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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Thermoeconomic Evaluation and Optimization of Using Different Environmentally Friendly Refrigerant Pairs for a Dual-Evaporator Cascade Refrigeration System

Applications of dual-evaporator refrigeration systems have recently gained much attention both in academia and industry due to their multiple benefits. In this study, a comprehensive thermodynamic and economic analysis is conducted to evaluate the potential of using several environmentally friendly refrigerant couples and identifies the most suitable one yielding the best economic results. To achieve this goal, a detailed parametric study is conducted, and an optimization process is performed using a particle swarm optimization (PSO) approach to minimize the unit production cost of cooling (UPCC) of the cascade refrigeration system. The results showed that among all selected 18 refrigerant pairs and for all ranges of examined operating parameters, the R170-R161 pair and R1150-R1234yf pair are identified as the best and worst pairs, respectively, from both thermodynamic and economic viewpoints. The results also confirm that R170-R161 pair has an improvement over R717-R744, used as a typical refrigerant pair of cascade refrigeration cycles. For a base case analysis, the COP of R170-R161 and R1150-R1234yf pairs is determined as 1.727 and 1.552, respectively, while their UPCC is found to be $0.395/ton-hr and $0.419/ton-hr, respectively, showing the influence of proper selection of refrigerant pairs on the cascade cycle’s performance. Overall, this study offers a useful thermodynamic and economic insight regarding the selection of proper refrigerant pairs for a dual-evaporator cascade vapor compression refrigeration system.

42 ENGINEERING↗

Near-infrared spectroscopy as a green analytical tool for sustainable biomass characterization for biofuels and bioproducts: An overview

Biomass, a widely used renewable energy source, requires characterization to optimize biofuel and bioproduct processes, customize feedstocks, and ensure economic and environmental sustainability. Conventional wet-chemistry methods for biomass analysis are slow, expensive, and require significant reagents and skilled personnel. In contrast, near-infrared (NIR) spectroscopy, a faster, cost-effective, and reagent-free green technology, enables non-destructive biomass analysis with minimal sample preparation. This study provides an overview of the fundamentals of NIR spectroscopy and explores its recent applications for analyzing various biomass properties important to the biofuel and bioproduct industry. The study also critically evaluates the challenges and opportunities of using NIR spectroscopy for biomass analysis. This review aims to guide future research for rapid and high throughput characterization of biomass in the biomass industry, supporting the United Nations’ sustainable development goal (SDG) 7: producing affordable and sustainable energy.

Biofuels↗

Hydrogen-rich syngas production from the steam co-gasification of low-density polyethylene and coal refuse

Gasification provides a promising pathway for transforming waste materials into valuable products, such as fuels and chemicals. Here, this study investigates the steam co-gasification of low-density polyethylene (LDPE) and compressed thickener underflow, representative of coal refuse (CR), in a drop tube reactor. The effects of feed blend ratio (0–100 wt% LDPE) and temperature (800–1000 °C) on syngas composition, tar formation, and process efficiency are examined. The high volatility of LDPE makes it more reactive than CR but also promotes the formation of 2–7 ring aromatic tars. Increasing temperature improves carbon conversion efficiency (CCE), cold gas efficiency (CGE), and syngas yield, although the lower heating value (LHV) of syngas decreases. Hydrogen is the dominant gas product, reaching 59 vol% with the H 2 /CO molar ratio ranging from 2.27 to 4.74. Synergistic effects from alkali and alkali earth metals (AAEMs), particularly K and Ca, in CR ash enhance syngas yield by catalyzing char gasification and tar cracking. Hematite (Fe 2 O 3 ) and ash from sub-bituminous/bituminous coals are explored as tar reforming catalysts. Fe 2 O 3 achieves 100 % tar reforming efficiency, while coal ash, with a lower Fe 2 O 3 content (15 wt%), is less effective at cracking polycyclic aromatic hydrocarbons, particularly naphthalene. These findings demonstrate the flexibility of co-gasification, allowing precise tuning of syngas characteristics for specific downstream applications. Further optimization of waste-derived catalysts could enhance the economic viability of gasification in waste-to-energy processes.

