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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

SMOS Salinity Retrieved from New Seawater Dielectric Constant Models at L-band

The accuracy of the Sea Surface Salinity (SSS) retrieved from L-Band radiometer measurements is strongly dependent on the accuracy of the modelling of the dielectric constant. Two new parametrizations have recently been developed based on one hand on the Soil Moisture and Ocean Salinity (SMOS) satellite multi-angular brightness temperature measurements [1] (BV) and on the other hand on new laboratory measurements [3] (GW2020). These two approaches are fully independent. The brightness temperatures, Tb, simulated with the BV and GW2020 parametrizations are compared with each other and with the ones derived from dielectric constant models previously in use in the SMOS, Soil Moisture Active Passive (SMAP) and Aquarius SSS retrievals. Tb simulated with the BV and GW2020 parametrizations agree particularly well for most SSS and SST commonly observed over the open ocean and are found to be in closer agreement than with earlier parametrizations. Nevertheless, uncertainty remains at low SST where a ∼ 0.1 K relative difference between the two models is observed. A complete reprocessing of SMOS SSS (2010–2020) has been performed using the BV parametrization instead of the Klein and Swift (1977) model previously used in SMOS processing. When compared with Argo derived near surface salinity maps, clear improvements are observed in warm and cold regions. Remaining uncertainties in cold waters will be discussed relatively to the uncertainties in SMOS Tb linked to sea ice contamination and given the constraints given by the GW2020 laboratory measurements.

J. Boutin↗

The Impact of Drifting Orbits on the Monthly Regional TOA Flux Assuming Constant Meteorology

The NASA Clouds and the Earth's Radiant Energy System (CERES) gridded Single Scanner Footprint (SSF1deg) product provides TOA SW and LW monthly 1° regional all-sky fluxes, which are used to monitor the Earth’s energy balance. The CERES long-term climate data record relies on Terra and Aqua satellite sun-synchronous orbits that are maintained at 10:30 and 1:30 local equator crossing times (LECT), respectively. The Terra and Aqua satellites are expected to drift outside of their respective LECT during mid 2022. Both Terra and Aqua will drift over several years towards sunrise and sunset, respectively, and eventually will be deorbited. The CERES SSF1deg product monthly regional fluxes are based on the well calibrated and stable CERES observed fluxes and are temporally interpolated assuming constant meteorology between measurements to resolve the regional diurnal flux cycle to obtain a daily averaged flux. The drifting orbits may impact the monthly regional TOA flux over regions with systematic diurnal cycles, because the observations will shift in local time. The CERES project would like to determine the maximum Terra and Aqua LECT time shift before the monthly regional fluxes are diurnally impacted and become unreliable for long-term climate monitoring. To determine the impact of the drifting orbits on the SSF1deg monthly regional fluxes,15-minute Geostationary Earth Radiation Budget (GERB) broadband observed fluxes over the Meteosat geostationary satellite domain (±60° in longitude and latitude) are used as proxy CERES observations. The drifting orbit sampling pattern is achieved by simply incrementing the observation time by steps of 15 minutes from the CERES footprint time. For each 15-minute time interval, the CERES observed fluxes are replaced by the GERB observed fluxes. The-15 minute incremented monthly regional fluxes based on constant meteorology are compared to the reference 10:30 and 1:30 LECT fluxes. Regions with systematic diurnal cycles, include morning maritime stratus, where the clouds dissipate during the morning, and land afternoon convection, where clouds increase in the afternoon will impact the regional flux differences. Based on January and July 2010 GERB data, even a 15-minute LECT change caused regional monthly flux differences that would impact long term regional trend analysis. Results will be shown at the conference.

David Doelling↗

The Orbital Drift Impact on the Monthly Regional TOA Flux Assuming Constant Meteorology

The NASA Clouds and the Earth's Radiant Energy System (CERES) gridded Single Scanner Footprint (SSF1deg) product provides TOA SW and LW monthly 1° regional all-sky fluxes, which are used to monitor the Earth’s energy balance. The CERES long-term climate data record relies on Terra and Aqua satellite sun-synchronous orbits that are maintained at 10:30 and 1:30 local equator crossing times (LECT), respectively. The Terra and Aqua satellites are expected to drift outside of their respective LECT during mid 2022. Both Terra and Aqua will drift over several years towards sunrise and sunset, respectively, and eventually will be deorbited. The CERES SSF1deg product monthly regional fluxes are based on the well calibrated and stable CERES observed fluxes and are temporally interpolated assuming constant meteorology between measurements to resolve the regional diurnal flux cycle to obtain a daily averaged flux. The drifting orbits may impact the monthly regional TOA flux over regions with systematic diurnal cycles, because the observations will shift in local time. The CERES project would like to determine the maximum Terra and Aqua LECT time shift before the monthly regional fluxes are diurnally impacted and become unreliable for long-term climate monitoring. To determine the impact of the drifting orbits on the SSF1deg monthly regional fluxes,15-minute Geostationary Earth Radiation Budget (GERB) broadband observed fluxes over the Meteosat geostationary satellite domain (±60° in longitude and latitude) are used as proxy CERES observations. The drifting orbit sampling pattern is achieved by simply incrementing the observation time by steps of 15 minutes from the CERES footprint time. For each 15-minute time interval, the CERES observed fluxes are replaced by the GERB observed fluxes. The-15 minute incremented monthly regional fluxes based on constant meteorology are compared to the reference 10:30 and 1:30 LECT fluxes. Regions with systematic diurnal cycles, include morning maritime stratus, where the clouds dissipate during the morning, and land afternoon convection, where clouds increase in the afternoon will impact the regional flux differences. Based on January and July 2010 GERB data, even a 15-minute LECT change caused regional monthly flux differences that would impact long term regional trend analysis. Results will be shown at the conference.

