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At least 415 records · Page 23

Fluorescence of dissolved organic matter: A comparison of north Pacific and north Atlantic Oceans during April 1991

Profiles of airborne-laser-induced fluorescence emission from dissolved organic matter in the upper ocean have been produced and compared for the Southern California Bight (SCB) and the Mid-Atlantic Bight (MAB). Findings were as follows. (1) The fluorescent components of dissolved organic matter (FDOM) are present in easily measurable quantities from near shore to well over 300 km offshore in the SCB and are likewise easily measurable in the coastal, shelf, slope, and Gulf Stream waters of the MAB. (2) The reange of FDOM in the MAB is considerably greater than that in the SCB. (3) The lowest FDOM levels observed in the SCB were higher than those found in the Gulf Stream. (4) The onshore-to-offshore spatial gradient of the FDOM was found to be considerably lower in the SCB than in the MAB, with the highest levels of FDOM being found immediately adjacent to the coast in the MAB. This suggests that the water adjacent to the SCB shoreline is not as strongly influenced by terrestrial and estuarine sources of FDOM as the MAB is. (5) The spatial distribution of the FDOM within both the SCB and the MAB is frequently coherent with the spatial distribution of chlorophyll determined form the concurrent airborne- laser- induced phytoplankton pigment fluorescence measurements. However, distinct noncoherency is sometimes observed, especially at water mass boundaries.

Hoge, Frank E.↗

Partitioning of ocean and land uptake of CO2 as inferred by delta C-13 measurements from the NOAA Climate Monitoring and Diagnostics Laboratory Global Air Sampling Network

Using delta C-13 measurements in atmospheric CO2 from a cooperative global air sampling network, we determined the partitioning of the net uptake of CO2 between ocean and land as a function of latitude and time. The majority of delta C-13 measurements were made at the Institute of Arctic and Alpine Research (INSTAAR) of the University of Colorado. We perform an inverse deconvolution of both CO2 and delta C-13 observations, using a two-dimensional model of atmospheric transport. Also, the discrimination against C-13 by plant photosynthesis, as a function of latitude and time, is calculated from global runs of the simple biosphere (SiB) model. Uncertainty due to the longitudinal structure of the data, which is not represented by the model, is studied through a bootstrap analysis by adding and omitting measurement sites. The resulting error estimates for our inferred sources and sinks are of the order of 1 GTC (1 GTC = 10(exp 15) gC). Such error bars do not reflect potential systematic errors arising from our estimates of the isotopic disequilibria between the atmosphere and the oceans and biosphere, which are estimated in a separate sensitivity analysis. With respect to global totals for 1992 we found that 3.2 GTC of carbon dissolved into the ocean and that 1.5 GTC were sequestered by land ecosystems. Northern hemisphere ocean gyres north of 15 deg N absorbed 2.7 GTC. The equatorial oceans between 10 deg S and 10 deg N were a net source to the atmosphere of 0.9 GTC. We obtained a sink of 1.6 GTC in southern ocean gyres south of 20 deg S, although the deconvolution is poorly constrained by sparse data coverage at high southern latitudes. The seasonal uptake of CO2 in the northern gyres appears to be correlated with a bloom of phytoplankton in surface waters. On land, northern temperate and boreal ecosystems between 35 deg N and 65 deg N were found to be a major sink of CO2 in 1992, as large as 3.5 GTC. Northern tropical ecosystems (equator-30 deg N) appear to be a net source to the source to the atmosphere of 2 GTC which could reflect biomass burning. A small sink, 0.3 GTC, was inferred for southern tropical ecosystems (30 deg S-equator).

