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The properties of materials selected for use in oxygen systems are examined. Specifically, materials are selected according to trade-offs between chemical compatibility, ignition temperature, combustion characteristics, and physical properties. Quantitative energy sources and energy release rates capable of causing material combustion or explosion were also considered.
We report near-infrared (NIR) spectroscopic observations of 12 'branch-normal' Type Ia supernovae (SNe Ia) that cover the wavelength region from 0.8 to 2.5 microns. Our sample more than doubles the number of SNe Ia with published NIR spectra within 3 weeks of maximum light. The epochs of observation range from 13 days before maximum light to 18 days after maximum light. A detailed model for a Type Ia supernovae is used to identify spectral features. The Doppler shifts of lines are measured to obtain the velocity and thus the radial distribution of elements. The NIR is an extremely useful tool to probe the chemical structure in the layers of SNe Ia ejecta. This wavelength region is optimal for examining certain products of the SNe Ia explosion that may be blended or obscured in other spectral regions. We identify spectral features from Mg II, Ca II, Si II, Fe II, Co II, Ni II, and possibly Mn II. We find no indications for hydrogen, helium, or carbon in the spectra. The spectral features reveal important clues about the physical characteristics of SNe Ia. We use the features to derive upper limits for the amount of unburned matter, to identify the transition regions from explosive carbon to oxygen burning and from partial to complete silicon burning, and to estimate the level of mixing during and after the explosion. Elements synthesized in the outer layers during the explosion appear to remain in distinct layers. That provides strong evidence for the presence of a detonation phase during the explosion as it occurs in delayed detonation or merger models. Mg II velocities are found to exceed 11,000 - 15,000 km/s, depending on the individual SNe Ia. That result suggests that burning during the explosion reaches the outermost layers of the progenitor and limits the amount of unburned material to less than 10% of the mass of the progenitor. Small residuals of unburned material are predicted by delayed detonation models but are inconsistent with pure deflagration or merger models. Differences in the spectra of the individual SNe Ia demonstrate the variety of these events.
inXitu Inc., of Mountain View, California, entered into a Phase II SBIR contract with Ames Research Center to develop technologies for the next generation of scientific instruments for materials analysis. The work resulted in a sample handling system that could find a wide range of applications in research and industrial laboratories as a means to load powdered samples for analysis or process control. Potential industries include chemical, cement, inks, pharmaceutical, ceramics, and forensics. Additional applications include characterizing materials that cannot be ground to a fine size, such as explosives and research pharmaceuticals.
Soot is a powdery substance composed of solid residues that results from the incomplete combustion of hydrocarbons. Soot holds valuable information because its chemical makeup can provide answers for condensed carbon kinetics in HE detonations by quantitively identifying what carbon species remain. For carbon-rich explosives, this is particularly important because carbon kinetics is a major pathway for energy release. Current efforts have been able to qualitatively identify the carbons and confirm their presence, but we haven’t been able to successfully quantify them. For example, small angle x-ray diffraction has been fielded to qualitatively identify carbon phases as a function of time during a detonation (work by Trevor Willey and Mike Nielson). Other work (ice experiments) has focused on measuring the “effective” static cold curve equation of state (EOS) of the recovered carbon soots.
The astrophysical origin for the chemical elements between the first and second r-process peaks is a matter of intense debate, with a number of nucleosynthesis processes at explosive stellar environments possibly contributing to their production. Reliable data on the trends of neutron separation energies of neutron-rich isotopes are required to model neutron-capture processes that would produce these elements. Masses of 104 Y, 106 Zr, 112 Mo, and 115 Tc have been measured with the time-of-flight-magnetic-rigidity (ToF–Bρ) technique at the National Superconducting Cyclotron Laboratory at Michigan State University. The experiment is the first application of the ToF–Bρ technique at the S800 spectrograph that reached the mass region relevant to heavy-element nucleosynthesis. Finally, the two-neutron separation energy deduced from the measured masses exhibits a smooth trend consistent with the theoretical predictions within the range of experimental uncertainty, indicating that there is no sudden shape transition in these isotopes as hinted at by previous data.
