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All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

A Return to Io: Science Goals and Implementation

Io remains one of the most fascinating objects in the solar system: the only place beyond Earth where we can watch hard-rock geology in action. In its high heat flow Io resembles the early Earth, providing a present-day analog to some of the processes that dominated the Earth's geology at the time that life first appeared. Io's usefulness as an early-Earth analog has been underscored recently by the detection of very high eruption temperatures, hotter than terrestrial basaltic lavas. These temperatures are most plausibly interpreted as resulting from ultramafic lava compositions, analagous to the komatiites that were common on Earth in the Precambrian but which have been virtually absent during the Phanerozoic. The large scale of many Io eruptions also provides useful analogs to Phanerozoic terrestrial eruptions, such as flood basalts, which are important for the Earth's geological and biological evolution but which occur too rarely to be witnessed by humans on our own planet. By providing living examples, Io can thus play the same role in understanding large-scale planetary volcanism that volcanically active terrestrial regions have played in understanding the results of smaller-scale volcanic processes seen in the geological record worldwide. Additional information is contained in the original extended abstract.

Spencer, J. R.↗
NASA NTRS2006

NASA Tech Briefs, August 2006

Topics covered include: Measurement and Controls Data Acquisition System IMU/GPS System Provides Position and Attitude Data Using Artificial Intelligence to Inform Pilots of Weather Fast Lossless Compression of Multispectral-Image Data Developing Signal-Pattern-Recognition Programs Implementing Access to Data Distributed on Many Processors Compact, Efficient Drive Circuit for a Piezoelectric Pump; Dual Common Planes for Time Multiplexing of Dual-Color QWIPs; MMIC Power Amplifier Puts Out 40 mW From 75 to 110 GHz; 2D/3D Visual Tracker for Rover Mast; Adding Hierarchical Objects to Relational Database General-Purpose XML-Based Information Managements; Vaporizable Scaffolds for Fabricating Thermoelectric Modules; Producing Quantum Dots by Spray Pyrolysis; Mobile Robot for Exploring Cold Liquid/Solid Environments; System Would Acquire Core and Powder Samples of Rocks; Improved Fabrication of Lithium Films Having Micron Features; Manufacture of Regularly Shaped Sol-Gel Pellets; Regulating Glucose and pH, and Monitoring Oxygen in a Bioreactor; Satellite Multiangle Spectropolarimetric Imaging of Aerosols; Interferometric System for Measuring Thickness of Sea Ice; Microscale Regenerative Heat Exchanger Protocols for Handling Messages Between Simulation Computers Statistical Detection of Atypical Aircraft Flights NASA's Aviation Safety and Modeling Project Multimode-Guided-Wave Ultrasonic Scanning of Materials Algorithms for Maneuvering Spacecraft Around Small Bodies Improved Solar-Radiation-Pressure Models for GPS Satellites Measuring Attitude of a Large, Flexible, Orbiting Structure

Source record↗
NASA NTRS2015

Mineralogy of the Pahrump Hills Region, Gale Crater, Mars

The Pahrump Hills region of Gale crater is a approximately 12 millimeter thick section of sedimentary rocks in the Murray formation, interpreted as the basal geological unit of Mount Sharp. The Mars Science Laboratory, Curiosity, arrived at the Pahrump Hills in September, 2014, and performed a detailed six-month investigation of the sedimentary structures, geochemistry, and mineralogy of the area. During the campaign, Curiosity drilled and delivered three rock samples to its internal instruments, including the CheMin XRD/XRF. The three targets, Confidence Hills, Mojave 2, and Telegraph Peak, contain variable amounts of plagioclase, pyroxene, iron oxides, jarosite, phyllosilicates, and X-ray amorphous material. Hematite was predicted at the base of Mount Sharp from orbital visible/near-IR spectroscopy, and CheMin confirmed this detection. The presence of jarosite throughout Pahrump Hills suggests the sediments experienced acid-sulfate alteration, either in-situ or within the source region of the sediments. This acidic leaching environment is in stark contrast to the environment preserved within the Sheepbed mudstone on the plains of Gale crater. The minerals within Sheepbed, including Fe-saponite, indicate these sediments were deposited in a shallow lake with circumneutral pH that may have been habitable.