Ciais, Philippe↗

Ocean color and atmospheric dimethyl sulfide: On their mesoscale variability

The mesoscale variability of dimethyl sulfide (DMS) and ocean color is explored to determine the feasibility of a predictive relationship. During NASA's Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation (GTE/CITE 3), simultaneous shipboard and aircraft studies were carried out in the North Atlantic, followed by aircraft studies in the South Atlantic. Surface concentrations of chlorophyll alpha were measured with an airborne spectroradiometer, the Ocean Data Acquisition System (ODAS), with simultaneous determinations of tropospheric DMS. Shipboard measurements of DMS in air and water as well as in situ chlorophyll alpha were taken in the North Atlantic. No relation was observed between shipboard aquatic DMS and chlorophyll alpha or primary productivity. Higher levels of aqueous DMS were not always reflected by atmospheric DMS, although shipboard and aircraft measurements of atmospheric DMS agreed very well. A significant relationship between atmospheric DMS and ocean color was seen once at low altitudes in both the North and South Atlantic only under clean air conditions. Atmospheric DMS levels during the North Atlantic experiment were probably lowered by the presence of mostly polluted air masses in the study area and were, overall, probably not representative of the in situ sea-to-air flux of DMS. Changes in concentration of aircraft-sensed chlorophyllous pigments were not reflected by atmospheric DMS. If a predictive algorithm is to be found, phytoplankton blooms should probably be the first place to study an ocean color-DMS relationship.

Matrai, Patricia A.↗

Analysis of ocean color components within stratified and well-mixed waters of the western English Channel

In situ pigment and dissolved organic carbon (DOC) data from two distinct hydrographic regions of the western English Channel are used to explore the possible marine DOC contamination of the past satellite estimates of phytoplankton biomass. To compare with field measurements, the individual spectral contributions of DOC, pigments, and water to the total diffuse attenuation coefficient, K(sub par), are summed on a quantum basis within stratified waters near Plymouth, England; and for the spectrally averaged diffuse attenuation coefficient, K(sub d), on an energy basis within tidally mixed waters near Roscoff, France. In addition, coastal zone color scanner (CZCS) images from 1979 to 1986 were used to compute DOC concentrations for comparison with in situ values. Our analysis suggests that almost 50% of the color signal of satellite-sensed pigments may be attributed to absorption by marine colored DOC (CDOC) within the English Channel. These results compare favorably to the in situ DOC measurements off Plymouth, but not to off-Roscoff measurements, suggesting that there may be more CDOC in the stratified waters and more nonabsorbing DOC in the tidally mixed waters.

Hochmann, Herschel T.↗

Earth System science

Recent research has solidified a view of the Earth as a global-scale interactive system with complex chemical, physical, biological and dynamical processes that link the ocean, atmosphere, land (soils, ice, snow) and marine and terrestrial living organisms. These processes both within and between the major parts of the system help determine global and regional climate and control the biogeochemical and hydrologic cycles essential to life. The study of the Earth System requires measurements ranging from the scales of the smallest processes to the global scale. An ambitious satellite observational program, the Earth Observing System (EOS), carried out along with the complementary and ongoing World Climate Research Program (WCRP) and International Geosphere-Biosphere Program (IGBP) represents a major international effort to understand this System and predict its future changes. The complex and intriguing nature of the Earth System is discussed along with a number of closely coupled processes occurring within it. These are: clouds, precipitation and vegetation; ocean circulation, sea-surface temperature and phytoplankton; coupled oceanic and atmospheric circulation (the Southern Oscillation); biological activity, atmospheric chemistry and climate; and biological emissions and the ozone layer.

Prinn, R. G.↗

Optical characterization of the oceanic unicellular cyanobacterium Synechococcus grown under a day-night cycle in natural irradiance

The optical properties of the ocenanic cyanobacterium Synechococcus (clone WH8103) were examined in a nutrient-replete laboratory culture grown under a day-night cycle in natural irradiance. Measurements of the spectral absorption and beam attenuation coefficients, the size distribution of cells in suspension, and microscopic analysis of samples were made at intervals of 2-4 hours for 2 days. These measurements were used to calculate the optical properties at the level of a single 'mean' cell representative of the acutal population, specifically, the optical cross sections for spectral absorption bar-(sigma(sub a)), scattering bar-sigma(sub b))(lambda), and attentuation bar-(sigma(sub c))(lambda). In addition, concurrent determinations of chlorophyll a and particulate organic carbon allowed calculation of the Chl a- and C-specific optical coefficients. The refractive index of cells was derived from the observed data using a theory of light absorption and scattering by homogeneous spheres. Low irradiance because of cloudy skies resulted in slow division rates of cells in the culture. The percentage of dividing cells was unusually high (greater than 30%) throughout the experiment. The optical cross sections varied greatly over a day-night cycle, with a minimum near dawn or midmorning and maximum near dusk. During daylight hours, bar-(sigma(sub b)) and bar-(sigma(sub c)) can increase more than twofold and bar-(sigma(sub a) by as much as 45%. The real part of the refractive index n increaed during the day; changes in n had equal or greater effect than the varying size distribution on changes in bar-(sigma(sub c)) and bar-(sigma(sub b)). The contribution of changes in n to the increase of bar-(sigma(sub c))(660) during daylight hours was 65.7% and 45.1% on day 1 and 2, respectively. During the dark period, when bar-(sigma(sub c))(660) decreased by a factor of 2.9, the effect of decreasing n was dominant (86.3%). With the exception of a few hours during the second light period, the imaginary part of the refractive index n' showed little variation over a day-night cycle, and bar-(sigma(sub a)) was largely controlled by variations in cell size. The real part of the refractive index at lambda = 660 nm was correlated with the intracellular C concentration and the imaginary part at lambda = 678 nm with the intracellular Chl a concentration. The C-specfic attenuation coefficient showed significant diel variability, which has implications for the estimation of oceanic primary production from measurements of diel variability in beam attenuation. This study provides strong evidence that diel variability is an important component of the optical characterization of marine phytoplankton.