01 COAL, LIGNITE, AND PEAT↗

Probing elemental speciation in hydrochar produced from hydrothermal liquefaction of anaerobic digestates using quantitative X-ray diffraction

Valorization of hydrochar, a solid byproduct from hydrothermal liquefaction (HTL) of anaerobically-digested agriculture wastes (digestates), requires fundamental knowledge of elemental speciation. This study investigated the effects of reaction temperatures (320–360 °C), digestate pH (3.5–8), and digestate cellulose-to-lignin ratios (0.2–1.8) on the speciation (chemical form) and composition of organics and inorganics in hydrochars produced during hydrothermal treatment. Quantitative X-ray diffraction (XRD) method was the primary technique used to characterize hydrochars. The comprehensive XRD pattern processing including the Rietveld refinement protocols demonstrated that the organic phase was comprised of mostly crystalline monocyclic, heterocyclic, and polycyclic aromatics with diverse aliphatic and aromatic substituents, while the inorganic mineral phase consisted of calcium-phosphates, magnesium-phosphates, calcium-carbonates, and magnesium-carbonates. Further, XRD results were validated by the elemental yields of products and the distribution of chemical functionalities measured using solid-state nuclear magnetic resonance (NMR) spectroscopy. The characterization data were used to evaluate proposed mechanistic pathways using compositional analysis of biocrude and aqueous-phase coproducts. Mechanistic pathways developed in the study suggested that benzoic acids, phenols, benzaldehydes, phenolic aldehydes, α-dicarbonyls, and α-hydroxycarbonyls were responsible for the precipitation of organics through various reactions depending on operating conditions. Meanwhile, the formation of inorganic compounds appeared to be consistently represented by reactions including dehydration, hydrolysis, endergonic reduction, and structure rearrangement of native minerals in the digestates. This study provides basic knowledge needed to create and assess potential elemental speciation pathways. In addition, the results of the study facilitate the specification of process conditions to optimize targeted utilization routes of hydrochar for more economically-feasible and sustainable HTL processing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Multi-objective Microgrid Assessment and Sizing Framework for Economic and Resilience Benefits

This paper presents an innovative multi-objective assessment and sizing framework for battery energy storage system paired with photovoltaics for a cost-effective and resilient microgrid. In the proposed framework, we simultaneously consider i) economic benefits from bundling grid services in grid-connected mode and ii) enhanced resilience by operating the microgrid in island mode upon outages of the main grid. Instead of simply treating resilience as another monetary value stream, this paper models resilience and economic benefits as two separate objectives. Multi-objective optimization is developed to explore different sizing and dispatch options and generate the Pareto front to assist decision-making in system design. Case studies on a real-world microgrid project in Puget Sound Energy system are presented to illustrate the proposed modeling and sizing methods.

Battery energy storage, Microgrid, Optimal Sizingp↗

BLING

The Bounded Linearized Iteration for Natural Gas (BLING) algorithm solves an optimization problem for gas pipeline flow scheduling that maximizes economic surplus and minimizes the energy used for gas compression subject to pressure, flow, and engineering constraints.

Zlotnik, Anatoly↗

Magnetic Field Vector Measurements Using Doppler-Free Saturation Spectroscopy

Experimentally measuring the magnetic-field vector topology in low-cost fusion-concept devices will provide critical information required to optimize and accelerate the development of those concepts for economical fusion energy. The magnetic-field measurement techniques most commonly used in modern tokamaks, i.e., beam-emission spectroscopy and optical emission spectroscopy, are not suitable below 5000 Gauss due to a lack of sensitivity. To diagnose magnetic field relevant to some of the ARPA-E-supported fusion concepts (50 to 1000 Gauss), a novel approach is required. Doppler-free saturation spectroscopy (DFSS) is a pump/probe laser-based technique and has been successfully demonstrated in the laboratory to provide a magnetic-field measurement accuracy of <10 Gauss. DFSS is implemented to obtain ultra-high-resolution spectra at a localized point in space. The spectral data is then fit to the Schrödinger equation for determination of the magnetic-field vector. To obtain the magnetic-field topology, the measurement spatial location is scanned over the desired region of space by steering the DFSS pump laser beam. The goal of this project is to assemble and commission a portable DFSS diagnostic capable of 2-D magnetic-field vector measurements utilizing the Hα spectral line profile.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Role of On-Site Generation in Carbon Emissions and Utility Bill Savings under Different Electric Grid Scenarios

