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At least 415 records · Page 23

Thermal Balance of a Manned Space Station

In order for any analysis to yield reasonable results when applied to a realistic configuration, it must account for convective, conductive, and radiative heat transfer through and within the vehicle, and, unless the vehicle surface is wholly convex, for the complex interchange of radiation between external surfaces. The following is a comprehensive view of the entire heat balance problem, including internal and external radiation, conduction, and internal convection heat transfer. In addition, a specific method of temperature control, particularly suited to manned space stations is suggested. The method makes use of the "atmosphere" within the space station as a major factor in the process of heat distribution. The vehicle air is circulated between the living quarters and an area containing the bulk of the heat generating equipment. By regulating the flow rate, temperature changes in the living quarters are minimized at the expense of increased fluctuation of the equipment are temperature. This technique has been applied to a manned orbital space station (MOSS) configuration, suggested by NASA's Langley Research Center. The feasibility of this approach has been demonstrated in terms of required and available flow rates, and the range of allowable equipment temperatures.

Environmental control↗

Asteroid Impacts, Microbes, and the Cooling of the Atmosphere

Earth's surface temperature constrained microbial evolution, according to Schwartzman et al. (1993). Their hypothesis states that the maximal temperature that extant organisms of a given type tolerate is the surface temperature occurring when that type of organism arose. Schwartzman and his colleagues concluded that the temperature changed from 100 C to 50 C between 3.75 billion years ago (BYA) and 1 BYA. These temperatures are consistent with those derived from oxygen isotope ratios in ancient sediments (Karhu and Epstein 1986, Knauth and Lowe 1978). The 100 C surface temperature they derive for 3.75 BYA is also the same as Earth's surface temperature 4.4 BYA (Kosting and Ackerman 1986). In this article, we address the cause of the delay in surface cooling until 3.75 BYA, and we explore the implications for microbial evolution of a high temperature on early Earth. We propose that three effects of the early heavy bombardment of Earth by asteroids and comets, until 3.8 BYA, could have delayed onset of surface cooling.

Oberbeck, Verne R.↗

The Effect of Climate Change on Ozone Depletion through Changes in Stratospheric Water Vapour

Several studies have predicted substantial increases in Arctic ozone depletion due to the stratospheric cooling induced by increasing atmospheric CO2 concentrations. But climate change may additionally influence Arctic ozone depletion through changes in the water vapor cycle. Here we investigate this possibility by combining predictions of tropical tropopause temperatures from a general circulation model with results from a one-dimensional radiative convective model, recent progress in understanding the stratospheric water vapor budget, modelling of heterogeneous reaction rates and the results of a general circulation model on the radiative effect of increased water vapor. Whereas most of the stratosphere will cool as greenhouse-gas concentrations increase, the tropical tropopause may become warmer, resulting in an increase of the mean saturation mixing ratio of water vapor and hence an increased transport of water vapor from the troposphere to the stratosphere. Stratospheric water vapor concentration in the polar regions determines both the critical temperature below which heterogeneous reactions on cold aerosols become important (the mechanism driving enhanced ozone depletion) and the temperature of the Arctic vortex itself. Our results indicate that ozone loss in the later winter and spring Arctic vortex depends critically on water vapor variations which are forced by sea surface temperature changes in the tropics. This potentially important effect has not been taken into account in previous scenarios of Arctic ozone loss under climate change conditions.

Kirk-Davidoff, Daniel B.↗

Thermal properties of Rhea's Poles: Evidence for a Meter-Deep Unconsolidated Subsurface Layer

