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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Synodic and Semiannual Oscillations of Argon-40 in the Lunar Exosphere

The neutral mass spectrometer on the Lunar Atmosphere and Dust Environment Explorer (LADEE) spacecraft collected a trove of exospheric data, including a set of high-quality measurements of radiogenic Ar-40 over a period of 142 days. Data synthesis studies, using well-established exosphere simulation tools, show that the LADEE argon data are consistent with an exosphere-regolith interaction that is dominated by adsorption and that the desorption process generates the Armand distribution of exit velocities. The synthesis work has uncovered an apparent semiannual oscillation of argon that is consistent with temporal sequestration in the seasonal cold traps created at the poles by the obliquity of the Moon. In addition, the LADEE data provide new insight into the pristine nature of lunar regolith, its spatially varying sorption properties, and the influence of sorption processes on the synodic oscillation of the argon exosphere.

argon-40↗

2 mm GISMO Observations of the Galactic Center. I. Dust Emission

The Central Molecular Zone (CMZ), covering the inner ~1degree of the Galactic plane has been mapped at 2 mm using the GISMO bolometric camera on the 30 m IRAM telescope. The 21" resolution maps show abundant emission from cold molecular clouds, from star forming regions, and from one of the Galactic center nonthermal filaments. In this work we use the Herschel Hi-GAL data to model the dust emission across the Galactic center. We find that a single-temperature fit can describe the 160 - 500 mu m emission for most lines of sight, if the long-wavelength dust emissivity scales as lambda (exp beta) with beta approximately equal 2.25. This dust model is extrapolated to predict the 2 mm dust emission. Subtraction of the model from the GISMO data provides a clearer look at the 2 mm emission of star-forming regions and the brightest nonthermal lament.

Richard G Arendt↗

Scale Model Experiments on Sound Propagation From a Mach 2.5 Cold Nitrogen Jet Flowing Through a Rigid-Walled Duct With a J-Deflector

The Launch Systems Testbed (LST) represents the evolution of vibroacoustics research and development work performed at NASA John F. Kennedy Space Center (KSC) over the last 15 years. The LST is located at the Launch Equipment Test Facility (LETF) in the KSC industrial complex. The LETF is operated by Sierra Lobo, Inc., as a member of University-Affiliated Technology Development Contract (USTDC) to KSC Spaceport and Engineering and Technology Directorate (YA), with ASRC Aerospace Corporation as a the prime contractor. Trajectory Simulation Mechanism (TSM) is a major component of the LST, developed specifically to simulate nonstationary acoustic loads on launch pad structures, vehicles, and payloads. TSM enhances the capabilities within LST for simulating launch environments of future vehicles. The scaled launch environments will be used to predict the full-scale launch environment via an appropriate scaling procedure. Air Force Research Laboratory (AFRL) has tasked NASA KSC to perform a basic technology test program in support of developing a low-cost clean pad (incorporating passive mitigation techniques) for future launch vehicles. The overall goal of the program is to develop innovative launch exhaust management systems, which effectively reduce launch acoustic environment with innovative duct designs, while eliminating traditional sound suppression water systems. Passive techniques, such as nontraditional duct geometries, resonators, and diffusers, etc., will be investigated. The overall goals are to advance innovative concepts for a clean pad while developing ideas to reduce transmitted sound via investigation and modeling of jet exhaust acoustic and flow field characteristics. The series of tests outlined in this report represent baseline tests and are geared towards defining the acoustic load environment on the TSM pad for open and closed duct configurations. This report summarizes the cold jet acoustic testing for Mach 2.5 supersonic nitrogen jet issuing from a nozzle with 1-inch exit diameter. Acoustic data, including spectral sound power and Overall Sound Pressure Level (OASPL), are obtained both for a free jet and with the jet flowing through a rigid-walled duct with a J-deflector. The relative performance of closed duct and open duct is evaluated. The results show that the closed duct is superior to the partially open duct, and results in about 3-decibel (dB) noise reduction (near the duct axis) relative to the free jet. The location of the nozzle exit plane (NEP) relative to the duct inlet plane (DIP) has a significant effect on the acoustic field. The results suggest that the location of NEP at 10 inches above the DIP results in reduced acoustic loads relative to 5 inches above the duct inlet and 1 inch into the duct inlet.