Stramski, Dariusz↗

Volume 35, AMT-1 Cruise Report and Preliminary Results

This report documents the scientific activities on board the Royal Research Ship (RRS) 'James Clark Ross' during the irst Atlantic Meridional Transect (AMT-1), 21 September to 24 October 1995. The ship sailed from Grimsby (England) for Montevideo (Uruguay) and then continued on to Stanley (Falkland Islands). The primary objective of the AMT program is to investigate basic biological processes in the open Atlantic Ocean over very broad spatial scales. For AMT-1, the meridional range covered was approximately 50 deg N to 50 deg S or nearly 8,000 nmi. The measurements to be taken during the AMT cruises are fundamental for the calibration, validation, and continuing understanding of remotely sensed observations of biological oceanography. They are also important for understanding plankton community structure over latitudinal scales and the role of the world ocean in global carbon cycles. During AMT-1 a variety of instruments were used to map the physical, chemical, and biological structure of the upper 200 m of the water column. Ocean color measurements were made using state-of-the-art sensors, whose calibration was traceable to the highest international standards. New advances in fluorometry were used to measure photosynthetic activity, which was then used to further interpret primary productivity. A unique set of samples and data were collected for the planktonic assemblages that vary throughout the range of the transect. These data will yield new interpretations on community composition and their role in carbon cycling. While the various provinces of the Atlantic Ocean were being crossed, the partial pressure of CO2 was related to biological productivity. This comparison revealed the areas of drawdown of atmospheric CO2 and how these areas relate to the surrounding biological productivity. These data, plus the measurements of light attenuation and phytoplankton optical properties, will be used as a primary input for basin-scale biological productivity models to help develop ecosystem dynamics models which will be important for improving the forecasting abilities of modelers. The AMT program is also attempting to meet the needs of international agencies in their implementation of Sensor Intercomparison and Merger for Biological and Interdisciplinary Ocean Studies (SIMBIOS), a program to develop a methodology and operational capability to combine data products from the various ocean color satellite missions.

Hooker, Stanford B.↗

Model for the Interpretation of Hyperspectral Remote-Sensing Reflectance

Remote-sensing reflectance is easier to interpret for the open ocean than for coastal regions because the optical signals are highly coupled to the phytoplankton (e.g., chlorophyll) concentrations. For estuarine or coastal waters, variable terrigenous colored dissolved organic matter (CDOM), suspended sediments, and bottom reflectance, all factors that do not covary with the pigment concentration, confound data interpretation. In this research, remote-sensing reflectance models are suggested for coastal waters, to which contributions that are due to bottom reflectance, CDOM fluorescence, and water Raman scattering are included. Through the use of two parameters to model the combination of the backscattering coefficient and the Q factor, excellent agreement was achieved between the measured and modeled remote-sensing reflectance for waters from the West Florida Shelf to the Mississippi River plume. These waters cover a range of chlorophyll of 0.2-40 mg/cu m and gelbstoff absorption at 440 nm from 0.02-0.4/m. Data with a spectral resolution of 10 nm or better, which is consistent with that provided by the airborne visible and infrared imaging spectrometer (AVIRIS) and spacecraft spectrometers, were used in the model evaluation.

