Economic assessment of clean hydrogen production from fossil fuels in the intermountain-west region, USA
Not Available
Chen, Fangxuan↗
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Synchrotron Micro Computed Tomography for Non-destructive 3D Studies of Fossil Fish
Abstract not provided
Van Loon, Lisa↗
3D Non-Destructive Identification of Fossil Fish from the Late Cretaceous of Alberta, Canada using S
Explore the source record for details and available documents.
Brinkman, Don↗
Polymer-Cement Composites with Self-Healing Ability for Geothermal and Fossil Energy Applications
Sealing of wellbores in geothermal and tight oil/gas reservoirs by filling the annulus with cement is a well-established practice. Failure of the cement as a result of physical and/or chemical stress is a common problem with serious environmental and financial consequences. Numerous alternative cement blends have been proposed for the oil and gas industry. Most of these possess poor mechanical properties, or are not designed to work in high temperature environments. This work reports on a novel polymer-cement composite with remarkable self-healing ability that maintains the required properties of typical wellbore cements and may be stable at most geothermal temperatures. We combine for the first time experimental analysis of physical and chemical properties with density functional theory simulations to evaluate cement performance. The thermal stability and mechanical strength are attributed to the formation of a number of chemical interactions between the polymer and cement matrix including covalent bonds, hydrogen bonding, and van der Waals interactions. Self-healing was demonstrated by sealing fractures with 0.3–0.5 mm apertures, 2 orders of magnitude larger than typical wellbore fractures. This polymer-cement composite represents a major advance in wellbore cementing that could improve the environmental safety and economics of enhanced geothermal energy and tight oil/gas production.
36 MATERIALS SCIENCE↗
Life Cycle Greenhouse Gas Emissions and Water and Fossil-Fuel Consumptions for Polyethylene Furanoate and Its Coproducts from Wheat Straw
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Solid-State NMR Studies of Fossil Fuels using One- and Two-Dimensional Methods at High Magnetic Field
We examine the opportunities offered by advancements in solid-state NMR (SSNMR) methods, which increasingly rely on the use of high magnetic fields and fast magic angle spinning (MAS), in the studies of coals and other carbonaceous materials. The sensitivity of one- and two-dimensional experiments tested on several Argonne Premium coal samples is only slightly lower than that of traditional experiments performed at low magnetic fields in large MAS rotors, since higher receptivity per spin and the use of 1H detection of low-gamma nuclei can make up for most of the signal loss due to the small rotor size. The advantages of modern SSNMR methodology in these studies include improved resolution, simplicity of pulse sequences, and the possibility of using J-coupling during mixing.
36 MATERIALS SCIENCE↗
Synthetic fossilization of soft biological tissues and their shape-preserving transformation into silica or electron-conductive replicas
Structural preservation of complex biological systems from the subcellular to whole organism level in robust forms, enabling dissection and imaging while preserving 3D context, represents an enduring grand challenge in biology. Here we report a simple immersion method for structurally preserving intact organisms via conformal stabilization within silica. This self-limiting process, which we refer to as silica bioreplication, occurs by condensation of water-soluble silicic acid proximally to biomolecular interfaces throughout the organism. Conformal nanoscopic silicification of all biomolecular features imparts structural rigidity enabling the preservation of shape and nano-to-macroscale dimensional features upon drying to form a biocomposite and further high temperature oxidative calcination to form silica replicas or reductive pyrolysis to form electrically conductive carbon replicas of complete organisms. Ultimately, the simplicity and generalizability of this approach should facilitate efforts in biological preservation and analysis and could enable the development of new classes of biomimetic composite materials.
59 BASIC BIOLOGICAL SCIENCES↗
Modeling suggests fossil fuel emissions have been driving increased land carbon uptake since the turn of the 20th Century
Terrestrial vegetation removes CO 2 from the atmosphere; an important climate regulation service that slows global warming. This 119 Pg C per annum transfer of CO 2 into plants—gross primary productivity (GPP)—is the largest land carbon flux globally. While understanding past and anticipated future GPP changes is necessary to support carbon management, the factors driving long-term changes in GPP are largely unknown. In this study, we show that 1901 to 2010 changes in GPP have been dominated by anthropogenic activity. Our dual constraint attribution approach provides three insights into the spatiotemporal patterns of GPP change. First, anthropogenic controls on GPP change have increased from 57% (1901 decade) to 94% (2001 decade) of the vegetated land surface. Second, CO 2 fertilization and nitrogen deposition are the most important drivers of change, 19.8 and 11.1 Pg C per annum (2001 decade) respectively, especially in the tropics and industrialized areas since the 1970’s. Third, changes in climate have functioned as fertilization to enhance GPP (1.4 Pg C per annum in the 2001 decade). These findings suggest that, from a land carbon balance perspective, the Anthropocene began over 100 years ago and that global change drivers have allowed GPP uptake to keep pace with anthropogenic emissions.