Rampe, E. B.↗
NASA NTRS2019

Biomarker and Geochemical Assay Validation in Mars Analog Sites: Lessons from the FELDSPAR (Field Exploration and Life Detection Sampling for Planetary Analog Research) Project

Missions looking for signs of life on other worlds can often only take a few samples once they arrive. Making sense of these "few and far between" observations is easier if we know what a "normal" level of variation for that kind of planet is. Recent eruption sites in Iceland are good places to learn about this, because they have very little life present and the same types of rocks as many places on Mars. We have visited several of these sites in Iceland and tested many different kinds of measurements: the energy available for life, the amount of DNA (an important biological molecule) present, the relative amounts of different kinds of micro-organisms, and the specific minerals that make up the rocks and ground. In addition to recommendations for future expeditions, we have also shown that using early on-site measurements to choose later on-site sample sites is very helpful in reducing the number of sample sites needed.

Geochemical Assay Validation↗
NASA NTRS1973

Application of ERTS-1 imagery to detecting and mapping modern erosion features and to monitoring erosional changes, in southern Arizona

The author has identified the following significant results. The chief results during the reporting period were three 1:1,000,000 scale maps made from one ERTS-1 frame (1085-17330, 16 October 1972) showing: (1) the three most important types of materials in terms of the modern erosion problem: the readily erodible soils, gravel piedmonts and basin-fill areas, and consolidated rocks; (2) alluvial fans (dissected and relatively undissected); and (3) (as an additional bonus) linear structural features. Eight key areas (small parts of the whole study area) were selected for detailed study, and mapping was started in two of them, by interpretation of ultrahigh (U-2 and RB-57) airphotos, supplemented by field studies. In these areas detailed mapping was done not only on the modern erosion phenomena (arroyos, gullies, modern flood plains and terraces, and areas of sheet erosion and deposition), but also other features pertinent to the erosion problem, such as slope-local relief, landforms rock units, soil particle size and erodibility, and classes of vegetative cover.

Morrison, R. B.↗
NASA NTRS1985

Robust detection, isolation, and accommodation for sensor failures

Recent advances in multivariable robust control system design are extended to sensor failure, detection, isolation, and accommodation (FDIA) and estimator design. A new concept called threshold selector is introduced. It represents a significant and innovative tool for the analysis and synthesis of FDIA algorithms. Analytical results are obtained for the SISO case to compute optimal thresholds and size of minimum detectable failures, and a computer-aided technique is developed for the multivariable case. The techniques have been applied to sensor FDIA for an aircraft turbine engine control system.

Emami-Naeini, A.↗
NASA NTRS2015

Smectite Formation from Basaltic Glass Under Acidic Conditions on Mars

Massive deposits of phyllosilicates of the smectite group, including Mg/Fe-smectite, have been identified in Mars's ancient Noachian terrain. The observed smectite is hypothesized to form through aqueous alteration of basaltic crust under neutral to alkaline pH conditions. These pH conditions and the presence of a CO2-rich atmosphere suggested for ancient Mars were favorable for the formation of large carbonate deposits. However, the detection of large-scale carbonate deposits is limited on Mars. We hypothesized that smectite deposits may have formed under acidic conditions that prevented carbonate precipitation. In this work we investigated formation of saponite at a pH of approximately 4 from Mars-analogue synthetic Adirondack basaltic glass of composition similar to Adirondack class rocks located at Gusev crater. Hydrothermal (200º Centigrade) 14 day experiments were performed with and without 10 millimoles Fe(II) or Mg under anoxic condition [hereafter denoted as anoxic_Fe, anoxic_Mg and anoxic (no addition of Fe(II) or Mg)] and under oxic condition [hereafter denoted as oxic (no addition of Fe(II) or Mg)]. Characterization and formation conditions of the synthesized saponite provided insight into the possible geochemical conditions required for saponite formation on Mars.