Explosive volcanic eruptions can produce sustained, buoyant columns of ash and gas in the atmosphere (Fig. 1). Large flood basalt eruptions may also include significant explosive phases that generate eruption columns. Such eruptions can transport volcanic volatiles to great heights in the atmosphere. Volcanic eruption columns can also redistribute chemical species within the atmosphere by entraining ambient atmosphere at low altitudes and releasing those species at much higher altitudes.
Theoretical results predicting yields of various isotopes in nova outbursts are reviewed. Emphasis is placed on the stardust and gas-phase chemical anomalies that may be contributed to the Galactic ISM by classic novae. It is concluded that most of the heavy isotope anomalies are produced by about 25 percent of novae that occur in systems containing massive O-Ne-Mg white dwarfs. The dust-production scenario for novae is summarized, and it is argued that explosions on O-Ne-Mg white dwarfs may lead to the formation of dust grains that carry the Ne-E and Mg-26 anomalies. Quantitative constraints are placed on the degree to which classical novae participate in the production of chemical anomalies, both in the primitive solar system and on a Galactic scale.
W49B is a unique Galactic supernova remnant with centrally peaked, “bar”-like ejecta distribution, which was once considered evidence for a hypernova origin that resulted in a bipolar ejection of the stellar core. However, chemical abundance measurements contradict this interpretation. Closely connected to the morphology of the ejecta is its velocity distribution, which provides critical details for understanding the explosion mechanism. We report the first ever observational constraint on the kinematics of the ejecta in W49B using the Resolve microcalorimeter spectrometer on the X-ray Imaging and Spectroscopy Mission (XRISM). Using XRISM/Resolve, we measured the line-of-sight velocity traced by the Fe Heα emission, which is the brightest feature in the Resolve spectrum, to vary by ±300 km s −1 with a smooth east-to-west gradient of a few tens of kilometers per second per parsec along the major axis. Similar trends in the line-of-sight velocity structure were found for other Fe-group elements Cr and Mn, traced by the Heα emission, and also for intermediate-mass elements Si, S, Ar, and Ca, traced by the Lyα emission. The discovery of the east–west gradient in the line-of-sight velocity, together with the absence of a twin-peaked line profile or enhanced broadening in the central region, clearly rejects the equatorially expanding disk model. In contrast, the observed velocity structure suggests bipolar flows reminiscent of a bipolar explosion scenario. An alternative scenario would be a collimation of the ejecta by an elongated cavity sculpted by bipolar stellar winds.
A theoretical study of the chemical and gas dynamical processes resulting from the release of reactive gases into the daytime ionosphere is discussed. Only point releases, such as from an explosion or a pulsed jet, are considered. Some scientific uses of the artificial reduction of the ionospheric plasma are considered.
The reported investigation has been conducted in connection with studies concerning the development of a propulsion system based on the use of a detonating fluid propellant. Measurements have been made of the pressure and shock wave velocity in a conical nozzle at various ambient pressures and at an ambient temperature of 25 C. In the experiments a small amount of explosive was placed at the end wall of a conical aluminum nozzle and detonated by a microdetonator inside the nozzle. Differences regarding the characteristics of conventional chemical propulsion and detonation propulsion are illustrated with the aid of a graph. One- and two-dimensional numerical flow calculations were performed and compared with the experimental data.
The Stanford University research program on the study of stimulation and reservoir engineering of geothermal resources commenced as an interdisciplinary program in September, 1972. The broad objectives of this program have been: (1) the development of experimental and computational data to evaluate the optimum performance of fracture-stimulated geothermal reservoirs; (2) the development of a geothermal reservoir model to evaluate important thermophysical, hydrodynamic, and chemical parameters based on fluid-energy-volume balances as part of standard reservoir engineering practice; and (3) the construction of a laboratory model of an explosion-produced chimney to obtain experimental data on the processes of in-place boiling, moving flash fronts, and two-phase flow in porous and fractured hydrothermal reservoirs.