Energy-efficient and sustainable technologies are necessary to lower energy and carbon footprints. Many technologies are being pursued to meet the increasing energy demand in buildings. An attractive option is efficient utilization of available energy resources, including renewables, to support current and future building energy needs while targeting grid resiliency, energy, and environmental security at an affordable cost via on-site cogeneration-based approaches. This must include energy-efficient technologies with lower greenhouse gas emissions and optimized cost, performance, and reliability. This paper presents the economic and environmental benefits associated with power technologies such as thermionics and solid oxide fuel cells. Hybrid configurations consisting of heat pumps, power systems, and renewable photovoltaics in cogeneration and trigeneration modes of operation are presented. The role of such technologies in lowering CO2 emissions while improving energy resiliency and serving the needs of underprivileged communities is discussed. The key barriers of affordability and potential solutions for large-scale implementation of these promising technologies are reviewed. Case studies demonstrating the influence of power rating, electrical efficiency, design configuration, carbon dioxide intensity of the grid, and fuel on annual greenhouse gas emissions are presented for residential and commercial buildings.

24 POWER TRANSMISSION AND DISTRIBUTION↗

REopt: Energy Decision Analysis

The REopt techno-economic decision support platform is used by researchers to optimize energy systems for buildings, campuses, communities, microgrids, and more. REopt recommends the optimal mix of renewable energy, conventional generation, and energy storage technologies to meet cost savings, resilience, emissions reductions, and energy performance goals.

battery↗

Development of Supervisory Control System for Thermal Energy Distribution System

The integrated energy system (IES) refers to the combination of nuclear energy generation with other energy sources to enable the efficiency and reliability of power generations. To create technologically viable and economically competitive systems, supervisory control strategies are critical for optimizing performance and ensuring stability across different energy generation, transportation, and utilization. This work focuses on the control strategies for the thermal energy distribution system (TEDS), which is a cornerstone of the Dynamic Energy Transport and Integration Laboratory at Idaho National Laboratory. TEDS currently relies on operators to coordinate across different components to manage energy storage and ensure efficiency. This work demonstrates the use of model predictive control (MPC) with surrogate models in determining optimal setpoints for major TEDS components. The capability of MPC-based supervisory control system is evaluated by autonomously matching the power outputs from a Dymola-based TEDS with target heat demands.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Charting the Path to Electrification: Analyzing the Economic and Technological Potential of Advanced Vehicle Powertrains

The U.S. Department of Energy’s Vehicle Technologies Office (DOE-VTO) is driving advancements in highway transportation by targeting energy efficiency, environmental sustainability, and cost reductions. This study investigates the fuel economy potential and cost implications of advanced powertrain technologies using comprehensive system simulations. Leveraging tools such as Autonomie and TechScape, developed by Argonne National Laboratory, this study evaluates multiple timeframes (2023–2050) and powertrain types, including conventional internal combustion engines, hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and battery electric vehicles (BEVs). Simulations conducted across standard regulatory driving cycles provide detailed insights into fuel economy improvements, cost trajectories, and total cost of ownership. The findings highlight key innovations in battery energy density, lightweighting, and powertrain optimization, demonstrating the growing viability of BEVs and their projected economic competitiveness with conventional vehicles by 2050. This work delivers actionable insights for policymakers and industry stakeholders, underscoring the transformative potential of vehicle electrification in achieving sustainable transportation goals.