Peretyazhko, T. S.↗
NASA NTRSDate not supplied

Organic Carbon Concentrations in 3-Billion-Year-Old Lacustrine Mudstones of Mars

Understanding the inventory of carbon on Mars is relevant to the question of whether Mars was ever habitable. While the Mars atmosphere represents a large reservoir of carbon, in situ pyrolysis performed on Mars and meteorite analyses indicate that another significant reservoir of carbon is the rocks themselves. Complex organic carbon was discovered in 3.5 Ga mudstones sampled at Cumberland (CB) in the Yellowknife Bay Formation in Gale Crater by the Sample Analysis at Mars (SAM) instrument suite on the Mars Science Laboratory (MSL) using a thermal decomposition technique called evolved gas analysis (EGA). Other simple organics have also been detected in these same CB materials. Low temperature co-evolution of CO and CO2 (~200°C – 500°C) has been detected in many samples from Gale Crater where SAM EGA has been performed, and potential sources include combustion of terrestrial organics from SAM, as well as combustion and/or decarboxylation of either indigenous martian or exogenous organic carbon.

J. C. Stern↗
NASA NTRS1984

Calderas of the Sierra Madre Occidental volcanic field western Mexico

The data base on the mineral content, geomorphology, and extent of caldera in the Sierra Madre Occidental volcanic field is surveyed. Caldera identified from Landsat imagery and confirmed by field studies have generally had high structural levels and are therefore the youngest calderas and sometimes overlap. Detectable margins have been vertical and abrupt, while other structures indicate collapse during eruption and accumulation of thick, intracaldera facies. Calderas which collapsed are generally filled with sedimentation. Mineral deposits hosted by the caldera include tin, silver, gold, and iron, and a spatial relationship has been characterized between the Ocampa caldera structure and mineralized precaldera rocks. The survey has confirmed the locations of several dozen caldera, while the volume of silicic rocks surveyed indicates the presence of several hundred caldera in the Sierra Madre.

Swanson, E. R.↗
NASA NTRS1985

Atmospheric neutrinos observed in underground detectors

Atmospheric neutrinos are produced when the primary cosmic ray beam hits the atmosphere and initiates atmospheric cascades. Secondary mesons decay and give rise to neutrinos. The neutrino production was calculated and compared with the neutrino fluxes detected in underground detectors. Contained neutrino events are characterized by observation of an interaction within the fiducial volume of the detector when the incoming particle is not observed. Both the neutrino flux and the containment requirement restrict the energy of the neutrinos observed in contained interactions to less than several GeV. Neutrinos interact with the rock surrounding the detector but only muon neutrino interactions can be observed, as the electron energy is dissipated too fast in the rock. The direction of the neutrino is preserved in the interaction and at energies above 1 TeV the angular resolution is restricted by the scattering of the muon in the rock. The muon rate reflects the neutrino spectrum above some threshold energy, determined by the detector efficiency for muons.

Gaisser, T. K.↗
NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 17

The following topics were discussed: A Model for the Formation of Paterae on Io; LIBS-based Detection of As, Br, C, Cl, P, and S in the VUV Spectral Region in a Mars Atmosphere; Mass Independent Sulfur in Achondrites: Possible Evidence of Photochemistry in the Solar Nebula; Grain Size-dependent Viscosity and Oceans in Icy Satellites; Claritas Paleolake Studied from the MEX HRSC Data; Mars Express HRSC Colors of White Rock, Arabia, Mars; Lava and Flows of the Arcadia Region of Mars; Isotopic Composition of Lunar Soils and the Early Differentiation of the Moon; Trace Element Analysis of Lunar Soils by ICP-MS; Highly Siderophile Elements and Osmium Isotope Systematics in Ureilites: Are the Carbonaceous Veins Primary Components?; Evaporative Evolution of Martian Brines Based on Halogens in Nakhlites and MER Samples; Io from High-Resolution Galileo PPR Data Taken Simultaneously with SSI or NIMS Observations; Loki, Io: Groundbased Observations and a Model for Periodic Overturn; Deconstructing a Few Myths in the Interpretation of Satellite-Altitude Crustal Magnetic Field: Examples from Mars Global Surveyor; Semi-Autonomous Rover Operations: A Mars Technology Program Demonstration; Rotational Studies of Asteroids with Small Telescopes; Mineralogy and Temperature-induced Spectral Investigations of A-type Asteroids 246 Asporina and 446 Aeternitas; and Thermal History Calculations Versus Full Convection Models: Application to the Thermal Evolution of Mercury. Recent Solar-Proton Fluxes