Cassini's Composite Infrared Spectrometer (CIRS) observed both of Rhea's polar regions during a close (2000 km) flyby on 9th March 2013 during orbit 183. Rhea's southern pole was again observed during a more distant (51,000 km) flyby on 10th February 2015 during orbit 212. The results show Rhea's southern winter pole is one of the coldest places directly observed in our Solar System: surface temperatures of 25.4 +/-7.4 K and 24.7 +/-6.8 K are inferred from orbit 183 and 212 data, respectively. The surface temperature of the northern summer pole inferred from orbit 183 data is warmer: 66.6 +/-0.6 K. Assuming the surface thermophysical properties of the two polar regions are comparable then these temperatures can be considered a summer and winter seasonal temperature constraint for the polar region. Orbit 183 will provide solar longitude ( LS ) coverage at 133 deg and 313 deg for the summer and winter poles respectively, while orbit 212 provides an additional winter temperature constraint at LS 337 deg. Seasonal models with bolometric albedo values between 0.70 and 0.74 and thermal inertia values between 1 and 46 J m( exp −2) K( exp −1) s (exp −1/2) (otherwise known as MKS units) can provide adequate fits to these temperature constraints (assuming the winter temperature is an upper limit). Both these albedo and thermal inertia values agree within the uncertainties with those previously observed on both Rhea's leading and trailing hemispheres. Investigating the seasonal temperature change of Rhea's surface is particularly important, as the seasonal wave is sensitive to deeper surface temperatures ( approximately tens of centimeters to meter depths) than the more commonly reported diurnal wave (typically less than a centimeter), the exact depth difference dependent upon the assumed surface properties. For example, if a surface porosity of 0.5 and thermal inertia of 25 MKS is assumed then the depth of the seasonal thermal wave is 76 cm, which is much deeper than the approximately 0.5 cm probed by diurnal studies of Rhea ( Howett et al., 2010 ). The low thermal inertia derived here implies that Rhea's polar surfaces are highly porous even at great depths. Analysis of a CIRS focal plane 1 (10-600 cm(exp −1 ) stare observation, taken during the orbit 183 encounter between 16:22:33 and 16:23:26 UT centered on 71.7 deg W, 58.7 deg S provides the first analysis of a thermal emissivity spectrum on Rhea. The results show a flat emissivity spectrum with negligible emissivity features. A few possible explanations exist for this flat emissivity spectrum, but the most likely for Rhea is that the surface is both highly porous and composed of small particles ( less than approximately 50 micrometers).

Howett, C. J. A.↗

The doubled CO2 climate and the sensitivity of the modeled hydrologic cycle

Four doubled CO2 experiments with the GISS general circulation model are compared to investigate the consistency of changes in water availability over the United States. The experiments compare the influence of model sensitivity, model resolution, and the sea-surface temperature gradient. The results show that the general mid-latitude drying over land is dependent upon the degree of mid-latitude eddy energy decrease, and thus the degree of high-latitude temperature change amplification. There is a general tendency in the experiments for the northern and western United States to become wetter, while the southern and eastern portions dry. However, there is much variability from run to run, with different regions showing different degrees of sensitivity to the parameters tested. The results for the western United States depend most on model resolution; those for the central United States, on the sea-surface temperature gradient and the degree of mid-latitude ocean warming; and those for the eastern United States, on model sensitivity. The changes in particular seasons depend on changes in other seasons, and will therefore be sensitive to the realism of the ground hydrology parameterization.

Rind, D.↗

On the semiannual change in exospheric temperature.

Discussion of some uncertainties about the semiannual density variations of the neutral atmosphere at heights above 100 km ascribed by Jacchia (1965), on the basis of long observations of the decay of satellite orbits, to changes in exosphere temperature, but later, because of some difficulties, attributed by Jacchia (1971) to semiannual density variations that may not be produced primarily by changes in temperature. Temperature values derived from ionosphere electron content data recorded since 1965 at several sites in New Zealand using the Faraday rotation of geostationary satellite signals and from their comparison with ionosonde measurements are shown to suggest that the semiannual variations represent primarily changes in temperature and only secondarily in density.

Titheridge, J. E.↗

Thermal stresses in thick laminated composite shells

The paper provides an analytical formulation to investigate the thermomechanical behavior of thick composite shells subjected to a temperature distribution which varies arbitrarily in the radial direction. For illustrative purposes, shells under uniform temperature change are presented. It is found that thermal twist would occur even for symmetric laminated shells. Under uniform temperature rise, results for off-axis graphite/epoxy shells show that extensional-shear coupling can cause tensile radial stress throughout the shell and tensile hoop stress in the inner region. Laminated graphite/epoxy shells can exhibit negative effective thermal expansion coefficients in the longitudinal and transverse directions. Finally, the stacking sequence has a strong influence on the thermal stress distributions.