Islam, Ehsan Sabri (ORCID:0000000200220180)↗

DigiFloat (Final Scientific/Technical Report)

This purpose of this report is to document the development of a floating offshore wind platform Digital Twin for the ARPA-E-funded DigiFloat project led by Principle Power, Inc. In Offshore Wind, Digital Twins are aimed at reducing farm-wide OPEX expenditures through reduced-basis inspection, assessing life extension methods, and obtaining better knowledge of the deployed assets for future product optimization. There is a high level of technical effectiveness and economic feasibility for the technology investigated, as it uses commercial off-the-shelf sensors, and a commercial software package. A substantial portion of the project goals are improvement of existing technology for use with floating wind turbines, and new application of an existing technology to a rapidly-growing sector. A few sensors applied to a small number of units bring benefit to the entire fleet of floating wind turbines in a given farm, and in other future wind farms. The benefits to the public of this project are further optimization and maturation of floating wind technology, to bring it to the U.S. market faster and cheaper.

17 WIND ENERGY↗

Accelerating manufacturing for biomass conversion via integrated process and bench digitalization: a perspective

We present a perspective for accelerating biomass manufacturing via digitalization. We summarize the challenges for manufacturing and identify areas where digitalization can help. A profound potential in using lignocellulosic biomass and renewable feedstocks, in general, is to produce new molecules and products with unmatched properties that have no analog in traditional refineries. Discovering such performance-advantaged molecules and the paths and processes to make them rapidly and systematically can transform manufacturing practices. Furthermore, we discuss retrosynthetic approaches, text mining, natural language processing, and modern machine learning methods to enable digitalization. Laboratory and multiscale computation automation via active learning are crucial to complement existing literature and expedite discovery and valuable data collection without a human in the loop. Such data can help process simulation and optimization select the most promising processes and molecules according to economic, environmental, and societal metrics. We propose the close integration between bench and process scale models and data to exploit the low dimensionality of the data and transform the manufacturing for renewable feedstocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Economic Comparison Between Battery and Supercapacitor for Hourly Dispatching Wave Energy Converter Power

This paper demonstrates a dispatching scheme of slider-crank wave energy converter (WEC) power generation using two different kinds of energy storage components, namely, Lithium-ion (Li-ion) battery and Supercapacitors (SC). The performance of the two energy storage components has been compared in order to develop the most economical energy storage system for WEC hourly dispatching scheme. The cost optimization of the energy storage system considering both cycling and calendar aging expenses is made based on its usage of depth of discharge. In this study, extensive simulation is conducted in MATLAB/Simulink platform, and it is found that SC is a better solution than Li-ion battery in terms of economic assessment for hourly dispatching WEC power.

50 EE - Wind and Water Power Program - Water (EE-4↗

Utility-Scale Shared Energy Storage Deployment: Challenges, Research Gaps, and Opportunities

Although community energy storage (CES) and behind-the-meter (BTM) energy storage systems have been widely used to offer homeowners and communities a variety of localized benefits, their scalability and grid support functionalities are limited. On the other hand, utility-scale shared energy storage (USES) systems may offer a number of benefits for grid integration, scalability, and economic viability. When compared to BTM and CES alternatives, these large-scale systems provide more storage capacity, more efficient operations, and more economically viable options. The deployment of USES presents opportunities for optimizing grid performance, integrating renewable energy resources, and improving energy security at the community level. However, significant research gaps exist in optimizing the integration and operation of these systems, especially to allocate energy for consumer use, grid services, and enhancing energy resilience. This paper reviews the literature in this regard, focusing on the opportunities, research gaps, and challenges associated with USES deployment. Firstly, the paper provides an overview of USES systems and emphasizes their benefits. Secondly, the key challenges are identified, and research gaps associated with the operation and integration of these systems are highlighted. Lastly, some potential solutions and opportunities that can be adopted to facilitate the rapid deployment and management of USES are presented. Technological, economic, regulatory, and environmental aspects are also discussed in this paper, providing an overview of the current state and future prospects of this technology.