Lee, Zhongping↗

Tests of a Semi-Analytical Case 1 and Gelbstoff Case 2 SeaWiFS Algorithm with a Global Data Set

A semi-analytical algorithm was tested with a total of 733 points of either unpackaged or packaged-pigment data, with corresponding algorithm parameters for each data type. The 'unpackaged' type consisted of data sets that were generally consistent with the Case 1 CZCS algorithm and other well calibrated data sets. The 'packaged' type consisted of data sets apparently containing somewhat more packaged pigments, requiring modification of the absorption parameters of the model consistent with the CalCOFI study area. This resulted in two equally divided data sets. A more thorough scrutiny of these and other data sets using a semianalytical model requires improved knowledge of the phytoplankton and gelbstoff of the specific environment studied. Since the semi-analytical algorithm is dependent upon 4 spectral channels including the 412 nm channel, while most other algorithms are not, a means of testing data sets for consistency was sought. A numerical filter was developed to classify data sets into the above classes. The filter uses reflectance ratios, which can be determined from space. The sensitivity of such numerical filters to measurement resulting from atmospheric correction and sensor noise errors requires further study. The semi-analytical algorithm performed superbly on each of the data sets after classification, resulting in RMS1 errors of 0.107 and 0.121, respectively, for the unpackaged and packaged data-set classes, with little bias and slopes near 1.0. In combination, the RMS1 performance was 0.114. While these numbers appear rather sterling, one must bear in mind what mis-classification does to the results. Using an average or compromise parameterization on the modified global data set yielded an RMS1 error of 0.171, while using the unpackaged parameterization on the global evaluation data set yielded an RMS1 error of 0.284. So, without classification, the algorithm performs better globally using the average parameters than it does using the unpackaged parameters. Finally, the effects of even more extreme pigment packaging must be examined in order to improve algorithm performance at high latitudes. Note, however, that the North Sea and Mississippi River plume studies contributed data to the packaged and unpackaged classess, respectively, with little effect on algorithm performance. This suggests that gelbstoff-rich Case 2 waters do not seriously degrade performance of the semi-analytical algorithm.

Carder, Kendall L.↗

Bio-Optical Properties of the Arabian Sea as Determined by In Situ and Sea WiFS Data

The overall objective of this work was to characterize optical and fluorescence properties in the euphotic zone during two British Ocean Flux Study (BOFS) Arabian Sea cruises. This was later expanded in 1995 to include three U.S. JGOFS Arabian Sea Cruises. The region was to be divided into one or more "bio-optical provinces," within each of which a single set of regression models was to be developed to relate the vertical distribution of irradiance attenuation and normalized fluorescence (SF and NF) to remote sensing reflectance and diffuse attenuation coefficient. The working hypothesis was that over relatively large spatial and temporal scales, the vertical profiles of bio-optical properties were predictable. The specific technical objectives were: (1) To characterize the vertical distribution of the inherent and apparent optical properties by measuring downwelling and upwelling irradiances, upwelling radiances, scalar irradiance of PAR, and beam transmissions at each station - from these data, spectral diffuse attenuation coefficients, irradiance reflectances, remote sensing reflectances, surface-leaving radiances and beam attenuation coefficients were determined; (2) To characterize the spectral absorption of total particulate, detrital, and dissolved organic material at each station from discrete water samples; (3) To describe the vertical distribution of photoadaptive properties in the water column by measuring profiles of stimulated (SF) and natural (NF) fluorescence and examining relationships between SF and NF as a function of diffuse optical depth, pigment biomass and primary productivity; and (4) To establish locally derived, in-water algorithms relating remote sensing reflectance spectra to diffuse attenuation coefficients, phytoplankton pigment concentrations and primary productivity, through intercomparisons with in situ measurements, for application to SeaWiFS data.

Trees, Charles C.↗

Toward Describing the Effects of Ozone Depletion on Marine Primary Productivity and Carbon Cycling

This project was aimed at improved predictions of the effects of UVB and ozone depletion on marine primary productivity and carbon flux. A principal objective was to incorporate a new analytical description of photosynthesis as a function of UV and photosynthetically available radiation (Cullen et. al., Science 258:646) into a general oceanographic model. We made significant progress: new insights into the kinetics of photoinhibition were used in the analysis of experiments on Antarctic phytoplankton to generate a general model of UV-induced photoinhibition under the influence of ozone depletion and vertical mixing. The way has been paved for general models on a global scale.