Yuan, F. G.↗

Residual thermal stresses in composites for dimensionally stable spacecraft applications

An overview of NASA LaRC's research on thermal residual stresses and their effect on the dimensional stability of carbon fiber reinforced polymer-matrix composites is presented. The data show that thermal residual stresses can induce damage in polymer matrix composites and significantly affect the dimensional stability of these composites by causing permanent residual strains and changes in CTE. The magnitude of these stresses is primarily controlled by the laminate configuration and the applied temperature change. The damage caused by thermal residual stresses initiates at the fiber/matrix interface and micromechanics level analyses are needed to accurately predict it. An increased understanding of fiber/matrix interface interactions appears to be the best approach for improving a composite's resistance to thermally induced damage.

Bowles, David E.↗

Trends in Antarctic Surface Temperatures and Ice Extent from Satellite and Surface Observations

Surface air temperatures observed from stations around Antarctica have indicated predominantly positive trends which are as high as 0.4K per decade along the Antarctic Peninsula. Since the average air temperature during summer in the West Antarctic region is about -6 K, and since most of the stations are near coastal regions, it is important to know whether such trends are due to a local or large scale phenomenon. We analyzed about 19 years of infrared satellite data (1979-1997) to obtain a spatially detailed study of the variability of surface temperatures over the entire Antarctic region. We also analyzed potential impact of temperature changes over the sea ice cover using co-registered and nearly coincident microwave satellite data. The surface temperatures inferred from infrared data are shown to agree well with those observed from the limited number of Antarctic station data with a correlation coefficient of 0.98 and a standard deviation of less than 3K. The 19-year temperature data set shows positive trends of 0.12, 0.68, and 0.41 C per decade in ocean, sea ice and ice sheet surfaces, respectively. The sensitivity of the trend to record length was studied, using long term station data sets, and the results show that the trends start to stabilize at around 2 decades which is about the record length of satellite data. However, interannual fluctuations of the temperatures are large, especially in the ice sheets, and the 95% confidence level for the trends ranges from 0.12 to 1.22 for sea ice and from -0.74 to 1.55 C per decade for the ice sheet. In the sea ice regions, the position of the ice edge in winter with respect to the northernmost position of sea ice during the study period is also shown to be influenced by alternating warm and cold anomalies around the continent. This pattern is similar to that suggested by the presence of the Antarctic Circumpolar Wave (ACW) but the wavenumber appears to be predominantly mode 3 (instead of reported mode 2) for the Antarctic region. Unexpectedly, trends in the sea ice extent are found to be positive in most Antarctic sectors during the same period with the exception of the Bellingshausen and Amundsen Seas region.

Comisc, J. C.↗

Grace Under Pressure

Developed in response to a NASA requirement to remotely measure tension in critical bolts on the International Space Station, the SureBolt(TM) Correlation Bolt Gage is the first ultrasonic system to capture an entire "echo" pulse for determining the change in time of flight of an ultrasonic signal traversing a fastener for tension measurement. The standard SureBolt system hardware has the capability of recording over 1 million bolt tension readings-with their complete waveforms-in Microsoft Excel-compatible format. The user- friendly Tension-Not-Torque(Copyright) software interface offers tension change graphing in real time, and a place to store field notes, special parameters, tension calibration constants, and temperature changes for each measurement. The technology has been used on fasteners as small as fine-threaded, 1-inch bolts, and as large as 18-inch-diameter by 30-foot-long tie rods. SureBolt is finding increased application within NASA and the aerospace industry, as well as in the automotive and nuclear industries.

Source record↗

Implications for Climate Sensitivity from the Response to Individual Forcings

Climate sensitivity to doubled CO2 is a widely-used metric of the large-scale response to external forcing. Climate models predict a wide range for two commonly used definitions: the transient climate response (TCR: the warming after 70 years of CO2 concentrations that riseat 1 per year), and the equilibrium climate sensitivity (ECS: the equilibrium temperature change following a doubling of CO2 concentrations). Many observational datasets have been used to constrain these values, including temperature trends over the recent past 16, inferences from paleo-climate and process-based constraints from the modern satellite eras. However, as the IPCC recently reported different classes of observational constraints produce somewhat incongruent ranges. Here we show that climate sensitivity estimates derived from recent observations must account for the efficacy of each forcing active during the historical period. When we use single forcing experiments to estimate these efficacies and calculate climate sensitivity from the observed twentieth-century warming, our estimates of both TCR and ECS are revised upward compared to previous studies, improving the consistency with independent constraints.

