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At least 433 records · Page 24

Regional Geologic Cross Sections for Potential Storage and Containment Zones in the MRCSP Region

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO 2 ) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. Five geologic cross sections (labeled A through E) were constructed onshore across the parts of the MRCSP Region west of the Valley and Ridge Province, and one section (labeled F) was constructed beginning onshore in New Jersey and running eastward to offshore areas examined for carbon storage. Regional and local stratigraphic units were used in these cross sections to show current nomenclature as well as highlighting specific units/features pertinent to carbon capture, utilization and storage (CCUS) opportunities in the region. Each cross section uses 15 to 25 deep wells and other geologic information to illustrate the relative depth, thickness and location of rock units in the subsurface.

01 COAL, LIGNITE, AND PEAT↗

Techno-economic analysis of long-duration energy storage and flexible power generation technologies to support high-variable renewable energy grids

As variable renewable energy penetration increases beyond 80%, clean power systems will require long-duration energy storage or flexible, low-carbon generation. Here, we provide a detailed techno-economic evaluation and uncertainty analysis of applicable technologies and identify challenges and opportunities to support electric grid planning. We show that for a 120-h storage duration rating, hydrogen systems with geologic storage and natural gas with carbon capture are the least-cost low-carbon technologies for both current and future capital costs. These results are robust to uncertainty for the future capital cost scenario, but adiabatic compressed air and pumped thermal storage could be the least-cost technologies in the current capital cost scenario under uncertainty. Finally, we present a new storage system using heavy-duty vehicle fuel cells that could reduce the levelized cost of energy by 13%–20% compared with the best previously considered storage technology and, thus, could help enable very high (>80%) renewable energy grids.

