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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

In Situ Measurements of Ammonia In Plumes Emitted From Wildfires And Agricultural Fires in the US

Emissions of trace gases and particles from fires have a major impact on climate, visibility, air quality, and public health. Biomass burning emissions include reactive nitrogen gases, among which ammonia (NH3) plays a prominent role. NH3 is a short-lived gas that acts as precursor for secondary inorganic aerosols. This process is still poorly constrained in downwind fire plumes. In summer 2019, NASA and NOAA carried out the joint airborne FIREX-AQ (Fire Influence on Regional to global Environments and Air Quality) mission over the continental US to sample plumes from wildfires and agricultural fires. On board the NASA DC-8, we used a modified PTR-ToF-MS instrument for measuring NH3 in situ and at high time resolution. Over the course of the mission, we collected a large set of NH3 data in plumes emitted from fires differing in fuel type and burning stage. Herein, we will present the measured NH3 emissions ratios and factors, compare them with the literature, and investigate the dependence of NH3 emissions on fuel type and burning conditions.

ammonia↗
DOE OSTI2025

The 22 Ne(α,n) 25 Mg reaction - state of the art, astrophysics, and perspectives

One of the most important stellar neutron sources is the 22 Ne(α,n) 25 Mg reaction, which gets activated both during the helium intershell burning in asymptotic giant branch stars and in core helium and shell carbon burning in massive stars. The 22 Ne(α,n) 25 Mg reaction serves as the main neutron producer for the weak s-process and provides a short but strong neutron exposure during the helium flash phase of the main s-process, significantly affecting the abundances at the s-process branch points. The cross section needs to be known at very low energies, as close as possible to the neutron threshold at E α = 562 keV (Q = −478 keV), but both direct and indirect measurements have turned out to be very challenging, leading to significant uncertainties. Here we discuss the current status of the reaction, including recent and upcoming measurements, and provide a discussion on the astrophysical implications as well as an outlook into the near future.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1990

Past experience Skylab mission

The design of the Skylab missions, 1973 to 1974, was intended to exclude any direct handling of hazardous, toxic, or reactive materials. The materials processing facility and multipurpose furnace provided a contained environment for conducting metals melting, brazing, sphere forming, and crystal growth experiments. At the end of the third mission, following the completion of all other experiments, the materials processing facility was used for a series of flammability experiments. The flammability tests were done last because of the contamination expected from the burning of the materials within the facility. The flammability tests demonstrated a number of peculiar effects that have implications for future design (fire detection, location, and suppression/control). Although the results of the flammability tests contain lessons appropriate to planning, a number of events during the flight illustrate situations or conditions that pose considerations beyond the commonly accepted range of concern for safety-related matters. This presentation includes a discussion of: Skylab flammability studies and the implications for fire suppression/control; false fire alarms and the Skylab fire detection system; space environmental effects on materials that are normally benign; spills/release of contaminants; the detrimental effect that the release of non-hazardous materials have on detection systems; and the problem of locating sources/originating point of hazards.

Pogue, William↗
NASA NTRS2000

Active Combustion Control for Aircraft Gas Turbine Engines

Lean-burning combustors are susceptible to combustion instabilities. Additionally, due to non-uniformities in the fuel-air mixing and in the combustion process, there typically exist hot areas in the combustor exit plane. These hot areas limit the operating temperature at the turbine inlet and thus constrain performance and efficiency. Finally, it is necessary to optimize the fuel-air ratio and flame temperature throughout the combustor to minimize the production of pollutants. In recent years, there has been considerable activity addressing Active Combustion Control. NASA Glenn Research Center's Active Combustion Control Technology effort aims to demonstrate active control in a realistic environment relevant to aircraft engines. Analysis and experiments are tied to aircraft gas turbine combustors. Considerable progress has been shown in demonstrating technologies for Combustion Instability Control, Pattern Factor Control, and Emissions Minimizing Control. Future plans are to advance the maturity of active combustion control technology to eventual demonstration in an engine environment.