Sensitivity↗

Correlation of hippocampal theta rhythm with changes in cutaneous temperature

Investigation of the possibility that the hippocampus performs the function of alerting an animal to changes in cutaneous temperature, using unanesthetized, loosely restrained rabbits. The results indicate that the hippocampal theta rhythm, which appears to be evoked by changes in cutaneous temperature, can be related to a specific type of hyppocampal neuron which is, in turn, connected with other areas of the brain involved in temperature regulation.

Horowitz, J. M.↗

Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics

The physical properties (dielectric, ferroelectric, piezoelectric, etc.) of complex perovskite ferroelectrics depend on the degree of order/disorder and the scale of the ordered domains. In this study, the electrocaloric (EC) properties of three representative complex perovskite ferroelectrics, Pb(Mg 1/3 Nb 2/3 )O 3 -8PbTiO 3 (PMN-8PT), 1mol% Sm-doped Pb(Mg 1/3 Nb 2/3 )O 3 -8PbTiO 3 (1S-PMN-8PT) and Pb(Sc 1/2 Ta 1/2 )O 3 (PST) are evaluated. Multi-layer ceramic capacitors (MLCCs) with identical structural configurations were fabricated for these three compounds, and their EC properties were characterized by direct measurement using a thermocouple. The EC temperature change of PMN-8PT, 1S-PMN-8PT and PST MLCCs under 20 V μm –1 at room temperature were found to be 1.42 K, 1.54 K, and 3.10 K, respectively. X-ray diffraction and high-resolution transmission electron microscopy data suggests that the high EC performance of PST is related to the ordering of B-site cations (Sc 3+ and Ta 5+ ) with the ordering parameter S = 0.82 and a long coherence length of ~100 nm, such that the sample transitioned from a relaxor ferroelectric to a normal ferroelectric. Furthermore, these results provide pathway towards design of high performance EC materials required for solid state refrigeration and air-conditioning technologies.

36 MATERIALS SCIENCE↗

Structure, Dynamics, and Hydrogen Transport in Amorphous Polymers: An Analysis of the Interplay between Free Volume Element Distribution and Local Segmental Dynamics from Molecular Dynamics Simulations

Polymers are attractive membrane materials owing to their mechanical robustness and relatively inexpensive fabrication. An important indicator of membrane performance are free volume elements (FVE): microporous void spaces created by the inefficient packing of bulky groups along the polymer chain. FVEs tend to degrade over time, as polymer chains reorganize irreversibly. While it is widely accepted that polymer flexibility has an impact on membrane transport properties, the molecular nature of this impact is still not well understood. By the establishment of a correlation between local chain dynamics and the distribution of free volume elements (FVEs), penetrant transport can be regulated more efficiently in amorphous polymer membranes. In this work, we implement all-atom molecular dynamics (MD) simulations to explore the relationship between chain dynamics and free volume in three polymers with different levels of backbone flexibility: polymethylpentene (PMP), polystyrene (PS), and HAB-6FDA thermally rearranged polymer (TRP). We construct these polymers at different temperatures and examine how temperature impacts the FVE distribution and segmental mobility. Our analysis shows that chain segments near FVEs have higher mobility compared with the atoms in the bulk; the extent of this difference increases with chain flexibility. Increasing the chain flexibility by increasing the temperature results in a broader FVE distribution. Rigid polymers such as TRP show the most robust FVE distribution and are not significantly affected by the temperature change. To capture penetrant diffusion through the polymer matrix, hydrogen is inserted and the diffusion is measured at different temperatures; hydrogen mobility is influenced by the FVE structure and overall mobility of polymer chains. Lastly, at low temperatures, hydrogen mobility is influenced by void distribution, while at high temperatures, polymer dynamics dictate hydrogen transport.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Elastocaloric signatures of symmetric and antisymmetric strain-tuning of quadrupolar and magnetic phases in DyB 2 C 2