25 ENERGY STORAGE↗

Onshore U.S. Carbon Pipeline Deployment: Siting, Safety, and Regulation

Carbon capture, utilization, and storage (CCUS) technology has significant potential to reduce greenhouse gas (GHG) emissions and mitigate the impact of climate change, particularly in hard to decarbonize industrial and commercial sectors. CCUS involves capturing carbon dioxide (CO 2 ) from industrial processes or power generation and utilizing it for other purposes, such as enhanced oil recovery (EOR), or storing the captured CO 2 underground. CCUS technology can reduce the environmental impact of continued fossil fuel use while smoothing the transition to a low-carbon economy. CCUS can create new economic opportunities, such as the development of new industries and job creation, and can enhance energy security by diversifying energy sources. For these reasons, enabling CCUS has become a key objective of the Biden-Harris administration’s clean energy policy and has received bipartisan support. Despite its environmental and economic potential, CCUS faces multiple barriers to widespread deployment. One of the main challenges is the high cost and technical difficulty of implementing and operating large-scale CCUS infrastructure. CCUS remains a relatively expensive way to reduce carbon emissions (e.g., compared to solar photovoltaic technology’s displacement of coal generation). Additionally, financial incentives and supportive policies like those enacted to support solar photovoltaic development, especially at the state level, are inconsistent or nonexistent, which can discourage investment in CCUS projects. There are also technical challenges associated with safe and secure underground CO 2 storage and the development of new carbon utilization technologies. Public opposition to various aspects of CCUS technologies, ranging from concerns that CCUS will extend reliance on fossil fuels to CCUS infrastructure being sited in disadvantaged communities, is a growing challenge. This paper focuses on another significant barrier to broad CCUS deployment: the need for considerable expansion of the dedicated land-based CO 2 pipeline network in the United States to meet CCUS goals and the unique regulatory challenges to its development. To reach carbon emissions targets in the United States by 2050, CCUS technology will need to be supported by tens of thousands of miles of CO 2 pipelines. Estimates range from a minimum of roughly 29,000 pipeline miles (according to a 2020 Great Plains Institute study) to 66,000 pipeline miles (as per a 2021 Princeton University–led study). As of October 2022, however, the U.S. Department of Transportation (U.S. DOT) reports fewer than 5,400 miles of U.S. pipelines carrying CO 2 . This deficit—and what it means for the prospect of moving substantially larger quantities of CO 2 from source to use or storage—threatens to stifle the development of CCUS projects and technologies identified as an important tool to meet emissions targets. The current regulatory landscape facing CO 2 pipeline development can best be described as uncertain. At the federal level, the U.S. DOT Pipeline and Hazardous Materials Safety Administration (PHMSA) oversees safety regulation of pipelines transporting hazardous materials, including CO 2 upon commencement of operation. However, PHMSA’s definition of CO 2 as “a fluid consisting of more than 90 percent CO 2 molecules compressed to a supercritical state” has not been updated since its 1991 addition to the Federal Register. Because CO 2 can be transported in a gaseous, liquid, or supercritical state (indeed, the physical state of CO 2 can fluctuate within a single pipeline due to environmental changes), doubts persist about the extent of PHMSA’s purview—and raise questions about what, if anything, states should do to address this apparent gap. PHMSA has begun a major revision of its existing rules, but the agency does not expect a first draft before 2024. Economic oversight of CO 2 pipelines is even less clear. The Federal Energy Regulatory Commission (FERC) and Surface Transportation Board (STB)—which regulate the rates of interstate oil/natural gas and non-energy pipelines, respectively—have both declined jurisdiction over interstate CO 2 pipelines. This presumably leaves economic regulation to state and/or local governments, but few if any states have the laws or resources in place to oversee just and reasonable rates. Further, the interstate nature of CO 2 pipeline development creates questions around how different states should align their rate-making decisions. Onshore U.S. Carbon Pipeline Deployment: Siting, Safety, and Regulation Currently, regulatory responsibilities regarding CO 2 pipeline siting and permitting fall to state and local governments. The variety of laws and regulations across the country, however, creates a maze of requirements for pipeline developers to navigate. To secure necessary permits, most states require pipeline companies to be “common carriers” that provide transport service to the public at uniform rates. However, the specific definition of that term varies. Some states require clear evidence that a pipeline services the public, while others automatically deem any pipeline company transporting energy products or hazardous materials to be a “common carrier”—with little consideration for accessibility to third parties. Other states have eschewed common-carrier terminology entirely, placing private and publicly accessible pipelines on equal footing. Much like the variation in common-carrier requirements, laws governing eminent domain authority to secure rights-of-way (ROW) to commence construction on a planned pipeline route differ by state. Several states have no laws or rules governing CO 2 pipelines. In addition to creating questions about whether long-standing rules for other pipelines (e.g., natural gas or petroleum products) apply to CO 2 , this policy vacuum leaves local governments as the sole authority over sections of pipe within their boundaries. With dozens of counties along a given route, the probability of inconsistent regulation of the same pipeline is significant. Even in states with CO 2 pipeline laws in place, local regulatory attempts to address rising concerns over pipeline routing and safety have triggered lawsuits by pipeline companies seeking to delimit areas of federal, state, and local government responsibility. Meanwhile, legislators across the country have introduced bills to restrict the application of eminent domain to CO 2 pipeline projects, which could threaten a key means of securing ROW that companies cannot secure through negotiation with landowners. Taken separately, any of these regulatory issues—the narrow federal definition of CO 2 , FERC’s and STB’s decisions that CO 2 pipelines are not within their jurisdiction, and the considerable variation in state and local governments’ laws regulating CO 2 pipeline technologies—are extremely difficult to resolve. Adding the required scale of CO 2 pipeline expansion and the currently identified narrow window of time in which to reach climate target goals, the task becomes even more difficult—and raises a host of urgent questions for regulators. How should CO 2 be defined in federal regulations to ensure consistent safety standards across the country? What is the potential impact radius of a CO 2 pipeline rupture, and how should that inform local emergency response? In the absence of centralized federal oversight, what should state legislatures do to increase alignment for interstate CO 2 pipeline projects? This paper intends to serve as a primer for regulators and stakeholders who seek to better understand the regulatory challenges and opportunities facing this critical infrastructure.