DeLaat, John C.↗
NASA NTRS2008

Electronic Escape Trails for Firefighters

A proposed wireless-communication and data-processing system would exploit recent advances in radio-frequency identification devices (RFIDs) and software to establish information lifelines between firefighters in a burning building and a fire chief at a control station near but outside the building. The system would enable identification of trails that firefighters and others could follow to escape from the building, including identification of new trails should previously established trails become blocked. The system would include a transceiver unit and a computer at the control station, portable transceiver units carried by the firefighters in the building, and RFID tags that the firefighters would place at multiple locations as they move into and through the building (see figure). Each RFID tag, having a size of the order of a few centimeters, would include at least standard RFID circuitry and possibly sensors for measuring such other relevant environmental parameters as temperature, levels of light and sound, concentration of oxygen, concentrations of hazardous chemicals in smoke, and/or levels of nuclear radiation. The RFID tags would be activated and interrogated by the firefighters and control-station transceivers. Preferably, RFID tags would be configured to communicate with each other and with the firefighters units and the control station in an ordered sequence, with built-in redundancy. In a typical scenario, as firefighters moved through a building, they would scatter many RFID tags into smoke-obscured areas by use of a compressed-air gun. Alternatively or in addition, they would mark escape trails by dropping RFID tags at such points of interest as mantraps, hot spots, and trail waypoints. The RFID tags could be of different types, operating at different frequencies to identify their functions, and possibly responding by emitting audible beeps when activated by signals transmitted by transceiver units carried by nearby firefighters.

Jorgensen, Charles↗
NASA NTRS2012

Multi-Objective Optimization of a Turbofan for an Advanced, Single-Aisle Transport

Considerable interest surrounds the design of the next generation of single-aisle commercial transports in the Boeing 737 and Airbus A320 class. Aircraft designers will depend on advanced, next-generation turbofan engines to power these airplanes. The focus of this study is to apply single- and multi-objective optimization algorithms to the conceptual design of ultrahigh bypass turbofan engines for this class of aircraft, using NASA s Subsonic Fixed Wing Project metrics as multidisciplinary objectives for optimization. The independent design variables investigated include three continuous variables: sea level static thrust, wing reference area, and aerodynamic design point fan pressure ratio, and four discrete variables: overall pressure ratio, fan drive system architecture (i.e., direct- or gear-driven), bypass nozzle architecture (i.e., fixed- or variable geometry), and the high- and low-pressure compressor work split. Ramp weight, fuel burn, noise, and emissions are the parameters treated as dependent objective functions. These optimized solutions provide insight to the ultrahigh bypass engine design process and provide information to NASA program management to help guide its technology development efforts.

Berton, Jeffrey J.↗
DOE OSTI2025

THz Radiation Generation to Enable Internal Magnetic Field Measurement of Burning Plasmas (Final Scientific Report)

A one-year experimental program was performed using the Multi-TeraWatt (MTW) laser at the Laboratory for Laser Energetics (LLE) to investigate the efficiency and physical process of laser-driven—wire THz generation. This process was evaluated as a potential high-repetition-rate source of powerful THz pulses for use in THz pulsed polarimetry of a moderate-density magnetic-confinement fusion concept developed by TAE. The goal was to develop a source for short pulses in the THz regime (150 μm wavelength) containing 10’s of mJ. The campaign tested the impact of Cu wire diameter (25, 75, 160 μm), length (250 – 750 μm), and laser irradiation orientation on THz production efficiency in comparison to 20-μm thick Cu foils. Of these targets, the 160 µm diameter, 750 µm long wires with sharpened tips and irradiated at the base were found to produce the highest energy and shortest wavelength THz pulses, exceeding 2.5 Joule/sr and meeting the requirements for the polarimetry diagnostic. The brightest THz signal was radiated in the direction of the sharpened wire tip. A combination of two models – a traveling wave antenna combined with coherent transition radiation – describes the emission pattern, pulse energy, and spectrum observed in the experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1999

Dynamics of Droplet Extinction in Slow Convective Flows

The classical model for droplet combustion predicts that the square of the droplet diameter decreases linearly with time. It also predicts that a droplet of any size will burn to completion over a period of time. However, it has been known for some time that under certain conditions flames surrounding a droplet, in a quiescent environment, could extinguish because of insufficient residence time for the chemistry to proceed to completion. This type of extinction that occurs for smaller droplets has been studied extensively in the past. Large droplets, on the other hand, exhibit a different type of extinction where excessive radiative heat loss from the flame zone leads to extinction. This mode of "radiative extinction" was theoretically predicted for droplet burning by Chao et al. and was observed in recent space experiments in a quiescent environment. Thus far, the fundamental flammability limit prescribed by radiative extinction of liquid droplets has been measured only under quiescent environmental conditions. In many space platforms, however, ventilation systems produce small convective flows and understanding of the influences of this convection on the extinction process will help better define the radiative extinction flammability boundaries. Boundaries defined by experiments and captured using theoretical models could provide enhanced fire safety margin in space explor1999063d investigation of convective effects will help in interpretations of burning-rate data obtained during free-floated droplet combustion experiments with small residual velocities.