Kandula, Max↗

New technology in turbine aerodynamics

A cursory review is presented of some of the recent work that has been done in turbine aerodynamic research at NASA-Lewis Research Center. Topics discussed include the aerodynamic effect of turbine coolant, high work-factor (ratio of stage work to square of blade speed) turbines, and computer methods for turbine design and performance prediction. An extensive bibliography is included. Experimental cooled-turbine aerodynamics programs using two-dimensional cascades, full annular cascades, and cold rotating turbine stage tests are discussed with some typical results presented. Analytically predicted results for cooled blade performance are compared to experimental results. The problems and some of the current programs associated with the use of very high work factors for fan-drive turbines of high-bypass-ratio engines are discussed. Turbines currently being investigated make use of advanced blading concepts designed to maintain high efficiency under conditions of high aerodynamic loading. Computer programs have been developed for turbine design-point performance, off-design performance, supersonic blade profile design, and the calculation of channel velocities for subsonic and transonic flow fields. The use of these programs for the design and analysis of axial and radial turbines is discussed.

Glassman, A. J.↗

Evolutionary Models of Cold, Magnetized, Interstellar Clouds

We modeled the long-term and small-scale evolution of molecular clouds using direct 2D and 3D magnetohydrodynamic (MHD) simulations. This work followed up on previous research by our group under auspices of the ATP in which we studied the energetics of turbulent, magnetized clouds and their internal structure on intermediate scales. Our new work focused on both global and smallscale aspects of the evolution of turbulent, magnetized clouds, and in particular studied the response of turbulent proto-cloud material to passage through the Galactic spiral potential, and the dynamical collapse of turbulent, magnetized (supercritical) clouds into fragments to initiate the formation of a stellar cluster. Technical advances under this program include developing an adaptive-mesh MHD code as a successor to ZEUS (ATHENA) in order to follow cloud fragmentation, developing a shearing-sheet MHD code which includes self-gravity and externally-imposed gravity to follow the evolution of clouds in the Galactic potential, and developing radiative transfer models to evaluate the internal ionization of clumpy clouds exposed to external photoionizing UV and CR radiation. Gammie's work at UIUC focused on the radiative transfer aspects of this program.

Gammie, Charles F.↗

On the quality of tape-cast thin films of sulfide electrolytes for solid-state batteries

All-solid-state lithium batteries (ASSLBs) have the potential to increase energy density, improve safety, and allow for lower manufacturing costs compared to conventional, liquid-based Li-ion batteries. The thickness of solid electrolyte (SE) layer dictates the cell-level energy density and it is desirable to make the SE layer as thin as possible while maintaining uniformity and defect-free. Manufacturing a high- quality, thin sulfide SE layer at large-scale, however, is challenging. Previous studies have addressed the compatibility of materials used for manufacturing thin sulfide SE films, paving the way for further investigation of processing conditions and film quality. Here we report a strong correlation between the solid loading of dispersions and the quality of tape-casted thin sulfide SE films. We also demonstrate a method for quantifying the quality of thin SE films by observing both pin-hole defects and larger heterogeneous agglomerations of particles in the films. Our thin sulfide SE films containing ~5 wt% binder are defect-free and show similar ionic conductivity compared to a cold-pressed, binder-free, thick SE pellet, resulting in an ~11X reduction of area specific resistance. Here, this work on the solid loading of the dispersion used in a scalable tape casting process provides insight for manufacturing high-quality, thin sulfide SE films and to increase the cell-level energy density of ASSLB.

36 MATERIALS SCIENCE↗

Simulating neutron stars with a flexible enthalpy-based equation of state parametrization in sp ECTRE

Numerical simulations of neutron star mergers represent an essential step toward interpreting the full complexity of multimessenger observations and constraining the properties of supranuclear matter. Currently, simulations are limited by an array of factors, including computational performance and input physics uncertainties, such as the neutron star equation of state. In this work, we expand the range of nuclear phenomenology efficiently available to simulations by introducing a new analytic parametrization of cold, beta-equilibrated matter that is based on the relativistic enthalpy. Here we show that the new enthalpy parametrization can capture a range of nuclear behavior, including strong phase transitions. We implement the enthalpy parametrization in the spectre code, simulate isolated neutron stars, and compare performance to the commonly used spectral and polytropic parametrizations. We find comparable computational performance for nuclear models that are well represented by either parametrization, such as simple hadronic equations of state. We show that the enthalpy parametrization further allows us to simulate more complicated hadronic models or models with phase transitions that are inaccessible to current parametrizations.