42 ENGINEERING↗

Southeast Regional Carbon Sequestration Partnership Phase III Overview of Accomplishments (SECARB Phase III Final Report)

The Southeast Regional Carbon Sequestration Program (SECARB) is a carbon management program established in 2003 and managed by the Southern States Energy Board (SSEB). SECARB is one of seven regional carbon sequestration partnerships formed by the Department of Energy (DOE). The seven partnerships form a national network of more than 400 organizations covering 43 states and four Canadian provinces with expertise in the areas of carbon capture, transportation, and storage. The SECARB program was funded by DOE and cost-sharing partners. The primary goal of SECARB was to identify major sources of carbon emissions, characterize the geology of a 13-state region, determine the most promising options for commercial deployment of carbon dioxide (CO 2 ) sequestration technologies in the South, and validate the technology options through carefully executed field testing through 2017. This report summarizes significant Phase III accomplishments and is organized by task as established within the SECARB Phase III Statement of Project Objectives (SOPO). This document does not provide an exhaustive overview of individual tasks. Rather, this report provides an overview of programmatic accomplishments and a timeline of events. Where applicable, hyperlinks to specific project deliverables are provided.

54 ENVIRONMENTAL SCIENCES↗

PCOR Partnership Atlas 6th Edition, Revised

The Plains CO 2 Reduction (PCOR) Partnership Atlas provides a profile of CO 2 sources and potential storage locations across the PCOR Partnership region. The revised sixth edition of the Atlas provides an up-to-date look at PCOR Partnership initiative activities, including additional regional characterization and updates on commercial projects. Additional background information on carbon capture, utilization, and storage (CCUS) is included to give a better understanding of how CCUS addresses concerns about climate change while allowing future energy needs to be met.

01 COAL, LIGNITE, AND PEAT↗

The Potential and Cost of Carbon Dioxide Removal Using Direct Air Capture with Land-Based Wind and Utility-Scale Photovoltaics

The rapid deployment of direct air capture and storage (DACS) is critical for achieving emission targets, necessitating precise evaluation of the scale and cost of carbon dioxide removal. This study examines the availability of land, electricity generation, and geologic CO 2 storage within the United States, estimating a technical potential for low-temperature, adsorbent-based DACS to remove approximately 9 gigatonnes of CO 2 annually. By 2050, a substantial portion of this removal could be achieved at net-removed costs below $\$$300/tonneCO 2 , though costs are highly variable depending on factors such as facility scale, construction expenses, climate-dependent productivity and heating efficiency, and geologic storage conditions. In the short term, DACS deployment will help identify key research priorities for advancing technology and reducing removal costs. Concurrently, there is an urgent need for scientifically robust and standardized frameworks for monitoring, reporting, and verifying DACS performance across both established and emerging technologies and energy sources.

Carbon capture↗

Fracture Network Quantification for Enhanced Reservoir Characterization in CO2 Storage Sites

Presentation slides on “Fracture Network Quantification for Enhanced Reservoir Characterization in CO2 Storage Sites” for the CCUS 2025 conference held in Houston, Texas March 3-5, 2025. Accurate reservoir characterization is fundamental for the safe and efficient operation of carbon capture, utilization, and storage (CCUS) projects. This process is not only critical during initial site selection but also plays a key role in continuously updating reservoir geomodels throughout injection operations to effectively manage subsurface storage sites. Our primary objective is to develop a comprehensive understanding of fracture networks within CO2 injection reservoirs, which are critical for predicting the behavior of injected fluids, ensuring storage integrity post-injection, and mitigating risks such as leakage or induced seismicity.