Nayagam, V.↗
NASA NTRS2007

Iron Mineralogy and Aqueous Alteration on Mars from the MER Moessbauer Spectrometers

The twin Mars Exploration Rovers Spirit (Gusev crater) and Opportunity (Meridiani Planum) used MIMOS II Moessbauer spectrometers to analyze martian surface materials in the first application of extraterrestrial Moessbauer spectroscopy. The instruments acquired spectra that identified the speciation of Fe according to oxidation state, coordination state, and mineralogical composition and provided quantitative information about the distribution of Fe among oxidation states, coordination states, and Fe-bearing phases. A total of 12 unique Fe-bearing phases were identified: Fe(2+) in olivine, pyroxene, and ilmenite; Fe(2+) and Fe(3+) in magnetite and chromite; Fe(3+) in nanophase ferric oxide (npOx), hematite, goethite, jarosite, an unassigned Fe3+ sulfate, and an unassigned Fe(3+) phase associated with jarosite; and Fe(0) in kamacite. Weakly altered basalts at Gusev crater (SO3 = 2.5 +/- 1.4 wt.% and Fe(3+)/Fe(sub T) = 0.24 +/- 0.11) are widespread on the Gusev plains and occur in less abundance on West Spur and Husband Hill in the Columbia Hills. Altered low-S rocks (SO3 = 5.2 +/- 2.0 wt.% and Fe(3+)/Fe(sub T) = 0.63 +/- 0.18) are the most common type of rock in the Columbia Hills. Ilm-bearing, weakly altered basalts were detected only in the Columbia Hills, as was the only occurrence of chromite in an altered low-S rock named Assemblee. Altered high-S rocks (SO3 > 14.2 wt.% and Fe(3+)/Fe(sub T) = 0.83 +/- 0.05) are the outcrop rocks of the ubiquitous Burns formation at Meridiani Planum. Two Fe(0)-bearing rocks at Meridiani Planum (Barberton and Heat Shield Rock) are meteorites. Laguna Class soil is weakly altered (SO3 = 6 +/- 2 wt.% and Fe(3+)/Fe(sub T) = 0.29 +/- 0.08) and widely distributed at both Gusev crater and Meridiani Planum, implying efficient global mixing processes or a global distribution of precursor rocks with comparable Fe mineralogical compositions. Paso Robles Class soil is heavily altered (SO3 approx. 31 wt.% and Fe(3+)/Fe(sub T) = 0.83 +/- 0.05), is relatively uncommon, and occurs as subsurface deposits in the Columbia Hills. Berry Class soil is also heavily altered (SO3 = 5 +/- 1 wt.% and Fe(3+)/Fe(sub T) = 0.60 +/- 0.13) and occurs at Meridiani Planum as lag deposits, at the crests of aeolian bedforms, and as isolated pockets on outcrop surfaces. Magnetite is identified as the strongly magnetic component in martian soil. Jarosite (in the Burns outcrop at Meridiani Planum) and goethite (in Clovis Class rocks at Gusev crater) are mineralogical markers for aqueous processes because they contain the hydroxide anion (OH(-)) as an essential part of their structure. Each yields approx.10 wt.% H2O upon dehydroxylation. The presence of Fe sulfates on opposite sides of Mars is evidence that aqueous processes under acid sulfate conditions are or were common. Except for Independence Class rocks in the Columbia Hills, the overall Fe mineralogical compositions and similar basaltic bulk chemical compositions (calculated with respect to S = Cl = 0) of the population of altered rocks analyzed by MER imply isochemical alteration of basaltic precursors at low water-to-rock ratios.