The adiabatic elastocaloric effect measures the temperature change of a given system with strain and provides a thermodynamic probe of the entropic landscape in the temperature-strain space. Here, we demonstrate that the DC bias strain-dependence of AC elastocaloric effect allows decomposition of the latter into symmetric (rotation-symmetry-preserving) and antisymmetric (rotation-symmetry-breaking) strain channels, using a tetragonal f -electron intermetallic DyB 2 C 2 —whose antiferroquadrupolar order breaks local fourfold rotational symmetries while globally remaining tetragonal—as a showcase example. We capture the strain evolution of its quadrupolar and magnetic phase transitions using both singularities in the elastocaloric coefficient and its jumps at the transitions, and the latter we show follows a modified Ehrenfest relation. We find that antisymmetric strain couples to the underlying order parameter in a biquadratic (linear-quadratic) manner in the antiferroquadrupolar (canted antiferromagnetic) phase, which are attributed to a preserved (broken) global tetragonal symmetry, respectively. The broken tetragonal symmetry in the magnetic phase is further evidenced by elastocaloric strain-hysteresis and optical birefringence. Additionally, within the staggered quadrupolar order, the observed elastocaloric response reflects a quadratic increase of entropy with antisymmetric strain, analogous to the role magnetic field plays for Ising antiferromagnetic orders by promoting pseudospin flips. Our results demonstrate AC elastocaloric effect as a compact and incisive thermodynamic probe into the coupling between electronic degrees of freedom and strain in free energy, which holds the potential for investigating and understanding the symmetry of a wide variety of ordered phases in broader classes of quantum materials.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Kinetic Properties of Microbial Exoenzymes Vary With Soil Depth but Have Similar Temperature Sensitivities Through the Soil Profile

Current knowledge of the mechanisms driving soil organic matter (SOM) turnover and responses to warming is mainly limited to surface soils, although over 50% of global soil carbon is contained in subsoils. Deep soils have different physicochemical properties, nutrient inputs, and microbiomes, which may harbor distinct functional traits and lead to different SOM dynamics and temperature responses. We hypothesized that kinetic and thermal properties of soil exoenzymes, which mediate SOM depolymerization, vary with soil depth, reflecting microbial adaptation to distinct substrate and temperature regimes. We determined the Michaelis-Menten (MM) kinetics of three ubiquitous enzymes involved in carbon (C), nitrogen (N) and phosphorus (P) acquisition at six soil depths down to 90 cm at a temperate forest, and their temperature sensitivity based on Arrhenius/ Q 10 and Macromolecular Rate Theory (MMRT) models over six temperatures between 4–50°C. Maximal enzyme velocity ( V max ) decreased strongly with depth for all enzymes, both on a dry soil mass and a microbial biomass C basis, whereas their affinities increased, indicating adaptation to lower substrate availability. Surprisingly, microbial biomass-specific catalytic efficiencies also decreased with depth, except for the P-acquiring enzyme, indicating distinct nutrient demands at depth relative to microbial abundance. These results suggested that deep soil microbiomes encode enzymes with intrinsically lower turnover and/or produce less enzymes per cell, reflecting distinct life strategies. The relative kinetics between different enzymes also varied with depth, suggesting an increase in relative P demand with depth, or that phosphatases may be involved in C acquisition. V max and catalytic efficiency increased consistently with temperature for all enzymes, leading to overall higher SOM-decomposition potential, but enzyme temperature sensitivity was similar at all depths and between enzymes, based on both Arrhenius/ Q 10 and MMRT models. In a few cases, however, temperature affected differently the kinetic properties of distinct enzymes at discrete depths, suggesting that it may alter the relative depolymerization of different compounds. We show that soil exoenzyme kinetics may reflect intrinsic traits of microbiomes adapted to distinct soil depths, although their temperature sensitivity is remarkably uniform. These results improve our understanding of critical mechanisms underlying SOM dynamics and responses to changing temperatures through the soil profile.

59 BASIC BIOLOGICAL SCIENCES↗

Thin-film temperature sensor

Sensor measures rapid temperature changes in fluid streams. Sensor withstands contacts with various corrosive fluids, high fluid-flow rates, and turbulences caused by rapid changes in flow rates. Capacitor is part of resonant bridge circuit which produces ac voltage that is proportional to temperature.

Maserjian, J.↗

Role of a decrease in body heat content in the thermoregulatory reaction of the concha auriculae vessels

At the constant ambient temperature 28-30 C the rabbit ear vessels were dilated and their temperature was 34.8/0.1 C. Administration of the 23-29 C water into the stomach entailed thermoregulatory construction of the ear vessels within 15-25 min. The response occurred at various combinations of temperature changes in different parts of the body. The heat content of the rabbit body, as calculated by the blood temperature in the aorta arc, reduced by 266.3 + or - 26.2 cal/kg at the beginning of the response. The decrease in the organism heat content seems to serve as a signal for occurrence of a corresponding thermoregulatory response.

Slepchuk, N. A.↗