artifical intelligence / machine learning (AI/ML)↗

FracML: A Machine Learning Based Tool to Quantify Reservoir Scale Fracture Network for CO2 Storage

Poster on “FRACML: A Machine Learning Based Tool to Quantify Reservoir Scale Fracture Network for CO2 Storage” for the CCUS 2025 conference held in Houston, Texas March 3-5, 2025. The accurate characterization of subsurface fracture networks is essential for the secure operation of carbon capture, utilization, and storage (CCUS) projects. A thorough understanding of the spatial distribution of subsurface faults and fractures is crucial for predicting CO2 plume evolution and minimizing risks such as potential leakage into overlying formations or induced seismicity. In this context, robust fracture network quantification plays a pivotal role in reservoir management, providing the data necessary to fine-tune operational parameters, and ensure the environmental and economic viability of CCUS projects. As part of the U.S. Department of Energy’s SMART (Science-informed Machine Learning for Accelerating Real-time Decisions in Subsurface Applications) initiative, we focused on the development and application of a machine learning-based tool (FRACML) designed to quantify and map fracture networks using real-world (non-synthetic) data from an active CO2 injection site. Our objective is to demonstrate the utility of this tool in improving operational efficiency and safety across CCUS sites.

artifical intelligence / machine learning (AI/ML)↗

High-pressure CO 2 dissociation with nanosecond pulsed discharges

Herein we investigate the conversion of CO 2 into CO and O 2 with nanosecond repetitively pulsed (NRP) discharges in a high-pressure batch reactor. Stable discharges are obtained at up to 12 bar. By-products are measured with gas chromatography. The energy efficiency is determined for a range of processing times, pulse energy, and fill pressures. It is only weakly sensitive to the plasma operating parameters, i.e the extent of CO 2 conversion is almost linearly-dependent on the specific energy invested. A conversion rate as high as 14% is achieved with an energy efficiency of 23%. For long processing times, saturation in the yield and a drop in efficiency are observed, due to the increasing role of three-body recombination reactions, as described by zero-dimensional detailed kinetic modeling. The modeling reveals the presence of three-stage kinetics between NRP pulses, controlled by electron-impact CO 2 dissociation, vibrational relaxation, and neutral elementary kinetics. Transport effects are shown to be important for CO 2 conversion at high pressures. For fill pressures beyond 10 bar, CO 2 may locally transit into supercritical states. The supercritical plasma kinetics may bypass atomic oxygen pathways and directly convert CO 2 into O 2 . This work provides a detailed analysis of plasma-based high-pressure CO 2 conversion, which is of great relevance to future large-scale sustainable carbon capture, utilization, and storage.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Chemo‐mechanical Alterations Induced From CO 2 Injection in Carbonate‐Cemented Sandstone: An Experimental Study at 71 °C and 29 MPa

Abstract Carbon capture, utilization, and storage may lead to mechanical degradation of the subsurface reservoir from fluid‐rock interaction, which could lead to wellbore instability or reservoir compaction. To better understand potential relationship between mechanical degradation with various carbonate cement textures and compositions in sandstone reservoirs, six flow‐through experiments were conducted. Formation water (TDS = 5,390 mg/L) enriched with CO 2 flowed through two types of Pennsylvanian Morrow B Sandstone: an ankerite‐siderite‐cemented sandstone (disseminated cement texture) and a calcite‐cemented sandstone (poikilotopic cement texture). The experiments produced little change in permeability in the ankerite‐siderite‐cemented sandstone, but permeability increased up to more than 1 order of magnitude in the calcite‐cemented sandstone. Ultrasonic measurements and cylinder‐splitting tests (also known as Brazilian tests) suggested negligible mechanical degradation of the ankerite‐siderite‐cemented sandstone. Variable changes, with significant mechanical degradation in the static moduli, were observed in the calcite‐cemented sandstone. Thus, dissolution of the disseminated ankerite‐siderite cement (0.28–0.30%) had minimal impact on modifying the flow network and the mechanical integrity of the sandstone, whereas dissolution of the poikilotopic calcite cement (0.89–1.13%, quantified with fluid chemistry and visualized with X‐ray microcomputed tomography) impacted the mechanical strength of the sandstone by disconnecting framework grains. With the high water‐to‐rock mass ratios (7.3–8.2) and number of pore volumes (147–675) employed in these experiments, potential risks are most relevant to regions near injection wells. Ultimately, the chemo‐mechanical effects induced by CO 2 injection are strongly influenced by the cement texture and composition and the burial history of the reservoir rock.