Morris, Richard V.↗
DOE OSTI2025

The 22Ne($$\alpha $$,n)25Mg reaction - state of the art, astrophysics, and perspectives

Abstract One of the most important stellar neutron sources is the 22 Ne( $$\alpha ,n$$ α , n ) 25 Mg reaction, which gets activated both during the helium intershell burning in asymptotic giant branch stars and in core helium and shell carbon burning in massive stars. The 22 Ne( $$\alpha ,n$$ α , n ) 25 Mg reaction serves as the main neutron producer for the weak s -process and provides a short but strong neutron exposure during the helium flash phase of the main s -process, significantly affecting the abundances at the s -process branch points. The cross section needs to be known at very low energies, as close as possible to the neutron threshold at $$E_\alpha =$$ E α = 562 keV ( Q = −478 keV), but both direct and indirect measurements have turned out to be very challenging, leading to significant uncertainties. Here we discuss the current status of the reaction, including recent and upcoming measurements, and provide a discussion on the astrophysical implications as well as an outlook into the near future.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Enabling Production of Low Carbon Emissions Steel through CO 2 Capture from Blast Furnace Gases at Cleveland Cliffs’ 5 mtpa Steel Plant at Burns Harbor, Indiana

Dastur International Inc. has prepared a DOE-funded Pre-front-end engineering design (Pre-FEED) study to capture up to 2.8 mtpa of CO 2 from the available Blast Furnace (BF) gases at the Burns Harbor steel plant operated by Cleveland Cliffs in Burns Harbor, Indiana. The project consists of an amine solvent based pre-combustion carbon capture system, along with a unique BF gas conditioning process which significantly optimizes the project design and architecture in terms of higher volumes (2.8 mtpa vis-à-vis 1.6 mtpa without conditioning) & concentration (32 vol% in conditioned gas vs. 22% in raw BF gas) of CO 2 , which can be captured using a single train, resulting in reduced size and capital cost of the CO 2 capture island, and improved overall economics on a $\$$/tCO 2 captured basis.

42 ENGINEERING↗
NASA NTRS1986

Gated photochemical hole burning in photoadducts of polyacenes

A photoadduct of anthracene and tetracene (A-T) in a polymer matrix at 1.5 K generates an absorption spectrum which exhibits two-color, photon-gated photochemical hole burning (PHB) when irradiated with narrowband exciting light into the 0-0 band of the S1-S0 absorption. The efficiency of this PHB process is found to be enhanced by simultaneous irradiation near the maximum of the Tn-T1 absorption of A-T; hole widths of less than 0.07/cm have been observed for this photochemical cleavage of A-T.

Iannone, Mark↗
NASA NTRS1994

Summertime tropospheric ozone distributions over central and eastern Canada

Ozone measurements were obtained between the surface and the 6-km altitude on aircraft flights over central and eastern Canada during the summer 1990 NASA Global Tropospheric Experiment Arctic Boundary Layer Expedition (GTE/ABLE 3B). Tropospheric O3 budgets for these regions were observed to be highly variable and significantly impacted by long-range transport and regional scale air mass modification processes. For example, integrated O3 abundance below 5-km altitude averaged 40% and 30% greater in air masses influenced by anthropogenic sources and biomass burning, respectively, than in background (polar) air. Conversely, aged air transported from subtropical areas of the Pacific at times reduced O3 abundance in this height interval by up to 20%. Though intrusion of anthropogenic air was infrequent during the experiment period, the influence of biomass-burning emissions was particularly notable as two thirds of the flights sampled air influenced by plumes from fires burning in Alaska and western Canada. The impinging pollution, both natural and anthropogenic, not only elevated O3 levels directly but also was a source of reactive nitrogen (and nonmethane hydrocarbons) which generally increases the tropospheric lifetime of O3 via moderation of photochemical destruction rates.

Anderson, B. E.↗
NASA NTRS1995

Hybrid propulsion for launch vehicle boosters: A program status update

Results obtained in studying the origin and suppression of large-amplitude pressure oscillations in a 24 in. diameter hybrid motor using a liquid oxygen/hydroxylterminated polybutadiene/polycyclopentadiene propellant system are discussed. Tests conducted with liquid oxygen flow rates varying from 10 to 40 lbm/sec were designed to gauge the effectiveness of various vaporization chamber flow fields, injector designs, and levels of heat addition in suppressing high-frequency longitudinal mode oscillations. Longitudinal acoustic modes did not arise in any tests. However, initial testing revealed the presence of high-amplitude, sinusoidal, nonacoustic oscillations persisting throughout the burn durations. Analysis showed this to be analogous to chug mode instability in liquid rocket engines brought about by a coupling of motor combustion processes and the liquid oxygen feed system. Analytical models were developed and verified by test data to predict the amplitude and frequency of feed-system-coupled combustion pressure oscillations. Subsequent testing showed that increasing the feed system impedance eliminated the bulk mode instability. This paper documents the work completed to date in performance of the Hybrid Propulsion Technology for Launch Vehicle Boosters Program (NAS8-39942) sponsored by NASA's George C. Marshall Space Flight Center.