Cullen, John J.↗

Fuzzy Classification of Ocean Color Satellite Data for Bio-optical Algorithm Constituent Retrievals

The ocean has been traditionally viewed as a 2 class system. Morel and Prieur (1977) classified ocean water according to the dominant absorbent particle suspended in the water column. Case 1 is described as having a high concentration of phytoplankton (and detritus) relative to other particles. Conversely, case 2 is described as having inorganic particles such as suspended sediments in high concentrations. Little work has gone into the problem of mixing bio-optical models for these different water types. An approach is put forth here to blend bio-optical algorithms based on a fuzzy classification scheme. This scheme involves two procedures. First, a clustering procedure identifies classes and builds class statistics from in-situ optical measurements. Next, a classification procedure assigns satellite pixels partial memberships to these classes based on their ocean color reflectance signature. These membership assignments can be used as the basis for a weighting retrievals from class-specific bio-optical algorithms. This technique is demonstrated with in-situ optical measurements and an image from the SeaWiFS ocean color satellite.

Campbell, Janet W.↗

An Ecosystem Model for the Simulation of Physical and Biological Oceanic Processes-IDAPAK User's Guide and Applications

This TM describes the development, testing, and application of a 4-component (phytoplankton, zooplankton, nitrate, and ammonium) ecosystem model capable of simulating oceanic biological processes. It also reports and documents an in-house software package (Interactive Data Analysis Package - IDAPAK) for interactive data analysis of geophysical fields, including those related to the forcing, verification, and analysis of the ecosystem model. Two regions were studied in the Pacific: the Warm Pool (WP) in the Equatorial Pacific (165 deg. E at the equator) and at Ocean Weather Station P (OWS P) in the Northeast Pacific (50 deg. N, 145 deg. W). The WP results clearly indicate that the upwelling at 100 meters correlates well with surface blooms. The upwelling events in late 1987 and 1990 produced dramatic increases in the surface layer values of all 4 ecosystem components, whereas the spring-summer deep mixing events, do not seem to incur a significant response in any of the ecosystem quantities. The OWS P results show that the monthly profiles of temperature, the annual cycles of solar irradiance, and 0- to 50-m integrated nitrate accurately reproduce observed values. Annual primary production is 190 gC/m(exp 2)/yr, which is consistent with recent observations but is much greater than earlier estimates.

McClain, Charles R.↗

[MODIS Investigation]

Our first activity is based on delivery of code to Bob Evans (University of Miami) for integration and eventual delivery to the MODIS Science Data Support Team. As we noted in our previous semi-annual report, coding required the development and analysis of an end-to-end model of fluorescence line height (FLH) errors and sensitivity. This model is described in a paper in press in Remote Sensing of the Environment. Once the code was delivered to Miami, we continue to use this error analysis to evaluate proposed changes in MODIS sensor specifications and performance. Simply evaluating such changes on a band by band basis may obscure the true impacts of changes in sensor performance that are manifested in the complete algorithm. This is especially true with FLH that is sensitive to band placement and width. The error model will be used by Howard Gordon (Miami) to evaluate the effects of absorbing aerosols on the FLH algorithm performance. Presently, FLH relies only on simple corrections for atmospheric effects (viewing geometry, Rayleigh scattering) without correcting for aerosols. Our analysis suggests that aerosols should have a small impact relative to changes in the quantum yield of fluorescence in phytoplankton. However, the effect of absorbing aerosol is a new process and will be evaluated by Gordon.

Abbott, Mark R.↗

A Simulation of Biological Prosesses in the Equatorial Pacific Warm Pool at 165 deg E