54 ENVIRONMENTAL SCIENCES↗
Atmospheric benzenoid emissions from plants rival those from fossil fuels
Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y -1 ), pointing to the importance of these natural emissions in atmospheric physics and chemistry.
54 ENVIRONMENTAL SCIENCES↗
Stimuli-Responsive/Rheoreversible Hydraulic Fracturing Fluids as a Greener Alternative to Support Geothermal and Fossil Energy Production
Cost-effective yet safe creation of high-permeability reservoirs within deep bedrock is the primary challenge for the viability of enhanced geothermal systems (EGS) and unconventional oil/gas recovery. Although fracturing fluids are commonly used for oil/gas, standard fracturing methods are not developed or proven for EGS temperatures and pressures. Furthermore, the environmental impacts of currently used fracturing methods are only recently being determined. Widespread concerns about the environmental contamination have resulted in a number of regulations for fracturing fluids advocating for greener fracturing processes. To enable EGS feasibility and lessen environmental impact of reservoir stimulation, an environmentally benign, CO2-activated, rheoreversible fracturing fluid that enhances permeability through fracturing (at significantly lower effective stress than standard fracturing fluids) due to in situ volume expansion and gel formation is investigated herein. The chemical mechanism, stability, phase-change behavior, and rheology for a novel polyallylamine (PAA)-CO2 fracturing fluid was characterized at EGS temperatures and pressures. Hydrogel is formed upon reaction with CO2 and this process is reversible (via CO2 depressurization or solubilizing with a mild acid) allowing removal from the formation and recycling, decreasing environmental impact. Rock obtained from the Coso geothermal field was fractured in laboratory experiments under various EGS temperatures and pressures with comparison to standard fracturing fluids, and the fractures were characterized with imaging, permeability measurement, and flow modeling. This novel fracturing fluid and process may vastly reduce water usage and the environmental impact of fracturing practices and effectively make EGS production and unconventional oil/gas exploitation cost-effective and cleaner.
Environmental Molecular Sciences Laboratory↗
Carbon capture from corn stover ethanol production via mature consolidated bioprocessing enables large negative biorefinery GHG emissions and fossil fuel-competitive economics
Potential to capture 70% of feedstock carbon while >50% of feedstock lower heating value is converted to biofuel and coproducts.
Kubis, Matthew R.↗
Galactic ArchaeoLogIcaL ExcavatiOns (GALILEO) II. t-SNE portrait of local fossil relics and structures
Based on high-quality Apache Point Observatory Galactic Evolution Experiment (APOGEE) DR17 and Gaia DR3 data for 1742 red giants stars within 5 kpc of the Sun and not rotating with the Galactic disk (V φ < 100 km s -1 ), we used the nonlinear technique of unsupervised analysis t-Distributed Stochastic Neighbor Embedding (t-SNE) to detect coherent structures in the space of ten chemical-abundance ratios: [Fe/H], [O/Fe], [Mg/Fe], [Si/Fe], [Ca/Fe], [C/Fe], [N/Fe], [Al/Fe], [Mn/Fe], and [Ni/Fe]. Additionally, we obtained orbital parameters for each star using the nonaxisymmetric gravitational potential GravPot16. Seven structures are detected, including Splash, Gaia-Sausage-Enceladus (GSE), the high-α heated-disk population, N-C-O peculiar stars, and inner disk-like stars, plus two other groups that did not match anything previously reported in the literature, here named Galileo 5 and Galileo 6 (G5 and G6). These two groups overlap with Splash in [Fe/H], with G5 having a lower metallicity than G6, and they are both between GSE and Splash in the [Mg/Mn] versus [Al/Fe] plane, with G5 being in the α-rich in situ locus and G6 on the border of the α-poor in situ one. Nonetheless, their low [Ni/Fe] hints at a possible ex situ origin. Their orbital energy distributions are between Splash and GSE, with G5 being slightly more energetic than G6. We verified the robustness of all the obtained groups by exploring a large range of t-SNE parameters, applying it to various subsets of data, and also measuring the effect of abundance errors through Monte Carlo tests.