Gautam, Mukesh [BATTELLE (PACIFIC NW LAB)] (ORCID:↗

Co-synthesis of Hydrogen and High-Value Carbon Products from Methane Pyrolysis

The ARPA-E Methane Pyrolysis Project successfully developed a scalable technology for hydrogen production with low-CO x emission through methane pyrolysis, co-producing high-value carbon nanotubes (CNTs). The project focused on optimizing reactor design, enhancing catalyst performance, and assessing techno-economic feasibility to create a commercially viable and environmentally sustainable process. The fluidized bed reactor achieved over 90% methane (CH 4 ) conversion by using a 5% CO 2 co-feed, which stabilizes carbon yields and minimizes catalyst deactivation. This setup allowed for continuous operation across ten cycles, each consisting of a 14-minute pyrolysis phase followed by a 10-minute dislodging phase to remove a fraction of the accumulated carbon, resulting in stable performance and high-quality CNT production. In parallel, monolith reactors coated with Fe demonstrated a sustained methane conversion of 73% while producing CNTs with high crystallinity. Although promising for continuous operation, monolith reactors face challenges in coating durability and scalability, highlighting areas for further optimization in commercial applications. Catalyst formulation played a key role in enhancing process efficiency. The core catalyst used was 5%Fe/Al 2 O 3 (wt%), optimized through wet impregnation, which improved CNT morphology, yielding longer and more uniform CNTs. The catalyst's performance was further enhanced by adding promoters: 2.5 wt% Ni increased methane conversion close to the thermodynamic limit, while 2.5 wt% Mn improved CNT alignment and crystallinity, and 1.5 wt% NaCl boosted CNT morphology but slightly lowered methane conversion. These adjustments allowed the reactor to maintain high methane conversion while producing high-quality CNTs, enabling stable performance over multiple cycles. To address carbon buildup and ensure uninterrupted operation, a pneumatic conveying tube was implemented for effective carbon dislodging in the fluidized bed configuration. CO 2 and H 2 O co-feeds were also introduced to enhance carbon removal, with CO 2 boosting CNT yield by approximately 15%. This setup enabled stable reactor operation across multiple cycles, preventing clogging and minimizing catalyst wear, making the process suitable for industrial scaling. Techno-economic analysis (TEA) projected hydrogen production costs between $\$$1.00 and $\$$1.64 per kilogram, with CNT values assumed at $\$$375/ton and $\$$100/ton. The life cycle assessment showed that CO 2 emissions could be as low as 0.64 kg CO 2 e/kg H 2 at 95% methane conversion assuming an electricity input of 50 kg CO 2 e/MWh. Even at 50% methane conversion, emissions remained below 1 kg CO 2 e/kg H 2 , demonstrating the process's low-emission potential and making it a viable alternative to traditional steam methane reforming. Overall, the results from this project demonstrate the feasibility of a pyrolysis process where carbon is continuously removed from the catalyst surface and hydrogen is continuously produced until a catalyst regeneration step is required to fully clean the catalyst surface and renew catalyst performance. Major open challenges are related to avoiding the loss of catalyst material in the dislodged carbon during fluidized bed conditions, since our best result demonstrated a carbon purity of ~70 wt. % (rest being iron and alumina). A monolith reactor was used to favor dislodgement of carbon compared to fluidized bed conditions but our results do not demonstrate an advantage of the monolith configuration. Catalyst performance was similar to fluidized bed conditions with slower deactivation rates overall, but we could not observe carbon dislodging in any of the tens of experiments that were run at Stanford. Our results show that the most relevant areas of improvement are related to the fundamental understanding of the iron-carbon interface for dislodging, and the development of catalyst that can produce CNTs via a base-growth mechanism such that catalyst is not lost in the dislodgement steps. The final report documents all findings and methodologies in detail, providing a valuable resource for the scientific community. By building on these results, researchers can further advance methane pyrolysis technology, moving toward a more sustainable, scalable pathway for hydrogen production. This work lays the foundation for future research and commercial efforts to reduce emissions in hydrogen production while generating valuable carbon products.