Source record↗
NASA NTRS2001

The Combined Detection of Morphological and Molecular Biomarkers: Implications for Astrobiology

Experience gathered by previous researchers during their hunt for evidence of early Earth life has shown the complexity in interpreting observations of possible microfossils and to establish the evidence to be positive. Similarly, the stillsimmering controversy on the nature of the nano-structures in Martian meteorite ALH84001 described by McKay et al. (1996) emphasizes the difficulties of conclusively identifying those structures as (a) fossilized bacterial cells and (b) establish their indigeneity. A better understanding of biological signatures in rocks is needed in order to identify traces of microbial life, which include morphological, mineralogical and chemical traces. It is thus considered crucial to tackle the problems emerging in the search for evidence of early life on Earth and in exopaleontological research with a multidisciplinary approach. With this is mind we applied surface sensitive Time of Flight-Secondary Ion Mass Spectroscopy (ToF-SIMS) to a previously described 25 m.y. old fossil bacterial biofilm. This technique allows in situ analysis with high mass resolution as well as molecular imaging of micron sized structures. As no extraction or derivatisation of the sample is required for ToF-SIMS analysis, electron microscopical investigation of the same samples subsequent to analysis is possible, thus allowing the combination of molecular and morphological biomarkers. The analysed fossil bacterial biofilms were associated with macrofossils from volcanoclastic lacustrine sediments from the Upper Oligocene Enspel formation (Germany). Preliminary scanning electron microscopy (SEM) studies have shown that a fossil structure interpreted as a coprolite purely consisted of fossilized bacterial biofilm. For ToF-SIMS investigation small particles were taken from the fossil biofilm and mounted onto Au-coated In-foil and analysed in a Phi Evans T-2000 TRIFT system. The ToF-SIMS analysed samples were Au/Pd-sputter coated and imaged using a Philips XL40 Field Emission Gun SEM (FEG-SEM). ToF-SIMS analysis of the organic rich fossil biofilm (TOC 29%) in the 0-100 Dalton (Da) range showed significant amounts of inorganic species, confirming the results obtained previously by EDX analysis, clearly showing the bacterial fossils to be mineralised. ToF-SIMS furthermore revealed the presence of a variety of low- and high-mass organic molecules and fragments thereof. These include peaks indicative of alkenes and alkanes, aromatic organic species and the polycyclic aromatic hydrocarbon naphthalene. More tentatively, peaks indicative of alkyl pyrroles and pyridyl-CH2 were identified. Other peaks of interest include peaks indicative of C(n)H(2n)O2 and C(n)H(2n-2)O2, which according to their general formula would suggest the presence of both saturated and unsaturated fatty acids although further in situ derivatisation experiments and GC-MS (Gas Chromatography MS) need to be applied to verify this beyond doubt. Furthermore, peaks at m/z 370, 384, 398, 412, 426, 440, 454 and 468 were identified, which indicate the potential presence of bacterial hopanes, a class of biomarkers indicative of bacteria. The main diagnostic peak for this group of chemicals is the fragment at m/z 191.18. Our studies conducted on purified hopane standards have shown that in the high-mass resolution mode differentiation of this diagnostic hopane peak and polyethylene at m/z 191.05 is possible. However, the spectra discussed here were collected in the lower resolution mapping mode, therefore this differentiation was not possible. The centroids of the possible hopane peaks obtained on the fossil biofilms are well within the range associated with bacterial hopanes. There is a strong possibility therefore that hopanoids may be associated with the fossil bacterial cells. Due to the non-destructive nature of ToF-SIMS, analysed samples can be studied using SEM, thus allowing the combination of morphological and molecular biomarkers. Subsequent SEM analysis of the ToF-SIMS analysed samples confirmed that the analysed material purely consists of fossil bacterial cells. This is thus the first successful effort to demonstrate the combination of spectral and morphological biomarkers. The advantages of highly sensitive non-destructive in situ analysis techniques for biomarker detection are invaluable, particularly with respect to envisaged Mars sample return missions, as it may allow us to identify remains and traces of former microbial life in both ancient terrestrial and extraterrestrial materials. This technique may prove particularly useful in the quest for extraterrestrial life with respect to precious extraterrestrial materials, as minute quantities are sufficient to conduct analysis.