79 ASTRONOMY AND ASTROPHYSICS↗
Microbially induced precipitation of silica by anaerobic methane-oxidizing consortia and implications for microbial fossil preservation
Authigenic carbonate minerals can preserve biosignatures of microbial anaerobic oxidation of methane (AOM) in the rock record. It is not currently known whether the microorganisms that mediate sulfate-coupled AOM—often occurring as multicelled consortia of anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB)—are preserved as microfossils. Electron microscopy of ANME-SRB consortia in methane seep sediments has shown that these microorganisms can be associated with silicate minerals such as clays [Chen et al., Sci. Rep. 4, 1–9 (2014)], but the biogenicity of these phases, their geochemical composition, and their potential preservation in the rock record is poorly constrained. Long-term laboratory AOM enrichment cultures in sediment-free artificial seawater [Yu et al., Appl. Environ. Microbiol. 88, e02109-21 (2022)] resulted in precipitation of amorphous silicate particles (~200 nm) within clusters of exopolymer-rich AOM consortia from media undersaturated with respect to silica, suggestive of a microbially mediated process. The use of techniques like correlative fluorescence in situ hybridization (FISH), scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS), and nanoscale secondary ion mass spectrometry (nanoSIMS) on AOM consortia from methane seep authigenic carbonates and sediments further revealed that they are enveloped in a silica-rich phase similar to the mineral phase on ANME-SRB consortia in enrichment cultures. Like in cyanobacteria [Moore et al., Geology 48, 862–866 (2020)], the Si-rich phases on ANME-SRB consortia identified here may enhance their preservation as microfossils. Finally, the morphology of these silica-rich precipitates, consistent with amorphous-type clay-like spheroids formed within organic assemblages, provides an additional mineralogical signature that may assist in the search for structural remnants of microbial consortia in rocks which formed in methane-rich environments from Earth and other planetary bodies.
54 ENVIRONMENTAL SCIENCES↗
Plant, insect, and fungi fossils under the center of Greenland’s ice sheet are evidence of ice-free times
The persistence and size of the Greenland Ice Sheet (GrIS) through the Pleistocene is uncertain. This is important because reconstructing changes in the GrIS determines its contribution to sea level rise during prior warm climate periods and informs future projections. To understand better the history of Greenland’s ice, we analyzed glacial till collected in 1993 from below 3 km of ice at Summit, Greenland. The till contains plant fragments, wood, insect parts, fungi, and cosmogenic nuclides showing that the bed of the GrIS at Summit is a long-lived, stable land surface preserving a record of deposition, exposure, and interglacial ecosystems. Knowing that central Greenland was tundra-covered during the Pleistocene informs the understanding of Arctic biosphere response to deglaciation.
58 GEOSCIENCES↗
THE ACS LCID PROJECT. III. THE STAR FORMATION HISTORY OF THE CETUS dSph GALAXY: A POST-REIONIZATION FOSSIL
We use deep HST/ACS observations to calculate the star formation history (SFH) of the Cetus dwarf spheroidal (dSph) galaxy. Our photometry reaches below the oldest main-sequence turnoffs, which allows us to estimate the age and duration of the main episode of star formation in Cetus. This is well approximated by a single episode that peaked roughly 12 {+-} 0.5 Gyr ago and lasted no longer than about 1.9 {+-} 0.5 Gyr (FWHM). Our solution also suggests that essentially no stars formed in Cetus during the past 8 Gyr. This makes Cetus' SFH comparable to that of the oldest Milky Way dSphs. Given the current isolation of Cetus in the outer fringes of the Local Group, the dominant old population implies that Cetus is a clear outlier in the morphology-Galactocentric distance relation that holds for the majority of the Milky Way dwarf satellites. Our results also show that Cetus continued forming stars until z{approx_equal} 1, long after the universe was reionized, and that there is no clear signature of the epoch of reionization in Cetus' SFH. We briefly discuss the implications of these results for dwarf galaxy evolution models. Finally, we present a comprehensive account of the data reduction and analysis strategy adopted for all galaxies targeted by the LCID (Local Cosmology from Isolated Dwarfs) project. We employ two different photometry codes (DAOPHOT/ALLFRAME and DOLPHOT), three different SFH reconstruction codes (IAC-pop/MinnIAC, MATCH, and COLE), and two stellar evolution libraries (BaSTI and Padova/Girardi), allowing for a detailed assessment of the modeling and observational uncertainties.
79 ASTRONOMY AND ASTROPHYSICS↗
A FOSSIL BULGE GLOBULAR CLUSTER REVEALED BY VERY LARGE TELESCOPE MULTI-CONJUGATE ADAPTIVE OPTICS
The globular cluster HP 1 is projected on the bulge, very close to the Galactic center. The Multi-Conjugate Adaptive Optics Demonstrator on the Very Large Telescope allowed us to acquire high-resolution deep images that, combined with first epoch New Technology Telescope data, enabled us to derive accurate proper motions. The cluster and bulge fields' stellar contents were disentangled through this process and produced an unprecedented definition in color-magnitude diagrams of this cluster. The metallicity of [Fe/H] {approx} -1.0 from previous spectroscopic analysis is confirmed, which together with an extended blue horizontal branch imply an age older than the halo average. Orbit reconstruction results suggest that HP 1 is spatially confined within the bulge.