A nine-year simulation (1984-1992) of biological processes in the equatorial Pacific Warm Pool is presented. A modified version of the 4-component (phytoplankton, zooplankton, nitrate and ammonium) ecosystem model by McClain et al. (1996) is used. Modifications include use of a spectral model for computation of PAR and inclusion of fecal pellet remineralization and ammonium nitrification. The physical parameters (horizontal and vertical velocities and temperature) required by the ecosystem model were derived from an improved version of the Gent and Cane (1990) ocean general circulation model (Murtugudde and Busalacchi, 1997). Surface downwelling spectral irradiance was estimated using the clear-sky models of Frouin et al. (1989) and Gregg and Carder (1990) and cloud cover information from the International Satellite Cloud Climatology Project (ISCCP). The simulations indicate considerable variability on interannual time scales in all four ecosystem components. In particular, surface chlorophyll concentrations varied by an order of magnitude with maximum values exceeding 0.30 mg/cu m in 1988, 1989, and 1990, and pronounced minimums during 1987 and 1992. The deep chlorophyll maximum ranged between 75 and 125 meters with values occasionally exceeding 0.40 mg/cu m. With the exception of the last half of 1988, surface nitrate was always near depletion. Ammonium exhibited a subsurface maximum just below the DCM with concentrations as high as 0.5 mg-atN/cu m . Total integrated annual primary production varied between 40 and 250 gC/sq m/yr with an annual average of 140 gC/sq m/yr. Finally, the model is used to estimate the mean irradiance at the base of the mixed layer, i.e., the penetration irradiance, which was 18 Watts/sq m over the nine year period. The average mixed layer depth was 42 m.

McClain, Charles R.↗

Participation in the 1996 Arlindo Cruise to the Indonesian Seas

The objective of Arlindo-Productivity is to understand the factors responsible for regional differences in the response of phytoplankton and zooplankton to the SE and NW Monsoons in Indonesia. The hypothesis is that an interplay between circulation and shoaling of the nutricline, as a response to the monsoons, regulates productivity in the Indonesian Seas. My o@jective for the cruise in 1996 was to continue our collaboration with Indonesian scientists by conducting a set of hydrographic, primary production and spectral irradiance observations in the Indonesian Seas. This grant paid for shipping, travel and incidental costs associated with participation in the cruise in December, 1996. Ship costs were borne by the Indonesian Institute of Sciences as part of the collaborative effort. A plan for Arlindo in 1996 was agreed upon in March, 1996, by Indonesian scientists together with Arnold Gordon. The plan called for a 20-day physical oceanography and mooring cruise in November, 1996, followed by a 5-day bio-optical cruise. The bio-optical cruise departed from, and returned to, Ambon, and sampled in the Banda Sea. We completed a series of chlorophyll analyses, both a sampling of surface variability and depth profiles in the Banda Sea. We also completed three MER profiles for depth profiles of spectral irradiance. These data have a useful by-product in that they can be used for vicarious calibration of the OCTS sensor aboard the ADEOS satellite. As such, the data has been transmitted to NASDA in Japan for their use.

Marra, John↗

Ocean Thermal and Color Evolution During the 1997/1998 ENSO Event

A reduced gravity primitive equation modeling and assimilation system is used to study the evolution of the tropical Pacific during the 1997/1998 ENSO cycle. The modeling/assimilation scheme ingests satellite altimeter data and TAO temperature profiles and uses SSM/I satellite derived winds as surface boundary forcing. The four-dimensional structure of the upper ocean circulation structure will be compared against available in situ observations across the Pacific basin. In particular, variability near the Galapagos Islands will be highlighted during the spring of 1998 when phytoplankton concentrations were observed to increase a hundred-fold over a two week period.

Rienecker, Michele↗

One-Dimensional Coupled Ecosystem-Carbon Flux Model for the Simulation of Biogeochemical Parameters at Ocean Weather Station P

In this Technical Publication, we describe the model functionality and analyze its application to the seasonal and interannual variations of phytoplankton, nutrients, pCO2 and CO2 concentrations in the eastern subarctic Pacific at Ocean Weather Station P (OWSP, 50 deg. N 145 deg. W). We use a verified one-dimensional ecosystem model, coupled with newly incorporated carbon flux and carbon chemistry components, to simulate 22 years (1958-1980) of pCO2 and CO2 variability at Ocean Weather Station P (OWS P). This relatively long period of simulation verifies and extends the findings of previous studies using an explicit approach for the biological component and realistic coupling with the carbon flux dynamics. The slow currents and the horizontally homogeneous ocean in the subarctic Pacific make OWS P one of the best available candidates for modeling the chemistry of the upper ocean in one dimension. The chlorophyll and ocean currents composite for 1998 illustrates this premise. The chlorophyll concentration map was derived from SeaWiFS data and the currents are from an OGCM simulation (from R. Murtugudde).

Signorini, S.↗