Toporski, J.↗
NASA NTRS2018

Maximum Sample Temperature for Mars Sample Return: A Historical Perspective

Since the first Mars Sample Return (MSR) report published by the Jet Propulsion Laboratory (JPL) in 1974 [1], a series of panels, reports, and white papers have recognized the importance of sample temperature and offered an informed sample maximum temperature (henceforth SMT) limit for returning martian samples to Earth. The Mars Sample Handling and Requirements Panel (MSHARP, 1999) stated that "[t]he main issue in sample preservation is temperature" [2]. More recently, the Mars Exploration Program Analysis Group (MEPAG)'s "Science Priorities for Mars Sample Return" report (2008), declared that "[s]ignificant loss, particularly to biological studies, occurs if samples reach +50C for three hours", whereby "scientific objectives related to life goals could be seriously compromised" [3]. By contrast, the Mars 2020 mission has adopted a SMT of +60C as spelled out in Beaty et al., 2016 [4]. Samples will be collected and then deposited on the surface in sealed tubes for possible retrieval and return to Earth. Beaty et al. [4] calculates that the samples will experience maximum temperatures of ~+30 to +60C, depending on latitude. At present, there is no mission requirement for the measurement/data logging of sample temperature during this period. We will explore the history of martian SMTs, as they have been recorded since 1974 [1], effectively representing input across multiple generations of Mars scientists. Ten separate publications present SMTs for MSR samples [1-10]. One report [10] is for a mission concept specifically designed to exclude life detection investigations, and recommended an SMT of 50C. Another did not specify a temperature, recommending "Mars ambient temperature" [5]. Of the remaining eight, SMTs are given as: -30C [1], -20C [3], 60C [4], -73 to 41C depending on sample type [6], -40C [7], -43 to 13C depending on type [2,8], and -33C [9]. If we restrict the temperatures to samples highlighted in the Mars 2020 mission goals, i.e. organics-bearing and sedimentary rocks, then the average SMT is -28+/-39C (n=8). Applying a Dixon's Q Test at P=0.05 (two-tailed), the 60C SMT [4] fails with Q=0.602 versus Qcrit=0.526. Excluding the outlier produces an average SMT of -40+/-17C (n=7). Therefore, the average SMT expressed by the Mars science community over the past 44 years (two generations) is a sample temperature no greater than -40C. The difference in chemical reaction rates between this average SMT and Beaty et al [4] can be estimated using the Arrhenius equation. Assuming a generic chemical reaction with an activation energy of 50 kJ/mol and a pre-exponential factor invariant with temperature, this reaction will proceed 2300x faster at 60C than at -40C. To illustrate the effects of the increased reaction rate, consider 10 ppb of alanine in a Mars 2020 cache, and assume that it becomes unmeasurable if it degrades to 1 ppb, as per the Mars 2020 Organic Contamination Panel contamination limits [11]. If we illustrate the effect with an arbitrary degradation rate such that the alanine will become undetectable in ten years at -40C, then the same 10 ppb alanine degrades beyond detectability in only 38 days at 60C. Further research is required to quantify expected analyte losses in the cached samples due to thermal processing.