Carpenter, R. L.↗
NASA NTRS2004

Verification of RSRM Nozzle Thermal Models With ETM-3 Aft Exit Cone In-depth Temperature Measurements

One of the goals of the Engineering Test Motor (ETM-3) static test was to verify analytical models through the use of instrumentation that provide real-time transient temperature response of ablating phenolic liners. Accurate measurement of in-depth temperature is critical for validating the analytical models and assessing design safety margins for nozzle insulation materials. Recent developments of in-depth thermocouple plugs have been made to more accurately measure temperature response of nozzle Liners. Thermocouple plugs were installed at two axial stations (four plugs circumferentially at each station) near the end of the ETM-3 nozzle aft exit cone to gather temperature histories during and after motor operation. The thermocouple plugs were placed at depths that bounded the reusable solid rocket motor nominal measured char depth in order to portray the carbon phenolic temperature response during the charring process. The data were used to verify the analytical models during motor operation and to better define char penetration during heat soak after motor burn out.

Maw, Joel F.↗
NASA NTRS2008

An Overview of the NASA Spring/Summer 2008 Arctic Campaign - ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites)

ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) is a major NASA led airborne field campaign being performed in the spring and summer of 2008 at high latitudes (http://cloud1.arc.nasa.gov/arctas/). ARCTAS is a part of the International Polar Year program and its activities are closely coordinated with multiple U. S. (NOAA, DOE), Canadian, and European partners. Observational data from an ensemble of aircraft, surface, and satellite sensors are closely integrated with models of atmospheric chemistry and transport in this experiment. Principal NASA airborne platforms include a DC-8 for detailed atmospheric composition studies, a P-3 that focuses on aerosols and radiation, and a B-200 that is dedicated to remote sensing of aerosols. Satellite validation is a central activity in all these platforms and is mainly focused on CALIPSO, Aura, and Aqua satellites. Major ARCTAS themes are: (1) Long-range transport of pollution to the Arctic including arctic haze, tropospheric ozone, and persistent pollutants such as mercury; (2) Boreal forest fires and their implications for atmospheric composition and climate; (3) Aerosol radiative forcing from arctic haze, boreal fires, surface-deposited black carbon, and other perturbations; and (4) Chemical processes with focus on ozone, aerosols, mercury, and halogens. The spring deployment (April) is presently underway and is targeting plumes of anthropogenic and biomass burning pollution and dust from Asia and North America, arctic haze, stratosphere-troposphere exchange, and ozone photochemistry involving HOx and halogen radicals. The summer deployment (July) will target boreal forest fires and summertime photochemistry. The ARCTAS mission is providing a critical link to enhance the value of NASA satellite observations for Earth science. In this talk we will discuss the implementation of this campaign and some preliminary results.

Jacob, Daniel J.↗
NASA NTRS2009

Implementations of Sensor Webs Utilizing Uninhabited Aerial Systems

In this paper we describe the web services, processes, communication protocols and ad-hoc service chains utilized in the late summer and early fall 2007 Ikhana UAS response to the wildfires burning in southern California. Additionally, we describe the lessons learned that will be applied to the upcoming Global Hawk UAS Aura Satellite Validation Experiment planned for early 2009.

Sullivan, Donald V.↗
DOE OSTI2024

Impact of the Li 6 asymptotic normalization constant onto α -induced reactions of astrophysical interest

Indirect methods have become the predominant approach in experimental nuclear astrophysics for studying several low-energy nuclear reactions occurring in stars, as direct measurements of many of these relevant reactions are rendered infeasible due to their low reaction probability. Such indirect methods, however, require theoretical input that in turn can have significant poorly quantified uncertainties, which can then be propagated to the reaction rates and have a large effect on our quantitative understanding of stellar evolution and nucleosynthesis processes. Here we present two such examples involving α-induced reactions, 13 C (α,n)⁢ 16 O and 12 C (α,γ)⁢ 16 O, for which the low-energy cross sections have been constrained with ( 6 Li,d) transfer data. In this Letter, we discuss how a first-principle calculation of 6 Li leads to a 21% reduction of the 12 C⁡(α,γ) ⁢ 16 O cross sections with respect to a previous estimation. This calculation further resolves the discrepancy between recent measurements of the 13 C (α,n)⁢ 16 O reaction and points to the need for improved theoretical formulations of nuclear reactions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