08 HYDROGEN↗

Economic Comparison Between a Battery and Supercapacitor for Hourly Dispatching Wave Energy Converter Power: Preprint

This paper demonstrates a successful dispatching scheme of slider-crank wave energy converter (WEC) production using two different kinds of energy storage systems, namely, (i) Li-ion battery and (ii) Supercapacitors (SC). The performance of two energy storage systems has been compared in order to develop the most economical energy storage system for WEC hourly dispatching scheme. The cost optimization of the energy storage system considering both cycling and calendar aging expenses is made based on its usage of depth of discharge (DOD). In this study, the extensive simulation is conducted in MATLAB/Simulink platform, and it is found that SC is a better candidate than Li-ion battery in terms of economic assessment for hourly dispatching WEC power.

50 EE - Wind and Water Power Program - Water (EE-4↗

STOCHASTIC OPTIMAL POWER FLOW FOR REAL-TIME MANAGEMENT OF DISTRIBUTED RENEWABLE GENERATION AND DEMAND RESPONSE (Final Report)

To meet the grand challenge of a sustainable energy future, there has been a surge of interest in renewable energy. Today, the uncertainty associated with renewable resources is handled by using operating reserves. The high penetration of renewable resources, however, introduces difficult-to-control dynamics and challenges for power system operation. Decision support tools are necessary at the bulk system operational level to recognize and efficiently utilize renewable resources and distributed demand response products in concert with traditional grid resources. It is envisaged that responsive load can potentially have very significant cost advantages over either spinning or non-spinning ramping reserve. Critical decisions are made during hour(s)-ahead and real-time power system operation regarding the commitment and dispatch of generators to ensure power delivery is both reliable and economic. These decisions are typically made by a security constrained optimal flow, which determines future generator commitments, dispatches, and ensures adequate reserves are available in the event of a contingency (unexpected outage) or if future system conditions deviate from forecasts. However, security has been always based on a pre-specified subset of contingency constraints whose enforcement does not guarantee security under all possible future possibilities while also giving little or no weight to the likelihood of each contingent event or the severity of its consequences. Existing tools, which are based exclusively on deterministic optimization models, do not yield optimal operational decisions to address these new challenges, in terms of both reliability and cost-effectiveness. This project has focused on developing a stochastic optimal power flow (SOPF) framework, which integrates renewable resource uncertainty, load uncertainty, distributed storage (DS), demand response (DR) products, in a holistic manner to address the uncertainty associated with ever-increasing renewable resources, along with the inclusion of distributed demand response products in future power systems. A proof-of-concept problem was created using the Pennsylvania-Jersey-Maryland (PJM) power system network. Synthetic wind generation was added to the system to simulate 50% wind penetration. A 1-hour test of SOPF operation indicated more than 6% operational cost savings. The project continued by adding the Midwestern Independent System Operator (MISO) as a partner, with focus shifting from SOPF to Stochastic Look-Ahead Unit Commitment (SLAC). Unlike PJM, MISO is faced with significant renewable energy resources within its footprint and is challenged with substantial uncertainty in its operations. The SLAC distinguishes itself from existing tools that operators use. At best, today’s tools solve two to three cases independently, where one or two system parameters, such as forecasted load level (e.g., a low, base, and high forecast), are varied and the resulting scenarios are analyzed independently. The stochastic-based optimization of SLAC leverages statistical information from an ensemble of potential operational scenarios and their respective likelihood. The SLAC output can be translated into valuable information to the operator such as suggested commitments, optimal scheduling and dispatch of resources, reserve requirements at both locational and zonal resolutions, ramping availability and requirements, availability of demand response including operational guidance concerning the near-term and real-time coordination between distributed energy resources, and utilization of distributed storage resources. The developed SOPF/SLAC tool, a stand-alone tool compatible with existing EMSs, will provide system operators with unprecedented visibility, flexibility and predictability to these resources and operational guidance concerning the real-time coordination between DERs and DR/DS products. The game changing and practical impact of this disruptive technology will be dramatic and will usher in a new era in the electric power industry, wherein green energy concepts are fully embraced, and electric power costs are lowered throughout the nation.

42 ENGINEERING↗