A compact, lightweight heat exchanger has been designed to be fault-tolerant in the sense that a single-point leak would not cause mixing of heat-transfer fluids. This particular heat exchanger is intended to be part of the temperature-regulation system for habitable modules of the International Space Station and to function with water and ammonia as the heat-transfer fluids. The basic fault-tolerant design is adaptable to other heat-transfer fluids and heat exchangers for applications in which mixing of heat-transfer fluids would pose toxic, explosive, or other hazards: Examples could include fuel/air heat exchangers for thermal management on aircraft, process heat exchangers in the cryogenic industry, and heat exchangers used in chemical processing. The reason this heat exchanger can tolerate a single-point leak is that the heat-transfer fluids are everywhere separated by a vented volume and at least two seals. The combination of fault tolerance, compactness, and light weight is implemented in a unique heat-exchanger core configuration: Each fluid passage is entirely surrounded by a vented region bridged by solid structures through which heat is conducted between the fluids. Precise, proprietary fabrication techniques make it possible to manufacture the vented regions and heat-conducting structures with very small dimensions to obtain a very large coefficient of heat transfer between the two fluids. A large heat-transfer coefficient favors compact design by making it possible to use a relatively small core for a given heat-transfer rate. Calculations and experiments have shown that in most respects, the fault-tolerant heat exchanger can be expected to equal or exceed the performance of the non-fault-tolerant heat exchanger that it is intended to supplant (see table). The only significant disadvantages are a slight weight penalty and a small decrease in the mass-specific heat transfer.
This report presents bounding pressurization and flammability evaluations from the radiolytic gas generation expected during extended (>50 years) dry storage of aluminum-clad spent nuclear fuel (ASNF) elements in a sealed Department of Energy (DOE) Standard Canister. The primary questions involving extended ASNF dry storage center around the adequacy of dry storage conditioning processes (i.e., drying) and the behavior of residual hydrated aluminum oxides on the cladding—specifically, the radiolytic breakdown of chemically bound water in these corrosion products. The objectives of the presented work include providing a bounding assessment of the pressure with respect to the DOE Standard Canister’s structural integrity limits and identifying the potential for forming flammable or explosive gas mixtures (i.e., exceedance of the lower flammability limit of the molecular hydrogen [H2] and oxygen [O2] concentrations). The evaluation results confirm the findings of previous, more complex M&S work. That is, the structural integrity of the canister remains unchallenged by a wide margin. Nevertheless, it is important to recognize that the presented pressure calculations consider a full breakdown of the chemisorbed water, including a consequent release of all available H2. In reality, the breakdown of water in these systems will likely remain incomplete, due to competing chemical and radiolytic reactions, thereby attaining an equilibrium in the storage environment.
While it is now well established that copper-oxide-based powder, or virtually any other ceramic superconductor powder, can be consolidated and encapsulated within a metal matrix by explosive consolidation, the erratic superconductivity following fabrication has posed a major problem for bulk applications. The nature of this behavior was found to arise from microstructural damage created in the shock wave front, and the residual degradation in superconductivity was demonstrated to be directly related to the peak shock pressure. The explosively fabricated or shock loaded YBa2Cu3Ox examples exhibit drastically altered rho (or R) - T curves. The deterioration in superconductivity is even more noticeable in the measurement of ac magnetic susceptibility and flux exclusion or shielding fraction which is also reduced in proportion to increasing peak shock pressure. The high-frequency surface resistance (in the GHz range) is also correspondingly compromised in explosively fabricated, bulk metal-matrix composites based on YBa2Cu3O7. Transmission electron microscopy (including lattice imaging techniques) is being applied in an effort to elucidate the fundamental (microstructural) nature of the shock-induced degradation of superconductivity and normal state conductivity. One focus of TEM observations has assumed that oxygen displaced from b-chains rather than oxygen-vacancy disorder in the basal plane of oxygen deficient YBa2Cu3Ox may be a prime mechanism. Shock-wave displaced oxygen may also be locked into new positions or interstitial clusters or chemically bound to displaced metal (possibly copper) atoms to form precipitates, or such displacements may cause the equivalent of local lattice cell changes as a result of stoichiometric changes. While the shock-induced suppression of T(sub c) is not desirable in the explosive fabrication of bulk metal-matrix superconductors, it may be turned into an advantage if the atomic-scale distortion can be understood and controlled as local flux pinning sites.