79 ASTRONOMY AND ASTROPHYSICS↗

Temperature-adaptive radiative coating for all-season household thermal regulation

The sky is a natural heat sink that has been extensively used for passive radiative cooling of households. A lot of focus has been on maximizing the radiative cooling power of roof coating in the hot daytime using static, cooling-optimized material properties. However, the resultant overcooling in cold night or winter times exacerbates the heating cost, especially in climates where heating dominates energy consumption. In this work, we approached thermal regulation from an all-season perspective by developing a mechanically flexible coating that adapts its thermal emittance to different ambient temperatures. The fabricated temperature-adaptive radiative coating (TARC) optimally absorbs the solar energy and automatically switches thermal emittance from 0.20 for ambient temperatures lower than 15°C to 0.90 for temperatures above 30°C, driven by a photonically amplified metal-insulator transition. Simulations show that this system outperforms existing roof coatings for energy saving in most climates, especially those with substantial seasonal variations.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Cellulose Nanofibrils Dewatered with Poly(Lactic Acid) for Improved Bio-Polymer Nanocomposite Processing

Cellulose nanofibrils (CNFs) have theoretically ideal properties for bio-based composite applications; however, the incorporation of these materials into polymers is made challenging by the strong binding of water to CNFs and the irreversible agglomeration of CNFs during drying. Previous methods used “contact dewatering”, wherein the addition of wood flour (WF) to CNFs facilitated the mechanical removal of water from the system via cold pressing, which showed potential in producing dried CNF fibrils attached to wood fibers for biocomposite applications. In this work, the viability of contact dewatering with poly(lactic) acid (PLA) powder for PLA/CNF composites was evaluated. The energy efficiency of dewatering, preservation of nanoscale CNF morphology, and mechanical properties were examined by mixing wet CNFs with pulverized PLA at various loading levels, pressing water out of the system, and compression molding and shear mixing composites for testing. The most impressive results from this dewatering method were the preservation of micron-to-nanoscale fibers with high aspect ratios in PLA-CNF composites; increased strength and modulus of 1.7% and 4.2%, respectively, compared to neat PLA; equivalent or better properties than spray-dried nanocellulose at similar loading levels; and an 11-194x reduction in drying energy compared to spray-drying CNFs.

Chemistry↗

Union through UNITY: Cosmology with 2000 SNe Using a Unified Bayesian Framework

Type Ia supernovae (SNe Ia) were instrumental in establishing the acceleration of the Universe’s expansion. By virtue of their combination of distance reach, precision, and prevalence, they continue to provide key cosmological constraints, complementing other cosmological probes. Individual SN surveys cover only over about a factor of 2 in redshift, so compilations of multiple SN data sets are strongly beneficial. We assemble an up-to-date “Union” compilation of 2087 cosmologically useful SNe Ia from 24 data sets (“Union3”). We take care to put all SNe on the same distance scale and update the light-curve fitting with SALT3 to use the full rest-frame optical. Over the next few years, the number of cosmologically useful SNe Ia will increase by more than a factor of 10, and keeping systematic uncertainties subdominant will be more challenging than ever. We discuss the importance of treating outliers, selection effects, light-curve shape/color populations/standardization relations, unexplained dispersion, and heterogeneous observations simultaneously. We present an updated Bayesian framework, called UNITY1.5 (Unified Nonlinear Inference for Type-Ia cosmologY), that incorporates significant improvements in our ability to model selection effects, standardization, and systematic uncertainties compared to earlier analyses. As an analysis byproduct, we also recover the posterior of the SN-only peculiar-velocity field, although we do not interpret it in this work. We compute updated cosmological constraints with Union3 and UNITY1.5, finding weak 1.7σ–2.6σ tension with flat cold dark matter and possible evidence for thawing dark energy (w0 > − 1, wa < 0). We release our SN distances, light-curve fits, and UNITY1.5 framework to the community.

Rubin, David↗

Liquid-fuel valve with precise throttling control

Prototype liquid-fuel valve performs on-off and throttling functions in vacuum without component cold-welding or excessive leakage. Valve design enables simple and rapid disassembly and parts replacement and operates with short working stroke, providing maximum throttling sensitivity commensurate with good control.