D R Doelling↗

Sustainable, degradable and malleable low-dielectric-constant thermosets derived from biomass for recyclable green electronics

In view of their excellent thermal and chemical resistance, favorable adhesion properties, high tensile strength, and other advantages, epoxy thermosets have numerous industrial applications such as coating, adhesive, and composite material production. However, bisphenol A (BPA)-based resins, which account for a significant fraction of the above thermosets, adversely affect human health by interfering with the normal functioning of the endocrine system and cannot be easily decomposed and recycled. Herein, degradable and sustainable bio-based epoxy thermosets with crosslinked network structures are prepared by the epoxidation of isosorbide with epichlorohydrin and the curing of the produced isosorbide diglycidyl ether (ISDGE) with cyclic lactones through a cationic ring-opening reaction. The ISDGE thermosets fully decompose into soluble and recyclable products under mildly basic conditions within three days, which is ascribed to the presence of ester moieties within the polymer network structure. Compared to a representative BPA-based epoxy, ISDGE-based thermosets exhibit lower dielectric constants and are more flexible. Moreover, the glass fibers in ISDGE-based prepregs can be fully recovered after on-demand degradation. Furthermore, our work provides promising eco-friendly alternatives to conventional epoxy thermosets and paves the way for the reduction of plastic waste generation and the development of recyclable green electronics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optical constants of magnetron sputtered aluminum in the range 17–1300 eV with improved accuracy and ultrahigh resolution in the L absorption edge region

This work determines a new set of EUV/x-ray optical constants for aluminum (Al), one of the most important materials in science and technology. Absolute photoabsorption (transmittance) measurements in the 17–1300 eV spectral range were performed on freestanding Al films protected by carbon (C) layers, to prevent oxidation. The dispersive portion of the refractive index was obtained via the Kramers–Kronig transformation. Our data provide significant improvements in accuracy compared to previously tabulated values and reveal fine structure in the Al L 1 and L 2,3 regions, with photon energy step sizes as small as 0.02 eV. The implications of this work in the successful realization of EUV/x-ray instruments and in the validation of atomic and molecular physics models are also discussed.

74 ATOMIC AND MOLECULAR PHYSICS↗

Stability Considerations for Virtual Capacitor Control in Constant Power DC Loads

In a DC grid, constant power loads (CPLs) necessitate a large bus capacitor to prevent negative impedance instability. Some of the capacitance can be realized virtually through CPL control to reduce the bus capacitor size. Here, this paper analytically studies system stability with virtual capacitor control. We demonstrate that the effectiveness of virtual capacitor control is highly sensitive to the implementation of the derivative action required to emulate the capacitor. For the first time, we theoretically demonstrate that a virtual capacitor can stabilize the system without any physical bus capacitor, provided that a set of analytically derived conditions are met. However, this stabilization is not achievable in practice due to the influence of non-idealities. In an example system requiring a $14$ mF capacitor to stably support the CPL, we show that stability can be achieved through virtual capacitor control, using only a 2 mF physical capacitor to account for the switching ripple non-idealities. Hardware-in-the-loop tests verify the analysis.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Improved Calculation of the Young’s Modulus of Rectangular Prisms from Their Resonant Frequency Overtones by Identifying Appropriate Shear Constants

Young’s modulus is an important parameter for characterizing the strength of, and wave propagation through, a given material. This study improves the estimation of Young’s modulus using the impulse excitation technique based on an experimental analysis of 19 borosilicate glass bars. Analysis of the frequency equations relating Young’s modulus to the out-of-plane and in-plane flexural resonant frequencies of rectangular prisms has been conducted for both the fundamental frequency and its overtones at higher orders of vibration. Furthermore, the Young’s moduli of three novaculite rocks with various porosities were then measured up to the seventh order of vibration to validate the optimum shear constant equation for estimating Young’s modulus. Young’s modulus was found to be nearly frequency independent for these rock samples.

Impulse excitation↗

Measurements of Radical Reactivity with an Imine, (CF 3 ) 2 CNH: Rate Constants for Chlorine Atoms and Hydroxyl Radicals and the Global Warming Potential

The rate constant kOH for the reaction of 1,1,1,3,3,3-hexafluoroprop-2-imine with OH radicals was measured relative to two reference compounds, CH 3 F and CH 3 CHF 2 , to be k OH = (4.2 ± 1.1) × 10 −14 cm 3 molecule −1 s −1 at 295 K. This implies an atmospheric lifetime with respect to consumption by OH of 0.75 years. Reaction with Cl atoms yielded k Cl = (7.9 ± 1.7) × 10 −16 cm 3 molecule −1 s −1 at 295 K, and reaction with O 3 has an upper limit of k O3 < 4 × 10 −23 cm 3 molecule −1 s −1 , so that the atmospheric consumption by Cl and O 3 is negligibly slow. Absolute infrared cross sections of the imine yield a radiative efficiency of 0.34 W m −2 ppb −1 , which is corrected to 0.23 W m −2 ppb −1 for the effects of atmospheric lifetime. The imine’s corresponding 100-year global warming potential is 64 ± 19. This value is an upper limit, given that heterogenous atmospheric removal paths, such as hydrolysis in water droplets, are not included.

climate metric↗