compressor length-to-diameter ratio. Small values of this latter quantity tend to favor the occurrence of surge, as do large values of B. A limited parametric study is carried out to show the impact of the different system features on transient behavior. Based on analytical and numerical results, several specific topics are suggested for future research on post-stall transients.

Moore, F. K.↗
NASA NTRS1986

Description of concept and first feasibility test results of a life support subsystem of the Botany Facility based on water reclamation

The Botany Facility allows the growth of higher plants and fungi over a period of 6 months maximum. It is a payload planned for the second flight of the Eureca platform around 1990. Major tasks of the Life Support Subsystem (LSS) of the Botany Facility include the control of the pressure and composition of the atmosphere within the plant/fungi growth chambers, control of the temperature and humidity of the air and the regulation of the soil water content within specified limits. Previous studies have shown that various LSS concepts are feasible ranging from heavy, simple and cheap to light, complex and expensive solutions. A summary of those concepts is given. A new approach to accomplish control of the temperature and humidity of the air within the growth chambers based on water reclamation is discussed. This reclamation is achieved by condensation with a heat pump and capillary transport of the condensate back into the soil of the individual growth chamber. Some analytical estimates are given in order to obtain guidelines for circulation flow rates and to determine the specific power consumption.

Loeser, H. R.↗
NASA NTRS1986

Forecasts of time averages with a numerical weather prediction model

Forecasts of time averages of 1-10 days in duration by an operational numerical weather prediction model are documented for the global 500 mb height field in spectral space. Error growth in very idealized models is described in order to anticipate various features of these forecasts and in order to anticipate what the results might be if forecasts longer than 10 days were carried out by present day numerical weather prediction models. The data set for this study is described, and the equilibrium spectra and error spectra are documented; then, the total error is documented. It is shown how forecasts can immediately be improved by removing the systematic error, by using statistical filters, and by ignoring forecasts beyond about a week. Temporal variations in the error field are also documented.

Roads, J. O.↗
NASA NTRS1987

High pressure cosmochemistry of major planetary interiors: Laboratory studies of the water-rich region of the system ammonia-water

Several studies relative to high pressure cosmochemistry of major planetary interiors are summarized. The behavior of gas-ice mixtures at very high pressures, studies of the phase diagram of (NH3) sub x (H2O) sub 1-x at pressures to 5GPa and temperatures from 240 to 370 K, single crystal growth of ammonia dihydrate at room temperature in order to determine their structures by x-ray diffraction, spectroscopy of chemical reactions during shock compression in order to evaluate how the reactions affect the interpretation of equation of state data obtained by shock methods, and temperature and x-ray diffraction measurements made on resistively heated wire in diamond anvil cells in order to obtain phase and structural data relevant to the interiors of terrestrial planets are among the studies discussed.

Nicol, Malcolm↗
NASA NTRS1992

Effect of impact angle on central-peak/peak-ring formation and crater collapse on Venus

Although asymmetry in ejecta patterns and craters shape-in-plan are commonly cited as diagnostic features of impact angle, the early-time transfer of energy from impactor to target also creates distinctive asymmetries in crater profile with the greatest depth uprange. In order to simulate gravity-controlled crater-growth, laboratory experiments use loose particulate targets as analogs for low-strength material properties following passage of the shock. As a result, impact crater diameter D in laboratory experiments generally is many times greater than the impactor diameter 2r (factor of 40), and early-time asymmetries in energy transfer from oblique impacts are consumed by subsequent symmetrical crater growth, except at the lowest angles (less than 25 deg). Such asymmetry is evident for oblique (less than 60 deg from horizontal) impacts into aluminum where D/2r is only 2 to 4. Because cratering efficiency decreases with increasing crater size and decreasing impact angle, large scale planetary craters (4080 km) should have transient excavation diameters only 6-10 times larger than the impactor. At basin scales, D/2r is predicted to be only 3-5, i.e., approaching values for impacts into aluminum in laboratory experiments. As a result, evidence for early-time asymmetry in impactor energy transfer should become evident on planetary surfaces, yet craters generally retain a circular outline for all but the lowest impact angles.

Schultz, Peter H.↗
NASA NTRS1994

The stabilizing effect of compressibility in turbulent shear flow

Direct numerical simulation of turbulent homogeneous shear flow is performed in order to clarify compressibility effects on the turbulence growth in the flow. The two Mach numbers relevant to homogeneous shear flow are the turbulent Mach number M(t) and the gradient Mach number M(g). Two series of simulations are performed where the initial values of M(g) and M(t) are increased separately. The growth rate of turbulent kinetic energy is observed to decrease in both series of simulations. This 'stabilizing' effect of compressibility on the turbulent energy growth rate is observed to be substantially larger in the DNS series where the initial value of M(g) is changed. A systematic companion of the different DNS cues shows that the compressibility effect of reduced turbulent energy growth rate is primarily due to the reduced level of turbulence production and not due to explicit dilatational effects. The reduced turbulence production is not a mean density effect since the mean density remains constant in compressible homogeneous shear flow. The stabilizing effect of compressibility on the turbulence growth is observed to increase with the gradient Mach number M(g) in the homogeneous shear flow DNS. Estimates of M(g) for the mixing and the boundary layer are obtained. These estimates show that the parameter M(g) becomes much larger in the high-speed mixing layer relative to the high-speed boundary layer even though the mean flow Mach numbers are the same in the two flows. Therefore, the inhibition of turbulent energy production and consequent 'stabilizing' effect of compressibility on the turbulence (over and above that due to the mean density variation) is expected to be larger in the mixing layer relative to the boundary layer in agreement with experimental observations.

Sarkar, S.↗
NASA NTRS2001

Antisense expression of an Arabidopsis ran binding protein renders transgenic roots hypersensitive to auxin and alters auxin-induced root growth and development by arresting mitotic progress

We cloned a cDNA encoding an Arabidopsis Ran binding protein, AtRanBP1c, and generated transgenic Arabidopsis expressing the antisense strand of the AtRanBP1c gene to understand the in vivo functions of the Ran/RanBP signal pathway. The transgenic plants showed enhanced primary root growth but suppressed growth of lateral roots. Auxin significantly increased lateral root initiation and inhibited primary root growth in the transformants at 10 pM, several orders of magnitude lower than required to induce these responses in wild-type roots. This induction was followed by a blockage of mitosis in both newly emerged lateral roots and in the primary root, ultimately resulting in the selective death of cells in the tips of both lateral and primary roots. Given the established role of Ran binding proteins in the transport of proteins into the nucleus, these findings are consistent with a model in which AtRanBP1c plays a key role in the nuclear delivery of proteins that suppress auxin action and that regulate mitotic progress in root tips.

Non-NASA Center↗