Mcdougal, A. R.↗

Diurnal and Seasonal Cold Lands Signatures in SSM/I-scale Microwave Radiometry of the North Slope of Alaska

In this paper, we explore scaling and data assimilation-related issues associated with utilizing passive microwave satellite observations of Cold Lands-in this case, the climatologically and ecologically sensitive arctic tundra. Our approach expands on our earlier work using a one-year dataset from the Radiobrightness Energy Balance Experiment-3 (REBEX-3). REBEX-3 featured a tower-based SSM/I (Special Sensor Microwave/Imager) simulator deployed on the North Slope of Alaska in 1994-95. Two findings are significant here. First, a comparison of tower and satellite signatures at 19 and 37 GHz strongly suggested that the North Slope is radiometrically homogeneous for spatial scales up to SSM/I footprints (approximately 25 km), an unusual and valuable characteristic for monitoring and retrieving land surface conditions. And second, at the plot scale, signatures of snow/no-snow and freeze/thaw transitions were identifiable for tussock tundra land cover, so that even snow-free frozen tundra could be unambiguously distinguished from tundra covered with dry snow, another unusual and valuable characteristic. We present results from analyzing satellite brightness signatures of selected North Slope pixels corresponding to instrumented sites along a transect from the Brooks Range to the Arctic Ocean. A custom EASE (Equal Area Scalable Earth)-Grid processor was used to extract SSMJI data for every orbit with observations of this region during the 1994-95 year. The resulting high temporal-resolution (4-8 points/day), gridded data were then analyzed for evidence of the same diurnal and seasonal signatures seen at the plot scale (through micrometeorological and/or brightness data). Differences between satellite and tower brightness observations are quantified for various conditions at the REBEX-3 site. Such differences from the less-frequent and/or larger-scale satellite observations represent a form of input 'noise' in data assimilation applications. For the other sites, the performance of snow/no-snow and freeze/thaw discriminators vs. ground truth represents an opportunity to gauge the homogeneity of other pixels.

Kim, Edward J.↗

Development of Oxidation Resistant Coatings on GRCop-84 Substrates by Cold Spray Process

GRCop-84, a Cu-CR-Nb alloy, has been developed for rocket engine liner applications. For maximum life additional oxidation protection is required to prevent blanching. NiCrAlY was identified as a suitable coating, and efforts were initiated to develop suitable coating techniques. Cold spray is one technique under consideration. Efforts at ASB Industries to produce dense, adherent coatings are detailed. The work culminated in the production of samples for testing at NASA Glenn Research Center.

Karthikeyan, J.↗

Photoionization in Ultraviolet Processing of Astrophysical Ice Analogs at Cryogenic Temperatures

Two recent experimental studies have demonstrated that amino acids or amino acid precursors are generated when astrophysical ice analogs are subjected to ultraviolet (UV) irradiation at cryogenic temperatures. Understanding the complete phenomenology of photoprocessing is critical to elucidating chemical reaction mechanisms that can function within an ice matrix under very cold conditions. Pushing beyond the much better characterized study of photolytic dissociation of chemical bonds through electronic excitation, this work explored the ability of UV radiation present in the interstellar medium to ionize small molecules embedded in ices. Quantum chemical calculations, including bulk solvation effects, were used to study the ionization of hydrogen (H2), water, and methanol (CH3OH) bound in small clusters of water. Ionization potentials were found to be much smaller in the condensed phase than in the gas phase; even a small cluster can account for large changes in the ionization potentials in ice, as well as the known formation of an OH--H3O+ pair in the case of H2O photoionization. To gauge the impact of photoionization on subsequent grain chemistry, the reaction between OH and CO in the presence of H3O+ was studied and compared with the potential energy surface without hydronium present, which is relevant to chemistry following photolysis. The differences indicate that the reaction is somewhat more likely to proceed to products (H + CO2) in the case of photoionization.

Woon, David E.↗

Deep Space Observations of Sun Glints from Marine Ice Clouds

The Earth Polychromatic Camera (EPIC) onboard the Deep Space Climate Observatory (DSCOVR) spacecraft takes images of the sunlit face of Earth from a million miles away. Earlier work showed that EPIC detected the specular reflection of sunlight (that is, sun glint) from ice crystals floating in cold clouds over land; here we show that this phenomenon can also be detected over oceans. Furthermore, the results show that - using its observations at Oxygen A-band absorption bands - EPIC can distinguish glints off marine ice clouds from those off the ocean surface. The analysis of more than two years of EPIC data reveals that the two kinds of glints are detected with comparable frequency. Glints off clouds are shown to be generally brighter but smaller in spatial extent. It is also demonstrated that glints off ice clouds have a discernible effect on the regional mean reflectance and that EPIC observations can help constrain the radiative contribution of oriented ice crystals.