79 ASTRONOMY AND ASTROPHYSICS↗
STELLAR MASS-GAP AS A PROBE OF HALO ASSEMBLY HISTORY AND CONCENTRATION: YOUTH HIDDEN AMONG OLD FOSSILS
We investigate the use of the halo mass-gap statistic—defined as the logarithmic difference in mass between the host halo and its most massive satellite subhalo—as a probe of halo age and concentration. A cosmological N-body simulation is used to study N ∼ 25, 000 group/cluster-sized halos in the mass range 10{sup 12.5} < M{sub halo}/M{sub ☉} < 10{sup 14.5}. In agreement with previous work, we find that halo mass-gap is related to halo formation time and concentration. On average, older and more highly concentrated halos have larger halo mass-gaps, and this trend is stronger than the mass-concentration relation over a similar dynamic range. However, there is a large amount of scatter owing to the transitory nature of the satellite subhalo population, which limits the use of the halo mass-gap statistic on an object-by-object basis. For example, we find that 20% of very large halo mass-gap systems (akin to {sup f}ossil groups{sup )} are young and have likely experienced a recent merger between a massive satellite subhalo and the central subhalo. We relate halo mass-gap to the observable stellar mass-gap via abundance matching. Using a galaxy group catalog constructed from the Sloan Digital Sky Survey Data Release 7, we find that the star formation and structural properties of galaxies at fixed mass show no trend with stellar mass-gap. This is despite a variation in halo age of ≈2.5 Gyr over ≈1.2 dex in stellar mass-gap. Thus, we find no evidence to suggest that the halo formation history significantly affects galaxy properties.
79 ASTRONOMY AND ASTROPHYSICS↗
Fossil imprint of a powerful flare at the galactic center along the Magellanic stream
The Fermi satellite discovery of the gamma-ray emitting bubbles extending 50° (10 kpc) from the Galactic center has revitalized earlier claims that our Galaxy has undergone an explosive episode in the recent past. We now explore a new constraint on such activity. The Magellanic Stream is a clumpy gaseous structure free of stars trailing behind the Magellanic Clouds, passing over the south Galactic pole (SGP) at a distance of at least 50-100 kpc from the Galactic center. Several groups have detected faint Hα emission along the Magellanic Stream (1.1 ± 0.3 × 10{sup –18} erg cm{sup –2} s{sup –1} arcsec{sup –2}) which is a factor of five too bright to have been produced by the Galactic stellar population. The brightest emission is confined to a cone with half angle θ{sub 1/2} ≈ 25° roughly centered on the SGP. Time-dependent models of Stream clouds exposed to a flare in ionizing photon flux show that the ionized gas must recombine and cool for a time interval T{sub o} = 0.6 – 2.9 Myr for the emitted Hα surface brightness to drop to the observed level. A nuclear starburst is ruled out by the low star formation rates across the inner Galaxy, and the non-existence of starburst ionization cones in external galaxies extending more than a few kiloparsecs. Sgr A{sup *} is a more likely candidate because it is two orders of magnitude more efficient at converting gas to UV radiation. The central black hole (M {sub •} ≈ 4 × 10{sup 6} M {sub ☉}) can supply the required ionizing luminosity with a fraction of the Eddington accretion rate (f{sub E} ∼ 0.03-0.3, depending on uncertain factors, e.g., Stream distance) typical of Seyfert galaxies. In support of nuclear activity, the Hα emission along the Stream has a polar angle dependence peaking close to the SGP. Moreover, it is now generally accepted that the Stream over the SGP must be farther than the Magellanic Clouds. At the lower halo gas densities, shocks become too ineffective and are unlikely to give rise to a polar angle dependence in the Hα emission. Thus it is plausible that the Stream Hα emission arose from a 'Seyfert flare' that was active 1-3 Myr ago, consistent with the cosmic ray lifetime in the Fermi bubbles. Sgr A{sup *} activity today is greatly suppressed (70-80 dB) relative to the Seyfert outburst. The rapid change over a huge dynamic range in ionizing luminosity argues for a compact UV source with an extremely efficient (presumably magneto-hydrodynamic) 'drip line' onto the accretion disk.
79 ASTRONOMY AND ASTROPHYSICS↗