Wu, Z.↗

Tetrameric self-assembling of water-lean solvents enables carbamate anhydride-based CO2 capture chemistry

Abstract Carbon capture, utilization and storage is a key yet cost-intensive technology for the fight against climate change. Single-component water-lean solvents have emerged as promising materials for post-combustion CO 2 capture, but little is known regarding their mechanism of action. Here we present a combined experimental and modelling study of single-component water-lean solvents, and we find that CO 2 capture is accompanied by the self-assembly of reverse-micelle-like tetrameric clusters in solution. This spontaneous aggregation leads to stepwise cooperative capture phenomena with highly contrasting mechanistic and thermodynamic features. The emergence of well-defined supramolecular architectures displaying a hydrogen-bonded internal core, reminiscent of enzymatic active sites, enables the formation of CO 2 -containing molecular species such as carbamic acid, carbamic anhydride and alkoxy carbamic anhydrides. This system extends the scope of adducts and mechanisms observed during carbon capture. It opens the way to materials with a higher CO 2 storage capacity and provides a means for carbamates to potentially act as initiators for future oligomerization or polymerization of CO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Active Seismoelectric Monitoring of CO 2 Injection

Conference presentation at Carbon Capture, Utilization, and Storage (CCUS) Conference 2024, Houston, Texas, March 11–13, 2024. We investigated the use of active seismoelectric monitoring (ASE) to determine its effectiveness in detecting CO 2 injected deep underground and as an additional monitoring option for carbon storage projects. The EERC performed an ASE survey in February of 2023 at Pennel oil field near Baker, Montana, as part of the U.S. Department of Energy-sponsored Williston Basin CO 2 Field Laboratory in conjunction with operating partner Denbury Inc. The field site is part of the Cedar Creek Anticline geologic structure, with CO 2 planned for injection into a stacked storage complex (SSC) in the Interlake Formation containing both a residual oil zone and a conventional reservoir. The objective was to test the ASE method’s ability to characterize baseline fluid distribution in both the near surface and the SSC prior to CO 2 injection.

04 OIL SHALES AND TAR SANDS↗

Quantitative Risk Assessment (Topical Report)

Carbon capture, utilization, and storage (CCUS) in geological formations plays a key role in mitigating anthropogenic CO 2 emissions and achieving the aggressive goal of net-zero greenhouse gas emissions. Quantitative risk assessment is crucial for ensuring the safety and reliability of geologic carbon storage (GCS) by evaluating CO 2 migration in subsurface, forecasting potential leakage and induced seismicity risks, and optimizing operational and monitoring plans. We present the use, progress, and research trends of risk assessment from the Southwest Regional Partnership on Carbon Sequestration (SWP) as an example of large-scale CCUS projects in North America. The information provided in this report can help readers understand the significance of risk and uncertainty assessment and apply them effectively in large-scale CCUS projects.