Fries, Marc↗
NASA NTRS1983

Use of laboratory spectra for determining vegetation assemblages in Landsat images

A spectral library is a diverse collection of reflectance spectra which are used, not as an image-matching data base, but rather as an interpretive link to the physical/chemical processes that cause absorption of light in plants, minerals, rocks, and soils. Techniques for using this library to interpret Landsat MSS data are described, including the process of normalization which largely eliminates brightness effects of both laboratory and image data. Three image-to-library programs are explained. These have been used successfully to descriminate very small (less than 10 percent) changes in plant species components, to detect the presence of vegetation in units where percent cover is only 5 percent, and to recognize unusual vegetation patterns that relate to substrate changes where the substrate is not directly resolvable.

Adams, J. D.↗
NASA NTRS1976

Exploring with Gravity

Among oil and mineral prospecting tools are instruments that measure anomalies in gravitational and related fields. These instruments work because density of hydrocarbon bearing rock or ore deposits is different from normal soil. Langley Research Center undertook a six month feasibility study to adapt a sensitive resonance fluorescence spectrometer as a gravitometer. The spectrometer was improved initially by Langley Research Center to investigate small changes in atomic composition of spacecraft metals that might cause structural fatigue. Results indicate that such device can detect gravitational normalities from air with sufficient accuracy to reveal mineral and oil sources.

Source record↗
NASA NTRS2008

Mid-Infrared OPO for High Resolution Measurements of Trace Gases in the Mars Atmosphere

The Martian atmosphere is composed primarily (>95%) of CO2 and N2 gas, with CO, O2, CH4, and inert gases such as argon comprising most of the remainder. It is surprisingly dynamic with various processes driving changes in the distribution of CO2, dust, haze, clouds and water vapor on global scales in the meteorology of Mars atmosphere [I]. The trace gases and isotopic ratios in the atmosphere offer important but subtle clues as to the origins of the planet's atmosphere, hydrology, geology, and potential for biology. In the search for life on Mars, an important process is the ability of bacteria to metabolize inorganic substrates (H2, CO2 and rock) to derive energy and produce methane as a by-product of anaerobic metabolism. Trace gases have been measured in the Mars atmosphere from Earth, Mars orbit, and from the Mars surface. The concentration of water vapor and various carbon-based trace gases are observed in variable concentrations. Within the past decade multiple groups have reported detection of CH4, with concentrations in the 10's of ppb, using spectroscopic observations from Earth [2]. Passive spectrometers in the mid-infrared (MIR) are restricted to the sunlit side of the planet, generally in the mid latitudes, and have limited spectral and spatial resolution. To accurately map the global distribution and to locate areas of possibly higher concentrations of these gases such as plumes or vents requires an instrument with high sensitivity and fine spatial resolution that also has global coverage and can measure during both day and night. Our development goal is a new MIR lidar capable of measuring, on global scales, with sensitivity, resolution and precision needed to characterize the trace gases and isotopic ratios of the Martian atmosphere. An optical parametric oscillator operating in the MIR is well suited for this instrument. The sufficient wavelength tuning range of the OPO can extend the measurements to other organic molecules, CO2, atmospheric water vapor, clouds, temperature, dust, and aerosols, as well as possibly polar-cap properties. Our OPO-approach may allow a new capability for active remote sensing of the outer planets and moons, where the weaker sunlight further limit passive instruments. Here we report on the OPO development effort for this lidar instrument.

Yu, Anthony W.↗
NASA NTRS2020

Aqueous Processes and Microbial Habitability of Gale Crater Sediments from the Blunts Point to the Glenn Torridon Clay Unit

A driving factor for sending the Mars Science Laboratory, Curiosity rover to Gale Crater was the orbital detection of clay minerals in the Glen Torridon (GT) clay unit. Clay mineral detections in GT suggested a past aqueous environment that was habitable, and could contain organic evidence of past microbiology. The mission of the Sample Analysis at Mars (SAM) instrument onboard Curiosity was to detect organic evidence of past microbiology and to detect volatile bearing mineralogy that can inform on whether past geochemical conditions would have supported microbiological activity. The objective of this work was to 1) evaluate the depositional/alteration conditions of Blunt’s Point (BP) to GT sediments 2) search for evidence of organics, and 3) evaluate microbial habitability in the BP, Vera Rubin Ridge (VRR), and GT sedimentary rock.

Sutter, Brad↗