While it is now well established that copper-oxide-based power, or virtually any other ceramic superconductor powder, can be consolidated and encapsulated within a metal matrix by explosive consolidation, the erratic superconductivity following fabrication has posed a major problem for bulk applications. The nature of this behavior was found to arise from microstructural damage created in the shock wave front, and the residual degradation in superconductivity was demonstrated to be directly related to the peak shock pressure. The explosively fabricated or shock loaded YBa2Cu3Ox examples exhibit drastically altered rho (or R) - T curves. The deterioration in superconductivity is even more noticeable in the measurement of ac magnetic susceptibility and flux exclusion or shielding fraction which is also reduced in proportion to increasing peak shock pressure. The high frequency surface resistance (in the GHz range) is also correspondingly compromised in explosively fabricated, bulk metal-matrix composites based on YBa2Cu3O7. Transmission electron microscopy (including lattice imaging techniques) is being applied in an effort to elucidate the fundamental (microstructural) nature of the shock-induced degradation of superconductivity and normal state conductivity. One focus of TEM observations has assumed that oxygen displaced from b-chains rather than oxygen-vacancy disorder in the basal plane of oxygen deficient YBa2Cu3Ox may be a prime mechanism. Shock-wave displaced oxygen may also be locked into new positions or interstitial clusters or chemically bound to displaced metal (possibly copper) atoms to form precipitates, or such displacements may cause the equivalent of local lattice cell changes as a result of stoichiometric changes. While the shock-induced suppression of T(sub c) is not desirable in the explosive fabrication of bulk metal-matrix superconductors, it may be turned into an advantage if the atomic-scale distortion can be understood and controlled as local flux pinning sites.
Neutrinos are believed to have a key role in the explosion mechanism of core-collapse supernovae as they carry most of the energy released by the gravitational collapse of a massive star. If their flavor is converted fast inside the neutrino sphere, the supernova explosion may be influenced. This paper is reporting the results of the extended work of our previous paper. Here, we perform a thorough survey of the electron lepton number (ELN) crossing in one of our self-consistent, realistic Boltzmann simulations in two spatial dimensions under axisymmetry for the existence of the crossings between $ν_e$ and $\bar{ν}_e$ angular distributions, or the ELN crossing. We report for the first time the positive detections deep inside the core of the massive star in the vicinity of neutrino sphere at $\textit{r}$ ≈ 16 – 21 km . We find that low values of the electron fraction $Y_e$ produced by convective motions together with the appearance of light elements are critically important to give rise to the ELN crossing by enhancing the chemical potential difference between proton and neutron, and hence by mitigating the Fermi-degeneracy of $ν_e$. Since the region of positive detection are sustained and, in fact, expanding with time, it may have an impact on the explosion of core-collapse supernovae, observational neutrino astronomy, and nucleosynthesis of heavy nuclei.
A chemical kinetics procedure for soot formation calculation is summarized. By importing Lagrangian hydrodynamic calculations, species history is consistently accounted for. Detonation product composition is assumed in region with the burnt high explosive (HE). Soot formation is calculated using the density and energy obtained in the hydrodynamics calculation of HE detonation. Ideal gas equation-of-state (EOS) with temperature-dependent specific heat is used in the HE product region. Sample calculations show reasonably-expected temperature and soot formation.
Indicator for valves or other control mechanisms easy to mount, reliable, and explosion proof. Replaces slidewires expensive and difficult to mount. Used in hazardous areas that require nonexplosive electrical contacts, and controlling highly flammable fuels. Readily adapted to oil-refining and other chemical processing plants.