42 ENGINEERING↗

Semi‐Continuous Ex Situ Carbon Dioxide Mineralization in Produced Water for Calcite Production

ABSTRACT The mineralization of carbon dioxide (CO 2 ) to stable carbonate products is a desirable process for carbon capture utilization and storage (CCUS). However, improving the process economics through creative use of available reactants is necessary to develop a scalable mineralization process. This study details the development of a semi‐continuous CO 2 mineralization process that uses flue gas as a point CO 2 source, produced water (PW) as an alkaline source of Ca 2+ , and NaOH effluent (potentially sourced from integration with the chlor‐alkali process. Operating at a controlled pH allowed for both complete reaction of available Ca 2+ (100% carbonation potential or 9.9 g CO 2 .L –1 PW brine) and for reproducible control of the produced calcium carbonate (CaCO 3 ) product. A full factorial design of experiments was implemented to study the effects of reaction temperature, pH, and gaseous CO 2 concentration on the mineralization and CO 2 capture rates as well as product crystalline structure and morphology. A maximum CO 2 capture rate of 0.315 ± 0.007 kg.L –1 .d –1 was achieved at 25°C and 25% CO 2 . CO 2 gas to liquid phase mass transport is believed to be the rate limiting step. With improved reactor design and optimization, the proposed semi‐continuous mineralization process shows promise for scaling to a pilot scale CO 2 capture technology.

Bennett, Quinn [Institute for Sustainable Energy &↗

PCOR Partnership: A Catalyst for Commercial CCUS Deployment

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. This paper presents an overview of the Plains CO 2 Reduction (PCOR) Partnership Initiative and the current commercial carbon capture, utilization, and storage (CCUS) activity in the region, discusses challenges facing CCUS in the region, and highlights important challenges that have recently been overcome to enable CCUS deployment in the region.

01 COAL, LIGNITE, AND PEAT↗

Annual Technology Baseline: The 2024 Electricity Update

Consistent cost and performance data for various electricity generation technologies can be difficult to find and may change frequently for certain technologies. With the Annual Technology Baseline (ATB), the National Renewable Energy Laboratory annually provides an organized and centralized set of such cost and performance data. The ATB uses the best information from the Department of Energy national laboratories' energy analysts. The ATB has been reviewed by experts and it includes the following electricity generation and storage technologies: land-based wind, offshore wind, distributed wind, utility-scale solar photovoltaics (PV), commercial-scale solar PV, residential-scale solar PV, concentrating solar power, geothermal power, hydropower, utility-scale battery storage, commercial battery storage, residential battery storage, pumped storage hydropower, nuclear, coal, and natural gas. EIA data for conventional biopower are included for reference. This webinar presentation introduces the 2024 update to the ATB Electricity data and documentation.

battery storage↗

Regional Geologic Cross Sections for Potential Storage and Containment Zones in the MRCSP Region [plus Plates 1-6]

The regional characterization work conducted by the Geoteams during the MRCSP Phase III project period (2010 –2019) focused on the following tasks: (1) refinement of geologic seals/reservoir systems; (2) assessment of Atlantic Coastal Plain and offshore opportunities; (3) expanded assessments of oil and gas fields, particularly as they relate to enhanced recovery opportunities; (4) regional support for implementation of carbon capture utilization and storage (CCUS) in the partnership area; and (5) communication and data sharing. This report, entitled Regional Geology, has been prepared in association with (4), regional support for implementation of CCUS in the partnership area..

58 GEOSCIENCES↗

First Wave of Incentive-Driven CCS Projects in North Dakota

Conference poster presented at American Association of Petroleum Geologists (AAPG) Carbon Capture, Utilization, and Storage (CCUS) Conference, Houston, Texas, March 28–30, 2022. While the central interior of North America offers a tremendous storage resource, optimization will be key to meaningfully reducing the more than 2.6 billion tons of CO 2 emitted annually from large point sources in the United States. These initial projects tend to have the most favorable economics and are often able to take advantage of the best geology, with little to no competition for resource. This initial wave of projects is informing investment in and creating the opportunity for innovation that will enable the next wave of incentive-based CCS projects. Such innovation is critical for reducing costs, enhancing the design and operability of the next wave of CCS projects, and realizing more of the 250 billion tons of storage resource in North Dakota.

01 COAL, LIGNITE, AND PEAT↗