Atmosphere↗

2 mm GISMO Observations of the Galactic Center. I. Dust Emission

The central molecular zone, covering the inner 1° of the Galactic plane has been mapped at 2mm using the Goddard-IRAM Superconducting 2-Millimeter Observer (GISMO) bolometric camera on the 30 m IRAM telescope. The 21 resolution maps show abundant emission from cold molecular clouds, from star-forming regions, and from one of the Galactic center nonthermal filaments. In this work we use the Herschel Hi-GAL data to model the dust emission across the Galactic center. We find that a single-temperature fit can describe the 160-500 um emission for most lines of sight, if the long-wavelength dust emissivity scales as with 2.25. This dust model is extrapolated to predict the 2 mm dust emission. Subtraction of the model from the GISMO data provides a clearer look at the 2 mm emission of star-forming regions and the brightest nonthermal filament.

Arendt, Richard G.↗

Evaluation of Common Thermoplastic Polymers in High-Pressure Cycling Hydrogen Under Ambient and Cold Environments as Applicable to the Hydrogen Infrastructure

Thermoplastic polymers are required to perform unfailingly under stringent conditions of changing pressures (35 MPa to 70 MPa) and temperatures (-40°C to +85°C) in storage and fueling operations. Although diffusivity in glassy polymers appear to be an order of magnitude lower than elastomers, polymer microstructural attributes such as degree of crystallinity and presence of polar and non-polar groups on the main chain with and without branching can play a substantial role in influencing their behaviors in hydrogen environments. In the work described here, the effect of high-pressure hydrogen cycling on PEEK, PTFE, PA11, HDPE, POM (and different commercial grades of these polymers) under ambient and cold (-40°C) conditions is addressed. Ex-situ characterization for polymer changes included density measurements for impact of hydrogen retention, hardness changes using nanoindentation, storage modulus and glass transition changes using dynamic mechanical and thermal analysis (DMTA), degree of crystallization with Differential Scanning Calorimetry (DSC) and tensile testing following ASTM D412. In other evaluations, solid-state nuclear magnetic resonance (NMR), attenuated total reflectance Fourier transform infra-red spectroscopy (ATRFTIR), X-ray diffraction (XRD), and X-ray CT results are presented. The overall impact of these evaluations is to establish a technical basis for the behaviors of common thermoplastics in cycling hydrogen environments under ambient and cold temperatures while establishing the relationship between polymer structure-based properties and hydrogen transport effects.

Menon, Nalini C.↗

Jovian Plasma Torus Interaction with Europa: 3D Hybrid Kinetic Simulation. First results

The hybrid kinetic model supports comprehensive simulation of the interaction between different spatial and energetic elements of the Europa-moon-magnetosphere system with respect to variable upstream magnetic field and flux or density distributions of plasma and energetic ions, electrons, and neutral atoms. This capability is critical for improving the interpretation of the existing Europa flyby measurements from the Galileo orbiter mission, and for planning flyby and orbital measurements, (including the surface and atmospheric compositions) for future missions. The simulations are based on recent models of the atmosphere of Europa (Cassidy etal.,2007;Shematovichetal.,2005). In contrast to previous approaches with MHD simulations, the hybrid model allows us to fully take into account the finite gyro radius effect and electron pressure, and to correctly estimate the ion velocity distribution and the fluxes along the magnetic field (assuming an initial Maxwellian velocity distribution for upstream background ions).Non-thermal distributions of upstream plasma will be addressed in future work. Photoionization,electron-impact ionization, charge exchange and collisions between the ions and neutrals are also included in our model. We consider two models for background plasma:(a) with O(++) ions; (b) with O(++) and S(++) ions. The majority of O2 atmosphere is thermal with an extended cold population (Cassidyetal.,2007). A few first simulations already include an induced magnetic dipole; however, several important effects of induced magnetic fields arising from oceanic shell conductivity will be addressed in later work.

Lipatov, A. S.↗